BS EN ISO 3233-1-2013 Paints and varnishes Determination of the percentage volume of non-volatile matter Method using a coated test panel to determine non-volatile matter and to dei.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationPaints and varnishes Determination of the percentage volume of non-volatile matterPart 1: Method using a coated test panel to determine non-volatile matter and to determine dry f

2、ilm density by the Archimedes principleBS EN ISO 3233-1:2013National forewordThis British Standard is the UK implementation of EN ISO 3233-1:2013. Itsupersedes BS 3900-A10:1998 which is withdrawn.The UK participation in its preparation was entrusted to Technical CommitteeSTI/10, Test methods for pai

3、nts.A list of organizations represented on this committee can be obtained onrequest to its secretary.This publication does not purport to include all the necessary provisions of acontract. Users are responsible for its correct application. The British Standards Institution 2013Published by BSI Stand

4、ards Limited 2013ISBN 978 0 580 70350 8ICS 87.040Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of the StandardsPolicy and Strategy Committee on 31 March 2013.Amendments issued since publicationAmd. No. Date Tex

5、t affectedBRITISH STANDARDBS EN ISO 3233-1:2013EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 3233-1 January 2013 ICS 87.040 English Version Paints and varnishes - Determination of the percentage volume of non-volatile matter - Part 1: Method using a coated test panel to determine non-vola

6、tile matter and to determine dry film density by the Archimedes principle (ISO 3233-1:2013) Peintures et vernis - Dtermination du pourcentage en volume de matire non volatile - Partie 1: Mthode utilisant un panneau dessai revtu pour dterminer la matire non volatile et pour dterminer la masse volumiq

7、ue du feuil sec par le principe dArchimde (ISO 3233-1:2013) Beschichtungsstoffe - Bestimmung des Volumens nichtflchtiger Anteile durch Bestimmung der Trockenfilmdichte (ISO 3233-1:2013) This European Standard was approved by CEN on 28 December 2012. CEN members are bound to comply with the CEN/CENEL

8、EC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or

9、 to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the offi

10、cial versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands,

11、 Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2013 CEN All rights of exploitation

12、 in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 3233-1:2013: EBS EN ISO 3233-1:2013EN ISO 3233-1:2013 (E) 2 Contents Page Foreword . 3 BS EN ISO 3233-1:2013EN ISO 3233-1:2013 (E) 3 Foreword This document (EN ISO 3233-1:2013) has been prepared by Technical C

13、ommittee ISO/TC 35 “Paints and varnishes“ in collaboration with Technical Committee CEN/TC 139 “Paints and varnishes” the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the

14、 latest by July 2013, and conflicting national standards shall be withdrawn at the latest by July 2013. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all su

15、ch patent rights. According to the CEN/CENELEC Internal Regulations, the national standards organisations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Mace

16、donia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Endorsement notice The text of ISO 3233-1:2013 has been approved by C

17、EN as a EN ISO 3233-1:2013 without any modification. BS EN ISO 3233-1:2013ISO 3233-1:2013(E) ISO 2013 All rights reserved iiiContents PageIntroduction v1 Scope 12 Normative references . 13 Terms and definitions . 24 Principle . 25 Apparatus and reagents 26 Sampling 57 Procedure 57.1 Number of determ

18、inations and preparation . 57.2 Choice of receptacle . 57.3 Determination of volume of uncoated receptacle 57.4 Application 67.5 Determination of volume of dry coating . 77.6 Determination of density of the liquid coating material 78 Calculation 78.1 Calculation of the practical dry-film density, no

19、n-volatile-matter content and non-volatile matter by volume 78.2 Calculation of the spreading rate 89 Precision 89.1 Repeatability limit 89.2 Reproducibility limit . 910 Test report . 9Annex A (informative) Examples of test conditions 10Annex B (informative) Overview of the existing methods for dete

20、rmination of non-volatile-matter content and volume of non-volatile matter 11Bibliography .12BS EN ISO 3233-1:2013ISO 3233-1:2013(E)IntroductionThis method is used to measure the density and to determine the volume of a dry coating obtainable from a given volume of liquid paint. This volume is consi

