BS EN 14598-3-2005 Reinforced thermosetting moulding compounds - Specification for sheet moulding compound (SMC) and bulk moulding compound (BMC) - Specific requirements《增强热固性模塑化合物.pdf

1、BRITISH STANDARD BS EN 14598-3:2005 Reinforced thermosetting moulding compounds Specification for Sheet Moulding Compound (SMC) and Bulk Moulding Compound (BMC) Part 3: Specific requirements The European Standard EN 14598-3:2005 has the status of a British Standard ICS 83.120 BS EN 14598-3:2005 This

2、 British Standard was published under the authority of the Standards Policy and Strategy Committee on 25 May 2005 BSI 25 May 2005 ISBN 0 580 46020 7 National foreword This British Standard is the official English language version of EN 14598-3:2005. Together with BS EN 14598-1:2005 and BS EN 14598-2

3、:2005, it supersedes BS 5734-1:1990, BS 5734-2:1990, BS 5734-3:1990, and BS 5734-4:1990 which are withdrawn. The UK participation in its preparation was entrusted to Technical Committee PRI/42, Fibre reinforced thermosetting plastics and prepregs, which has the responsibility to: A list of organizat

4、ions represented on this committee can be obtained on request to its secretary. Cross-references The British Standards which implement international or European publications referred to in this document may be found in the BSI Catalogue under the section entitled “International Standards Corresponde

5、nce Index”, or by using the “Search” facility of the BSI Electronic Catalogue or of British Standards Online. This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. Compliance with a British Standard does not of its

6、elf confer immunity from legal obligations. aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and keep the UK interests informed; monitor related international and European developments and

7、promulgate them in the UK. Summary of pages This document comprises a front cover, an inside front cover, the EN title page, pages 2 to 21 and a back cover. The BSI copyright notice displayed in this document indicates when the document was last issued. Amendments issued since publication Amd. No. D

8、ate CommentsEUROPEANSTANDARD NORMEEUROPENNE EUROPISCHENORM EN145983 April2005 ICS83.120 Englishversion ReinforcedthermosettingmouldingcompoundsSpecification forSheetMouldingCompound(SMC)andBulkMoulding Compound(BMC)Part3:Specificrequirements Mlangesmoulerthermodurcissablesrenforcs Spcificationpourma

9、tsprimprgns(SMC)etmlanges moulerenmasse(BMC)Partie3:Exigences spcifiques VerstrktehrtbareFormmassenSpezifikationfr Harzmatten(SMC)undfaserverstrktePressmassen (BMC)Teil3:SpezifischeAnforderungen ThisEuropeanStandardwasapprovedbyCENon21February2005. CENmembersareboundtocomplywiththeCEN/CENELECInterna

10、lRegulationswhichstipulatetheconditionsforgivingthisEurope an Standardthestatusofanationalstandardwithoutanyalteration.Uptodatelistsandbibliographicalreferencesconcernings uchnational standardsmaybeobtainedonapplicationtotheCentralSecretariatortoanyCENmember. ThisEuropeanStandardexistsinthreeofficia

11、lversions(English,French,German).Aversioninanyotherlanguagemadebytra nslation undertheresponsibilityofaCENmemberintoitsownlanguageandnotifiedtotheCentralSecretariathasthesamestatusast heofficial versions. CENmembersarethenationalstandardsbodiesofAustria,Belgium,Cyprus,CzechRepublic,Denmark,Estonia,F

12、inland,France, Germany,Greece,Hungary,Iceland,Ireland,Italy,Latvia,Lithuania,Luxembourg,Malta,Netherlands,Norway,Poland,Portugal, Slovakia, Slovenia,Spain,Sweden,SwitzerlandandUnitedKingdom. EUROPEANCOMMITTEEFORSTANDARDIZATION COMITEUROPENDENORMALISATION EUROPISCHESKOMITEEFRNORMUNG ManagementCentre:

