BS EN 14984-2016 Liming materials Determination of product effect on soil pH Soil incubation method《石灰材料 测定肥料对土壤pH值的影响 土壤肥力法》.pdf

1、Liming materials Determination of producteffect on soil pH Soilincubation methodBS EN 14984:2016Incorporating corrigendum .BSDI 2017BSI Standards PublicationBS EN 14984:2016 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 14984:2016. Itsupersedes BS EN 14984:200

2、6 which is withdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee CII/37, Fertilisers and related chemicals.A list of organizations represented on this committee can be obtainedon request to its secretary.This publication does not purport to include all the necessary p

3、rovisionsof a contract. Users are responsible for its correct application. The British Standards Institution 2017.Published by BSI Standards Limited 2017ISBN 978 0 580 97514 1 ICS 65.080 Compliance with a British Standard cannot confer immunity from legal obligations.This British Standard was publis

4、hed under the authority of the StandardsPolicy and Strategy Committee on 31 July 2016.Amendments/corrigenda issued since publicationDate Text affected31 .arch 2017 Implementation of CEN Correction Notice 31 August 2016: Figure 1 correctedg3g3g3g8g24g21g18g19g8g4g17g3g22g23g4g17g7g4g21g7g3g17g18g21g1

5、6g8g3g8g24g21g18g19g50g8g17g17g8g3g8g24g21g18g19g34g12g22g6g11g8g3g17g18g21g16g3EN 14984 g3 g3g3 g13g151g142g155g3g884g882g883g888g3g12g6g22g3g888g887g484g882g890g882g3 g22g151g146g135g148g149g135g134g135g149g3g8g17g3g883g886g891g890g886g483g884g882g882g888g8g144g137g142g139g149g138g3g25g135g148g149

6、g139g145g144g3g3g15g139g143g139g144g137g3g143g131g150g135g148g139g131g142g149g3g486g3g7g135g150g135g148g143g139g144g131g150g139g145g144g3g145g136g3g146g148g145g134g151g133g150g3g135g136g136g135g133g150g3g145g144g3g149g145g139g142g3g146g11g3g486g3g22g145g139g142g3g139g144g133g151g132g131g150g139g145g

7、144g3g143g135g150g138g145g134g3g4g143g135g144g134g135g143g135g144g150g149g3g143g139g144g177g148g131g151g154g3g132g131g149g139g147g151g135g149g3g486g3g7g177g150g135g148g143g139g144g131g150g139g145g144g3g134g135g3g142g821g135g136g136g135g150g3g134g821g151g144g3g146g148g145g134g151g139g150g3g149g151g14

8、8g3g142g135g3g146g11g3g134g821g151g144g3g149g145g142g3g486g3g16g177g150g138g145g134g135g3g146g131g148g3g139g144g133g151g132g131g150g139g145g144g3g134g151g3g149g145g142g3g3 g14g131g142g141g134g242g144g137g135g148g3g486g3g5g135g149g150g139g143g143g151g144g137g3g134g135g149g3g19g148g145g134g151g141g150

9、g135g139g144g136g142g151g149g149g135g149g3g131g151g136g3g134g135g144g3g5g145g134g135g144g486g146g11g486g26g135g148g150g3g486g3g5g145g134g135g144g139g144g141g151g132g131g150g139g145g144g149g152g135g148g136g131g138g148g135g144g3g23g138g139g149g3g8g151g148g145g146g135g131g144g3g22g150g131g144g134g131g1

10、48g134g3g153g131g149g3g131g146g146g148g145g152g135g134g3g132g155g3g6g8g17g3g145g144g3g883g891g3g16g131g155g3g884g882g883g888g484g3g3g3g6g8g17g3g143g135g143g132g135g148g149g3g131g148g135g3g132g145g151g144g134g3g150g145g3g133g145g143g146g142g155g3g153g139g150g138g3g150g138g135g3g6g8g17g512g6g8g17g8g15

11、g8g6g3g12g144g150g135g148g144g131g142g3g21g135g137g151g142g131g150g139g145g144g149g3g153g138g139g133g138g3g149g150g139g146g151g142g131g150g135g3g150g138g135g3g133g145g144g134g139g150g139g145g144g149g3g136g145g148g3g137g139g152g139g144g137g3g150g138g139g149g3g8g151g148g145g146g135g131g144g3g22g150g13

