BS EN ISO 150-2006 Raw refined and boiled linseed oil for paints and varnishes - Specifications and methods of test《涂料和清漆用生的、精制的和熟的亚麻籽油 规范和试验方法》.pdf

1、 g49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58Specifications and methods of testThis European Standard EN ISO 150:2007 has the status of a Britis

2、h StandardICS 87.060.20Raw, refined and boiled linseed oil for paints and varnishes BRITISH STANDARDBS EN ISO 150:2007Incorporating amendment no. 1 (renumbers BS ISO 150:2006 as BS EN ISO 150:2007)BS EN ISO 150:2007This British Standard was published under the authority of the Standards Policy and S

3、trategy Committee on 16 March 2006 BSI 2007ISBN 0 580 47966 8This publication does not purport to include all the necessary provisions of a Amendments issued since publicationAmd. No. Date Comments17093 30 April 2007 Renumbers BS ISO 150:2006 as BS EN ISO 150:2007contract. Users are responsible for

4、its correct application.Compliance with a British Standard cannot confer immunity from legal obligations.National forewordThis British Standard was published by BSI. It is the UK implementation of EN ISO 150:2007. It is identical with ISO 150:2006. It supersedes BS 6900:1987, which is withdrawn. The

5、 UK participation in its preparation was entrusted to Technical Committee STI/3, Paints, media and related products.A list of organizations represented on STI/3 can be obtained on request to its secretary.EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN ISO 150February 2007ICS 87.060.20English Vers

6、ionRaw, refined and boiled linseed oil for paints and varnishes -Specifications and methods of test (ISO 150:2006)Huiles de lin brutes, raffines et cuites, pour peintures etvernis - Spcifications et mthodes dessai (ISO 150:2006)Rohleinl, Lackleinl und Leinlfirnis frBeschichtungsstoffe - Anforderunge

7、n und Prfung (ISO150:2006)This European Standard was approved by CEN on 21 January 2007.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists

8、 and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsi

9、bility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland,

10、 Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart

11、, 36 B-1050 Brussels 2007 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN ISO 150:2007: EForeword The text of ISO 150:2006 has been prepared by Technical Committee ISO/TC 35 “Paints and varnishes” of the International Organization fo

12、r Standardization (ISO) and has been taken over as EN ISO 150:2007 by Technical Committee CEN/TC 139 “Paints and varnishes“, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement,

13、 at the latest by August 2007, and conflicting national standards shall be withdrawn at the latest by August 2007. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulga

14、ria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Endorsement notice The text of I

15、SO 150:2006 has been approved by CEN as EN ISO 150:2007 without any modifications. EN ISO 150:2007INTERNATIONALSTANDARDISO150Second edition2006-02-15Reference numberISO 150:2006(E)Raw, refined and boiled linseed oil for paints and varnishes Specifications and methods of testHuiles de lin brutes, raf

16、fines et cuites, pour peintures et vernis Spcifications et mthodes dessaiEN ISO 150:2007iiiiiContents Page1 Scope 12 Normative references 13 Terms and definitions 14 Required characteristics and their tolerances 25 Sampling . 26 Density 27 Refractive index . 28 Clarity 29 Phosphoric acid test (PAT)

17、value (for raw linseed oil only) . 410 Drying time (for boiled linseed oil only) 711 Assessment of break in alkali-refined linseed oils . 712 Test report 8Annex A (informative) Standard values for the composition of fatty acids of raw linseed oil 9EN ISO 150:2007ivForewordISO (the International Orga

18、nization for Standardization) is a worldwide federation of national standards bodies(ISO member bodies). The work of preparing International Standards is normally carried out through ISOtechnical committees. Each member body interested in a subject for which a technical committee has beenestablished

19、 has the right to be represented on that committee. International organizations, governmental andnon-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the InternationalElectrotechnical Commission (IEC) on all matters of electrotechnical standardization.Inte

20、rnational Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.The main task of technical committees is to prepare International Standards. Draft International Standardsadopted by the technical committees are circulated to the member bodies for voting. Publicati

21、on as anInternational Standard requires approval by at least 75 % of the member bodies casting a vote.Attention is drawn to the possibility that some of the elements of this document may be the subject of patentrights. ISO shall not be held responsible for identifying any or all such patent rights.I

