BS EN ISO 105-C12-2006 Textiles - Tests for colour fastness - Colour fastness to industrial laundering《纺织品 色牢度试验 工业洗涤的色牢度》.pdf

1、 g49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58launderingThe European Standard EN ISO 105-C12:2006 has the status of a British StandardICS 97.060;

2、 59.080.01Textiles Tests for colour fastness Part C12 : Colour fastness to industrial BRITISH STANDARDBS EN ISO 105-C12:2006BS EN ISO 105-C12:2006This British Standard was published under the authority of the Standards Policy and Strategy Committee on 29 December 2006 BSI 2006ISBN 0 580 49818 2Amend

3、ments issued since publicationAmd. No. Date Commentscontract. Users are responsible for its correct application.Compliance with a British Standard cannot confer immunity from legal obligations.National forewordThis British Standard was published by BSI. It is the UK implementation of EN ISO 105-C12:

4、2006. It is identical with ISO 105-C12:2004. The UK participation in its preparation was entrusted to Technical Committee TCI/81, Colour fastness and colour measurement of textiles.A list of organizations represented on TCI/81 can be obtained on request to its secretary.This publication does not pur

5、port to include all the necessary provisions of a EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN ISO 105-C12February 2006ICS 97.060; 59.080.01English VersionTextiles - Tests for colour fastness - Part C12: Colour fastnessto industrial laundering (ISO 105-C12:2004)Textiles - Essais de solidit des

6、teintures - Partie C12:Solidit des teintures au lavage industriel (ISO 105-C12:2004)Textilien - Farbechtheitsprfungen - Teil C12: Farbechtheitgegen industrielle Wsche (ISO 105-C12:2004)This European Standard was approved by CEN on 16 January 2006.CEN members are bound to comply with the CEN/CENELEC

7、Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the Central Secretariat or to any CEN mem

8、ber.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the officialversions.CEN members ar

9、e the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania,Slovakia, Slovenia, Spain, Sweden, Switzerland and Un

10、ited Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2006 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN ISO 105-C12:20

11、06: EForeword The text of ISO 105-C12:2004 has been prepared by Technical Committee ISO/TC 38 “Textiles” of the International Organization for Standardization (ISO) and has been taken over as EN ISO 105-C12:2006 by Technical Committee CEN/TC 248 “Textiles and textile products“, the secretariat of wh

12、ich is held by BSI. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by August 2006, and conflicting national standards shall be withdrawn at the latest by August 2006. According to the CEN/CENELEC In

13、ternal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Net

14、herlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Endorsement notice The text of ISO 105-C12:2004 has been approved by CEN as EN ISO 105-C12:2006 without any modifications. EN ISO 105-C12:2006Reference numberISO 105-C12:2004(E)INTERNATION

15、AL STANDARD ISO105-C12First edition2004-11-01Textiles Tests for colour fastness Part C12: Colour fastness to industrial laundering Textiles Essais de solidit des teintures Partie C12: Solidit des teintures au lavage industriel EN ISO 105-C12:2006ii iiiForeword ISO (the International Organization for

16、 Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the

17、right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. Internatio

18、nal Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication a

19、s an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. I

20、SO 105-C12 was prepared by Technical Committee ISO/TC 38, Textiles, Subcommittee SC 1, Tests for coloured textiles and colorants. ISO 105 was previously published in thirteen “parts”, each designated by a letter (e.g., “Part A”), with publication dates between 1978 and 1985. Each part contained a se

21、ries of “sections”, each designated by the respective part letter and by a two-digit serial number (e.g., “Section A02”). These sections are being republished as separate documents, themselves designated “parts” but retaining their earlier alphanumeric designations. A complete list of these parts is

22、 given in ISO 105-A01. EN ISO 105-C12:2006iv Introduction The test method in this part of ISO 105 is intended to reflect the effect of comprehensive laundering during industrial laundry procedures, as distinct from the domestic washing test methods as given in ISO 105-C05, ISO 105-C06 and ISO 105-C0

