BS EN 15344-2007 Plastics - Recycled plastics - Characterization of polyethylene (PE) recyclates《塑料 再生塑料 聚乙烯(PE)回收再生物的特性》.pdf

1、Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 23/04/2008 02:21, Uncontrolled Copy, (c) BSIg49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58P

2、olyethylene (PE) recyclatesICS 13.030.50; 83.080.20Plastics Recycled Plastics Characterization of BRITISH STANDARDBS EN 15344:2007BS EN 15344:2007Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 23/04/2008 02:21, Uncontrolled Copy, (c) BSIThis British Standard was published under the authority

3、 of the Standards Policy and Strategy Committee on 31 January 2008 BSI 2008ISBN 978 0 580 53965 7Amendments/corrigenda issued since publicationDate CommentsCompliance with a British Standard cannot confer immunity from legal obligations.National forewordThis British Standard is the UK implementation

4、 of EN 15344:2007.The UK participation in its preparation was entrusted to Technical Committee PRI/89, Plastics recycling.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a c

5、ontract. Users are responsible for its correct application.EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN 15344December 2007ICS 13.030.50; 83.080.20English VersionPlastics - Recycled Plastics - Characterisation of Polyethylene(PE) recyclatesPlastiques - Plastiques recycls - Caractrisation desrecy

6、clats de polythylne (PE)Kunststoffe - Kunststoff-Rezyklate - Charakterisierung vonPolyethylen (PE)-RezyklatenThis European Standard was approved by CEN on 25 October 2007.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European

7、Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, Fre

8、nch, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, C

9、zech Republic, Denmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROP

10、EN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2007 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 15344:2007: ELicensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 23/04/20

11、08 02:21, Uncontrolled Copy, (c) BSIEN 15344:2007 (E) 2 Contents Page Foreword3 Introduction .4 1 Scope 5 2 Normative references 5 3 Terms, definitions and abbreviated terms 6 4 Characterisation of PE recyclates6 5 Quality assurance7 Annex A (normative) Method for the determination of contaminants .

12、9 A.1 General9 A.2 Principle9 A.3 Apparatus .9 A.3.1 Method A.9 A.3.2 Method B.9 A.3.3 Method C.9 A.3.4 Device for visual examination 9 A.4 Procedure .10 A.4.1 Method A.10 A.4.2 Method B.10 A.4.3 Method C.10 A.5 Expression of results 10 A.6 Test report 11 Annex B (normative) Test Method for the dete

13、rmination of bulk density.12 B.1 Scope 12 B.2 Material .13 B.3 Apparatus .13 B.4 Preparation of test sample13 B.5 Procedure .13 B.6 Expression of results 13 B.7 Test report 14 Bibliography 15 Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 23/04/2008 02:21, Uncontrolled Copy, (c) BSIEN 15344:

14、2007 (E) 3 Foreword This document (EN 15344:2007) has been prepared by Technical Committee CEN/TC 249 “Plastics”, the secretariat of which is held by NBN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the lat

15、est by June 2008, and conflicting national standards shall be withdrawn at the latest by June 2008. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such p

16、atent rights. This standard is one part of a series of CEN publications on Plastics Recycling which is structured as follows: EN 15342 PlasticsRecycled PlasticsCharacterization of polystyrene (PS) recyclates EN 15343 PlasticsRecycled PlasticsPlastics recycling traceability and assessment of conformi

17、ty and recycled content EN 15344 PlasticsRecycled PlasticsCharacterisation of Polyethylene (PE) recyclates EN 15345 PlasticsRecycled PlasticsCharacterisation of Polypropylene (PP) recyclates EN 15346 PlasticsRecycled plasticsCharacterisation of poly(vinyl chloride) (PVC) recyclates EN 15347 Plastics

18、 Recycled Plastics Characterisation of plastics wastes EN 15348 PlasticsRecycled plasticsCharacterization of poly(ethylene terephthalate) (PET) recyclates CEN/TR 15353 Plastics Recycled plastics Guidelines for the development of standards for recycled plastics According to the CEN/CENELEC Internal R

