BS EN 896-2012 Chemicals used for treatment of water intended for human consumption Sodium hydroxide《人类用水处理用化学试剂 氢氧化钠》.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationChemicals used for treatment of water intended for human consumption Sodium hydroxideBS EN 896:2012Copyright European Committee for Standardization Provided by IHS under license

2、with CENNot for Resale-,-,-National forewordThis British Standard is the UK implementation of EN 896:2012. It supersedesBS EN 896:2005 which is withdrawn.The UK participation in its preparation was entrusted to Technical CommitteeCII/59, Chemicals for drinking water treatment.A list of organizations

3、 represented on this committee can be obtained onrequest to its secretary.This publication does not purport to include all the necessary provisions of acontract. Users are responsible for its correct application. The British Standards Institution 2013Published by BSI Standards Limited 2013ISBN 978 0

4、 580 77697 7ICS 13.060.20; 71.100.80Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of the StandardsPolicy and Strategy Committee on 28 February 2013.Amendments issued since publicationAmd. No. Date Text affected

5、BRITISH STANDARDBS EN 896:2012Copyright European Committee for Standardization Provided by IHS under license with CENNot for Resale-,-,-EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 896 November 2012 ICS 71.100.80 Supersedes EN 896:2005English Version Chemicals used for treatment of water int

6、ended for human consumption - Sodium hydroxide Produits chimiques utiliss pour le traitement de leau destine la consommation humaine - Hydroxyde de sodium Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch - Natriumhydroxid This European Standard was approved by CEN on 16 September 20

7、12. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained

8、on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CEN

9、ELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Ita

10、ly, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 1

11、7, B-1000 Brussels 2012 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 896:2012: EBS EN 896:2012Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking per

12、mitted without license from IHSEN 896:2012 (E) 2 Contents Page Foreword 3Introduction .41 Scope 52 Normative references 53 Description .54 Purity criteria 85 Test methods . 106 Labelling Transportation Storage . 12Annex A (informative) General information on sodium hydroxide . 15Annex B (normative)

13、Analytical methods 16Annex C (normative) General rules relating to safety . 26Bibliography . 27BS EN 896:2012Copyright European Committee for Standardization Provided by IHS under license with CENNot for Resale-,-,-EN 896:2012 (E) 3 Foreword This document (EN 896:2012) has been prepared by Technical

14、 Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2013, and conflicting national standards shall be withdrawn at

15、the latest by May 2013. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 896:2005. Significant technical di

16、fferences between this edition and EN 896:2005 are as follows: a) Modification of 6.2 on labelling, deletion of the reference to EU Directive 80/778/EEC of 15 July 1980 in order to take account of the latest Directive in force. According to the CEN/CENELEC Internal Regulations, the national standard

17、s organisations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxem

18、bourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 896:2012Copyright European Committee for Standardization Provided by IHS under license with CENNot for Resale-,-,-EN 896:2012 (E) 4 Introduction In respe

19、ct of potential adverse effects on the quality of water intended for human consumption, caused by the product covered by this European Standard: a) this European Standard provides no information as to whether the product may be used without restriction in any of the Member States of the EU or EFTA;

20、b) it should be noted that, while awaiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the characteristics of this product remain in force. NOTE Conformity with this European Standard does not confer or imply acceptance or approval of the pro

21、duct in any of the Member States of the EU or EFTA. The use of the product covered by this European Standard is subject to regulation or control by National Authorities. BS EN 896:2012Copyright European Committee for Standardization Provided by IHS under license with CENNot for Resale-,-,-EN 896:201

22、2 (E) 5 1 Scope This European Standard is applicable to sodium hydroxide used for treatment of water intended for human consumption. It describes the characteristics and specifies the requirements and the corresponding test methods for sodium hydroxide. It gives information on its use in water treat

23、ment. It also determines the rules relating to safe handling and use (see Annex C). 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For un