23、8. Four test conditions are described, one at (92 2)C intended for the evaluation of workwear and three, as given below, at (75 2) C, for the evaluation of bed and table linen and corporate wear: without the addition of peroxy bleach compounds; with the addition of hydrogen peroxide (for the bleachi

24、ng of white work with coloured trimmings); with the addition of sodium perborate tetrahydrate and tetra-acetylethylene diamine (TAED) (for the bleaching of white work with coloured trimmings). NOTE The addition of TAED/perborate is a conveniently stable way of producing peracetic acid in situ. This

25、method of test does not reflect the effect of optical brightening agents. This method and the single cycle test methods described in ISO 105-C06 and ISO 105-C08 may not reproduce the effect of coloured fabrics treated with certain dye fixing agents and finishes after multiple (5 to 10) industrial wa

26、shes. EN ISO 105-C12:20061Textiles Tests for colour fastness Part C12: Colour fastness to industrial laundering 1 Scope This part of ISO 105 specifies methods for determining the resistance of the colour of textiles of all kinds exposed to all forms of industrial laundering procedures. One cycle app

27、roximates to the colour loss and cross staining resulting from chemical and/or mechanical action achieved after multiple (5 to 10) industrial launderings. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the

28、edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 105-A01:1994, Textiles Tests for colour fastness Part A01: General principles of testing ISO 105-A02, Textiles Tests for colour fastness Part A02: Grey scale for asses

29、sing change in colour ISO 105-A03, Textiles Tests for colour fastness Part A03: Grey scale for assessing staining ISO 105-A04, Textiles Tests for colour fastness Part A04: Method for the instrumental assessment of the degree of staining of adjacent fabrics ISO 105-A05, Textiles Tests for colour fast

30、ness Part A05: Instrumental assessment of change in colour for determination of grey scale rating ISO 105-F02, Textiles Tests for colour fastness Part F02: Specification for cotton and viscose adjacent fabrics ISO 105-F04, Textiles Tests for colour fastness Part F04: Specification for polyester adja

31、cent fabric ISO 105-F10:1989, Textiles Tests for colour fastness Part F10: Specification for reference adjacent fabric: Multifibre ISO 139, Textiles Standard atmospheres for conditioning and testing 3 Principle A specimen of the textile in contact with specified adjacent fabrics is laundered, rinsed

32、 and dried. Specimens are laundered under appropriate conditions of temperature, alkalinity, bleaching and mechanical action such that the result is obtained in a conveniently short time. The mechanical action is accomplished by the use of an appropriate number of steel balls. The change in colour o

33、f the specimens and the staining of the adjacent fabrics are assessed using the grey scale. EN ISO 105-C12:20062 4 Reagents NOTE All chemicals should be of at least general purpose laboratory grade. 4.1 Detergent, as specified in Annex A. 4.2 Solution, containing 0,2 g/l of glacial acetic acid, if r

34、equired for souring treatment. 4.3 Hydrogen peroxide solution, 30 %. 4.4 Sodium hydroxide (NaOH) pellets. 4.5 Tetra-acetylethylenediamine (TAED). 4.6 Sodium perborate tetrahydrate. 4.7 Distilled water, grade 3 water (see 8.2 of ISO 105-A01:1994) 5 Apparatus 5.1 Suitable mechanical device, consisting

35、 of a water bath containing a rotatable shaft which supports, radially, stainless steel containers (75 5) mm diameter (125 10) mm high of capacity (550 50) ml, the bottom of the containers being (45 10) mm from the centre of the shaft. The shaft/container assembly is rotated at a frequency of (40 2)

36、 min1. The temperature of the water bath is thermostatically controlled to maintain the test solution at the prescribed temperature ( 2)C. NOTE Other mechanical devices may be used for this test, provided that the results are identical with those obtained by the apparatus described. 5.2 Mechanical s

37、tirrer, minimum (1 100 100) min1or equivalent, to ensure dispersion and prevent settling. 5.3 Steel balls, non-corrodible (stainless), approximately 6,0 mm in diameter. 5.4 Adjacent fabrics. 5.4.1 A multifibre adjacent fabric complying to type (TV) of ISO 105-F10:1989 or 5.4.2 Two single-fibre adjac

