BS EN 15029-2012 Products used for treatment of water intended for human consumption Iron (III) hydroxide oxide《人类生活用水的处理产品 氢氧化铁(III)》.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN 15029:2012Products used for treatmentof water intended for humanconsumption Iron (III)hydroxide oxideCopyright European Committee for Standardization Provided by IHS under

2、license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15029:2012 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 15029:2012.It supersedes BS EN 15029:2006 which is withdrawn.The UK participation in its preparati

3、on was entrusted to TechnicalCommittee CII/59, Chemicals for drinking water treatment.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its

4、 correctapplication. The British Standards Institution 2013. Published by BSI StandardsLimited 2013 ISBN 978 0 580 77570 3 ICS 13.060.20; 71.100.80 Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards

5、Policy and Strategy Committee on 31 January 2013. Amendments issued since publicationDate T e x t a f f e c t e dCopyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15029:2012E

6、UROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 15029 November 2012 ICS 71.100.80 Supersedes EN 15029:2006English Version Products used for treatment of water intended for human consumption - Iron (III) hydroxide oxide Produits utiliss pour le traitement de leau destine la consommation humaine -

7、 Oxyde hydroxyde de fer (III) Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch - Eisen(III)hydroxidoxid This European Standard was approved by CEN on 9 September 2012. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving

8、 this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three offici

9、al versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of A

10、ustria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sw

11、eden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2012 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national

12、 Members. Ref. No. EN 15029:2012: ECopyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15029:2012EN 15029:2012 (E) 2 Contents Page Foreword 3Introduction .41 Scope 52 Normative

13、 references 53 Terms, definitions and symbols .54 Description .55 Physical properties 66 Chemical properties 67 Specific properties.78 Test methods 79 Labelling, transportation and storage .7Annex A (informative) General information on iron (III) hydroxide oxide .9Copyright European Committee for St

14、andardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15029:2012EN 15029:2012 (E) 3 Foreword This document (EN 15029:2012) has been prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of whi

15、ch is held by AFNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2013, and conflicting national standards shall be withdrawn at the latest by May 2013. Attention is drawn to the possibilit

16、y that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 15029:2006. The significant technical difference between this edition and EN 15029:2006 is as

17、follows: Updating of 9.2 in line with current legislation. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,

18、Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Copyright European Committee

19、 for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15029:2012EN 15029:2012 (E) 4 Introduction In respect of potential adverse effects on the quality of water intended for human consumption caused by the

20、product covered by this European Standard: a) this European Standard provides no information as to whether the product may be used without restriction in any of the Member States of the EU or EFTA; b) it should be noted that, while awaiting the adoption of verifiable European criteria, existing nati

21、onal regulations concerning the use and/or the characteristics of this product remain in force. NOTE Conformity with the European Standard does not confer or imply acceptance or approval of the product in any of the member states of the EU or EFTA. The use of the product covered by this European Sta

22、ndard is subject to regulation or control by national authorities. Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15029:2012EN 15029:2012 (E) 5 1 Scope This European Stand

23、ard is applicable to iron (III) hydroxide oxide used for the treatment of water intended for human consumption. It describes the characteristics of iron (III) hydroxide oxide and specifies the requirements and the corresponding test methods for iron (III) hydroxide oxide. It gives information on its

24、 use in water treatment. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced docu

25、ment (including any amendments) applies. EN 12901:1999, Products used for treatment of water intended for human consumption Inorganic supporting and filtering materials Definitions EN 12902, Products used for treatment of water intended for human consumption Inorganic supporting and filtering materi

26、als Methods of test ISO 9277, Determination of the specific surface area of solids by gas adsorption BET method 3 Terms, definitions and symbols For the purposes of this document, the terms, definitions and symbols given in EN 12901:1999 apply. 4 Description 4.1 Identification 4.1.1 Chemical name(s)

27、 Iron (III) hydroxide, iron hydroxide oxide. 4.1.2 Synonym or common names Granular ferric hydroxide, granulated iron oxide, granulated iron oxide hydroxide, synthetic iron oxide, synthetic iron oxide hydroxide, Goethite, Akaganeite. 4.1.3 Chemical formula Fe(OH)3, FeOOH. 4.1.4 CAS Registry Number 1

28、)Iron hydroxide oxide: 51274-00-1. 1) Chemical Abstracts Service Registry Number. Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15029:2012EN 15029:2012 (E) 6 4.1.5 EINECS

29、 Reference 2)Iron hydroxide oxide: 257-098-5. 4.2 Commercial form Iron (III) hydroxide oxide is a granular product consisting of irregularly shaped (non-moulded) particles; the product is available in different particle sizes. The water content is a mass fraction of up to 50 %. 5 Physical properties