24、dated references, the latest edition of the referenced document (including any amendments) applies. EN ISO 3696, Water for analytical laboratory use Specification and test methods (ISO 3696) EN ISO 12846:2012, Water quality Determination of mercury Method using atomic absorption spectrometry (AAS) w

25、ith and without enrichment (ISO 12846:2012) ISO 979, Sodium hydroxide for industrial use Method of assay ISO 3165, Sampling of chemical products for industrial use Safety in sampling ISO 3196; Sodium hydroxide for industrial use Determination of carbonates content Titrimetric method ISO 6206, Chemic

26、al products for industrial use Sampling Vocabulary ISO 8213, Chemical products for industrial use Sampling techniques Solid chemical products in the form of particles varying from powders to coarse lumps 3 Description 3.1 Identification 3.1.1 Chemical name Sodium hydroxide. 3.1.2 Synonym or common n

27、ame Caustic soda. 3.1.3 Relative molecular mass 40,0. 3.1.4 Empirical formula NaOH. 3.1.5 Chemical formula NaOH. BS EN 896:2012Copyright European Committee for Standardization Provided by IHS under license with CENNot for Resale-,-,-EN 896:2012 (E) 6 3.1.6 CAS Registry Number1)1310-73-2. 3.1.7 EINEC

28、S reference2)215-185-5. 3.2 Commercial forms The product is available as flakes, pearls, solid, or as an aqueous solution of different concentrations. 3.3 Physical properties 3.3.1 Appearance Solid: the product is white, deliquescent. Liquid: the product is a clear solution, slightly turbid colourle

29、ss solution, slightly viscous. 3.3.2 Density Solid : the density of this product is 2,1 g/cm3. The bulk density of pearls is 1,2 kg/dm3.Liquid : the density of solution is 1,52 g/ml for a product concentration of mass fraction of 50 % at 20 C. 3.3.3 Solubility in water The product is highly soluble

30、at all temperatures above 20 C (partial crystallization occurs above concentration of mass fraction of 55 %, (see Figure 1). 1) Chemical Abstracts Service Registry Number. 2) European Inventory of Existing Commercial Chemical Substances. BS EN 896:2012Copyright European Committee for Standardization

31、 Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHSEN 896:2012 (E) 7 Key 1 temperature in C. 2 NaOH concentration in mass fraction in % Figure 1 Solubility of sodium hydroxide 3.3.4 Vapour pressure Solution of concentration of mass fr

32、action of 50 % - 120 Pa at 20 C; - 450 Pa at 40 C; - 5 000 Pa at 80 C. BS EN 896:2012Copyright European Committee for Standardization Provided by IHS under license with CENNot for Resale-,-,-EN 896:2012 (E) 8 3.3.5 Boiling point at 100 kPa3)145 C for a solution of concentration of mass fraction of 5

33、0 %. 3.3.6 Crystallization point + 12 C for a solution of concentration of mass fraction of 50 % (see Figure 1). 3.3.7 Specific heat 3 220 J/(kg K) at 20 C for a solution of concentration of mass fraction of 50 %. 3.3.8 Viscosity (dynamic) For a solution of concentration of mass fraction of 50 %: -

34、100 Pa.s at 20 C; - 25 Pa.s at 40 C; - 5 Pa.s at 80 C. 3.3.9 Critical temperature Not applicable. 3.3.10 Critical pressure Not applicable. 3.3.11 Physical hardness Not applicable. 3.4 Chemical properties The solutions of sodium hydroxide are strongly alkaline. Dilution of sodium hydroxide is very ex

35、othermic. 4 Purity criteria 4.1 General This European Standard specifies the minimum purity requirements for sodium hydroxide used for the treatment of water intended for human consumption. Limits are given for impurities commonly present in the product. Depending on the raw material and the manufac

