BS EN ISO 3233-2-2014 Paints and varnishes Determination of the percentage volume of non-volatile matter Method using the determination of non-volatile-matter content in accordances.pdf

1、BSI Standards PublicationBS EN ISO 3233-2:2014Paints and varnishes Determination of thepercentage volume of non-volatile matterPart 2: Method using the determination ofnon-volatile-matter content in accordancewith ISO 3251 and determination of dryfilm density on coated test panels by theArchimedes p

2、rincipleBS EN ISO 3233-2:2014 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN ISO3233-2:2014.The UK participation in its preparation was entrusted to TechnicalCommittee STI/10, Test methods for paints.A list of organizations represented on this committee can beo

3、btained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2014. Published by BSI StandardsLimited 2014ISBN 978 0 580 70337 9ICS 87.040Compliance with

4、a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 31 July 2014.Amendments issued since publicationDate Text affectedEUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 3233-2 J

5、uly 2014 ICS 87.040 English Version Paints and varnishes - Determination of the percentage volume of non-volatile matter - Part 2: Method using the determination of non-volatile-matter content in accordance with ISO 3251 and determination of dry film density on coated test panels by the Archimedes p

6、rinciple (ISO 3233-2:2014) Peintures et vernis - Dtermination du pourcentage en volume de matire non volatile - Partie 2: Mthode utilisant la teneur en matire non volatile dtermine conformment lISO 3251 et la masse volumique du feuil sec dtermine par le principe dArchimde sur des panneaux dessai rev

7、tus (ISO 3233-2:2014) Beschichtungsstoffe - Bestimmung des Volumens nichtflchtiger Anteile - Teil 2: Verfahren mit Bestimmung des Gehaltes an nichtflchtigen Anteilen nach ISO 3251 und Bestimmung der Trockenfilmdichte beschichteter Probenplatten nach dem Archimedes-Prinzip (ISO 3233-2:2014) This Euro

8、pean Standard was approved by CEN on 17 April 2014. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references con

9、cerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member i

10、nto its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France,

11、 Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMIT

12、EE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2014 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 3233-2:2014 EBS EN ISO 3233-2:2014EN ISO 3233-2:2014 (E) 3 Foreword This document (EN ISO 3233-

13、2:2014) has been prepared by Technical Committee ISO/TC 35 “Paints and varnishes” in collaboration with Technical Committee CEN/TC 139 “Paints and varnishes” the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an

14、identical text or by endorsement, at the latest by January 2015, and conflicting national standards shall be withdrawn at the latest by January 2015. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be

15、held responsible for identifying any or all such patent rights. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Esto

16、nia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Endorsement notice The

17、text of ISO 3233-2:2014 has been approved by CEN as EN ISO 3233-2:2014 without any modification. BS EN ISO 3233-2:2014ISO 3233-2:2014(E) ISO 2014 All rights reserved iiiContents PageForeword iv1 Scope . 12 Normative references 13 Terms and definitions . 14 Principle 25 Apparatus . 26 Sampling 37 Pro

18、cedure. 37.1 Number of determinations and preparation . 37.2 Determination of the practical dry-film density 37.3 Determination of the density 47.4 Determination of the non-volatile-matter content 47.5 Determination of film thickness 48 Evaluation 58.1 Calculation of the practical dry-film density .

19、 58.2 Calculation of the non-volatile matter by volume using the practical dry-film density 58.3 Determination of the practical spreading rate 59 Precision . 69.1 Repeatability . 69.2 Reproducibility . 610 Test report . 6Annex A (informative) Overview of existing methods for determination of non-vol

20、atile matter content and volume of non-volatile matter 8Bibliography .10BS EN ISO 3233-2:2014ISO 3233-2:2014(E)ForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is

21、 normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part

22、 in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.The procedures used to develop this document and those intended for its further maintenance are described in the ISO/IEC Directives, Part 1. In particula

23、r the different approval criteria needed for the different types of ISO documents should be noted. This document was drafted in accordance with the editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).Attention is drawn to the possibility that some of the elements of this d

24、ocument may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any patent rights identified during the development of the document will be in the Introduction and/or on the ISO list of patent declarations received (see www.iso

25、.org/patents).Any trade name used in this document is information given for the convenience of users and does not constitute an endorsement.For an explanation on the meaning of ISO specific terms and expressions related to conformity assessment, as well as information about ISOs adherence to the WTO

26、 principles in the Technical Barriers to Trade (TBT) see the following URL: Foreword - Supplementary informationThe committee responsible for this document is ISO/TC 35, Paints and varnishes, Subcommittee SC 9, General test methods for paints and varnishes.ISO 3233 consists of the following parts, u

27、nder the general title Paints and varnishes Determination of the percentage volume of non-volatile matter: Part 1: Method using a coated test panel to determine non-volatile matter and to determine dry film density by the Archimedes principle Part 2: Method using the determination of non-volatile-ma

28、tter content in accordance with ISO 3251 and determination of dry film density on coated test panels by the Archimedes principle Part 3: Determination by calculation from the non-volatile-matter content determined in accordance with ISO 3251, the density of the coating material and the density of th

29、e solvent in the coating materialiv ISO 2014 All rights reservedBS EN ISO 3233-2:2014INTERNATIONAL STANDARD ISO 3233-2:2014(E)Paints and varnishes Determination of the percentage volume of non-volatile matter Part 2: Method using the determination of non-volatile-matter content in accordance with IS

