BS EN 62259-2004 Secondary cells and batteries containing alkaline or other non-acid electrolytes - Nickel-cadmium prismatic secondary single cells with partial gas recombination《含.pdf

1、BRITISH STANDARD BS EN 62259:2004 Secondary cells and batteries containing alkaline or other non-acid electrolytes Nickel-cadmium prismatic secondary single cells with partial gas recombination The European Standard EN 62259:2004 has the status of a British Standard ICS 29.220.99 BS EN 62259:2004 Th

2、is British Standard was published under the authority of the Standards Policy and Strategy Committee on 17 February 2004 BSI 17 February 2004 ISBN 0 580 43450 8 National foreword This British Standard is the official English language version of EN 62259:2004. It is identical with IEC 62259:2003. The

3、 UK participation in its preparation was entrusted to Technical Committee PEL/21/1, Secondary cells and batteries containing alkaline and other non-acidic electrolytes, which has the responsibility to: A list of organizations represented on this committee can be obtained on request to its secretary.

4、 Cross-references The British Standards which implement international or European publications referred to in this document may be found in the BSI Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Search” facility of the BSI Electronic Catalogue o

5、r of British Standards Online. This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. aid enquirers to understand the tex

6、t; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and keep the UK interests informed; monitor related international and European developments and promulgate them in the UK. Summary of pages This document comprises a front cov

7、er, an inside front cover, the EN title page, pages 2 to 18, an inside back cover and a back cover. The BSI copyright notice displayed in this document indicates when the document was last issued. Amendments issued since publication Amd. No. Date CommentsEUROPEAN STANDARD EN 62259 NORME EUROPENNE EU

8、ROPISCHE NORM January 2004 CENELEC European Committee for Electrotechnical Standardization Comit Europen de Normalisation Electrotechnique Europisches Komitee fr Elektrotechnische Normung Central Secretariat: rue de Stassart 35, B - 1050 Brussels 2004 CENELEC - All rights of exploitation in any form

9、 and by any means reserved worldwide for CENELEC members. Ref. No. EN 62259:2004 E ICS 29.220.99 English version Secondary cells and batteries containing alkaline or other non-acid electrolytes Nickel-cadmium prismatic secondary single cells with partial gas recombination (IEC 62259:2003) Accumulate

10、urs alcalins et autres accumulateurs lectrolyte non acide - Elments daccumulateurs individuels paralllpipdiques au nickel-cadmium recombinaison partielle des gaz (CEI 62259:2003) Sekundrzellen und -batterien mit alkalischem oder anderen nichtsurehaltigen Elektrolyten - Wiederaufladbare prismatische

11、Nickel- Cadmium-Einzelzellen mit teilweiser Gasrekombination (IEC 62259:2003) This European Standard was approved by CENELEC on 2003-12-01. CENELEC members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a n

12、ational standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the Central Secretariat or to any CENELEC member. This European Standard exists in three official versions (English, French, German). A versio

13、n in any other language made by translation under the responsibility of a CENELEC member into its own language and notified to the Central Secretariat has the same status as the official versions. CENELEC members are the national electrotechnical committees of Austria, Belgium, Czech Republic, Denma

14、rk, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Foreword The text of document 21A/386/FDIS, future edition 1 of IEC 62259,

15、prepared by SC 21A, Secondary cells and batteries containing alkaline or other non-acid electrolytes, of IEC TC 21, Secondary cells and batteries, was submitted to the IEC-CENELEC parallel vote and was approved by CENELEC as EN 62259 on 2003-12-01. The following dates were fixed: latest date by whic

16、h the EN has to be implemented at national level by publication of an identical national standard or by endorsement (dop) 2004-09-01 latest date by which the national standards conflicting with the EN have to be withdrawn (dow) 2006-12-01 Annex ZA has been added by CENELEC. _ Endorsement notice The

17、text of the International Standard IEC 62259:2003 was approved by CENELEC as a European Standard without any modification. In the official version, for Bibliography, the following notes have to be added for the standards indicated: IEC 60622 NOTE Harmonized as EN 60622:2003 (not modified). IEC 60623

18、 NOTE Harmonized as EN 60623:2001 (not modified). _ Page2 EN62259:2004Page2 EN62259:2004CONTENTS INTRODUCTION.4 1 Scope.5 2 Normative references.5 3 Terms and definitions .6 4 Parameter measurement tolerances.6 5 Designation and marking7 5.1 Cell designation7 5.2 Cell termination.7 5.3 Marking.7 5.4