13、ruedeStassart,36B1050Brussels 2005CEN Allrightsofexploitationinanyformandbyanymeansreserved worldwideforCENnationalMembers. Ref.No.EN145983:2005:EEN 14598-3:2005 (E) 2 Contents Page Foreword3 1 Scope 4 2 Normative references 4 3 Terms and definitions .4 4 Requirements.5 4.1 General5 4.2 Type and con

14、tent of filler/reinforcement.5 4.3 Recycling 5 4.4 Property data5 Bibliography 20 EN 14598-3:2005 (E) 3 Foreword This document (EN 14598-3:2005) has been prepared by Technical Committee CEN/TC 249 “Plastics”, the secretariat of which is held by IBN. This European Standard shall be given the status o

15、f a national standard, either by publication of an identical text or by endorsement, at the latest by October 2005, and conflicting national standards shall be withdrawn at the latest by October 2005. EN 14598 consists of the following parts, under the general title Reinforced thermosetting moulding

16、 compounds Specification for Sheet Moulding Compound (SMC) and Bulk Moulding Compound (BMC) Part 1: Designation Part 2: Methods of test and general requirements Part 3: Specific requirements This document includes a Bibliography. According to the CEN/CENELEC Internal Regulations, the national standa

17、rds organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slo

18、vakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EN 14598-3:2005 (E) 4 1 Scope This part of EN 14598 specifies the requirements for physical and chemical properties of Sheet moulding Compounds (SMC) and Bulk Moulding Compound (BMC) and compression or injection moulded specimens. The s

19、election in this part is limited to those materials the composition and properties of which are significantly different. Furthermore the selection is limited to those materials which are of more general technical and/or economical importance. The properties which are used for the characterization of

20、 the moulding compounds, the test methods and the test conditions are based on Part 2 of this document. The list of properties is selected, initially, from those general test methods found in EN ISO 10350-2, Plastics - Acquisition and presentation of comparable single-point data Part 2: Long-fibre-r

21、einforced plastics (ISO 10350-2:2001). The moulding compounds are divided into types corresponding to their composition and properties. The designation of the types of moulding compounds is based on Part 1 - Designation of this document. 2 Normative references The following referenced documents are

22、indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 60695-11-10, Fire hazard testing Part 11-10: Test flames 50 W horizontal and vertical

23、 flame test methods (IEC 60695-11-10:1999) EN 60707, Flammability of solid non-metallic materials when exposed to flame sources List of test methods (IEC 60707:1999) EN ISO 295, Plastics - Compression moulding of test specimens of thermosetting materials. (ISO 295:2004) EN ISO 12114, Fibre-reinforce

24、d plastics - Thermosetting moulding compounds and prepregs - Determination of cure characteristics (ISO 12114:1997) EN ISO 12115, Fibre-reinforced plastics -Thermosetting moulding compounds and prepregs - Determination of flowability, maturation and shelf life (ISO 12115:1997) ISO 3795, Road vehicle

25、s, and tractors and machinery for agriculture and forestry - Determination of burning behaviour of interior materials 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 Sheet Moulding Compound reinforced thermosetting moulding material, flat she

26、ets 3.2 Bulk Moulding Compound - BMC reinforced thermosetting moulding materials, bulk 3.3 thermal flow characterizes the flow behaviour of plastizised thermosetting moulding compounds, e.g. when filling a mould cavity and for which the minimum torque EN 14598-3:2005 (E) 5 4 Requirements 4.1 General

27、 Sheet moulding compounds, bulk moulding compounds and test specimens prepared by compression moulding complying with this document shall meet the appropriate property requirements shown in Table 1 to Table 4. No specific limits are placed on rheological and processing properties. Never the less sui

28、table rheological and processing properties are essential for the satisfactory use of a sheet moulding compound (SMC) and bulk moulding compound (BMC). Appropriate properties shall therefore be specified in any contract. The test method and the test condition shall be as agreed by the interested par

29、ties. In addition, for some applications, it may be desirable for information to be made available on other properties of the moulding compounds, for example: curing time; peak exotherm; flowability. If this is so, these properties and test methods as well as the test conditions to be used shall be