38、ent fabrics, one cotton and one polyester, in accordance with ISO 105-F02 and ISO 105-F04 or as otherwise specified between interested parties. 5.4.3 If required, a non-dyeable fabric (e.g. polypropylene) (e.g. to mechanically stabilize a knitwear specimen). 5.5 Grey scale, for assessing change in c

39、olour in accordance with ISO 105-A02, or instrumentally ISO 105-A05, and for assessing staining in accordance with ISO 105-A03, or instrumentally ISO 105-A04. 5.6 Flat-iron, of mass not exceeding 2,5 kg ( 100 g) and capable of giving the temperature indicated in 7.2.5, if a pressing treatment is req

40、uired. Condition the sample for 24 h before assessing to allow for temporary colour change caused by heat. EN ISO 105-C12:200636 Test specimens 6.1 Fabric specimen Cut two fabric test specimens each 80 mm 160 mm, one specimen in the warp direction and one specimen in the weft direction. In the case

41、of knitwear prepare two specimens. Weigh the two specimens to two decimal places (grams). Fold each specimen across the narrow dimension in the centre of the specimen with fabric face on the outside (see Figure 1). Using dimensionally stable thread, sew along the two sides to form a bag. Place 25 st

42、ainless steel balls inside each bag and seal by sewing. 6.2 Adjacent fabrics Either: a) cut a sample of multifibre TV adjacent fabric (5.4.1) and weigh to two decimal places (grams); or b) cut a sample 100 mm 80 mm, of the two single-fibre adjacent fabrics (5.4.2) and weigh to two decimal places (gr

43、ams). NOTE The two-fabric test specimen and adjacent staining fabrics are not sewn to each other. This allows fabric abrasion to occur. Dimensions in millimetes Key 1 fold line 2 folded edge 3 folded specimen aSew along two open sides. Figure 1 Preparation of test specimens EN ISO 105-C12:20064 7 Te

44、st procedures 7.1 Preparation of wash liquor 7.1.1 Tests without the addition of hydrogen peroxide Using the mixer (5.2), disperse 5 g/l of the industrial reference detergent (4.1) base powder (without optical brightener) in grade 3 water (4.7) at ambient temperature for (10 1) min. Add 1 g of sodiu

45、m hydroxide (4.4) per litre of solution. Using glacial acetic acid (4.2), adjust the pH to be within the range 12,0 to 12,5 and use immediately. Proceed as in 7.2. 7.1.2 Tests with the addition of hydrogen peroxide Using the mixer (5.2), disperse 5 g/l of the industrial reference detergent (4.1) bas

46、e powder (without optical brightener) in grade 3 water (4.7) at ambient temperature for (10 1) min. Add 1 g of sodium hydroxide (4.4) per litre of solution. Using glacial acetic acid (4.2), adjust the pH to be within the range 11,0 to 11,5. Add 2 ml of 30 % hydrogen peroxide (4.3) and use immediatel

47、y. Proceed as in 7.2. 7.1.3 Tests with the addition of sodium perborate and tetra acetylethylenediamine (peracetic acid) Using the mixer (5.2), disperse 5 g/l of the industrial reference detergent (4.1) base powder (without optical brightener), 2 g of sodium perborate tetrahydrate (4.6) and 0,3 g TA

48、ED (4.5) (100 % activity) in grade 3 water (4.7) at ambient temperature for (10 1) min. Using sodium hydroxide (4.4), adjust the pH to be within the range 10,0 to 10,5 and use immediately. Proceed as in 7.2. 7.2 Testing the specimens 7.2.1 To each container (see 5.1) add wash liquor at a ratio of 15

49、:1 liquor:fabric (i.e., 15 ml of solution for each gram of combined specimen weight). Place both the prepared test specimens and the separate adjacent fabric in the container together with an additional 25 stainless steel balls (5.3). Close the containers, place them in the machine (5.1), commence rotation and raise the temperature at a rate of (1,5 0,5) C/min to the temperature specified in Table 1. Continue to run the test for a further 60 min a