BS EN 27201-1-1990 Fire protection - Fire extinguishing media - Halogenated hydrocarbons - Specifications for halon 1211 and halon 1301《防火 灭火介质 卤代烃 聚四氟乙烯1211和1301规格》.pdf

1、BRITISH STANDARD BSEN 27201-1:1994 ISO7201-1: 1989 Incorporating Amendment No.1 Fire protection Fire extinguishing media Halogenated hydrocarbons Part1: Specification for halon 1211 andhalon 1301 The European Standard EN 27201-1:1994 has the status of a British Standard UDC 614.842.612; 661.723BSEN2

2、7201-1:1994 This BritishStandard, having been prepared under the directionof the Fire Standards Policy Committee, was publishedunder the authority ofthe Board of BSI and comesintoeffect on 31October1990 BSI04-2000 First published November1984 Second edition October1990 The following BSI references r

3、elate to the work on this standard: Committee reference FSM/15 Draft (reference ISO) announced in BSI News March1990 ISBN 0 580 19019 6 Committees responsible for this BritishStandard The preparation of this BritishStandard was entrusted by the Fire Standards Policy Committee (FSM/-) to Technical Co

4、mmittee FSM/15, upon which the following bodies were represented: British Fire Protection Systems Association Ltd. Chemical Industries Association Chief and Assistant Chief Fire Officers Association Department of the Environment (Property Services Agency) Engineering Equipment and Materials Users As

5、sociation Fire Extinguishing Trades Association Home Office Institute of Petroleum Institution of Fire Engineers London Fire and Civil Defence Authority Loss Prevention Council Ministry of Defence Society of Fire Protection Engineers The following bodies were also represented in the drafting of the

6、standard, through sub-committees and panels: Department of Health Department of Transport (Marine Directorate) Fire Industry Council Amendments issued since publication Amd. No. Date Comments 8141 July1994 Indicated by a sideline in the marginBSEN27201-1:1994 BSI 04-2000 i Contents Page Committees r

7、esponsible Inside front cover National foreword ii Foreword 2 1 Scope 3 2 Normative references 3 3 Definition 3 4 Requirements 3 5 Sampling 3 6 Methods of test 3 7 Packaging and labelling 4 Annex A (informative) General properties 5 Annex A (informative) A-Deviations 5 Table 1 Requirements 3 Table A

8、.1 Physical properties of halons 1211 and 1301 5 Publication(s) referred to Inside back coverBSEN27201-1:1994 ii BSI 04-2000 National foreword This Part of this BritishStandard has been prepared under the direction of the Fire Standards Policy Committee and is one of a series currently being prepare

9、d, both nationally and internationally, covering fire extinguishing media. It is identical with ISO7201 “Fire protection Fire extinguishing media Halogenated hydrocarbons” Part1:1989 “Specifications for halon1211 and halon1301”, published by the International Organization for Standardization. Itis a

10、 new edition, containing editorial and other corrections toBS6535-2:1984, which was identical with ISO7201:1984. It is renumbered as Section2.1 as a consequence of the publication of BS6535-2.2 Code of practice for safe handling and transfer procedures. This edition supersedes BS6535-2:1984 which is

11、 withdrawn. In1994 the European Committee for Standardization (CEN) accepted ISO7201-1:1989 as European Standard EN27201-1:1994. As a consequence of implementing the European Standard, this BritishStandard is renumbered asBS EN27201-1 and any reference to BS6535-2.1 should be read as a reference toB

12、S EN27201-1. Marking. With reference to7.2 d), containers may, alternatively, be marked with the number of this BritishStandard, i.e.BS6535-2.1:1990 1) . The International Standard has a foreword which is as follows. “This International Standard is one of a series giving specifications for fire exti

13、nguishing media in common use and which are in need of standardization for fire fighting purposes. These specifications are designed to establish that the medium in question has at least a minimum useful fire extinguishing capability and can therefore be reasonably sold for fire extinguishing purpos

14、es. Requirements for media used in particular equipment will form the subject of future International Standards.” Cross-references International Standard Corresponding BritishStandard ISO3363:1976 BS5598 Methods of sampling and test for halogenated hydrocarbons Part6:1979 Determination of acidity of

15、 Fluorochlorinated hydrocarbons (Identical) ISO3427:1976 Part2:1979 Sampling of liquefied gases (Identical) ISO5789:1979 Part8:1980 Determination of non-volatile residue in fluourinated hydrocarbons (Identical) 1) “Marking BS6535-2.1:1990 on or in relation to a product represents a manufacturers dec