21、dered to be the most meaningful measure of the coverage (area of surface covered at a specified dry-film thickness per unit volume) of a paint, varnish or related product. The value obtained by this method might not be the same as that calculated on the basis of the addition of masses and volumes of

22、 the raw materials in a formulation. The volume occupied by a combination of resin and solvent can be the same as, greater than or less than the combined volume of the separate components, due to contraction or expansion of the resin and solvent. A second factor affecting the volume of a dry coating

23、 formulation is the degree to which the spaces between pigment particles are filled with binder. A third factor is the use of volatile components in reactive systems that, by their reaction, change into non-volatile film-building materials, i.e. amines and reactive solvents in high-build two-compone

24、nt coating materials.Above and close to the critical pigment volume concentration, the volume of a dry paint film is greater than the theoretical volume, due to an increase in unfilled voids between pigment particles. The porosity of the film means that this method is unsuitable.The values obtained

25、for the non-volatile matter by volume are dependent on the temperature and time of heating, and these conditions should be carefully considered for the material being tested. ISO 2013 All rights reserved vBS EN ISO 3233-1:2013Paints and varnishes Determination of the percentage volume of non-volatil

26、e matter Part 1: Method using a coated test panel to determine non-volatile matter and to determine dry film density by the Archimedes principle1 ScopeThis part of ISO 3233 describes a procedure for determining the non-volatile matter by volume, NVV, of coating materials and related products by meas

27、uring the density of a dried coating for any specified temperature range and period of drying or curing. This method determines the non-volatile matter immediately after application.Using the non-volatile matter by volume results obtained in accordance with this part of ISO 3233, it is possible to c

28、alculate the spreading rate of coating materials.The method specified in this part of ISO 3233 is the preferred method for air-drying materials. Its use for other materials still has to be tested.This part of ISO 3233 is not applicable to coating materials in which the critical pigment volume concen

29、tration is exceeded.2 Normative referencesThe following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.ISO 1513

30、, Paints and varnishes Examination and preparation of test samplesISO 2811-1, Paints and varnishes Determination of density Part 1: Pyknometer methodISO 2811-2, Paints and varnishes Determination of density Part 2: Immersed body (plummet) methodISO 2811-3, Paints and varnishes Determination of densi

31、ty Part 3: Oscillation methodISO 2811-4, Paints and varnishes Determination of density Part 4: Pressure cup methodISO 4618, Paints and varnishes Terms and definitionsISO 15528, Paints, varnishes and raw materials for paints and varnishes SamplingINTERNATIONAL STANDARD ISO 3233-1:2013(E) ISO 2013 All

32、 rights reserved 1BS EN ISO 3233-1:2013ISO 3233-1:2013(E)3 Terms and definitionsFor the purposes of this document, the terms and definitions given in ISO 4618 and the following apply.3.1non-volatile matterNVresidue by mass obtained by evaporation under specified conditionsISO 4618:2006NOTE This part

33、 of ISO 3233 and ISO 3251 specify different conditions for the determination of NV. Therefore in this part of ISO 3233, the symbol NVmis used for non-volatile matter by mass.3.2non-volatile matter by volumeNVVpercentage residue by volume obtained by evaporation under specified conditions3.3spreading

34、 ratessurface area that can be covered by a given quantity of coating material to give a dried film of the required thicknessNOTE It is expressed in m2/l or m2/kg.3.4practical dry-film densityppractically determined density of a dried and cured coating4 PrincipleA receptacle (disc or plate) is weigh

35、ed in air and in water (or other suitable liquid of known density), coated with the product to be tested, dried and reweighed in air and in the same liquid. From these measurements, the mass, the volume and hence the density of the dry coating are calculated. The non-volatile matter by volume is cal

36、culated from the quotient of the density of the coating material and the density of the dry film.5 Apparatus and reagentsStandard laboratory apparatus, together with the following:5.1 Analytical balance, accurate to 0,1 mg.A single-pan balance is most convenient, and a useful modification is to repl

