BS EN 14617-10-2012 Agglomerated stone Test methods Determination of chemical resistance《烧结石料 试验方法 耐化学性测定》.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN 14617-10:2012Agglomerated stone TestmethodsPart 10: Determination of chemicalresistanceBS EN 14617-10:2012 BRITISH STANDARDNational forewordThis British Standard is the UK

2、implementation of EN 14617-10:2012.It supersedes BS EN 14617-10:2005 which is withdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee B/545, Natural stone.A list of organizations represented on this committee can beobtained on request to its secretary.This publication d

3、oes not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2012. Published by BSI StandardsLimited 2012ISBN 978 0 580 75920 8ICS 91.100.15Compliance with a British Standard cannot confer immunity fromlegal

4、 obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 31 May 2012.Amendments issued since publicationDate Text affectedBS EN 14617-10:2012EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 14617-10 April 2012 ICS 91.100.15 Supersedes

5、EN 14617-10:2005English Version Agglomerated stone - Test methods - Part 10: Determination of chemical resistance Pierre agglomre - Mthodes dessai - Partie 10: Dtermination de la rsistance chimique Knstlich hergestellter Stein - Prfverfahren - Teil 10: Bestimmung der chemischen Bestndigkeit This Eur

6、opean Standard was approved by CEN on 9 March 2012. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references con

7、cerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member i

8、nto its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ire

9、land, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue

10、 Marnix 17, B-1000 Brussels 2012 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 14617-10:2012: EBS EN 14617-10:2012EN 14617-10:2012 (E) 2 Contents Page Foreword 31 Scope 42 Normative references 43 Principle 44 Determination of the

11、 chemical resistance 44.1 Chemical reagents .44.2 Apparatus .44.3 Preparation of the specimens 54.4 Test procedure .54.5 Expression of the results 54.6 Test report 6Annex A (normative) Determination of the resistance to stains 8A.1 Principle 8A.2 Staining agent 8A.3 Preparation of the specimens 8A.4

12、 Test procedure .8A.5 Expression of the results 9A.6 Test report 9Bibliography . 11BS EN 14617-10:2012EN 14617-10:2012 (E) 3 Foreword This document (EN 14617-10:2012) has been prepared by Technical Committee CEN/TC 246 “Natural stones”, the secretariat of which is held by UNI. This European Standard

13、 shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by October 2012, and conflicting national standards shall be withdrawn at the latest by October 2012. Attention is drawn to the possibility that some of the elements of this

14、 document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 14617-10:2005. 4.3, 4.4, 4.5, A.3 and A.4 have been modified since the last edition of this European Standard. This European Stan

15、dard is one of a series of standards for test methods for agglomerated stones which includes the following: EN 14617-1, Agglomerated stone Test methods Part 1: Determination of apparent density and water absorption EN 14617-2, Agglomerated stone Test methods Part 2: Determination of flexural strengt

16、h (bending) EN 14617-4, Agglomerated stone Test methods Part 4: Determination of the abrasion resistance EN 14617-5, Agglomerated stone Test methods Part 5: Determination of freeze and thaw resistance EN 14617-6, Agglomerated stone Test methods Part 6: Determination of thermal shock resistance EN 14

17、617-8, Agglomerated stone Test methods Part 8: Determination of resistance to fixing (dowel hole) EN 14617-9, Agglomerated stone Test methods Part 9: Determination of impact resistance EN 14617-10, Agglomerated stone Test methods Part 10: Determination of chemical resistance EN 14617-11, Agglomerate

18、d stone Test methods Part 11: Determination of linear thermal expansion coefficient EN 14617-12, Agglomerated stone Test methods Part 12: Determination of dimensional stability EN 14617-13, Agglomerated stone Test methods Part 13: Determination of electrical resistivity EN 14617-15, Agglomerated sto

19、ne Test methods Part 15: Determination of compressive strength EN 14617-16, Agglomerated stone Test methods Part 16: Determination of dimensions, geometric characteristics and surface quality of modular tiles According to the CEN/CENELEC Internal Regulations, the national standards organizations of

20、the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Roman

21、ia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 14617-10:2012EN 14617-10:2012 (E) 4 1 Scope This European Standard specifies a method for determining the chemical resistance and the resistance to stains of agglomerated stones (see EN 14618) with a polished su

22、rface after a prolonged contact with chemical materials. NOTE It is to be remembered that agglomerated stones containing calcium carbonate aggregates are sensitive to any acid attack. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and

23、 are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. Not applicable. 3 Principle Resistance to a chemical attack is the characteristic which defines the

24、behaviour of a floor/wall covering material in contact with chemically aggressive agents potentially able to react with the surface itself, and thereby either corrode it, penetrate it permanently or alter the visible aspect in some manner. The deteriorating action of the aggressive chemical can gene

25、rate two different effects: a real chemical action, according to which the alteration of the surface is due to the chemical reaction between the aggressive agent and some constituents of the surface itself; a physical absorbing action, according to which the aggressive agent is able to penetrate the

26、 surface so that the removal is either extremely difficult or impossible. Both these actions can involve a modification of the visible appearance of the surface of the chemically attacked material, but only in the first case can the damage also introduce a modification in the physical and mechanical

27、 properties of the material itself. 4 Determination of the chemical resistance 4.1 Chemical reagents 4.1.1 Water solution containing hydrochloric acid solution, 50 % (V/V), prepared from N hydrochloric acid solution. 4.1.2 Sodium hydroxide in a 50 % (V/V) water solution, prepared from a normal water

