BS EN 10245-3-2011 Steel wire and wire products Organic coatings on steel wire PE coated wire《钢丝及其制品 钢丝上的有机涂层 PE涂层线》.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN 10245-3:2011Steel wire and wire products Organic coatings on steel wirePart 3: PE coated wireBS EN 10245-3:2011 BRITISH STANDARDNational forewordThis British Standard is th

2、e UK implementation of EN 10245-3:2011.It supersedes BS EN 10245-3:2001 which is withdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee ISE/106, Wire Rod and Wire.A list of organizations represented on this committee can beobtained on request to its secretary.This publ

3、ication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. BSI 2011ISBN 978 0 580 62753 8ICS 25.220.60; 77.140.65Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published u

4、nder the authority of theStandards Policy and Strategy Committee on 30 November 2011.Amendments issued since publicationDate Text affectedBS EN 10245-3:2011EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 10245-3 October 2011 ICS 25.220.60; 77.140.65 Supersedes EN 10245-3:2001English Version Ste

5、el wire and wire products - Organic coatings on steel wire - Part 3: PE coated wire Fils et produits trfils en acier - Revtements organiques sur fils dacier - Partie 3: Fils revtement de PE Stahldraht und Drahterzeugnisse - Organische Beschichtungen auf Stahldraht - Teil 3: PE-beschichteter Draht Th

6、is European Standard was approved by CEN on 17 September 2011. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical ref

7、erences concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a C

8、EN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, I

9、celand, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Ave

10、nue Marnix 17, B-1000 Brussels 2011 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 10245-3:2011: EBS EN 10245-3:2011EN 10245-3:2011 (E) 2 Contents Page Foreword 3Introduction .41 Scope 42 Normative references 53 Terms and definiti

11、ons .54 Types of PE coating materials 55 Requirements and test methods for PE coating material .65.1 Requirements .65.1.1 The composition and method of application 65.1.2 PE organic coating material consistency .65.1.3 Density 65.1.4 Melt flow index .65.1.5 Tensile strength .65.1.6 Elongation 75.2 T

12、est methods 75.2.1 General 75.2.2 Melt flow index .76 Requirements and test methods for PE coating on wire .76.1 Requirements .76.1.1 General 76.1.2 Appearance 76.1.3 Colour-gloss and thickness 76.1.4 Elongation 76.1.5 Concentricity 86.1.6 Adherence 86.2 Test method 86.2.1 Appearance 86.2.2 Colour .

13、86.2.3 Gloss .86.2.4 Thickness .86.2.5 Concentricity 86.2.6 Tensile strength and elongation 86.2.7 Adherence (where required) .86.2.8 Resistance to artificial light exposure .87 Performance of PE coating materials as the coating on wire .87.1 Requirement for colour stability (accelerated weathering)

14、 .87.2 Test method for colour stability .98 Retests 99 Inspection and quality assurance 9Bibliography . 10BS EN 10245-3:2011EN 10245-3:2011 (E) 3 Foreword This document (EN 10245-3:2011) has been prepared by Technical Committee ECISS/TC 106 “Wire rod and wires”, the secretariat of which is held by A

15、FNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by April 2012, and conflicting national standards shall be withdrawn at the latest by April 2012. Attention is drawn to the possibility that some

16、 of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 10245-3:2001. This standard is made up of the following parts: Part 1: General Rules; Part 2: PVC finishe

17、d wire; Part 3: PE coated wire; Part 4: Polyester coated wire; Part 5: Polyamide coated wire. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus,

18、 Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. BS EN 10245-3:2011EN 10245-3:2011 (E) 4

19、Introduction This European Standard for organic coatings for steel wire covers the requirements of a general nature and applies also to coatings for which no specific requirements have been established in the subsequent parts of this standard. The subsequent parts of this standard deal more specific

20、ally with clearly defined coatings or groups of coatings. These coatings may have their own particular methods of application and their individual requirements which are specified in these parts of this standard, in other standards or in manufacturers data sheets. Because the standard specifies requ