12、1g144g134g131g148g134g3g150g138g135g3g149g150g131g150g151g149g3g145g136g3g131g3g144g131g150g139g145g144g131g142g3g149g150g131g144g134g131g148g134g3g153g139g150g138g145g151g150g3g131g144g155g3g131g142g150g135g148g131g150g139g145g144g484g3g24g146g486g150g145g486g134g131g150g135g3g142g139g149g150g149g3

13、g131g144g134g3g132g139g132g142g139g145g137g148g131g146g138g139g133g131g142g3g148g135g136g135g148g135g144g133g135g149g3g133g145g144g133g135g148g144g139g144g137g3g149g151g133g138g3g144g131g150g139g145g144g131g142g3g149g150g131g144g134g131g148g134g149g3g143g131g155g3g132g135g3g145g132g150g131g139g144g1

14、35g134g3g145g144g3g131g146g146g142g139g133g131g150g139g145g144g3g150g145g3g150g138g135g3g6g8g17g486g6g8g17g8g15g8g6g3g16g131g144g131g137g135g143g135g144g150g3g6g135g144g150g148g135g3g145g148g3g150g145g3g131g144g155g3g6g8g17g3g143g135g143g132g135g148g484g3g3g23g138g139g149g3g8g151g148g145g146g135g131

15、g144g3g22g150g131g144g134g131g148g134g3g135g154g139g149g150g149g3g139g144g3g150g138g148g135g135g3g145g136g136g139g133g139g131g142g3g152g135g148g149g139g145g144g149g3g523g8g144g137g142g139g149g138g481g3g9g148g135g144g133g138g481g3g10g135g148g143g131g144g524g484g3g4g3g152g135g148g149g139g145g144g3g139

16、g144g3g131g144g155g3g145g150g138g135g148g3g142g131g144g137g151g131g137g135g3g143g131g134g135g3g132g155g3g150g148g131g144g149g142g131g150g139g145g144g3g151g144g134g135g148g3g150g138g135g3g148g135g149g146g145g144g149g139g132g139g142g139g150g155g3g145g136g3g131g3g6g8g17g3g143g135g143g132g135g148g3g139g

17、144g150g145g3g139g150g149g3g145g153g144g3g142g131g144g137g151g131g137g135g3g131g144g134g3g144g145g150g139g136g139g135g134g3g150g145g3g150g138g135g3g6g8g17g486g6g8g17g8g15g8g6g3g16g131g144g131g137g135g143g135g144g150g3g6g135g144g150g148g135g3g138g131g149g3g150g138g135g3g149g131g143g135g3g149g150g131g

18、150g151g149g3g131g149g3g150g138g135g3g145g136g136g139g133g139g131g142g3g152g135g148g149g139g145g144g149g484g3g3g6g8g17g3g143g135g143g132g135g148g149g3g131g148g135g3g150g138g135g3g144g131g150g139g145g144g131g142g3g149g150g131g144g134g131g148g134g149g3g132g145g134g139g135g149g3g145g136g3g4g151g149g150

19、g148g139g131g481g3g5g135g142g137g139g151g143g481g3g5g151g142g137g131g148g139g131g481g3g6g148g145g131g150g139g131g481g3g6g155g146g148g151g149g481g3g6g156g135g133g138g3g21g135g146g151g132g142g139g133g481g3g7g135g144g143g131g148g141g481g3g8g149g150g145g144g139g131g481g3g9g139g144g142g131g144g134g481g3g

20、9g145g148g143g135g148g3g28g151g137g145g149g142g131g152g3g21g135g146g151g132g142g139g133g3g145g136g3g16g131g133g135g134g145g144g139g131g481g3g9g148g131g144g133g135g481g3g10g135g148g143g131g144g155g481g3g10g148g135g135g133g135g481g3g11g151g144g137g131g148g155g481g3g12g133g135g142g131g144g134g481g3g12g

21、148g135g142g131g144g134g481g3g12g150g131g142g155g481g3g15g131g150g152g139g131g481g3g15g139g150g138g151g131g144g139g131g481g3g15g151g154g135g143g132g145g151g148g137g481g3g16g131g142g150g131g481g3g17g135g150g138g135g148g142g131g144g134g149g481g3g17g145g148g153g131g155g481g3g19g145g142g131g144g134g481g

