BS EN ISO 1833-2-2010 Textiles Quantitative chemical analysis Ternary fibre mixtures《纺织品 定量化学分析 三组分纤维混合物》.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN ISO 1833-2:2010Textiles Quantitativechemical analysisPart 2: Ternary fibre mixtures (ISO1833-2:2006)Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 25/05/2011 08:25,

2、 Uncontrolled Copy, (c) BSIBS EN ISO 1833-2:2010 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN ISO1833-2:2010. It is identical to ISO 1833-2:2006. It supersedes BS4407:1988 which will be withdrawn on publication of the otherparts of the BS EN ISO 1833 series.T

3、he UK participation in its preparation was entrusted to TechnicalCommittee TCI/80, Chemical testing of textiles.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Use

4、rs are responsible for its correctapplication. BSI 2011ISBN 978 0 580 72123 6ICS 59.060.01Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 28 February 2011.Amendmen

5、ts issued since publicationDate Text affectedLicensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 25/05/2011 08:25, Uncontrolled Copy, (c) BSIEUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 1833-2 October 2010 ICS 59.060.01 English Version Textiles - Quantitative chemical analysis - Part

6、2: Ternary fibre mixtures (ISO 1833-2:2006) Textiles - Analyse chimique quantitative - Partie 2: Mlanges ternaires de fibres (ISO 1833-2:2006) Textilien - Quantitative chemische Analysen - Teil 2: Ternre Fasermischungen (ISO 1833-2:2006) This European Standard was approved by CEN on 12 September 201

7、0. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained o

8、n application to the CEN Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management C

9、entre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, N

10、orway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2010 CEN All rights of exploitation in any fo

11、rm and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 1833-2:2010: ELicensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 25/05/2011 08:25, Uncontrolled Copy, (c) BSIBS EN ISO 1833-2:2010EN ISO 1833-2:2010 (E) 3 Foreword The text of ISO 1833-2:2006 has been prepared by Te

12、chnical Committee ISO/TC 38 “Textiles” of the International Organization for Standardization (ISO) and has been taken over as EN ISO 1833-2:2010 by Technical Committee CEN/TC 248 “Textiles and textile products” the secretariat of which is held by BSI. This European Standard shall be given the status

13、 of a national standard, either by publication of an identical text or by endorsement, at the latest by April 2011, and conflicting national standards shall be withdrawn at the latest by April 2011. Attention is drawn to the possibility that some of the elements of this document may be the subject o

14、f patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgari

15、a, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. Endorsement notice Th

16、e text of ISO 1833-2:2006 has been approved by CEN as a EN ISO 1833-2:2010 without any modification. Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 25/05/2011 08:25, Uncontrolled Copy, (c) BSIISO 1833-2:2006(E) ISO 2006 All rights reserved iiiContents Page Foreword iv Introduction . vi 1 Sco

17、pe 1 2 Normative references 1 3 Principle1 4 Reagents and apparatus .1 5 Conditioning and testing atmosphere.1 6 Sampling and pre-treatment of sample .1 7 Procedure .2 8 Calculation and expression of results.2 9 Method of analysis by a combination of manual separation and chemical means7 10 Precisio

18、n of methods 7 11 Test report 7 Annex A (informative) Examples of the calculation of percentages of the components of certain ternary mixtures using some of the variants described in 8.2 .8 Annex B (informative) Table of typical ternary mixtures which may be analysed using methods of analysis of bin

19、ary mixtures specified in the parts of ISO 1833 11 Bibliography 14 Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 25/05/2011 08:25, Uncontrolled Copy, (c) BSIISO 1833-2:2006(E) iv ISO 2006 All rights reservedForeword ISO (the International Organization for Standardization) is a worldwide fed

20、eration of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that comm

21、ittee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accorda

22、nce with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires

23、 approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 1833-2 was prepared by Technical

24、Committee ISO/TC 38, Textiles. This first edition cancels and replaces ISO 5088:1976, which has been withdrawn. ISO 1833 consists of the following parts, under the general title Textiles Quantitative chemical analysis: Part 1: General principles of testing Part 2: Ternary fibre mixtures Part 3: Mixt

25、ures of acetate and certain other fibres (method using acetone) Part 4: Mixtures of certain protein and certain other fibres (method using hypochlorite) Part 5: Mixtures of viscose, cupro or modal and cotton fibres (method using sodium zincate) Part 7: Mixtures of polyamide and certain other fibres

26、(method using formic acid) Part 8: Mixtures of acetate and triacetate fibres (method using acetone) Part 9: Mixtures of acetate and triacetate fibres (method using benzyl alcohol) Part 10: Mixtures of triacetate or polylactide and certain other fibres (method using dichloromethane) Part 11: Mixtures

27、 of cellulose and polyester fibres (method using sulfuric acid) Part 12: Mixtures of acrylic, certain modacrylics, certain chlorofibres, certain elastanes and certain other fibres (method using dimethylformamide) Part 13: Mixtures of certain chlorofibres and certain other fibres (method using carbon

28、 disulfide /acetone) Part 14: Mixtures of acetate and certain chlorofibres (method using acetic acid) Part 15: Mixtures of jute and certain animal fibres (method by determining nitrogen content) Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 25/05/2011 08:25, Uncontrolled Copy, (c) BSIISO 18