21、irements and tests not only for the coating but also for the coating material, it has proved not practical to put all the requirements in one clause and all the tests in another one. Following structure has been chosen in order to limit complexity and to facilitate the use. In writing this series of

22、 standards consideration has been given to the nomenclature and transformation of organic coating materials as applied to steel wire products. These organic coating materials may, on application to wire and by their integration into the finished wire product, change their characteristics and propert

23、ies. This standard specifies characteristics and tests not only for the organic coating but also for the coating materials both before and after their application to steel wire and wire products. In addition it specifies the requirements for performance levels and testing methods on organic coating

24、material which have become an integral and permanent part of the finished wire product. Therefore it has proven not to be practical to put all requirements in one clause and all the tests in another one. To aid continuity and in order to limit complexity, the following structure has been chosen for

25、this standard: Clause 4 deals with the characteristics and testing methods of organic coating material as supplied by the manufacturer for the purposes of its application to the wire product. Tests described in this section are intended to be carried out by the organic coating material manufacturer

26、or the applicator before the coating operation. Clause 5 relates to the characteristics and testing methods for the “organic coating“ when the organic coating material has been applied to and has become an integral part of the finished wire. Consequently tests are intended to be in the main carried

27、out by the coating “applicators“. Clause 6 defines the performance requirements and testing methods on the “organic coating“ of the finished wire product, and where this is not possible, tests will be carried out on “coated“ panels. 1 Scope Complementary to EN 10245-1, this European Standard specifi

28、es the characteristics and requirements for steel wire and wire products coated with polyethylene (PE). BS EN 10245-3:2011EN 10245-3:2011 (E) 5 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cit

29、ed applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 10021, General technical delivery conditions for steel products EN 10204, Metallic products Types of inspection documents EN 10245-1:2008, Steel wire and wire products Organic coa

30、tings on steel wire Part 1: General rules EN ISO 1133:2005, Plastics Determination of the melt mass-flow rate (MFR) and the melt volume-flow rate (MVR) of thermoplastics (ISO 1133:2005) EN ISO 3668, Paints and varnishes Visual comparison of the colour of paints (ISO 3668:1998) EN ISO 4892-1, Plastic

31、s Methods of exposure to laboratory light sources Part 1: General guidance (ISO 4892-1:1999) EN ISO 4892-2, Plastics Methods of exposure to laboratory light sources Part 2: Xenon-arc lamps (ISO 4892-2:2006) EN ISO 4892-3, Plastics Methods of exposure to laboratory light sources Part 3: Fluorescent U

32、V lamps (ISO 4892-3:2006) ISO 813, Rubber, vulcanized or thermoplastic Determination of adhesion to a rigid substrate 90 degree peel method ISO 4582, Plastics Determination of changes in colour and variations in properties after exposure to daylight under glass, natural weathering or laboratory ligh

33、t sources 3 Terms and definitions For the purposes of this document, the terms and definitions given in EN 10245-1:2008 and the following apply. 3.1 PE coating coating on steel wire or wire products made from organic coating material comprising a polymer base compound made up of at least 85 % ethyle

34、ne (Ethene) which constitutes essentially the only monomer 4 Types of PE coating materials Polyethylene coatings are classified into three types according to their density. Type 1 : low density (0,910 g/cm3to 0,925 g/cm3) Type 2 : medium density (0,926 g/cm3to 0,940 g/cm3) Type 3 : high density (0,9

35、41 g/cm3to 0,965 g/cm3) BS EN 10245-3:2011EN 10245-3:2011 (E) 6 5 Requirements and test methods for PE coating material 5.1 Requirements 5.1.1 The composition and method of application The composition shall be agreed between manufacturer and the applicator and shall take account of the latters metho

36、d of application. However the PE coating material shall fulfil the requirements of this standard. The processing of the PE coating material shall be at the manufacturers discretion. 5.1.2 PE organic coating material consistency The manufacturer shall ensure that the organic coating material composit