22、SO 150 was prepared by Technical Committee ISO/TC 35, Paints and varnishes, Subcommittee SC 10, Testmethods for binders for paints and varnishes.This second edition cancels and replaces the first edition (ISO 150:1980), which has been technically revised.The main changes are: The requirements for tu

23、rbidity (clarity) have been changed. The maximum acid value for alkali-refined linseed oil has been changed to . The determination of unsaponifiable-matter content, foots, colophony (rosin), fish oil and mineral acid havebeen deleted because they are no longer necessary. The determination of volatil

24、e-matter content has been replaced by the determination of water content. The determination of ash has been deleted because it is not required very often. Standard values for the composition of fatty acids of raw linseed oil have been added (see Annex A).1,0 mg KOH/gEN ISO 150:20071Raw, refined and

25、boiled linseed oil for paints and varnishes Specifications and methods of test1ScopeThis International Standard specifies the requirements and the corresponding methods of test for raw, refinedand boiled linseed oils for paints and varnishes.2 Normative referencesThe following referenced documents a

26、re indispensable for the application of this document. For datedreferences, only the edition cited applies. For undated references, the latest edition of the referenced document(including any amendments) applies.ISO 835-1, Laboratory glassware Graduated pipettes Part 1: General requirementsISO 1517:

27、1973, Paints and varnishes Surface-drying test Ballotini methodISO 2114, Plastics (polyester resins) and paints and varnishes (binders) Determination of partial acid valueand total acid valueISO 2811-1, Paints and varnishes Determination of density Part 1: Pyknometer methodISO 3681, Binders for pain

28、ts and varnishes Determination of saponification value Titrimetric methodISO 3961, Animal and vegetable fats and oils Determination of iodine valueISO 4630-1, Clear liquids Estimation of colour by the Gardner colour scale Part 1: Visual methodISO 4630-2, Clear liquids Estimation of colour by the Gar

29、dner colour scale Part 2: SpectrophotometricmethodISO 4793, Laboratory sintered (fritted) filters Porosity grading, classification and designationISO 5661, Petroleum products Hydrocarbon liquids Determination of refractive indexISO 8534, Animal and vegetable fats and oils Determination of water cont

30、ent Karl Fischer methodISO 15528, Paints, varnishes and raw materials for paints and varnishes Sampling3 Terms and definitionsFor the purposes of this document, the following terms and definitions apply.3.1 raw linseed oiloil obtained solely from mature seeds of linseed (Linum usitatissimum L.)3.2 a

31、cid-refined linseed oiloil obtained by refining raw linseed oil with acidEN ISO 150:200723.3 alkali-refined linseed oiloil obtained by refining raw linseed oil with sodium hydroxide or other alkali solution3.4 boiled linseed oiloil obtained by incorporating driers in raw linseed oil or refined linse

32、ed oil and heating either alone or whileblowing air or oxygen through the oil3.5 breakseparation of an (insoluble) mucilaginous product which occurs when certain unrefined vegetable oils areheatedNOTE When separation occurs, the oil is said to “break”. The insoluble matter is also referred to as the

33、 “break”.4 Required characteristics and their tolerancesRaw, refined and boiled linseed oils shall have the characteristics specified in Table 1.5 SamplingTake a representative sample of the oil in accordance with ISO 15528.6DensityDetermine the density at or another agreed temperature by the method

34、 specified in ISO 2811-1. (SeeFootnote “a” to Table 1.)7 Refractive indexDetermine the refractive index at or another agreed temperature by the method specified in ISO 5661.(See Footnote “a” to Table 1)8Clarity8.1 Raw oilHeat a well-mixed test portion to and examine it immediately for the presence o

35、f insoluble impurities.8.2 Alkali-refined, acid-refined and boiled oilKeep a well-mixed test portion at to for and then examine it for the presence of sediment andfor other insoluble matter.23C23C65C15C 20C 24 hEN ISO 150:20073Table 1 Required characteristics and their tolerancesCharacteristicRequir

36、ementTest methodRaw linseed oilAlkali-refined linseed oilAcid-refined linseed oilBoiled linseed oilDensitya, , 0,924 to 0,931 0,924 to 0,931 0,924 to 0,931 0,926 to 0,948Clause 6 and ISO 2811-1Colourb, max. (Gardner)13 4 6To be agreed between purchaser and vendorISO 4630-1 ISO 4630-2Colour after hea