16、laration of conformity, i.e.a claim by or on behalf of the manufacturer that the product meets the requirements of the standard. The accuracy of the claim is therefore solely the responsibility of the person making the claim. Such a declaration is not to be confused with third party certification of

17、 conformity, which may also be desirable”.BSEN27201-1:1994 BSI 04-2000 iii A British Standard does not purport to include all the necessary provisions of a contract. Users of British Standards are responsible for their correct application. Compliance with a British Standard does not of itself confer

18、 immunity from legal obligations. Summary of pages This document comprises a front cover, an inside front cover, pagesi toiv, theENtitle page, pages2 to6, an inside back cover and a back cover. This standard has been updated (see copyright date) and may have had amendments incorporated. This will be

19、 indicated in the amendment table on the inside front cover.iv blankEUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN27201-1 May1994 UDC 614.842.612:661.723 Descriptors: Fire protection, fire extinguishing installations, hydrocarbons, halohydrocarbons, specifications, safety, tests English versio

20、n Fire protection Fire extinguishing media Halogenated hydrocarbons Part1:Specificationsforhalon1211andhalon1301 (ISO7201-1:1989) Protection contre lincendie Agents extincteurs Hydrocarbures halognes Partie1: Spcifications pour les halons1211 et1301 (ISO7201-1:1989) Brandbekmpfung Lschmittel Halogen

21、ierte Kohlenwasserstoffe Teil1: Spezifikationen fr Halon1211 undHalon1301 (ISO7201-1:1989) This European Standard was approved by CEN on1994-05-16. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of

22、 a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the Central Secretariat or to any CEN member. This European Standard exists in three official versions (English, French, German). A versio

23、n in any other language made by translation under the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Denmark, Finland, France, Germany, Greec

24、e, Iceland, Ireland, Italy, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland andUnitedKingdom. CEN European Committee for Standardization Comit Europen de Normalisation Europisches Komitee fr Normung Central Secretariat: rue de Stassart 36, B-1050 Brussels 1994 Copyright reserve

25、d to CEN members Ref. No. EN27201-1:1994 EEN27201-1:1994 BSI 04-2000 2 Foreword The endorsement of the International Standard ISO7201-1:1989 as a European Standard was recommended by the Technical Committee CEN/TC191, the secretariat of which is held by BSI, on 1992-10-20. The text of the Internatio

26、nal Standard ISO7201-1:1989 was approved by CEN as a European Standard without any modification. This European Standard is only available in the English and French versions. In accordance with CEN Regulations the foreword to the ISO standard is not included in this European Standard. The following w

27、arning which does not appear in the foreword to the ISO standard, is included here with the agreement of CEN/TC 191. WARNING. Halon 1211 and halon 1301 are listed in the Montreal Protocol on Substances that Deplete the Ozone Layer. There are agreements which limit their use. Users of this European S

28、tandard are advised to consult the relevant authorities on these matters when supplying or handling halon 1211 or halon 1301. Compliance with this European Standard does not in itself confer immunity from legal obligations. This European Standard shall be given the status of a national standard, eit

29、her by publication of an identical text or by endorsement, at the latest by November1994, and conflicting national standards shall be withdrawn at the latest by November1994. In accordance with the CEN/CENELEC Internal Regulations, the following countries are bound to implement this European Standar

30、d: Austria, Belgium, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and the UnitedKingdom.EN27201-1:1994 BSI 04-2000 3 1 Scope This part of ISO7201 specifies requirements for the following halogenated hydrocar

31、bons for use as fire extinguishing media: a) halon1211 bromochlorodifluoromethane (CF 2 ClBr); b) halon1301 bromotrifluoromethane (CF 3 Br). This part of ISO7201 does not deal with the conditions of use of these products in fire fighting equipment. Such equipment (portable fire extinguishers, fixed

32、installations, etc.) will be dealt with in future International Standards. 2 Normative references The following standards contain provisions which, through reference in this text, constitute provisions of this part of ISO7201. At the time of publication, the editions indicated were valid. All standa

33、rds are subject to revision, and parties to agreements based on this part of ISO7201 are encouraged to investigate the possibility of applying the most recent editions of the standards indicated below. Members of IEC and ISO maintain registers of currently valid International Standards. ISO3363:1976

34、, Fluorochlorinated hydrocarbons for industrial use Determination of acidity Titrimetric method. ISO3427:1976, Gaseous halogenated hydrocarbons (liquified gases) Taking of a sample. ISO5789:1979, Fluorinated hydrocarbons for industrial use Determination of non-volatile residue. 3 Definition For the