28、 sodium hydroxide non-carbonated solution. 4.2 Apparatus Glossmeter, able to measure with an accuracy and precision of 10 %, the brightness degree of the surface. The glossmeter shall measure the reflection of a light ray incident on a surface. The reflection degree is given by the amount of light s

29、pecularly reflected in a point of the surface in relationship to the amount of light BS EN 14617-10:2012EN 14617-10:2012 (E) 5 reflected by the standard glass plate. A light source representing average daylight shall be used, such as the source CIE1D 65, with the lighting intensity allowed by the gl

30、ossmeter calibration. The glossmeter shall be equipped with at least two optical systems placed at 60 and 20 angles. This allows for an efficient measurement of the different reflection directions: the 60 angle covers a range of reflection degrees from low to high, while the 20 angle lends greater a

31、ccuracy to the measurement of the higher reflection directions (see Annex A). 4.3 Preparation of the specimens For each type of material to be tested four samples shall be prepared with a polished surface2of at least 300 mm 300 mm onto which a containing ring (at least 100 mm diameter) is glued. The

32、 ring is made of chemically resistant material such as silicone. The surface to be measured shall be flat in order to permit the positioning of the instrument sensor in contact with the material to be tested. Before testing, the surface shall be cleaned of any possible wax, other finishes or treatme

33、nt layers using ketone or another appropriate solvent. 4.4 Test procedure The procedure consists of positioning the instrument sensor in contact with the surface to be measured, and of reading the number reported on the display which defines the reflection degree as a reference value of the examined

34、 surface. The test shall be carried out at an ambient temperature of (23 5) C. On each of the four specimens, it is necessary to carry out the reflection measurement on at least five different points, and to then calculate the average value (M1) of each specimen. On two specimens placed horizontally

35、 within the ring, pour 10 ml to 15 ml of hydrochloric acid solution (4.1.1), avoiding any possible overflowing. Repeat this operation on the other two specimens using the sodium hydroxide solution (4.1.2). Keep the specimens, protected with a polyethylene film, on a table for all the time requested

36、for the test. After 1 h 5 min draw out one specimen containing hydrochloric acid and one containing sodium hydroxide respectively; wash them carefully with water and remove the ring. Finally, dry them with soft cellulose paper. After 8 h 30 min draw out the two other specimens and perform the same w

37、ashing and drying procedure. Repeat the reflection measurement on at least in 5 points on each of the four specimens, and then calculate the average value for each specimen and the standard deviation of the 5 values. The reflection measurements are to be carried out with the glossmeter under an inci

38、dent light positioned at 60. 4.5 Expression of the results a) The effects of the chemical attack are expressed as the loss of the reference reflection value. This loss is calculated as a percentage of reflection of the material tested with respect to the reference value. A class of resistance to aci

39、ds and alkali shall be attributed as follows: 1Commission Internationale de lEclairage (Central Bureau, Kagelpasse 27, A-1030 Vienna-AT). 2Obtained by polishing with abrasive grit, grain size F500, according to ISO 8486-2:2007, Bonded abrasives Determination and designation of grain size distributio

40、n: Part 2: Microgrits F230 to F2000. BS EN 14617-10:2012EN 14617-10:2012 (E) 6 C4: materials, which keep at least 80 % of the reflection reference value after 8 h 30 min of acid and basic attack (or if only in one specimen the attack is between 60 % and 80 %); C3: materials, which keep between 60 %

41、and 80 % of the reflection reference value after 8 h 30 min of acid and basic attack; C2: materials, which keep between 60 % and 80 % of the reflection reference value after 1 h 30 min of acid and basic attack; C1: materials, which keep less than 60 % of the reflection reference values after 1 h 30

42、min of basic and acid attack. b) The values are calculated on the basis of 5 measurements and the dispersion is declared. 4.6 Test report The test report shall contain the following information: a) unique identification number of the report; b) number and year of issue of this European Standard, i.e

43、. EN 14617-10:2012; c) name and address of the test laboratory and the address where the test was carried out if different from the test laboratory; d) name and address of the client; e) it is the responsibility of the client to supply the following information: name of the supplier; name of the per

44、son or organization which carried out the sampling; surface finish of the specimens (if relevant to the test); nature of the binders; f) date of delivery of the sample or of the specimens; g) date when the specimens were prepared (if relevant) and the date of testing; h) number of specimens in the s

45、ample; i) dimensions of the specimens; j) water solutions preparation and concentration and chemical agents used; k) type of glossmeter used and the kind and intensity of the light source; l) reflection directions of the light; m) results obtained, using the following table: BS EN 14617-10:2012EN 14

46、617-10:2012 (E) 7 Table 1 Results Chemical resistance Sample N Reference value Class - Hydrochloric acid solution - Sodium hydroxide solution n) statement on measurement uncertainty (where appropriate); o) all deviations from the standard and their justification; p) remarks. The test report shall co

47、ntain the signature(s) and role(s) of the person(s) responsible for the testing and the date of issue of the report. It shall also state that the report shall not be partially reproduced without the written consent of the test laboratory. BS EN 14617-10:2012EN 14617-10:2012 (E) 8 Annex A (normative)

48、 Determination of the resistance to stains A.1 Principle This test is a reference method used to determine the potential damage caused by staining agents that could reasonably enter into contact with the surface of a material. The stain effect is dependent on the viscosity of the fluid that could en

49、ter the part of the material under test. At the least, substances of common use shall be poured onto the surface to evaluate the generic resistance to stains of agglomerated stones. A.2 Staining agent The staining agent shall be chosen among the substances proposed by the client or selected through agreement between the interested parties. A.3 Preparation of the specimens The specimens shall have dimensions of 70 mm 70 mm and a flat