36、turing process other impurities may be present and, if so, this shall be notified to the user and when necessary to relevant authorities. 3) 100 kPa = 1 bar. BS EN 896:2012Copyright European Committee for Standardization Provided by IHS under license with CENNot for Resale-,-,-EN 896:2012 (E) 9 User

37、s of this product should check the national regulations in order to clarify whether it is of appropriate purity for treatment of water intended for human consumption, taking into account raw water quality, required dosage, contents of other impurities and additives used in the products not stated in

38、 this product standard. Limits have been given for impurities and chemical parameters where these are likely to be present in significant quantities from the current production process and raw materials. If the production process or raw materials leads to significant quantities of impurities, by-pro

39、ducts or additives being present, this shall be notified to the user. 4.2 Composition of commercial product The product shall contain not less than a mass fraction of 96 % of NaOHfor the solid form. Typical concentration for solutions of sodium hydroxide is either a mass fraction of 50 % or 30 % , a

40、nd shall be in any case within the manufacturers stated tolerance. 4.3 Impurities and main by-products The product shall conform to the requirements specified in Table 1. The concentration limits refer to pure NaOH mass fraction of 100 %. Table 1 Impurities Impurity Limit in mass fraction in % of Na

41、OH Sodium chloride (NaCl)a)max. 2,4Sodium carbonate (Na2CO3)b)max. 0,4 Sodium chlorate (NaClO3)c)max. 0,7a) Too high concentrations can cause problems with some ion exchange resins. b) Sodium carbonate is formed in contact with atmospheric carbon dioxide. c) The presence of any oxidizing agent in so

42、dium hydroxide is to be avoided. 4.4 Chemical parameters The product shall conform to the requirements specified in Table 2. BS EN 896:2012Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from

43、 IHSEN 896:2012 (E) 10 Table 2 Chemical parameters Parameter Limit in mg/kg of NaOH Type 1 Type 2 Arsenic (As) max. 2 10 Cadmium (Cd) max. 1 5 Chromium (Cr) max. 1 10 Mercury (Hg) max. 0,1 1 Nickel (Ni) max. 2 10 Lead (Pb) max. 5 20 Antimony (Sb) max. 5 5 Selenium (Se) max. 5 5 NOTE Cyanides, pestic

44、ides and polycyclic aromatic hydrocarbons are not relevant in sodium hydroxide. For parametric values of sodium hydroxide on trace metal content in drinking water, see 1. 5 Test methods 5.1 Sampling Prepare the laboratory sample(s) required by the relevant procedure described in ISO 8213, observe th

45、e recommendations of ISO 3165 and also take into account ISO 6206. The nature of caustic alkalis requires special care at all points of sampling and preparation for analysis. Sampling techniques shall be such as to limit or prevent atmospheric exposure since sodium hydroxides, either as aqueous solu

46、tions or as anhydrous products, rapidly absorb moisture and carbon dioxide (and other acid gases) from the atmosphere. Additional precautions are necessary if trace constituents are to be determined. NOTE For sampling liquids see 2. BS EN 896:2012Copyright European Committee for Standardization Prov

47、ided by IHS under license with CENNot for Resale-,-,-EN 896:2012 (E) 11 5.2 Analyses 5.2.1 Main product 5.2.1.1 Total alkalinity The total alkalinity shall be determined by titration with an acid standard volumetric solution in accordance with ISO 979. 5.2.1.2 Caustic alkalinity The caustic alkalini

48、ty equals the total alkalinity as NaOH (see 5.2.1.1) minus the alkalinity as Na2CO3multiplied by 0,755 determined in accordance with ISO 3196. 5.2.2 Impurities 5.2.2.1 Sodium chloride The sodium chloride content shall be determined by potentiometric titration with silver nitrate solution (see B.1). 5.2.2.2 Sodium carbonate The sodium carbonate content shall be determined by the titrimetric method, in accordance with ISO 3196. 5.2.2.3 Sodium chlorate The sodium chlorate content shall be determined by ionic chrom