37、tingb, max. (Gardner)cClarityNo sedimentdat Slight turbidity is allowed. After heating briefly to the turbidity shall disappear and the oil shall stay clear after cooling to .Clause8Refractive indexa, 1,478 0 to 1,483 0 1,478 0 to 1,483 0 1,478 0 to 1,483 0 Clause 7 and ISO 5661Water, max., (by mass

38、)0,20 0,10 0,10 0,30 ISO 8534Acid value, max., 41f9e8eISO 2114Saponification value, 188 to 195 188 to 195 188 to 195 188 to 200 ISO 3681gIodine value, min. (Wijs method)h175 175 175 ISO 3961gPhosphoric acid test (PAT) value, max., (by mass)0,25 Clause 9Drying time, max. at to orat to ISO 1517 and Cl

39、ause 10Break Non-visible Clause 11ais the standard temperature unless otherwise agreed: for example , , or for tropical countries.bBy agreement between the interested parties, the Lovibond colour system may be substituted for the Gardner with the following limitsbeing recommended:Raw: 70Y 6R ( cell)

40、Alkali-refined: 15Y 1,5R ( cell)Alkali-refined, heated: 20Y 2,0R ( cell)Acid-refined: 20Y 1,5R ( cell)cIf the acid value of neutral oil has been increased by the addition of fatty acids, then the requirement for colour after heating shall beagreed upon between the interested parties, as the limits f

41、or neutral oil are not necessarily applicable.dStricter requirements may be agreed upon between the interested parties.eOr to be agreed between the interested parties.fAlkali-refined oil may have its acid value adjusted to other limits for specific uses. In such cases, the value shall be agreed upon

42、 by theinterested parties.gThe iodine value and saponification value can also be obtained from the fatty acid contents.hRaw or refined linseed oil with an iodine value over 190 should be designated “high iodine value linseed oil”. The Hanus method,sometimes used for this test, gives different result

43、s to the Wijs method; if it is used by agreement between the interested parties, prioragreement on specification limits is essential.23g/ml65C45C20Cn23D%mg KOH/gmg KOH/g%24 h 15C 20C15 h 25C 30C23C 20C 25C 27C25 mm25 mm133 mm25 mmEN ISO 150:200749 Phosphoric acid test (PAT) value (for raw linseed oi

44、l only)9.1 PrincipleMix a test portion thoroughly with (by mass) orthophosphoric acid. Separate the precipitated material bycentrifuging, wash the precipitate free of oil with acetone and then dry and weigh. Report the percentage ofprecipitated material by mass as the PAT value.9.2 Reagents and mate

45、rials9.2.1 Orthophosphoric acid, (by mass), .9.2.2 Acetone.9.2.3 Filter aid, of the diatomaceous type.9.3 ApparatusOrdinary laboratory apparatus, together with the following:9.3.1 Sintered-glass filter crucibles, of porosity grade P 16 (pore size index to in accordancewith ISO 4793) and of capacity

46、.The crucibles shall be cleaned periodically with cleaning solution. It is desirable to test the filtration rate of eachcrucible with pure acetone and discard any that cannot be cleaned to give satisfactory filtration rates.9.3.2 Agitator, consisting of a horizontal shaft suitably supported and fitt

47、ed with clamps or a clamping devicefor holding the pear-shaped centrifuge tubes.The tubes are held in such a manner that, when the shaft rotates, the tubes are tipped end over end, thusallowing the liquid content of the tube to mix as it flows from one end of the tube to the other. The shaft is rota

48、tedmechanically by any means which will give a frequency of .9.3.3 Centrifuge tubes, of capacity , pear-shaped as shown in Figure 1, fitted with a stopper.9.3.4 Centrifuge, capable of holding two or more tubes.It should be possible to control the rotational frequency of the centrifuge so as to give

49、a relative centrifugalacceleration of to at the tips of the tube (see Table 2), where is the standard acceleration due togravity.9.3.5 Pipette, of capacity , graduated in , complying with the requirements of ISO 835-1.9.3.6 Desiccator, containing an efficient desiccant.Anhydrous calcium sulfate, anhydrous calcium chloride and silica gel are satisfactory.85 %85 % = 1,7 g/ml10m 16m30 ml(16 2) r/min100 ml500g 800g g1ml 0,01