BS EN ISO 11890-1-2007 Paints and varnishes - Determination of volatile organic compound (VOC) content - Part 1 Difference method (ISO 11890-1 2007)《涂料和清漆 挥发性有机化合物(VOC)含量的测定 差分方法》.pdf

1、BS EN ISO11890-1:2007ICS 87.040NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBRITISH STANDARDPaints and varnishes Determinationof volatile organiccompound (VOC)contentPart 1: Difference method (ISO11890-1:2007)Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 15/01/2009

2、07:41, Uncontrolled Copy, (c) BSIThis British Standardwas published under theauthority of the StandardsPolicy and StrategyCommittee on 31 October2008 BSI 2008ISBN 978 0 580 55941 9Amendments/corrigenda issued since publicationDate CommentsBS EN ISO 11890-1:2007National forewordThis British Standard

3、is the UK implementation of EN ISO11890-1:2007. It is identical to . It supersedes BS EN ISO 11890-1:2001which is withdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee STI/10, Test methods for paints.A list of organizations represented on this committee can be obtaine

4、d onrequest to its secretary.This publication does not purport to include all the necessary provisionsof a contract. Users are responsible for its correct application.Compliance with a British Standard cannot confer immunityfrom legal obligations.Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS

5、, 15/01/2009 07:41, Uncontrolled Copy, (c) BSIEUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN ISO 11890-1July 2007ICS 87.040 Supersedes EN ISO 11890-1:2001 English VersionPaints and varnishes - Determination of volatile organiccompound (VOC) content - Part 1: Difference method (ISO11890-1:2007)Pei

6、ntures et vernis - Dtermination de la teneur encomposs organiques volatils (COV) - Partie 1: Mthodepar diffrence (ISO 11890-1:2007)Beschichtungsstoffe - Bestimmung des Gehaltes anflchtigen organischen Verbindungen (VOC-Gehalt) - Teil1: Differenzverfahren (ISO 11890-1:2007)This European Standard was

7、approved by CEN on 30 June 2007.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national

8、standards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notifie

9、d to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, N

10、etherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2007 CEN All rights of exploitation

11、 in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN ISO 11890-1:2007: ELicensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 15/01/2009 07:41, Uncontrolled Copy, (c) BSIBS EN ISO 11890-1:2007ISO 11890-1:2007(E) ISO 2007 All rights reserved iiiContents Page Foreword

12、iv 1 Scope . 1 2 Normative references . 1 3 Terms and definitions. 2 4 Principle. 2 5 Required supplementary information. 3 6 Sampling 3 7 Procedure 3 8 Calculation. 4 9 Expression of results . 5 10 Precision 6 11 Test report . 7 Annex A (normative) Required supplementary information 8 Bibliography

13、. 9 Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 15/01/2009 07:41, Uncontrolled Copy, (c) BSIBS EN ISO 11890-1:2007ISO 11890-1:2007(E) iv ISO 2007 All rights reservedForeword ISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (IS

14、O member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, gove

15、rnmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC

16、Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member

17、 bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. ISO 11890-1 was prepared by Technical Committee ISO/TC 35, Paints and varnish

18、es. This second edition cancels and replaces the first edition (ISO 11890-1:2000), which has been technically revised. The main change is that, in order to allow the method to be used for multi-component systems as well as single-component systems, the test portion preparation procedures for the det

19、ermination of the non-volatile-matter content of each of these two types of system has been included in Subclause 7.4. ISO 11890 consists of the following parts, under the general title Paints and varnishes Determination of volatile organic compound (VOC) content: Part 1: Difference method Part 2: G

20、as-chromatographic method Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 15/01/2009 07:41, Uncontrolled Copy, (c) BSIBS EN ISO 11890-1:2007INTERNATIONAL STANDARD ISO 11890-1:2007(E) ISO 2007 All rights reserved 1Paints and varnishes Determination of volatile organic compound (VOC) content Pa

