1、BSI Standards PublicationBS EN 16739:2015Emission safety of combustibleair fresheners Methodologyfor the assessment of testresults and application ofrecommended emission limitsBS EN 16739:2015 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN 16739:2015.The UK par
2、ticipation in its preparation was entrusted to TechnicalCommittee EH/2/5, Emissions to internal environments.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users
3、are responsible for its correctapplication. The British Standards Institution 2015.Published by BSI Standards Limited 2015ISBN 978 0 580 86159 8ICS 13.040.20Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theS
4、tandards Policy and Strategy Committee on 30 November 2015.Amendments/corrigenda issued since publicationDate T e x t a f f e c t e dBS EN 16739:2015EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 16739 November 2015 ICS 13.040.20 English Version Emission safety of combustible air fresheners -
5、Methodology for the assessment of test results and application of recommended emission limits Scurit des missions des dsodorisants combustion - Mthodologie de lvaluation des rsultats dessais et application des limites dmission recommandes Emissionssicherheit brennbarer Lufterfrischer - Methodik fr d
6、ie Bewertung von Prfergebnissen und Anwendung empfohlener Emissionsgrenzen This European Standard was approved by CEN on 17 October 2015. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a nationa
7、l standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A versio
8、n in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Cze
9、ch Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey andUnited Kingdom. EU
10、ROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 16739:2015 EBS
11、 EN 16739:2015EN 16739:2015 (E) 2 Contents Page European foreword . 3 1 Scope 4 2 Normative references 4 3 Terms and definitions . 4 4 Requirements . 4 4.1 Assessment of consumer exposure . 4 4.1.1 Consumer exposure based on habits and practices . 4 4.1.2 Consumer habits 5 4.1.3 Exposure levels 5 An
12、nex A (informative) Published guideline values . 7 Bibliography 8 BS EN 16739:2015EN 16739:2015 (E) 3 European foreword This document (EN 16739:2015) has been prepared by Technical Committee CEN/TC 421 “Project Committee - Emission safety of combustible air fresheners”, the secretariat of which is h
13、eld by UNI. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2016, and conflicting national standards shall be withdrawn at the latest by May 2016. Attention is drawn to the possibility that so
14、me of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to imp
15、lement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romani
16、a, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. BS EN 16739:2015EN 16739:2015 (E) 4 1 Scope This European standard specifies the methodology for the assessment of test results from the emissions of a combustible air freshener, when tested according to EN 16738 and f
17、ollows REACH Guidance and consumer habits and practices to produce a consumer exposure assessment. It provides reference to published emission limit or guidance values. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensa
18、ble for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 16738:2015, Emission safety of combustible air fresheners Test methods 3 Terms and definitions For the purposes
19、of this document, the terms and definitions given in EN 16738:2015 and the following apply. 3.1 exposure assessment process of measuring or estimating the concentrations, frequency and duration of consumer exposure to a chemical compound released in the environment, or estimating future exposures fo
20、r a chemical compound that has not yet been released 3.2 Time Weighted Average Concentration TWA average concentration to which the consumer is exposed during a week 3.3 unit specific emission rate SERuproduct specific rate describing the mass of a volatile organic compound emitted per unit of produ
21、ct per unit of time at a given time from the start of the test 4 Requirements 4.1 Assessment of consumer exposure 4.1.1 Consumer exposure based on habits and practices The approach and default values described under the European Chemicals Regulation “REACH (EC) N 1907/2006 have been used to estimate
22、 potential human inhalation exposures to chemicals released from consumer products. The following models can be used to estimate human indoor exposures to combustible air freshener emissions on the basis of their emission rates: ConsExpo 1-Box Model, RIVM 2; 2-Box Indoor Air Dispersion Model develop
23、ed by the RIFM 3; CONTAM Building Model 4. BS EN 16739:2015EN 16739:2015 (E) 5 These models can be used to determine peak and time-weighted average consumer exposure concentrations at maximum emission rates resulting from the use of the combustible air fresheners using the default room size and air
24、exchange rate stated in Table 1. Table 1 Default values afor room size and air exchange rate Room size (RV) 30 m3Air exchange rate (VR) 0,5 h1aValues to be used in absence of reliable specific data. 4.1.2 Consumer habits 4.1.2.1 Scented candles The consumer use pattern was based on a use behaviour s
