BS EN ISO 105-Z05-1998 Textiles - Tests for colour fastness - Determination of the dusting behaviour of dyes《纺织品 色牢度试验 染料粉化作用测定》.pdf

1、BRITISH STANDARD BS EN ISO 105-Z05:1998 Textiles Tests for colour fastness Part Z05: Determination of the dusting behaviour of dyes The European Standard EN ISO105-Z05:1998 has the status of a British Standard ICS59.080.01; 59.080.10BSEN ISO 105-Z05:1998 This British Standard, having been prepared u

2、nder the directionof the Sector Board for Materials and Chemicals, was published under the authority of the Standards Board and comes intoeffect on 15 July 1998 BSI 04-1999 ISBN 0 580 29972 4 National foreword This British Standard is the English language version of EN ISO105-Z05:1998. It is identic

3、al with ISO105-Z05:1996. The UK participation in its preparation was entrusted by Technical Committee TCI/25, Chemical properties, to Subcommittee TCI/25/-/10, Colour fastness, which has the responsibility to: aid enquirers to understand the text; present to the responsible international/European co

4、mmittee any enquiries on the interpretation, or proposals for change, and keep the UK interests informed; monitor related international and European developments and promulgate them in the UK. A list of organizations represented on this subcommittee can be obtained on request to its secretary. Cross

5、-references Attention is drawn to the fact that CEN and CENELEC standards normally include an annex which lists normative references to international publications with their corresponding European publications. The British Standards which implement these international or European publications may be

6、 found in the BSI Standards Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “Find” facility of the BSI Standards Electronic Catalogue. A British Standard does not purport to include all the necessary provisions of a contract. Users of British Stan

7、dards are responsible for their correct application. Compliance with a British Standard does not of itself confer immunity from legal obligations. Summary of pages This document comprises a front cover, an inside front cover, pagesi andii, theEN ISOtitle page, page2, the ISO title page, pages ii to

8、iv, pages1to10, an inside back cover and a back cover. This standard has been updated (see copyright date) and may have had amendments incorporated. This will be indicated in the amendment table on the inside front cover. Amendments issued since publication Amd. No. Date CommentsBSENISO105-Z05:1998

9、BSI 04-1999 i Contents Page National foreword Inside front cover Foreword 2 Foreword iii Text of ISO105-Z05 1ii blankEUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO105-Z05 March 1998 ICS59.080.01 Descriptors: See ISO document English version Textiles Tests for colour fastness Part Z05: Dete

10、rmination of the dusting behaviour of dyes (ISO105-Z05:1996) Textiles Essais de solidit des teintures Partie Z05:Dtermination du comportement des colorants au saupoudrage (ISSO105-Z05:1996) Textilien Farbechtheitsprfungen TeilZ05:Bestimmung des Staubverhaltens vonFarbstoffen (ISO105-Z05:1996) This E

11、uropean Standard was approved by CEN on 14 February 1998. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical referenc

12、es concerning such national standards may be obtained on application to the Central Secretariat or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into

13、its own language and notified to the Central Secretariat has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, CzechRepublic, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Luxembourg, Netherlands, Norway, Portugal, Spai

14、n, Sweden, Switzerland and United Kingdom. CEN European Committee for Standardization Comit Europen de Normalisation Europisches Komitee fr Normung Central Secretariat: rue de Stassart 36, B-1050 Brussels 1998 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN nati

15、onal Members. Ref. No. EN ISO105-Z05:1998 EENISO105-Z05:1998 BSI 04-1999 2 Foreword The text of the International Standard from Technical Committee ISO/TC38 “Textiles” of the International Organization for Standardization (ISO) has been taken over as an European Standard by Technical Committee CEN/T

16、C248 “Textiles and textile products”, the secretariat of which is held by BSI. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by September 1998, and conflicting national standards shall be withdrawn

17、 at the latest by September 1998. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, CzechRepublic, Denmark, Finland, France, Germany, Greece, Iceland, Ireland, Italy, Lux

18、embourg, Netherlands, Norway, Portugal, Spain, Sweden, Switzerland and the United Kingdom. Endorsement notice The text of the International Standard ISO105-Z05:1996 has been approved by CEN as a European Standard without any modification. NOTENormative references to International Standards are liste