19、 Safety recommendations.7 6 Dimensions7 7 Electrical tests8 7.1 Charging procedure for test purposes8 7.2 Discharge performance.8 7.3 Charge retention.10 7.4 Endurance.11 7.5 Charge acceptance at constant voltage.12 7.6 Overcharge.12 7.7 Vent operation.12 7.8 Electrolyte retention13 7.9 Determinatio

20、n of gas recombination efficiency.13 7.10 Storage.15 8 Mechanical tests.15 9 Physical appearance15 10 Conditions for approval and acceptance .15 10.1 Type approval.15 10.2 Batch acceptance16 Annex ZA (normative) Normative reference to international publications with their corresponding European publ

21、ications .17 Bibliography18 Page3 EN62259:2004INTRODUCTION Traditionally the manufacturers and users of alkaline secondary cells and batteries have expressed the current used to charge and discharge these cells and batteries as a multiple of the capacity. For example, a current of 20 A used to charg

22、e a cell with a rated capacity (C Ah) of 100 Ah would be expressed as C/5 A or 0,2 C A. This method of current designation has been used in earlier standards relating to alkaline secondary cells and batteries. Comments have been made, however, that this method of current designation is dimensionally

23、 incorrect in that a multiple of the capacity (ampere-hours) will be in ampere- hours and not, as required for current, in amperes. As a result of these comments, the method described in IEC 61434 has been used in this standard. In brief, the method states the reference test current (I t ) is expres

24、sed as I tA = C n Ah/1h where C nis the rated capacity declared by the manufacturer in ampere hours (Ah), and n is the time base in hours (h) for which the rated capacity is declared. Page4 EN62259:2004SECONDARY CELLS AND BATTERIES CONTAINING ALKALINE OR OTHER NON-ACID ELECTROLYTES NICKEL-CADMIUM PR

25、ISMATIC SECONDARY SINGLE CELLS WITH PARTIAL GAS RECOMBINATION 1 Scope This International Standard specifies marking, designation, dimensions, tests and require- ments for vented nickel-cadmium prismatic secondary single cells where special provisions have been made in order to have partial or, under

26、 very specific conditions, full gas recombination. NOTE In this context, “prismatic“ refers to cells having rectangular sides and base. When there exists an IEC standard specifying test conditions and requirements for cells used in special applications and which is in conflict with this standard, th

27、e former shall take precedence. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) app

28、lies. IEC 60050-486, International Electrotechnical Vocabulary (IEV) Chapter 486: Secondary cells and batteries IEC 60051 (all parts), Direct acting indicating analogue electrical measuring instruments and their accessories IEC 60410, Sampling plans and procedures for inspection by attributes IEC 60

29、417-DB:2002 1 , Graphical symbols for use on equipment IEC 60485, Digital electronic d.c. voltmeters and d.c. electronic analogue-to-digital converters IEC 61434, Secondary cells and batteries containing alkaline or other non-acid electrolytes Guide to the designation of current in alkaline secondar

30、y cell and battery standards IEC 61438, Possible safety and health hazards in the use of alkaline secondary cells and batteries Guide to equipment manufacturers and users 1“DB” refers to the IEC on-line database. Page5 EN62259:20043 Terms and definitions For the purposes of this document, the terms

31、and definitions contained in IEC 60050-486 and the following apply. 3.1 vented cell a secondary cell having a cover provided with an opening through which gaseous products may escape NOTE The opening may be fitted with a venting system, which may include an overpressure vent. 3.2 nominal voltage the

32、 nominal voltage of a vented nickel-cadmium rechargeable single cell with partial gas recombination is 1,2 V 3.3 rated capacity quantity of electricity C 5 Ah (ampere hours), declared by the manufacturer, which a single cell can deliver during a 5 h period when charged, stored and discharged under t

33、he conditions specified in clause 7.2.1 3.4 partial gas recombination ability of a cell to recombine most of the gases evolved during charging under the conditions specified in 7.9 4 Parameter measurement tolerances The overall accuracy of controlled or measured values, relative to the specified or

34、actual values, shall be within these tolerances: a) + 1 % . for voltage; b) + 1 % for current; c) + 2 C for temperature; d) + 0,1 % for time; e) + 1 % for capacity; f) + 5 % for gas volume. These tolerances comprise the combined accuracy of the measuring instruments, the measurement techniques used