21、rt 1: Difference method 1 Scope This part of ISO 11890 is one of a series of standards dealing with the sampling and testing of paints, varnishes and related products. It specifies a method for the determination of the volatile organic compound (VOC) content of paints, varnishes and their raw materi

22、als. This part may be used where the expected VOC content is greater than 15 % by mass. When the expected VOC content is greater than 0,1 % by mass and less than 15 % by mass, ISO 11890-2 should be employed. This method assumes that the volatile matter is either water or organic. However, other vola

23、tile inorganic compounds can be present and might need to be quantified by another suitable method and allowed for in the calculations. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited appli

24、es. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 760, Determination of water Karl Fischer method (General method) ISO 1513, Paints and varnishes Examination and preparation of samples for testing ISO 2811-1, Paints and varnishes Determ

25、ination of density Part 1: Pyknometer method ISO 2811-2, Paints and varnishes Determination of density Part 2: Immersed body (plummet) method ISO 2811-3, Paints and varnishes Determination of density Part 3: Oscillation method ISO 2811-4, Paints and varnishes Determination of density Part 4: Pressur

26、e cup method ISO 3251:2003, Paints, varnishes and plastics Determination of non-volatile-matter content ISO 3270, Paints and varnishes and their raw materials Temperatures and humidities for conditioning and testing ISO 11890-2, Paints and varnishes Determination of volatile organic compound (VOC) c

27、ontent Part 2: Gas-chromatographic method ISO 15528, Paints, varnishes and raw materials for paints and varnishes Sampling Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 15/01/2009 07:41, Uncontrolled Copy, (c) BSIBS EN ISO 11890-1:2007ISO 11890-1:2007(E) 2 ISO 2007 All rights reserved3 Term

28、s and definitions For the purposes of this document, the following terms and definitions apply. 3.1 volatile organic compound VOC any organic liquid and/or solid that evaporates spontaneously at the prevailing temperature and pressure of the atmosphere with which it is in contact NOTE 1 As to correc

29、t usage of the term VOC in the field of coating materials, see volatile organic compound content (VOC content). NOTE 2 Under U.S. government legislation, the term VOC is restricted solely to those compounds that are photochemically active in the atmosphere (see ASTM D 3960). Any other compound is de

30、fined as being an exempt compound. ISO 4618:2006 NOTE 3 Under European legislation, EU Directive 2004/42/EC, the term VOC refers to volatile organic compounds with boiling points up to 250 C, measured at a standard pressure of 101,3 kPa. 3.2 volatile organic compound content VOC content mass of the

31、volatile organic compounds present in a coating material, as determined under specified conditions NOTE 1 The properties and the amounts of the compounds to be taken into account will depend on the field of application of the coating material. For each field of application, the limiting values and t

32、he methods of determination or calculation are stipulated by regulations or by agreement. ISO 4618:2006 NOTE 2 If the term VOC refers to compounds with a defined maximum boiling point (see Note 3 to 3.1), the compounds considered to be part of the VOC content are those with boiling points below that

33、 limit and compounds with higher boiling points are considered to be non-volatile organic compounds. 3.3 exempt compound organic compound that does not participate in atmospheric photochemical reactions NOTE See Notes 2 and 3 to 3.1. 3.4 ready for use state of a product when it is mixed in accordanc

34、e with the manufacturers instructions in the correct proportions and thinned, if required, using the correct thinners so that it is ready for application by the approved method 4 Principle After preparation of the sample, the non-volatile matter content is determined in accordance with ISO 3251, and

35、 the water content is determined using a titration technique employing Karl Fischer reagent in accordance with ISO 760. The contents of exempt compounds, if applicable, are then determined using the method specified in ISO 11890-2. The VOC content of the sample is then calculated. Licensed Copy: Wan

36、g Bin, ISO/EXCHANGE CHINA STANDARDS, 15/01/2009 07:41, Uncontrolled Copy, (c) BSIBS EN ISO 11890-1:2007ISO 11890-1:2007(E) ISO 2007 All rights reserved 35 Required supplementary information For any particular application, the test method specified in this part of ISO 11890 shall be completed by supp