19、egulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, N

20、etherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 23/04/2008 02:21, Uncontrolled Copy, (c) BSIEN 15344:2007 (E) 4 Introduction Recycling plastics waste is one type of material r

21、ecovery process intended to save resources (virgin raw materials, water, and energy), while minimising harmful emissions into air, water and soil as well as any impacts on human health. The environmental impact of recycling has to be assessed over the whole life cycle of the recycling system (from t

22、he waste generation point to the disposal of final residues). To ensure that recycling constitutes the best environmental option for treating the available waste, some prerequisites should preferably be met: recycling scheme being contemplated should generate lower environmental impacts than alterna

23、tive recovery options; existing or potential market outlets should be identified that will secure a sustainable industrial recycling operation; collection and sorting schemes should be properly designed to deliver recyclable plastics waste fractions fitting reasonably well with the available recycli

24、ng technologies and with the (changing) needs of the identified market outlets, preferably at minimum costs to society. This standard has been produced in accordance with the guidance produced by CEN on Environmental Aspects and in accordance with CEN/TR 15353, Plastics Recycled plastics Guidelines

25、for the development of standards for recycled plastics. NOTE CEN/TR 15353 considers the general environmental aspects which are specific to the recycling process. It is often impossible to trace back each individual product at the end user stage and to check whether the product has been used correct

26、ly through its life. Consequently products are out of industrial control for a period of time. It is possible that during this period contamination with other materials may occur that could affect the products suitability for recycling into the intended application. Licensed Copy: Wang Bin, ISO/EXCH

27、ANGE CHINA STANDARDS, 23/04/2008 02:21, Uncontrolled Copy, (c) BSIEN 15344:2007 (E) 5 1 Scope This European Standard defines a method of specifying delivery conditions for polyethylene (PE) recyclates. It gives the most important characteristics and associated test methods for assessing PE recyclate

28、s intended for use in the production of semi-finished/finished products. It is intended to support parties involved in the use of recycled PE to agree on specifications for specific and generic applications. This standard is applicable without prejudice to any existing legislation. This standard doe

29、s not cover the characterisation of plastics wastes. See EN 15347. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced docu

30、ment (including any amendments) applies. EN 12099, Plastics piping systems Polyethylene piping materials and components Determination of volatile content EN 15348:2007, PlasticsRecycled plasticsCharacterization of poly(ethylene terephthalate) (PET) recyclates EN ISO 179-1, Plastics Determination of

31、Charpy impact properties Part 1: Non-instrumented impact test (ISO 179-1:2000) EN ISO 180, Plastics Determination of Izod impact strength (ISO 180:2000) EN ISO 472:2001, Plastics Vocabulary (ISO 472:1999) EN ISO 527-1, Plastics Determination of tensile properties Part 1: General principles (ISO 527-

32、1:1993 including Corr 1:1994) EN ISO 527-2, Plastics Determination of the tensile properties Part 2: Test conditions for moulding and extrusion plastics (ISO 527-2:1993 including Corr 1:1994) EN ISO 1043-1:2001, Plastics Symbols and abbreviated terms Part 1: Basic polymers and their special characte

33、ristics (ISO 1043-1:2001) EN ISO 1133, Plastics Determination of the melt mass flow-rate (MFR) and the melt-volume flow rate (MVR) of thermoplastics (ISO 1133:2005) EN ISO 1183-1, Plastics - Methods for determining the density of non-cellular plastics - Part 1: Immersion method, liquid pyknometer me

34、thod and titration method (ISO 1183-1:2004) EN ISO 3451-1, Plastics Determination of ash Part 1: General methods (ISO 3451-1:1997) ISO 3534-2, Statistics Vocabulary and symbols - Part 2: Applied statistics ISO 22498, Plastics Vinyl chloride homopolymer and copolymer resins Particle size determinatio

35、n by mechanical sieving CEN/TR 15353:2007, Plastics Recycled plastics Guidelines for the development of standards for recycled plastics Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 23/04/2008 02:21, Uncontrolled Copy, (c) BSIEN 15344:2007 (E) 6 3 Terms, definitions and abbreviated terms Fo