19、d in Annex ZA (normative).ENISO105-Z05:1998 ii BSI 04-1999 Contents Page Foreword iii Introduction 1 1 Scope 1 2 Normative references 1 3 Definition 1 4 Principle 1 5 Apparatus 1 6 Procedure 4 7 Assessment of filter 4 8 Expression of results 5 9 Test report 5 Annex A (informative) Reproducibility of

20、 the method 6 Annex B (informative) Bibliography 10 Annex ZA (normative) Normative references to international publications with their relevant European publications Inside back cover Figure 1 Typical graphical representations of the amount of dyestuff dust (by volume) as a function of the dust-part

21、icle diameter 2 Figure 2 Apparatus for dust determination 3 Figure 3 Filter holder 4 Table A.1 Dusting behaviour of dyestuff1 7 Table A.2 Dusting behaviour of dyestuff2 8 Table A.3 Dusting behaviour of dyestuff3 9 Table A.4 Dusting behaviour Sample prepared without asample divider 10ENISO105-Z05:199

22、8 BSI 04-1999 iii Foreword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a sub

23、ject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (I

24、EC) on all matters of electrotechnical standardization. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least75% of the member bodies casting a vote. International Stand

25、ard ISO105-Z05 was prepared by Technical Committee ISO/TC38, Textiles, Subcommittee SC1, Tests for coloured textiles and colorants. ISO105 was previously published in thirteen “parts”, each designated by a letter (e.g.“Part A”), with publication dates between 1978 and 1985. Each part contained a ser

26、ies of “sections”, each designated by the respective part letter and by a two-digit serial number (e.g.“Section A01”). These sections are now being republished as separate documents, themselves designated “parts” but retaining their earlier alphanumeric designations. A complete list of these parts i

27、s given in ISO105-A01. Annex A and Annex B of this part of ISO105 is for information only. Descriptors: Textiles, dyeing, colour fastness, powdery materials, dyes, tests, colour-fastness tests, determination, properties.iv blankENISO 105-Z05:1998 BSI 04-1999 1 Introduction The dustiness of dyestuffs

28、 is an important feature when considering aspects of hygiene, health and safety in the dyestuff-consuming industry. It is important therefore that a reliable and reproducible method exists to measure this property. Although other methods for dust measurement exist, the method given in this part of I

29、SO105 is both more representative of and comparable with actual practice when handling dyestuffs. In respect of a comparison of dyestuffs or the reliability of limits, it should be understood that the resulting value is not a specific value like density. Details of reproducibility data are given in

30、Annex A. 1 Scope This part of ISO105 specifies a method for determination of the dusting behaviour of dyes. 2 Normative references The following standards contain provisions which, through reference in this text, constitute provisions of this part of ISO105. At the time of publication, the editions

31、indicated were valid. All standards are subject to revision, and parties to agreements based on this part of ISO105 are encouraged to investigate the possibility of applying the most recent editions of the standards indicated below. Members of IEC and ISO maintain registers of currently valid Intern

32、ational Standards. ISO105-A01:1994, Textiles Tests for colour fastness Part A01: General principles of testing. ISO105-A03:1993, Textiles Tests for colour fastness Part A03: Grey scale for assessing staining. 3 Definition For the purposes of this part of ISO105, the following definition applies. 3.1

33、 dust particles of solid material dispersed in a gas NOTE 1Dyestuff dust is formed during handling operations such as dispensing, transferring, sprinkling, etc. NOTE 2Solid dyes are sold in different physical forms (powdered, granulated, etc.). The particle-size distribution of commercial products v

34、aries considerably. The mean particle diameter may be less than504m or as much as several millimetres. The range of the particle-size distribution of a solid dye may also be narrow or wide. NOTE 3The particle-size distribution of dyestuff dust is largely independent of the physical form of the dyest

35、uff. Two typical particle-size distributions for dyestuff dust are shown in Figure 1. 4 Principle Dust is generated from a dye sample by means of a dust-generating device, extracted from the dust-bearing air by vacuum and conveyed to a detection point, where the amount of dust generated is estimated

36、 visually or determined quantitatively by a gravimetric or photometric method. 5 Apparatus 5.1 Balance, accurate to 0,1g, for weighing out the dye. 5.2 Dust-generating device, with filter holder and connecting joints, and incorporating the following additional components (see Figure 2 and Figure 3).