30、agreed by the interested parties. 4.2 Type and content of filler/reinforcement Sheet moulding compounds (SMC), bulk moulding compound (BMC) and test specimens prepared by compression complying with this document shall meet the appropriate nature and form of the filler/reinforcement and its mass cont

31、ent according to its designation (see Part 1, 3.2, of this document). 4.3 Recycling All formulations can contain recycling materials. Some properties may be changing with contents more then 10 %. 4.4 Property data For those moulding compounds complying with this document the mean value for the numbe

32、r of test specimens to be used for each test method shall meet the appropriate requirement listed in Table 1.1 to Table 1.4 for SMC and Table 3.1 to Table 3.4 for BMC of this part. Properties which may be specified are shown in Table 2.1 to Table 2.4 for SMC and Table 4.1 to Table 4.3 for BMC. EN 14

33、598-3:2005 (E) 6 Table 1.1 - SMC-properties which shall be specified 1 2 3 4 Type/Grade SMC EN 14598-3 UP. . . Property Unit Proc a Max. min. GF15 G GF20 G GF25 G GF25 G 1. Mechanical properties 1.1 Tensile modulus E t MPa Q 7000 8000 8500 9000 1.2 Stress at break B MPa Q 40 45 50 55 1.3 Strain at b

34、reak B % Q 1,2 1,5 1,5 1,4 1.4 Flexural modulus E f MPa Q 7000 8500 9000 9500 1.5 Flexural strength f M MPa Q 100 120 145 150 1.6 Charpy Impact strength a c U kJ/m Q 35 40 50 60 2. Thermal properties 2.1 Temperature of deflect. Under load T f 1,8 C Q 180 180 180 190 2.2 Coefficient of linear thermal

35、 expansion 10E -6/K Q 18 18 18 18 3. Electrical properties 3.1 Dissipation factor Tan 100 - Q/M 10 1310 1310 1410 143.3 Surface resistivity e Q/M 10 1210 1210 1210 123.4 Proof tracking index CTI Q/M 600 600 600 600 4. Flammability, Burning behaviour 4.1 EN 60695-11-10 class Q/M HB HB HB V1 4.2 ISO 3

36、795 (3,2 mm) class Q/M NBR NBR NBR NBR 4.3 Glow bar EN 60707 step Q/M BH 2-95 BH 2-95 BH2-95 BH 2-30 5. Chemical and physical properties 5.1 Density g/cm Q/M 1,9 1,85 1,85 1,9 5.2 Moulding shrinkage % Q 0,15 0,15 0,15 0,14 6. Rheological and processing properties 6.1 Glass content % by mass Q/M 15 2

37、0 25 25 7. Remarks 7.1 Characteristic Standard Standard, Standard, E LS,E,FR 7.2 EN ISO 295, EN ISO 12114, EN ISO 12115 830, 830.5 831. 831.5 7.3 Special properties Properties to be specified are those, which should typically appear on a data sheet. A selection of these properties also should be inc

38、luded on the certificate of conformity. aProc.= Processing; Q = Compression moulding; M = Injection moulding, G = General purpose. EN 14598-3:2005 (E) 7 Table 1.2 - SMC-properties which shall be specified 5 6 7 8 9 10 11 Type/Grade SMC EN 14598-3 UP. . . GF30 Q a GF30 Q GF30 Q GF25 Q,M,T GF30 Q,M,T,

39、 GF28 Q GF27 Q 1. Mechanical properties 1.1 10500 10500 10000 10000 11500 7000 8500 1.2 70 70 65 55 80 65 60 1.3 1,4 1,4 1,5 1,4 1,5 1,5 1,3 1.4 10500 10500 9500 9500 10500 7000 7500 1.5 165 165 155 140 180 150 125 1.6 70 70 55 55 90 70 60 2. Thermal properties 2.1 200 200 190 180 200 190 180 2.2 18