29、33-2:2006(E) ISO 2006 All rights reserved v Part 16: Mixtures of polypropylene fibres and certain other fibres (method using xylene) Part 17: Mixtures of chlorofibres (homopolymers of vinyl chloride) and certain other fibres (method using sulfuric acid) Part 18: Mixtures of silk and wool or hair (me

30、thod using sulfuric acid) Part 19: Mixtures of cellulose fibres and asbestos (method by heating) Part 21: Mixtures of chlorofibres, certain modacrylics, certain elastanes, acetates, triacetates and certain other fibres (method using cyclohexanone) The following parts are under preparation: Part 6: M

31、ixtures of viscose or certain types of cupro or modal or lyocell and cotton fibres (method using formic acid and zinc chloride) Part 20: Mixtures of elastane and certain other fibres (method using dimethylacetamide) Part 22: Mixtures of viscose or certain types of cupro or modal or lyocell and flax

32、fibres (method using formic acid and zinc chlorate) Part 23: Mixtures of polyethylene and polypropylene (method using cyclohexanone) Part 24: Mixtures of polyester and some other fibres (method using phenol and tetrachloroethane) Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 25/05/2011 08:2

33、5, Uncontrolled Copy, (c) BSIISO 1833-2:2006(E) vi ISO 2006 All rights reservedIntroduction The methods of quantitative analysis of mixtures of textile fibres are based on two processes: the manual separation and the chemical separation of fibre types. The method of manual separation should be used

34、whenever possible, since it generally gives more accurate results than the chemical method. It can be used for all textiles whose component fibres do not form an intimate mixture, as, for example, in the case of yarns composed of several elements each of which is made up of one type of fibre, or fab

35、rics in which the warp is of a different type of fibre from the weft, or knitted fabrics capable of being unravelled and made up of yarns of different types. In general, the methods for quantitative chemical analysis of ternary fibre mixtures are based on the selective solution of the individual com

36、ponents of the mixture. Four variants of this procedure are possible. Variant 1: Using two different test specimens, component (a) is dissolved from the first test specimen and component (b) from the second test specimen. The insoluble residues of each test specimen are weighed and the percentage of

37、 each soluble component is calculated from the respective losses in mass. The percentage of the third component (c) is calculated by difference. Variant 2: Using two different test specimens, a component (a) is dissolved from the first test specimen, and two components (a and b) from the second test

38、 specimen. The insoluble residue of the first test specimen is weighed and the percentage of the component (a) is calculated from the loss in mass. The insoluble residue of the second test specimen is weighed: it corresponds to component (c). The percentage of the third component (b) is calculated b

39、y difference. Variant 3: Using two different test specimens, two components (a and b) are dissolved from the first test specimen and two components (b and c) from the second test specimen. The insoluble residues correspond to the two components (c) and (a) respectively. The percentage of the third c

40、omponent (b) is calculated by difference. Variant 4: Using only one test specimen, one of the components is removed, after which the insoluble residue formed by the two other fibres is weighed and the percentage of the soluble component is calculated from the loss in mass. One of the two fibres of t

41、he residue is dissolved, the insoluble component is weighed and the percentage of the second soluble component is calculated from the loss in mass. Where a choice is possible, it is advisable to use one of the first three variants. Where chemical analysis is used, take care to choose methods prescri

42、bing solvents which dissolve only the required fibre or fibres, and leave undissolved the other fibre or fibres. By way of example, Annex B contains a certain number of ternary mixtures, together with methods for analysing binary mixtures which can, in principle, be used for analysing these ternary

43、mixtures. In order to reduce the possibility of error to a minimum, it is recommended that, whenever possible, chemical analysis using at least two of the four above-mentioned variants should be made. Mixtures of fibres used during processing and, to a lesser extent, in finished textiles may contain

44、 non-fibrous matter such as fats, waxes or dressings, or water-soluble matter either occurring naturally or added to facilitate processing. Non-fibrous matter should be removed before analysis. A method of pre-treatment for removing oils, fats, waxes and water-soluble matter is given in ISO 1833-1:2

45、006, Annex A. In addition, textiles may contain resins or other matter added to confer special properties. Such matter, including dyestuffs in exceptional cases, may interfere with the action of the reagent on the soluble components and/or it may be partially or completely removed by the reagents. L

46、icensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 25/05/2011 08:25, Uncontrolled Copy, (c) BSIISO 1833-2:2006(E) ISO 2006 All rights reserved viiThis type of added matter may thus cause errors and should be removed before the sample is analysed. If it is impossible to remove such added matter, t

47、he methods for quantitative chemical analysis given in Annex B are no longer applicable. Dye in dyed fibre is considered to be an integral part of the fibre and is not removed. Analyses are conducted on the basis of dry mass and a procedure is given for its determination. The result is expressed by

48、reference to the dry mass or by reference to this mass after application of the conventional recovery rate. Before proceeding with any analysis, all the fibres present in the mixture should be identified. In some chemical methods, the insoluble components of a mixture may be partially dissolved in t

49、he reagent used to dissolve the soluble component or components. Whenever possible, reagents have been chosen that have little or no effect on the insoluble fibres. If a loss in mass is known to occur during the analysis, the result should be corrected; correction factors are given for this purpose. These factors have been determined in several laboratories by treating, with the appropriate reagent as specified in the method of analysis, fibres cleaned by the pre-treatment. These correction factors app