35、and all other sources of error in the test procedure. For assistance in selecting instrumentation, see IEC 60051 for analogue instruments and IEC 60485 for digital instruments. The details of the instrumentation used shall be provided in any report of results. Page6 EN62259:20045 Designation and mar

36、king 5.1 Cell designation Vented nickel-cadmium prismatic secondary cells with partial gas recombination shall be designated by the letter K which signifies cadmium, followed by the letter G which signifies partial gas recombination, and followed by a letter L, M, H or X which signifies: low rate of

37、 discharge (L); medium rate of discharge (M); high rate of discharge (H); very high rate of discharge (X ). NOTE These types of cells are typically but not exclusively used for the following discharge rates: L up to 0,5 I tA, M up to 3,5 I tA, H up to 7 I tA, X up to and above 7 I tA. This group of

38、three letters shall be followed by a group of figures indicative of the rated capacity of the cell in ampere-hours. Cells that have been tested at 20 C and 5 C but not at 18 C shall carry an additional marking of T5. For example: KGH 185 or KGH 185 T5. Cells in cases of plastic material shall be des

39、ignated by the letter “P“ after the figures. For example: KGH 185 P or KGH 185 P T5. 5.2 Cell termination This standard does not specify cell termination. 5.3 Marking Each cell or monobloc shall carry durable markings giving the following minimum information: designation as specified in 5.1 (In addi

40、tion, it is permissible for a manufacturer to use his own designation); name or identification of manufacturer or supplier; positive terminal: either a red washer or an indented or raised symbol, (see IEC 60417- 5005 DB-2002-10. 5.4 Safety recommendations The manufacturer shall provide recommendatio

41、ns for the safe handling of the cell. See also IEC 61438. 6 Dimensions No preferred dimensions are specified in this standard. Page7 EN62259:20047 Electrical tests Charge and discharge currents for the tests in accordance with 7.1 to 7.10 inclusive shall be based on the value of the rated capacity (

42、C 5Ah). These currents are expressed as a multiple of I tA, where I tA = C 5Ah / 1 h. 7.1 Charging procedure for test purposes Prior to charging, the cells shall have been discharged at 20 C 5 C, at a constant current of 0,2 I tA, down to a final voltage of 1,0 V. Unless otherwise specified in this

43、standard, the charge preceding the various discharge tests scheduled, shall be carried out in an ambient temperature of 20 C 5 C and at a constant current of 0,1 I tA. The duration of the charge shall be 14 h to 16 h. 7.2 Discharge performance The following discharge tests shall be carried out in th

44、e sequence given. All cells shall be tested at 20 C as well as at +5 C and / or 18 C. 7.2.1 Discharge performance at 20 C 7.2.1.1 Test procedure The cell shall have been charged in accordance with 7.1. After charging, the cell shall be stored for not less than 1 h and not more than 4 h in an ambient

45、 temperature of 20 C 5 C. It shall then be discharged in the same ambient temperature and as specified in Table 1. The discharge test with 0,2 I tA is performed in order to verify the rated capacity of the cell. Table 1 Discharge performance at 20 C Discharge conditions Minimum discharge duration Ra

46、te of constant current Final voltage Cell designation A V L M H X 0,2 I t1,0 5 h a5 h a5 h a5 h a1,0 I t1,0 - 38 min 48 min 54 min 5,0 I tb0,8 - - 2 min 30 s 6 min 30 s 10,0 I tb0,8 - - - 1 min 30 s aFive cycles are permitted for this test, which shall however be terminated at the end of the first c

47、ycle which meets the requirement. bBefore the 5 I tA and the 10 I tA tests, a conditioning cycle may be included if necessary. This cycle shall consist of charging at 0,1 I tA and discharging at 0,2 I tA in accordance with 7.1 and 7.2.1. 7.2.1.2 Acceptance criteria The duration of discharge shall be

48、 not less than the minimum specified in Table 1. Page8 EN62259:20047.2.2 Discharge performance at +5 C 7.2.2.1 Test procedure The cell shall have been charged in accordance with 7.1. After charging, the cell shall be stored in an ambient temperature of +5 C 2 C, for 24 h. Means shall be provided to

49、ensure that the electrolyte temperature has reached +5 C 2 C within 24 h. It shall then be discharged in the same ambient temperature and as specified in Table 2. Table 2 Discharge performance at +5 C Discharge conditions Minimum discharge duration Rate of constant current Final voltage Cell designation A V L M H X 0,2 I t1,0 3 h 24 min 3 h 42 min 3 h 54 min 4 h 18 min 1,0 I t1,0