37、ace the balance pan by a standard counterweight attachment as shown in Figure 1.2 ISO 2013 All rights reservedBS EN ISO 3233-1:2013ISO 3233-1:2013(E)Key1 balance arm2 standard counterweight attachment3 disc4 immersion liquidFigure 1 Special balance support5.2 Receptacle (see 7.2).5.2.1 Disc, about 6

38、0 mm in diameter and about 0,7 mm thick, with a small hole 2 mm to 3 mm from the edge.NOTE A stainless-steel disc has been found satisfactory but has the disadvantage of having a density much in excess of normal liquid coatings. Discs of lighter material, including plastics, for example poly(ethylen

39、e terephthalate), are permitted provided they do not change in volume by contact with the solvents contained in the liquid coating, or during the heating and drying processes involved.5.2.2 Plate, of size (75 5) mm by (120 5) mm, with a small hole 2 mm to 3 mm from the shorter side on the longitudin

40、al axis of the panel.Glass plates may be used as these are very flat. However, drilling a hole is difficult and therefore, if glass plates are used, they should preferably be suspended in a stirrup or cradle of thin wire (see Figure 2). The diameter of the wire shall not exceed 0,3 mm because of sur

41、face tension effects.Plates of this size might be difficult to accommodate in a balance case. Smaller plates may therefore be used provided the coated area is no less than 5 600 mm2. ISO 2013 All rights reserved 3BS EN ISO 3233-1:2013ISO 3233-1:2013(E)Key1 balance arm2 standard counterweight attachm

42、ent3 wire cradle4 plate5 immersion liquidFigure 2 Wire cradle support for plate5.3 Hook, made of stainless steel or synthetic thread, for attaching the receptacle to the balance during weighing operations. The diameter of the wire shall not exceed 0,3 mm because of surface tension effects.5.4 Beaker

43、, of size convenient for immersing the receptacle with a clearance of at least 10 mm and which can be accommodated in the balance case.5.5 Support, for holding the beaker under the balance stirrup without jamming the pan damper, if a counterweight as recommended in 5.1 is not available.5.6 Immersion

44、 liquid, of suitable density, in which the receptacle is immersed.Distilled water is suitable for most coating materials. An organic liquid which does not affect the paint film may also be used.5.7 Desiccator, containing a drying material.5.8 Air oven, capable of maintaining the specified or agreed

45、test temperature (see Annex A) to 2 C (for temperatures up to 150 C) or 3,5 C (for temperatures above 150 C and up to 200 C). An air oven with forced ventilation shall be used.4 ISO 2013 All rights reservedBS EN ISO 3233-1:2013ISO 3233-1:2013(E)WARNING To protect against explosions and fire, careful

46、 handling of products containing flammable volatile materials is essential.Air ovens of the same type shall be used by all parties for referee tests.6 SamplingTake a representative sample of the coating material to be tested, as described in ISO 15528.Examine and prepare the test samples, as describ

47、ed in ISO 1513.7 Procedure7.1 Number of determinations and preparationCarry out the determination in triplicate.Samples may be applied to discs or plates by dipping, brushing or applicator as described in 7.4.Examples of test temperatures and times of heating that may be used for various types of co

48、ating material are given in Annex A.7.2 Choice of receptacleThe choice of receptacle (disc or plate) will depend on the type of coating being measured. Discs should preferably be used for paints of low viscosity and paints which are thinned for spray application. Plates may be used for thixotropic a

49、nd other coatings which can be drawn down with a doctor blade or for paints applied by dipping or by spin coating.7.3 Determination of volume of uncoated receptacle7.3.1 Dry the receptacle (5.2) and suspension hook (5.3) in the oven (5.8), if required, at the recommended temperature for 10 min, cool in the desiccator (5.7) and weigh the receptacle in air. Record this mass as m1.7.3.2 Place in the beaker (5.4) sufficient of the liquid (5.6) to ensure that it will be at least 10 mm above t