37、ion and its characteristics remain constant from batch to batch and unchanged from that as agreed at the time of enquiry and order. The manufacturer shall immediately notify the applicator of any subsequent change in the type and quantity of the constituent parts of the composition once this has bee

38、n agreed between the two parties. At the request of the specifier/purchaser the presence of certain elements may be limited. In any case, the compound composition shall be cadmium free. 5.1.3 Density The density at a temperature of 20 C shall satisfy the values specified in Clause 4 of this standard

39、. 5.1.4 Melt flow index Polyethylene is classified in one of the following categories defined in Table 1 on the basis of the determined melt flow index: The melt flow index of the base material shall be 0,3 0,1 g/10 min. According to Table 1, the material is category 5, unless otherwise specified at

40、 the time of enquiry and order. Table 1 Classification according to the melt flow index Category Nominal melt flow index of the base material g/10 min (at 190C and 21,2 N load) 1 25 2 10 - 25 3 1,0 - 10 4 0,4 - 1,0 5 max 0,4 5.1.5 Tensile strength Depending on the type of coating specified the minim

41、um tensile strength shall satisfy the requirements of Table 2. BS EN 10245-3:2011EN 10245-3:2011 (E) 7 Table 2 Tensile strength Type of coating Minimum tensile strength (MPa) Type 1 8,5 Type 2 11,0 Type 3 17,0 5.1.6 Elongation The minimum elongation of the coating material shall be 800 %. However, f

42、or modified PE (cross linked), agreement should be taken at the time of order on elongation value, since no relevant official standard can be referred to. 5.2 Test methods 5.2.1 General Unless otherwise specified the test methods shall be in accordance with EN 10245-1. 5.2.2 Melt flow index The melt

43、 flow index shall be determined in accordance with EN ISO 1133:2005 condition E at 190 C under a load of 21,2 N. 6 Requirements and test methods for PE coating on wire 6.1 Requirements 6.1.1 General In addition to the general requirements of EN 10245-1, PE coatings shall satisfy following requiremen

44、ts. 6.1.2 Appearance When examined by visual inspection, the surface of the PE coating shall be smooth, shiny, free from irregularities and uniform in colour. Small dents, not affecting subsequent use and resulting from contact with adjacent turns shall not constitute a cause for rejection. 6.1.3 Co

45、lour-gloss and thickness In the absence of a product specification, these requirements shall be agreed at the time of enquiry and order. 6.1.4 Elongation The elongation of coating film on the wire product shall be not less than 300 %. BS EN 10245-3:2011EN 10245-3:2011 (E) 8 6.1.5 Concentricity This

46、shall be at least 60 %. 6.1.6 Adherence This requirement is optional, and shall be agreed at the time of order, if required. 6.2 Test method 6.2.1 Appearance Examination is visual with the naked eye. 6.2.2 Colour The test method to be used is EN ISO 3668. 6.2.3 Gloss The method to be used is ISO 813

47、. 6.2.4 Thickness Tests shall be performed in accordance with EN 10245-1. 6.2.5 Concentricity Tests shall be performed in accordance with EN 10245-1. 6.2.6 Tensile strength and elongation The tensile test shall be performed in accordance with EN 10245-1 on the plastic sheet carefully removed from th

48、e wire. 6.2.7 Adherence (where required) The tests shall be performed in accordance with EN 10245-1. 6.2.8 Resistance to artificial light exposure The tests shall be performed according to EN ISO 4892-1, with agreement at the time of order on the test conditions. If Xenon light is to be used, refere

49、nce to EN ISO 4892-2 will be done. If QUV (A) or QUV (B) light is to be used, reference will be EN ISO 4892-3. 7 Performance of PE coating materials as the coating on wire 7.1 Requirement for colour stability (accelerated weathering) After exposure to artificial Xenon arc source for a period of 2 500 hours, the colour difference and degradation shall be E 5. BS EN 10245-3:2011EN 10245-3:2011 (E) 9 7.2 Test method for colour stabilit