22、3g19g145g148g150g151g137g131g142g481g3g21g145g143g131g144g139g131g481g3g22g142g145g152g131g141g139g131g481g3g22g142g145g152g135g144g139g131g481g3g22g146g131g139g144g481g3g22g153g135g134g135g144g481g3g22g153g139g150g156g135g148g142g131g144g134g481g3g23g151g148g141g135g155g3g131g144g134g24g144g139g150

23、g135g134g3g14g139g144g137g134g145g143g484g3g3g3g3g3g8g24g21g18g19g8g4g17g3g6g18g16g16g12g23g23g8g8g3g9g18g21g3g22g23g4g17g7g4g21g7g12g29g4g23g12g18g17g3g6g18g16g12g23g50g3g8g24g21g18g19g50g8g17g3g7g8g3g17g18g21g16g4g15g12g22g4g23g12g18g17g3g8g24g21g18g19g34g12g22g6g11g8g22g3g14g18g16g12g23g8g8g3g9g1

24、11g21g3g17g18g21g16g24g17g10g3g3g3g3CEN-CENELECg3Management Centre: Avenue Marnix 17, B-1000 Brussels g825g3g884g882g883g888g3g6g8g17g3 g4g142g142g3g148g139g137g138g150g149g3g145g136g3g135g154g146g142g145g139g150g131g150g139g145g144g3g139g144g3g131g144g155g3g136g145g148g143g3g131g144g134g3g132g155g3

25、g131g144g155g3g143g135g131g144g149g3g148g135g149g135g148g152g135g134g3g153g145g148g142g134g153g139g134g135g3g136g145g148g3g6g8g17g3g144g131g150g139g145g144g131g142g3g16g135g143g132g135g148g149g484g3g21g135g136g484g3g17g145g484g3g8g17g3g883g886g891g890g886g483g884g882g883g888g3g8BS EN 14984:2016EN 14

26、984:2016 (E) 2 Contents Page European foreword . 4 Introduction 5 1 Scope 6 2 Normative references 6 3 Terms and definitions . 7 4 Principle . 9 4.1 General 9 4.2 Method A. 9 4.3 Method B. 9 5 Method A 10 5.1 Reagents and materials 10 5.1.1 Reference soil, . 10 5.1.2 Reference liming material (RLM),

27、 10 5.1.3 Water, . 10 5.2 Apparatus 10 5.2.1 Temperature-controlled room, . 10 5.2.2 pH meter, . 10 5.2.3 Beakers, . 10 5.2.4 Pots, . 10 5.2.5 Volumetric spoons, 10 5.2.6 Magnetic stirrer 10 5.2.7 Balance, 10 5.2.8 Precision balance, 10 5.2.9 Test sieves, 11 5.3 Sampling of products and sample prepa

28、ration . 11 5.4 Procedure 11 5.4.1 Preparation of the standard soil . 11 5.4.2 Test portions 11 5.4.3 Preparation of pots 11 5.4.4 Incubation . 12 5.4.5 pH measurements 12 5.5 Expression of results . 12 5.6 Precision 14 5.6.1 General . 14 5.6.2 Repeatability 14 5.6.3 Reproducibility . 15 6 Method B

29、17 6.1 Reagents and materials 17 6.1.1 Standard soil, . 17 6.1.2 Alternative standard soils, 18 6.1.3 Reference liming material, . 18 6.1.4 Water, . 18 6.2 Apparatus 18 6.2.1 Temperature-controlled room, . 18 BS EN 14984:2016g8g17g3g883g886g891g890g886g483g884g882g883g888g3g525g8g526EN 14984:2016 (E

30、) 3 6.2.2 pH meter, . 18 6.2.3 Beakers, 19 6.2.4 Pots, . 19 6.2.5 Volumetric spoons,. 19 6.2.6 Magnetic stirrer . 19 6.2.7 Balance, 19 6.2.8 Precision balance, . 19 6.2.9 Test sieves, 19 6.3 Sampling of products and sample preparation . 19 6.4 Procedure 19 6.4.1 Preparation of the standard soil . 19

31、 6.4.2 Test portions 20 6.4.3 Preparation of pots 20 6.4.4 Incubation . 21 6.4.5 pH measurements. 21 6.5 Expression of results . 21 6.5.1 pH measurements. 21 6.5.2 Soil-lime efficiency data . 21 6.6 Precision 22 6.6.1 General . 22 6.6.2 Repeatability 22 6.6.3 Reproducibility 23 7 Test report 26 Anne

