BS EN 10245-4-2011 Steel wire and wire products Organic coatings on steel wire Polyester coated wire《钢丝和钢丝产品 钢丝上的有机涂层 聚酯涂覆钢丝》.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN 10245-4:2011Steel wire and wire products Organic coatings on steel wirePart 4: Polyester coated wireIncorporating corrigendum November 2011BS EN 10245-4:2011 BRITISH STANDA

2、RDNational forewordThis British Standard is the UK implementation of EN 10245-4:2011.It supersedes BS EN 10245-4:2003 which is withdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee ISE/106, Wire Rod and Wire.A list of organizations represented on this committee can be

3、obtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication.ISBN 978 0 580 77243 6ICS 25.220.60; 77.140.65Compliance with a British Standard cannot confer immunity fromlegal obligations.

4、This British Standard was published under the authority of theStandards Policy and Strategy Committee on 30 November 2011.Amendments/corrigenda issued since publicationDate Text affectedImplementation of CEN correction notice:reference year 2001 from EN 10245-4:2001deleted throughout The British Sta

5、ndards Institution 201231 January 2012EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 10245-4 October 2011 ICS 25.220.60; 77.140.65 Supersedes EN 10245-4:2003English Version Steel wire and wire products - Organic coatings on steel wire - Part 4: Polyester coated wire Fils et produits trfils en

6、acier - Revtements organiques sur fils dacier - Partie 4: Fils revtement de polyester Stahldraht und Drahterzeugnisse - Organische Beschichtungen auf Stahldraht - Teil 4: Polyester beschichteter Draht This European Standard was approved by CEN on 17 September 2011. CEN members are bound to comply wi

7、th the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Mana

8、gement Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same st

9、atus as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portug

10、al, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2011 CEN All rights of exploitation in any form and by any means r

11、eserved worldwide for CEN national Members. Ref. No. EN 10245-4:2011: EEN 10245-4:2011 (E) 2 Contents Foreword 3Introduction .41 Scope 42 Normative references 53 Terms and definitions .64 Methods of application of polyester coatings 65 Requirements and testing methods for polyester coating material

12、.65.1 General 65.2 Composition and method of application .65.3 Consistency 65.4 Density 75.5 Hardness .75.6 Tensile strength .75.7 Elongation 76 Requirements and test methods for polyester coating on wire and wire products .76.1 General 76.2 Appearance 76.3 Colour .86.4 Gloss .86.5 Thickness .86.6 E

13、longation 86.7 Concentricity 86.8 Adherence 87 Performance requirements and tests for the polyester coating on the finished wire and wire products .97.1 General 97.2 Colour stability (accelerated weathering) .97.3 Kesternich test .97.4 Boiling water test 108 Retests . 109 Inspection and quality assu

14、rance . 10Bibliography . 11BS EN 10245-4:2011EN 10245-4:2011 (E) 3 Foreword This document (EN 10245-4:2011) has been prepared by Technical Committee ECISS/TC 106 “Wire rod and wires”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard,

15、either by publication of an identical text or by endorsement, at the latest by April 2012, and conflicting national standards shall be withdrawn at the latest by April 2012. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/

16、or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 10245-4:2003. This standard is made up of the following parts: Part 1: General Rules; Part 2: PVC finished wire; Part 3: PE coated wire; Part 4: Polyester coated wire; Part 5: Polyamid

17、e coated wire. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, I

18、celand, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. BS EN 10245-4:2011EN 10245-4:2011 (E) 4 Introduction This European Standard for organic coatings for steel wire covers

19、the requirements of a general nature and applies also to coatings for which no specific requirements have been established in the subsequent parts of this standard. The subsequent parts of this standard deal more specifically with clearly defined coatings or groups of coatings. These coatings may ha

20、ve their own particular methods of application and their individual requirements which are specified in these parts of this standard, in other standards or in manufacturers data sheets. Because the standard specifies requirements and tests not only for the coating but also for the coating material,