35、purpose of this part of ISO7201, the following definition applies. halon a halogenated hydrocarbon used as a fire extinguishing medium NOTEThe following numbering system is used to identify halons. The word “halon” is followed by a number, usually of four digits, giving, in turn, the number of carbo

36、n, fluorine, chlorine and bromine atoms. Terminal zeros are omitted. Thus halon1211 is bromochlorodifluorobromomethane (CF 2 ClBr) and halon1301 is bromotrifluoromethane (CF 3 Br). 4 Requirements Halons1211 and1301 shall comply with the requirements of Table 1, when tested by the appropriate method

37、of test specified in clause6. Table 1 Requirements 5 Sampling Samples of halons shall be taken from the manufacturers shipping container using the method specified in ISO3427. 2) 6 Methods of test 6.1 General For all tests, the sample shall be taken from the liquid phase. 6.2 Purity Determine the pu

38、rity by gas-liquid chromatography, using generally accepted laboratory techniques. 6.3 Acidity Determine the acidity by the appropriate method specified in ISO3363. 6.4 Water content Determine the water content by the orthodox KarlFischer method or by any other method giving equivalent results. Prop

39、erty Requirements Halon1211 Halon1301 Purity,% (mol/mol) min. Acidity, ppm by mass, max. Water content, ppm bymass, max. Non-volatile residue, %(m/m) max. Halogen ion Suspended matter or sediment 99,0 3,0 20 0,01 Passes test None visible 99,6 3,0 10 0,01 Passes test None visible 2) The sampling bott

40、le should be capable of safely resisting the vapour pressure of the sample at the highest temperature that could be encountered.EN27201-1:1994 4 BSI 04-2000 6.5 Non-volatile residue Determine the non-volatile residue by the method specified in ISO5789. 6.6 Halogen ions Mix5g of the sample with5ml of

41、 absolute methanol containing several drops of a saturated methanolic silver nitrate (AgNO 3 ) solution. The resulting solution shall exhibit no turbidity or precipitation of silver halide. 6.7 Suspended matter or sediment Examine the liquid phase of the sample visually. 7 Packaging and labelling 7.

42、1 Halons shall be shipped and stored in containers which will not alter the medium or be detrimentally affected by it. NOTEThe containers may need to comply with national regulations. 7.2 Containers shall be marked with the following information: a) suppliers name and address; b) “Halon1211” or “Hal

43、on1301”, as appropriate; c) package identification number; d) the number of this part of ISO7201, i.e.ISO7201-1; e) recommended storage precautions.EN27201-1:1994 BSI 04-2000 5 Annex A (informative) General properties A.1 Physical properties Halon 1211 is a colourless, faintly-smelling gas. Halon 13

44、01 is an odourless gas. A number of their other more important physical properties are given in Table A.1. A.2 Electrical conductivity Halons 1211 and 1301 have a very low electrical conductivity. In many cases they can be used to extinguish fires involving live electrical equipment, but this, to a

45、significant extent, may depend on the circumstances, particularly the method of discharge. In case of doubt, reference should be made to the instructions on the fire extinguishing equipment to be used. Table A.1 Physical properties of halons 1211 and 1301 Annex A (informative) A-Deviations A-Deviati

46、on: National deviation due to regulations, the alteration of which is for the time being outside the competence of the CEN/CENELEC member. This European Standard does not fall under any directive of the EC. In the relevant CEN/CENELEC countries these A-Deviations are valid instead of the provisions

47、of the European Standard until they have been removed. Property Halon 1211 Halon 1301 Relative molecular mass Boiling point at 1,013 bar a , C Freezing point, C Critical temperature, C Critical pressure, bar Critical volume, m 3 /kg Critical density, kg/m 3 Vapour pressure at 20 C, bar at 60 C, bar

48、Liquid density at 20 C, kg/m 3 Saturated vapour density at 20 C, kg/m 3 Specific volume of superheated vapour at1,013 bar and 20 C, m 3 /kg 165,38 4,0 160,5 153,8 42,06 0,001 41 713 2,53 7,20 1 830 17,4 0,145 148,93 57,8 168,0 67,0 39,6 0,001 34 745 14,63 34,58 1 575 115,6 0,159 a 1 bar = 10 5Pa Cla

49、use Deviation Sweden (SFS, Ordinance of CFCs, halons, etc. 1988:716) Note the following: Section6a Hand-held fire extinguishers containing halons may not be manufactured, sold, recharged or imported on a professional basis. Section6b The prohibitions in section6a do not apply to fire extinguishing systems and hand-held fire extinguishers in: 1) aircraft and submarines; 2) combat vehicles belonging to the Defense Force; 3) action information centres belonging to the Defence Force on vessels and below ground.