37、lementary information. The items of supplementary information are given in Annex A. 6 Sampling Take a representative sample of the product to be tested (or of each product in the case of a multi-coat system) as specified in ISO 15528. Examine and prepare each sample for testing, as specified in ISO

38、1513, preparing the final sample for testing in the “ready for use” state. 7 Procedure 7.1 Number of determinations and general test conditions Carry out all tests in duplicate at (23 2) C and a relative humidity of (50 5) % unless otherwise agreed (see ISO 3270). 7.2 Determination of parameters Det

39、ermine the parameters required by the calculation (see 8.2 to 8.5) as specified in 7.3 to 7.6. Some may be determined by difference, depending on the compounds present in the sample. 7.3 Density If required by the calculation (see 8.3 to 8.5), determine the density of the sample using the part of IS

40、O 2811 which will give the best precision for the type of sample concerned. Determine the density at 23 C. 7.4 Non-volatile-matter content For single-component products, weigh test portions of the appropriate size (see Table 1 in ISO 3251:2003) into dishes as specified in ISO 3251. Proceed in accord

41、ance with ISO 3251. For multi-component systems, thoroughly mix the components in accordance with the manufacturers instructions. Immediately weigh test portions of the appropriate size (see Table 1 in ISO 3251:2003) into dishes as specified in ISO 3251. Allow the test portions to stand in the dishe

42、s for 1 h at (23 2) C and atmospheric pressure. Then place the dishes in the oven and proceed in accordance with ISO 3251. If any unusual decomposition or degradation occurs during heating, periods of time and/or temperatures different from those given in ISO 3251 may be used by agreement between th

43、e interested parties. 7.5 Water content Determine the water content, as a percentage by mass, by the method given in ISO 760, selecting the reagents so that there will be no interference from the compounds contained in the sample. If the compounds are not known, then determine them qualitatively, e.

44、g. by the method given in ISO 11890-2. NOTE 1 Typical compounds likely to cause interference are ketones and aldehydes. Reagent manufacturers normally publish literature for guidance on correct reagent selection. NOTE 2 If the product to be tested is well characterized and known not to contain water

45、, it is not necessary to determine the water content, and the water content can be assumed to be zero. Licensed Copy: Wang Bin, ISO/EXCHANGE CHINA STANDARDS, 15/01/2009 07:41, Uncontrolled Copy, (c) BSIBS EN ISO 11890-1:2007ISO 11890-1:2007(E) 4 ISO 2007 All rights reserved7.6 Exempt compounds (only

46、 where national legislation applies) 7.6.1 If the organic compounds contained in the sample are not known, then determine them qualitatively, e.g. by the method specified in ISO 11890-2. 7.6.2 Determine the contents of the exempt compounds contained in the sample using the method specified in ISO 11

47、890-2. 7.6.3 Determine the densities of the exempt compounds by the method given in 7.3, or by referring to published reference data. 8 Calculation 8.1 General Calculate the VOC content by the method specified in the referring specification. If no particular method is specified, calculate the VOC co

48、ntent by method 1. Method 1 is the preferred calculation method as the precision is better since it does not involve the determination of density, which introduces the potential for additional errors. 8.2 Method 1: VOC content, as a percentage by mass, of the product “ready for use” wVOC 100 NV w= (

49、1) where VOC is the VOC content, as a percentage by mass, of the product “ready for use”; NV is the non-volatile-matter content, as a percentage by mass (see 7.4); wwis the water content, as a percentage by mass (see 7.5). 8.3 Method 2: VOC content, in grams per litre, of the product “ready for use” ()wsVOC 100 NV 10w = (2) where VOC is the VOC content, in grams per litre, of the product “ready for use”; NV is the non-volatile-matter content, as a percentage by mass (see 7.4); wwis the water