21、it has proved not practical to put all the requirements in one clause and all the tests in another one. Following structure has been chosen in order to limit complexity and to facilitate the use. In writing this series of standards consideration has been given to the nomenclature and transformation

22、of organic coating materials as applied to steel wire products. These organic coating materials may, on application to wire and by their integration into the finished wire product, change their characteristics and properties. This standard specifies characteristics and tests not only for the organic

23、 coating but also for the coating materials both before and after their application to steel wire and wire products. In addition it specifies the requirements for performance levels and testing methods on organic coating material which have become an integral and permanent part of the finished wire

24、product. Therefore it has proven not to be practical to put all requirements in one clause and all the tests in another one. To aid continuity and in order to limit complexity, the following structure has been chosen for this standard: Clause 5 deals with the characteristics and testing methods of o

25、rganic coating material as supplied by the manufacturer for the purposes of its application to the wire product. Tests described in this section are intended to be carried out by the organic coating material manufacturer or the applicator before the coating operation. Clause 6 relates to the charact

26、eristics and testing methods for the “organic coating“ when the organic coating material has been applied to and has become an integral part of the finished wire. Consequently tests are intended to be in the main carried out by the coating “applicators“. Clause 7 defines the performance requirements

27、 and testing methods on the “organic coating“ of the finished wire product, and where this is not possible, tests will be carried out on “coated“ panels Scope 1 Scope Complementary to EN 10245-1, this European Standard specifies the characteristics and requirements for steel wire and wire products c

28、oated with polyester. It covers both thermoplastic and thermosetting polyester. BS EN 10245-4:2011EN 10245-4:2011 (E) 5 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated

29、references, the latest edition of the referenced document (including any amendments) applies. EN 10021, General technical delivery conditions for steel products EN 10245-1, Steel wire and wire products Organic coatings on steel wire Part 1: General rules EN ISO 527-3, Plastics Determination of tensi

30、le properties Part 3: Test conditions for films and sheets (ISO 527-3:1995) EN ISO 868, Plastics and ebonite Determination of indentation hardness by means of a durometer (Shore hardness) (ISO 868:2003) EN ISO 1183-1, Plastics Methods for determining the density of non-cellular plastics Part 1: Imme

31、rsion method, liquid pyknometer method and titration method (ISO 1183-1:2004) EN ISO 1183-2, Plastics Methods for determining the density of non-cellular plastics Part 2: Density gradient column method (ISO 1183-2:2004) EN ISO 1183-3, Plastics Methods for determining the density of non-cellular plas

32、tics Part 3: Gas pyknometer method (ISO 1183-3:1999) EN ISO 2813, Paints and varnishes Determination of specular gloss of non-metallic paint films at 20, 60 and 85 (ISO 2813:1994, including Technical Corrigendum 1:1997) EN ISO 2815, Paints and varnishes Buchholz indentation test (ISO 2815:2003) EN I

33、SO 3231, Paints and varnishes Determination of resistance to humid atmospheres containing sulfur dioxide (ISO 3231:1993) EN ISO 3668, Paints and varnishes Visual comparison of the colour of paints (ISO 3668:1998) EN ISO 4892-1, Plastics Methods of exposure to laboratory light sources Part 1: General

34、 guidance (ISO 4892-1:1999) EN ISO 4892-2, Plastics Methods of exposure to laboratory light sources Part 2: Xenon-arc lamps (ISO 4892-2:2006) ISO 4582, Plastics Determination of changes in colour and variations in properties after exposure to daylight under glass, natural weathering or laboratory li

35、ght sources ISO 7724-1, Paints and varnishes Colorimetry Part 1: Principles ISO 7724-2, Paints and varnishes Colorimetry Part 2: Colour measurement ISO 7724-3, Paints and varnishes Colorimetry Part 3: Calculation of colour differences BS EN 10245-4:2011EN 10245-4:2011 (E) 6 3 Terms and definitions F