25、tudy commissioned by the Belgium Ministry of Health and completed by the market research organization IPSOS 1. This study reported that the daily average use of scented candles is 2,4 h in the living room, 2 h in the adults room and 1,9 h in the kitchen and dining area. This study also reported that
26、 between 7 and 10 candles are used by consumers over a monthly period. To assume a reasonable worst case, an exposure for 4 h per day in an average sized living room of 30 m3and a weekly usage of 4 is suggested. Therefore the following values are default values. Table 2 Default values afor scented c
27、andles Frequency of use 4 days per week Exposure time 4 h per day aValues to be used in absence of reliable specific data. 4.1.2.2 Other Combustible Air Fresheners For other combustible air fresheners, the frequency of use and the exposure time should be determined on a case by case basis. 4.1.3 Exp
28、osure levels The models listed above serve to translate a measured emission rate of the substance of interest to: 1) Short term peak (consumer exposure) concentration STPC over the measurement period (g/m3) is given by the formula: ( )( )( ) ( )=u331SER g hSTPC g mRV m VR h2) Worst case time weighte
29、d average (TWA) consumer exposure concentration (g/m3) according to the following formula: ( )( )( ) ( )= u331SER g hTWA g m AUFRV m VR hBS EN 16739:2015EN 16739:2015 (E) 6 where uSER = emission rate (g/h), RV = room volume (m3), VR = ventilation rate (h-1), AUF (Average Use Factor) = Exposure time
30、h per day/24 (h) x Frequency of use (day)/7 (day) Comparison of test results with relevant published indoor air limits: = /1CF CONC SLV where CF = Compliance Factor CONC = concentration (STPC or TWA) (g/m3) SLV = Selected Limit Value (g/m3) NOTE Indoor air concentration of a specific substance is us
31、ually attributed to more than one source. The contribution part of the product assessed is integrated in the process of defining the Selected Limit Value. It can be based for example on the published guideline values in Annex A, using a contribution factor which attributes a proportion of this maxim
32、um value to the product assessed. BS EN 16739:2015EN 16739:2015 (E) 7 Annex A (informative) Published guideline values Table A.1 Published guideline values Compound Cas N. CLP classification 5 INDEX 6 (g/m3) WHO 7 (g/m3) BENZENE 71432 Flammable Liquid: Category 2 Aspiration Toxicity: Category 1 Skin
33、 Irritation: Category 2 Eye Irritation: Category 2 Mutagenicity: Category1B Carcinogenicity: Category 1A STOT RE a: Category 1 None set 0,17 (air concentration for excess lifetime risk of leukaemia = 1/1 000 000) FORMALDEHYDE 50000 Acute Toxicity: Category 3 if swallowed, in contact with skin and if
34、 inhaled Skin Corrosion: Category 1B Skin Sensitization: Category 1 Carcinogenicity: Category 1B from 1st January 2016 30 100 (30-min average concentration). NAPTHALENE 91203 Acute Toxicity: Category 4 if swallowed Carcinogenicity: Category 2 Aquatic Acute Toxicity: Category 1 Aquatic Chronic Toxici
35、ty: Category 1 10 10 (yearly average) SO27446095 Skin Corrosion: category 1B Acute Toxicity: Category 3 if inhaled None set 20 (24-h-mean) 500 (10-min mean) NO210102440 Ox. Gas 1 Skin Corr. 1B Acute Tox. 2 if inhaled 40 (yearly average) 40 (yearly average) 200 (1-h mean) NO 10102439 Oxidizing Gas: C
36、ategory 1 Skin Corrosion: Category 1B Eye Damage: Category 1 Acute Toxicity: Category 1 if inhaled STOT RE a: Category 2 None set None set CO 630080 Reprotoxicity 1A, Acute Toxicity: 3, STOT 1 None set 100 000 (15 min), 35 000 (1 h), 10 000 (8 h), 7000 (24 h) a: STOT RE = Specific target organ toxic
37、ity repeated exposure BS EN 16739:2015EN 16739:2015 (E) 8 Bibliography 1 IPSOS, Analysis of air freshener shopping and consumer behaviour, Study conducted by the Market Research. Institute IPSOS, on the order of the Belgium Federal Public Service of Health, Food Chain Safety and Environment, Ref. 88
38、8BZ01, 2006 2 RIVM. ConsExpo 5.0 beta version, Consumer exposure model, Dutch National Institute for Public Health and the Environment. RIVM, 2012 3 RIFM. Estimating inhalation exposure to fragrance materials in air freshening products using a two-zone residential indoor air dispersion model; 2011,
39、Poster presented by the Research Institute of Fragrance Materials (RIFM) at the annual Society of Toxicology (SOT) Meeting in Salt Lake City, 711 March 2010 4 NIST. CONTAM multizone building modelling program. National Institute of Standards and Technology, Gaithersburg, MD, 2010 5 REGULATION (EC) N
40、o 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 6 The INDEX project Critical Appraisal of the Se
41、tting and Implementation of Indoor Exposure Limits in the EU European Commission, Joint Research Centre, Institute for Health and Consumer Protection,Physical and Chemical Exposure Unit, Ispra, Italy (JRC/IHCP/PCE) 7 WHO guidelines for indoor air quality:selected pollutants 8 Guidance on information
42、 requirements and chemical safety assessment, Chapter R.15: Consumer exposure estimation (ECHA 10- G-03-EN- October 2012) This page deliberately left blankBSI is the national body responsible for preparing British Standards and other standards-related publications, information and services.BSI is in
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