30、O 3251 and determination of dry film density on coated test panels by the Archimedes principle1 ScopeThis part of ISO 3233 specifies a method for determining the non-volatile matter by volume (NVv) of coating materials by determining the practical dry-film density. This method determines the volume

31、percentage of non-volatile matter in paints, varnishes and related products by measuring the density of a dry coating for any specified temperature range and period of drying or curing.Using the non-volatile matter by volume results obtained in accordance with this part of ISO 3233, it is possible t

32、o calculate the practical spreading rate of coating materials.This method specifies an additional shape of plate to those described in ISO 3233-1 and is suitable for all products which can be applied by dipping.This part of ISO 3233 is not applicable to coating materials which exceed the critical pi

33、gment volume concentration (CPVC).2 Normative referencesThe following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referen

34、ced document (including any amendments) applies.ISO 1513, Paints and varnishes Examination and preparation of test samplesISO 2808, Paints and varnishes Determination of film thicknessISO 2811 (all parts), Paints and varnishes Determination of densityISO 3251, Paints, varnishes and plastics Determin

35、ation of non-volatile-matter contentISO 15528, Paints, varnishes and raw materials for paints and varnishes Sampling3 Terms and definitionsFor the purposes of this document, the following terms and definitions apply.3.1non-volatile matterNVresidue by mass obtained by evaporation under specified cond

36、itionsSOURCE: ISO 4618:2006, 2.161 ISO 2014 All rights reserved 1BS EN ISO 3233-2:2014ISO 3233-2:2014(E)3.2non-volatile matter by volumeNVVpercentage residue by volume obtained by evaporation under specified conditions3.3spreading ratessurface area that can be covered by a given quantity of coating

37、material to give a dried film of requisite thicknessNote 1 to entry: It is expressed in m2/l or m2/kg.3.4practical spreading ratespspreading rate which is obtained in practice on the particular substrate being coated3.5practical dry-film densityppractically determined density of a dried and cured co

38、ating4 PrincipleThe non-volatile matter by volume is calculated from the quotient of the density of the coating material and the dry film, with the dry-film density being determined practically.5 ApparatusStandard laboratory apparatus together with the following:5.1 Metal plate, (40 1) mm (85 1) mm,

39、 with a small hole 2 mm to 3 mm from the edge. A plate with a tip on one of the shorter edges is easier to immerse in the coating material (see Figure 1).The material of the plate shall be suitable and adapted to the coating material under test. In addition the material of the plate shall not change

40、 its volume during contact with the coating material under test. The thickness of the plate is about 0,7 mm or it shall be agreed between the interested parties.Smaller plates may be used subject to agreement between the interested parties, provided that the coated surface area is at least 5 600 mm2

41、.Dimensions in millimetresFigure 1 Suitable plate for immersion2 ISO 2014 All rights reservedBS EN ISO 3233-2:2014ISO 3233-2:2014(E)5.2 Hook, made of stainless material or synthetic thread, for attaching the plate to the balance during weighing operations. The diameter of the wire shall not exceed 0

42、,30 mm because of surface tension effects.5.3 Beaker, of a size convenient for immersing the plate with a clearance of at least 10 mm and which can be accommodated in the balance case.5.4 Analytical balance, accurate to 0,1 mg. A single-pan balance is most convenient, and a useful modification is to

43、 replace the balance pan by a standard counterweight attachment.5.5 Support, for holding the beaker under the balance stirrup without jamming the pan damper, if a counterweight as recommended in 5.4 is not available.5.6 Immersion liquid of suitable density, in which the plate is immersed.NOTE Water

44、is a suitable immersion liquid for most coating materials. Other organic liquids are also suitable provided they do not attack the coating.5.7 Desiccator containing a suitable desiccant.5.8 Air oven, capable of maintaining the specified or agreed test temperature to 2,0C (for temperatures up to 150C

45、) or 3,5C (for temperatures above 150C and up to 200C). An air oven with forced ventilation shall be used.WARNING To protect against explosions and fire, careful handling of products containing flammable volatile materials is essential.Drying in a vacuum can be beneficial for certain applications. I

46、n such cases the conditions shall be agreed. Air ovens of the same type shall be used by all parties for referee tests.6 SamplingTake a representative sample of the coating material to be tested, in accordance with ISO 15528.Examine and prepare the samples for testing in accordance with ISO 1513.7 P

47、rocedure7.1 Number of determinations and preparationCarry out the determination in duplicate.Degrease and clean the plate (5.1). Dry the plate and hook at the specified temperature for 10 min, and cool in the desiccator.7.2 Determination of the practical dry-film density7.2.1 Determination of the ma

48、ss of the uncoated plate in air and in the immersion liquidWeigh the cleaned and dried plate plus hook in air to an accuracy of 1 mg (m1).Then place the plate in the beaker with the immersion liquid, e.g. water, and weigh to an accuracy of 1 mg (m2). Ensure that the plate is always immersed to the s

49、ame depth, with the liquid about 10 mm above the top of the plate. There shall be no air bubbles at any place on the plate (see Figure 2).NOTE If water is used as the immersion liquid, it is beneficial to add 1 or 2 drops of a wetting agent to ensure thorough wetting of the plate. ISO 2014 All rights reserved 3BS EN ISO 3233-2:2014ISO 3233-2:2014(E)Figure 2 Weighing the plate7.2.2 Weighing the coating material and determination of the mass of the plate with coating materialThe coating material shall alway