37、 NOTE 1Instead of a filter and filter holder, other dust-detection devices may be fitted to the apparatus, such as animpactor or an optical particle counter. NOTE 2For information on sources of supply of the dust-generating device and the filter, apply to the organizations listed in clause8 of ISO10

38、5-A01:1994. 5.2.1 Filter, white, diameter (50 2)mm, capable of trapping the dust quantitatively (pore size 5 4m). a) For the gravimetric and photometric methods, made of cellulose nitrate. b) For the visual method, suitable glass-fibre filters can be used. 5.2.2 Vacuum pump, with a suction capacity

39、of at least 20l/min. 5.2.3 Regulator, for adjusting the air flowrate. 5.2.4 Flowmeter, capable of monitoring air flowrate between 10l/min and20l/min. 5.2.5 Timer, for opening the slide valve to start suction, and for timing the period of suction. 5.3 Grey scale for assessing staining, complying with

40、 ISO105-A03. 5.4 Analytical balance, accurate to 0,01mg, for weighing the dust collected on the filter(5.2.1) (gravimetric assessment method), and/or photometer, for extinction measurement of the dust collected and dissolved in a suitable solvent (photometric assessment method). 5.5 Cleaning device,

41、 e.g.brush or vacuum cleaner, for cleaning the apparatus. 5.6 Tweezers, for removing filter paper from holder after dust generation.ENISO105-Z05:1998 2 BSI 04-1999 NOTEThe x-axis of both graphs has a logarithmic scale. Figure 1 Typical graphical representations of the amount of dyestuff dust (by vol

42、ume) asafunction of the dust-particle diameterENISO 105-Z05:1998 BSI 04-1999 3 Figure 2 Apparatus for dust determinationENISO105-Z05:1998 4 BSI 04-1999 6 Procedure Place the filter holder containing the filter(5.2.1) in the dust-generating apparatus(5.2) and close it to give an airtight fit. If the

43、gravimetric method of assessment is used, condition and weigh the filter before insertion into the filter holder. Using the balance(5.1), carefully weigh out10g 0,1g of the dye and place it in the hopper at the top of the apparatus. Start the timer(5.2.5) to open the slide valve with a sudden action

44、, allowing the dye to drop down through the tube into the dust chamber below. Five seconds after the slide has opened, apply a vacuum to extract the dust from the chamber for collection on the filter(5.2.1) under the following conditions: air flowrate:15l/min; extraction time:120s (starting5s after

45、dye has dropped); height of fall:(815 5)mm. Using tweezers(5.6), carefully remove the dust-laden filter from the holder and evaluate it by one of methods given in clause7. Clean the equipment thoroughly(5.5) after each test. If the equipment is wet-cleaned, take particular care that it is dried thor

46、oughly. 7 Assessment of filter 7.1 Visual method Compare the dust-laden filter visually with the grey scale for assessing staining(5.3), where Rating1=very dusty and Rating5=no dust. Half-ratings may be used. NOTEIt is also possible to carry out a visual assessment of colourless solid materials. How

47、ever, special care has to be exercised in such cases. Black filters may be helpful, but require separate preliminary trials. It is preferable to use the gravimetric or photometric method. 7.2 Gravimetric method Weigh the dust-laden filter on the analytical balance(5.4). Since with low-dusting produc

48、ts the mass of dust is very small (1mg), considerable errors are to be expected with the gravimetric method. In such cases, preference should be given to photometric measurement. 7.3 Photometric method For photometric measurement of the amount ofdust, dissolve the dyestuff by shaking well the dust-l

49、aden filter in a suitable solvent at room temperature. When a clear solution has formed, measure the transmission with a photometer and read the corresponding amount of dust off a previously prepared calibration graph. NOTEFurther details may be found in the literature. See for example Annex B. Figure 3 Filter holderENISO105-Z05:1998 BSI 04-1999 5 8 Expression of results The generation and detection of dust depend on a great number of parameters. For this reason, the determination of the amount of dus