40、 16 16 17 10 10 12 3. Electrical properties 3.1 0,01 0,01 0,01 0,01 0,01 0.01 0,01 3.2 10 14 10 1410 1410 1410 1410 1410 14 3.3 10x 12 10 1210 1210 1210 1210 1210x 12 3.4 600 600 600 600 600 600 600 4. Flammability, Burning behaviour 4.1 V 0 V1 V0 V0 HB HB HB 4.2 NBR NBR NBR NBR NBR NBR NBR 4.3 BH 2

41、-10 BH 2-30 BH 2-10 BH 2-10 BH2-95 BH 2-95 BH 2-95 5 Chemical and physical properties 5.1 1,8 1,85 1,85 1,85 1,9 1,8 1,8 5.2 0,12 0,12 0,07 0,07 -0,08 -0,08 -0,06 6. Rheological and processing properties 6.1 32 32 30 25 30 28 27 8. Remarks 7.1 LS,E,FR,M LS,E,FR,M, LS,E, FR, LS,E,FR, LP Class A LP Cl

42、ass A flex LP,Low press. 7.2 832, 832.5 833, 833,5 834, 834.5 7.3 Properties to be specified are those, which should typically appear on a data sheet. A selection of these properties also should be included on the certificate of conformity. aProc.= Processing; Q = Compression moulding; M = Injection

43、 moulding, G = General purpose. EN 14598-3:2005 (E) 8 Table 1.3 - SMC-properties which shall be specified 12 13 14 15 16 17 18 Type/Grade SMC EN 14598-3 UP. . . GF25 Q a GF25 Q GF20 Q GF25 Q GF25 Q GF25 Q GF30 Q 1. Mechanical properties 1.1 9000 9000 8000 6000 9000 10500 10000 1.2 70 70 45 45 55 60

44、60 1.3 1,5 1,5 1,3 1,3 1,5 1,4 1,2 1.4 9000 9000 8000 6000 9000 10500 9000 1.5 160 160 115 120 155 155 160 1.6 70 70 45 45 60 60 70 2. Thermal properties 2.1 200 200 200 180 200 200 180 2.2 15 16 18 18 14 18 16 3. Electrical properties 3.1 0,01 0,01 0,01 0,01 0,01 0.01 0,01 3.2 10 1410 1410 1410 141

45、0 1410 1510 10 3.3 10 1210 1210 1210 1210 1210 1410 7 3.4 600 600 600 600 600 600 400 4. Flammability, Burning behaviour 4.1 HB HB VO HB VO HB VO 4.2 NBR NBR NBR NBR NBR NBR NBR 4.3 BH 2-95 BH 2-95 BH 2-10 BH 2-95 BH1 BH 2-95 BH 2-10 5. Chemical and physical properties 5.1 1,8 1,7 1,8 1,4 1,9 1,8 1,

46、75 5.2 0,03 0,06 0,08 0,02 0,0 0,03 0,14 6. Rheological and processing properties 6.1 25 25 20 20 25 25 30 7. Remarks 7.1 LP, N LS, C LS,Sanitary LP,Low density LP, extremely FR LS,E3 LS,FR,E4, 7.2 7.3 Properties to be specified are those, which should typically appear on a data sheet. A selection o

47、f these properties also should be included on the certificate of conformity. aProc.= Processing; Q = Compression moulding; M = Injection moulding, G = General purpose. EN 14598-3:2005 (E) 9 Table 1.4 - SMC-properties which shall be specified 19 20 21 22 23 24 Type/Grade SMC EN 14598-3 UP Type/grade

48、SMC EN 14598-3 - VE GF35 Q a GF25 Q GF50 Q GF50 Q 1. Mechanical properties 1.1 18000/9000 9500 13000 25000/11000 1.2 200/29 80 160 320/50 1.3 1,7/0,8 1,4 1,8 1,5/0,9 1.4 18000/5500 9500 12000 24000/9000 1.5 500/75 160 280 450/160 1.6 180/35 80 150 280/50 2. Thermal properties 2.1 200 200 180 190 2.2 12/25 16 14 11/25 3. Electrical properties 3.1 0,01 0,01 0,01 0.01 3.2 10 1410 1410 1410 143.3 10 1210 1210 1210 123.4 600 600 600 600 4. Flammability, Burnin