32、x A (informative) Variations to the test methods 27 A.1 General . 27 A.2 Variations 27 A.2.1 Different measurement periods 27 A.2.2 Supply of different amounts . 27 A.2.3 Soil different from the standard soil 27 A.2.4 Different incubation temperature 28 A.2.5 Additional measurements . 28 Annex B (no

33、rmative) Determination of moisture at full soil water holding capacity 29 Bibliography . 31 BS EN 14984:2016g8g17g3g883g886g891g890g886g483g884g882g883g888g3g525g8g526EN 14984:2016 (E) 4 European foreword This document (EN 14984:2016) has been prepared by Technical Committee CEN/TC 260 “Fertilizers

34、and liming materials”, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by January 2017, and conflicting national standards shall be withdrawn at the latest by

35、 January 2017. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 14984:2006. The following changes have been made to the fo

36、rmer edition: a) effective neutralizing value by incubation (ENVI) added as alternative way for the expression of results; b) Formula for calculation of ENVI for method A added; c) Formula for calculation of ENVI for method B added; d) editorially revised. According to the CEN-CENELEC Internal Regul

37、ations, the national standards organisations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, It

38、aly, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 14984:2016g8g17g3g883g886g891g890g886g483g884g882g883g888g3g525g8g526EN 14984:2016 (E) 5 Introduction The chemical methods f

39、or determining the neutralizing value (NV) (see EN 12945) and the reactivity (see EN 13971 and EN 16357) of liming materials are not always appropriate indicators for any material claimed to have a liming effect in the soil, particularly materials with a high organic matter content. The biological m

40、ineralization of organic matter contained in some products can, in the field, have an effect on pH, which cannot be quantified by the chemical methods. The two methods described in this document overcome these problems. Both methods characterize products through their effect on the pH of a soil unde

41、r controlled, standard conditions, and establish the efficiency of products when applied to a standard soil. Method A specifies a reference soil with tight characteristics with respect to pH range before incubation, cation exchange capacity (CEC), mass fraction of organic carbon, and mass fraction o

42、f particles finer than 0,002 mm (clay). Method B can apply the same reference soil as Method A, but also allows alternative standard soils with a wider content of particles finer than 0,002 mm (clay), and a wider range of mass fraction of organic matter. Clay and organic matter are the decisive reac

43、tants to a liming material However, attention is drawn to the limitations of these methods. They are laboratory methods carried out under controlled conditions and care should be taken when applying the results to field conditions. The quality of incorporation of the liming material into the soil an

44、d the eventual need to break down the product agglomerates, together with the soil and climate conditions, can affect the results. Nevertheless, these methods allow a comparison of the potential neutralizing effect of liming products under optimum and reproducible conditions. BS EN 14984:2016g8g17g3

45、g883g886g891g890g886g483g884g882g883g888g3g525g8g526EN 14984:2016 (E) 6 1 Scope This document specifies two methods (method A and method B) of measuring the effect of the addition of any material claimed to have a liming effect on the soil, using the same basic principles. Method A measures the chan

46、ges to the soil pH resulting from the addition of any material claimed to have a liming effect on a standard soil, measured over a period of one month. Method B assesses the efficiency of any material claimed to have a liming effect, using a range of defined soils and measured over a period of up to

47、 2,5 years. The methods are not applicable to mineral products coarser than 6,3 mm for method A or 20 mm for method B, determined according to EN 12948. NOTE These methods allow comparison of products under controlled climatic conditions but do not replace field experiments. 2 Normative references T

48、he following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 1482-

49、1, Fertilizers and liming materials - Sampling and sample preparation - Part 1: Sampling EN 1482-3, Fertilizers and liming materials Sampling and sample preparation Part 3: Sampling of static heaps EN 12048, Solid fertilizers and liming materials - Determination of moisture content - Gravimetric method by drying at (105 +/- 2)C (ISO 8190:1992 modified) EN 12049, Solid fertilizers and liming materials - Determination of moisture content - Gravimetric method by drying under reduced pressure (ISO 8189:1992 modified) EN 12945, Liming materials - Determination of neutralizing value -