30、 5.1 Appearance The product consists of black to brown granular material with particles of irregular shape. The product shall be generally homogeneous and shall be visibly free of extraneous matter. 5.2 Particle size distribution The particle size distribution shall be described by either: a) effect

31、ive size (d10)with a maximum deviation of 5 %; uniformity coefficient (U) less than 2,1; minimum size (d1) with a maximum deviation of 5 %. or b) particle size range and mass fraction of oversize and undersize particles; see A.2.2.1. The proportion of oversize plus undersize particles shall not exce

32、ed a mass fraction of 20 % and not more than a mass fraction of 10 % shall be undersized. NOTE 1 The particle size can decrease during transportation and handling. NOTE 2 Other values can be necessary for certain applications. 5.3 Density The bulk density (loose) shall be within 10 % of the value sp

33、ecified by the manufacturer or supplier. The bed density (backwashed and drained) should be in the range of 500 kg/m3to 1 800 kg/m3. 6 Chemical properties This European Standard specifies the minimum purity requirements for iron (III) hydroxide oxide used for the treatment of water intended for huma

34、n consumption. Limits are given for impurities commonly present in the product. Depending on the raw material and the manufacturing process other impurities may be present and, if so, this shall be notified to the user and when necessary to relevant authorities. 2) European Inventory of Existing Com

35、mercial Chemical Substances. Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15029:2012EN 15029:2012 (E) 7 Users of this product should check the national regulations in or

36、der to clarify whether it is of appropriate purity for treatment of water intended for human consumption, taking into account raw water quality, contents of other impurities and additives used in the products not stated in this product standard. Limits have been given for impurities and chemical par

37、ameters where these are likely to be present in significant quantities from the current production process and raw materials. If the production process or raw materials lead to significant quantities of impurities, by-products or additives being present, this shall be notified to the user. After fil

38、ling, washing and commissioning of a filter system producing drinking water, iron (III) hydroxide oxide should not increase the concentrations of chemical parameters (see 1). NOTE Water-extractable substances, determined in accordance with the method for granular materials given in EN 12902, can be

39、used to estimate the leaching of the chemicals specified in EN 12902. 7 Specific properties The surface area shall be not less than 100 m2/g. 8 Test methods 8.1 Sampling Prepare the laboratory sample(s) required by the relevant procedures described in EN 12902. 8.2 Analysis 8.2.1 Particle size distr

40、ibution The particle size distribution shall be determined on samples taken at the point of manufacture in accordance with the method of test given EN 12902, using wet sieving. 8.2.2 Bulk density loose The bulk density loose shall be determined in accordance with EN 12902, without drying the sample,

41、 which could lead to a reduced volume. 8.2.3 Surface area The surface area shall be determined by the BET method, degassing at a maximum of 200 C, in accordance with ISO 9277. 9 Labelling, transportation and storage 9.1 Means of delivery Iron (III) hydroxide oxide shall be delivered in bulk, in semi

42、-bulk containers, big bags or in drums of plastics-lined cardboard, plastics or steel or suitable bags of various sizes. NOTE In case of dry iron (III) hydroxide oxide, cardboard drums without plastics-lining can be used. In order that the purity of the product is not affected, the means of delivery

43、 shall not have been used previously for any different product or it shall have been specially cleaned and prepared before use. Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS

44、 EN 15029:2012EN 15029:2012 (E) 8 9.2 Labelling according to EU legislation 3)Iron (III) hydroxide oxide is not listed in Annex VI of Regulation (EC) No 1272/2008 at the date of publication of this European Standard. The legislation 2, and its amendments for the purposes of its adaptation to technic

45、al and scientific progress contains a list of substances classified by the EU. Substances not listed in this regulation should be classified on the basis of their intrinsic properties according to the criteria in the regulation by the person responsible for the marketing of the substance. 9.3 Transp

46、ortation regulations and labelling Iron (III) hydroxide oxide is not listed under a UN 4)number. Iron (III) hydroxide oxide is not classified as a dangerous product for road, rail, sea and air transportation. 9.4 Marking The marking shall include the following: name “Iron (III) hydroxide oxide”, tra

47、de name and commercial grade; net mass; name and the address of the supplier and/or manufacturer; statement “This product conforms to EN 15029.” 9.5 Storage 9.5.1 Long-term chemical stability The product is stable and can be stored for a period of at least one year. 9.5.2 Storage incompatibilities T

48、he product shall be kept away from strong acids, oxidants, solvents and odorous products. 3) See 2. 4) United Nations Number. Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-BS EN 15029:2012EN 15029:2012 (E) 9 Annex A (informative) General information on iron (III) hydroxide oxide A.1 Origin A.1.1 Raw materials The raw material for iron (III) hydroxide oxide is a synthesised iron (III) hyd