36、r the purposes of this European Standard, the terms and definitions given in EN ISO 472:2001 and CEN/TR 15353:2007 apply. The abbreviated terms related to recyclates are given in EN ISO 1043-1:2001. 4 Characterisation of PE recyclates A single batch is the quantity of PE recyclate that has homogeneo

37、us characteristics within the specified tolerances. The characteristics of PE recyclates, which shall be determined for every batch (see ISO 3534-2) of recyclate, are given in Table 1, and are divided into two types: Required characteristics, needed to define PE recyclates in general, and required f

38、or all recyclates. Optional characteristics, needed to define PE recyclates according to customer specifications and applications. NOTE 1 Polyethylene plastics waste originate from different types or grades of PE containing additives to modify characteristics. Polyethylene is generally classified as

39、 PE-HD (high density polyethylene), PE-LD (low density polyethylene), PE-LLD (linear low density polyethylene) and others of less common use. The properties and performance of recyclates derived from such wastes may depend on the type or relative proportions of blends of PE, but it is not in the sco

40、pe of this Standard to investigate such relations. These characteristics shall be assessed by using the test methods given in Table 1. Where possible the supplier should provide information on the original applications. A certificate of analysis, giving the test results for each batch of recyclate s

41、hall be provided by the supplier to the purchaser upon request. To secure the legal use of the recyclate, the supplier shall provide the necessary information about the material composition of the recyclate, as specified by the purchaser. NOTE 2 In this European Standard, PE (R) is composed of: - Po

42、lymeric matrix, consisting of polyethylene (PE content); - Fillers, pigments and additives; - Impurities or contamination in a quantity which do not compromise the workability characteristics of PE (R); - Polymers compatible with the polymeric matrix. Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STAN

43、DARDS, 23/04/2008 02:21, Uncontrolled Copy, (c) BSIEN 15344:2007 (E) 7 Table 1 Characterisation of PE recyclates Characteristics Unit Tests method Comments Required Bulk density kg/m3ANNEX B Test may be used for powder or granulates ASTM D 1895-96 may be used for powder Colour Visual inspection Part

44、icle size mm ISO 22498aFor powder used for rotomoulding (particle size distribution also required). For flakes or regrind the Annex A of EN 15348:2007 and Annex E of EN 15346:2007 draft standards may be used. ASTM D 1921-01 may also be used Melt mass flow rate (MFR) g/10 min EN ISO 1133 190 C-2,16 k

45、g for density 0,945 kg/dm3190 C-5 kg for density 0,945 kg/dm3Shape Visual inspection Typical shape are pellets, flakes, regrind, powder and agglomeratedOptional Ash content % EN ISO 3451-1 With this method, any organic pigments are destroyed Density kg/m3EN ISO 1183-1 Pycnometer, parties to agree on

46、 method A or B Contaminants Number ANNEX A Method A, B or C Parties to agree on which method Filtration level m Mesh size Only finest filter. Alternatively dimension of net passage. Izod impact strength or Charpy impact strength kJ/m2EN ISO 180 EN ISO 179-1 Temperature conditions agreed between the

47、interested parties Residual humidity % EN 12099b Weight loss, 105 C Tensile stress at yield MPa EN ISO 527-1 EN ISO 527-2 Test speed and at the temperature conditions agreed between the interested parties Test specimen 1 A Tensile strain at break % EN ISO 527-1 EN ISO 527-2 Test speed and at the tem

48、perature conditions agreed between the interested parties Test specimen 1 A X: required characteristics to be quantified. O: optional characteristics to be quantified. a Although ISO 22498 is specific to PVC, it is considered relevant to PP. bAlthough the scope of EN 12099 is limited, it is consider

49、ed relevant. 5 Quality assurance In order that the purchaser of the recyclate may have confidence in the quality of the product, the supplier shall maintain records of the quality control carried out, including incoming materials, processes and finished products. Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 23/04/2008 02:21, Uncontrolled Copy, (c) BSIEN 15344:2007 (E) 8 NOTE A quality management system certified to EN ISO 9001 may be a sui