36、or the purposes of this document, the terms and definitions given in EN 10245-1 and the following apply. 3.1 polyester organic material which is the result of a polycondensation reaction of a polyhydroxy compound with di- or polycarbon acids NOTE There are two main classes of polyester: the linear p

37、olyesters and the crosslinked polyesters. Linear polyesters generally are thermoplastic, whereas crosslinked polyester is thermosetting and is hard. 3.2 polyethyleneglycoltereftalate (PET) one of the most commonly used linear polyesters NOTE PET is only the abbreviation of polyethyleneglycoltereftal

38、ate. The designation of other types of polyester by PET is not correct and is to be avoided. 4 Methods of application of polyester coatings The most commonly used method for polyester coating on wire is by extrusion and for coating of wire products is by powder coating. The coating may be applied di

39、rectly on the surface of the wire or wire product or after applying a primer. Where appropriate other methods may be used. 5 Requirements and testing methods for polyester coating material 5.1 General Unless otherwise specified the test methods for polyester coating material shall be in accordance w

40、ith EN 10245-1. 5.2 Composition and method of application The coating material shall be free of lead (Pb), cadmium (Cd) and benzoin. Other requirements for the composition shall be agreed between manufacturer and applicator and shall take account of this method of application. However, the polyester

41、 coating material shall fulfil the requirements of this standard. The processing of the polyester coating material shall be at the manufacturers discretion. The requirements for the polyester intended for extrusion are those for PET. For other coating material other requirements may be agreed betwee

42、n the parties. 5.3 Consistency The manufacturer shall ensure that the organic coating material composition and its characteristics shall remain constant from batch to batch and unchanged from that as agreed at the time of inquiry and ordering. The manufacturer shall immediately notify the applicator

43、 of any subsequent change in the type and quantity of the constituent parts of the composition once this has been agreed between the two parties. At the request of the supplier or purchaser the presence of certain elements may be limited. In any case, the compound composition shall be cadmium-free.

44、BS EN 10245-4:2011EN 10245-4:2011 (E) 7 5.4 Density Unless otherwise agreed between the applicator and the coating material supplier the density of the coating material, when tested in accordance with EN ISO 1183- 1 to -3, shall be in accordance with Table 1. Where the apparent density of the suppli

45、ed powder is specified, requirements and test methods shall be agreed between the parties. 5.5 Hardness When measured in accordance with EN ISO 868 the Shore hardness D shall be in accordance with Table 1. If so agreed between the parties the Bucholtz hardness, when measured in accordance with EN IS

46、O 2815, shall be in accordance with Table 1. 5.6 Tensile strength When tested in accordance with EN ISO 527-3 the minimum tensile strength shall be in accordance with Table 1. 5.7 Elongation When tested in accordance with EN ISO 527-3 the elongation shall be in accordance with Table 1. Table 1 Requi

47、rements and tests for the coating material Characteristics Requirements for Test method Thermoplastics materials Thermosetting materials Density (kg/dm3) Neutral, uncoloured: 1,30 1,40 aWhite: 1,50 1,70 0,05 aEN ISO 1183-1 to -3 Green: 1,45 1,65 0,05 Shore hardness D Min. 76 not applicable EN ISO 86

48、8 Bucholtz hardness Not applicable Min. 90 EN ISO 2815 Tensile strength MPa Min. 55 not applicable EN ISO 527-3 Elongation % Min. 300 50 EN ISO 527-3 aFor other colours the density shall be by agreement. 6 Requirements and test methods for polyester coating on wire and wire products 6.1 General In a

49、ddition to the general requirements of EN 10245-1, polyester coatings shall satisfy following requirements. The coating requirements are summarized in Table 2. 6.2 Appearance Following examination by visual inspection with the naked eye, the surface of the polyester coating shall be smooth, shiny, free from irregularities and uniform in colour. Small dents, not affecting subsequent use and resulting from contact with adjacent turn