BS EN ISO 11890-2-2013 Paints and varnishes Determination of volatile organic compound (VOC) content Gas-chromatographic method《色漆和清漆 挥发性有机化合物 (VOC) 含量的测定 气相色谱法》.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN ISO 11890-2:2013Paints and varnishes Determination of volatileorganic compound (VOC)contentPart 2: Gas-chromatographic method (ISO11890-2:2013)BS EN ISO 11890-2:2013 BRITIS

2、H STANDARDNational forewordThis British Standard is the UK implementation of EN ISO11890-2:2013. It supersedes BS EN ISO 11890-2:2006 which iswithdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee STI/10, Test methods for paints.A list of organizations represented on t

3、his committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2013. Published by BSI StandardsLimited 2013ISBN 978 0 580 77889 6ICS 8

4、7.040Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 30 April 2013.Amendments issued since publicationDate Text affectedEUROPEAN STANDARD NORME EUROPENNE EUROPISCH

5、E NORM EN ISO 11890-2 March 2013 ICS 87.040 Supersedes EN ISO 11890-2:2006English Version Paints and varnishes - Determination of volatile organic compound (VOC) content - Part 2: Gas-chromatographic method (ISO 11890-2:2013) Peintures et vernis - Dtermination de la teneur en composs organiques vola

6、tils (COV) - Partie 2: Mthode par chromatographie en phase gazeuse (ISO 11890-2:2013) Beschichtungsstoffe - Bestimmung des Gehaltes an flchtigen organischen Verbindungen (VOC-Gehalt) - Teil 2: Gaschromatographisches Verfahren (ISO 11890-2:2013)This European Standard was approved by CEN on 28 Februar

7、y 2013. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtai

8、ned on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN

9、-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland,

10、 Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marn

11、ix 17, B-1000 Brussels 2013 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 11890-2:2013: EBS EN ISO 11890-2:2013EN ISO 11890-2:2013 (E) 3 Foreword This document (EN ISO 11890-2:2013) has been prepared by Technical Committee IS

12、O/TC 35 “Paints and varnishes“ in collaboration with Technical Committee CEN/TC 139 “Paints and varnishes” the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by

13、September 2013, and conflicting national standards shall be withdrawn at the latest by September 2013. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all suc

14、h patent rights. This document supersedes EN ISO 11890-2:2006. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Eston

15、ia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Endorsement notice The t

16、ext of ISO 11890-2:2013 has been approved by CEN as EN ISO 11890-2:2013 without any modification. BS EN ISO 11890-2:2013ISO 11890-2:2013(E) ISO 2013 All rights reserved iiiContents PageForeword v1 Scope . 12 Normative references 13 Terms and definitions . 14 Principle 25 Required supplementary infor

17、mation 26 Apparatus . 26.1 Gas chromatograph . 26.2 Sample injection system . 36.3 Oven 36.4 Detector . 36.5 Capillary column 46.6 Qualitative-analysis equipment 46.7 Injection syringe 46.8 Chart recorder . 46.9 Integrator . 46.10 Sample vials . 46.11 Gas filters . 46.12 Gases 47 Reagents 57.1 Inter

18、nal standard 57.2 Calibration compounds . 57.3 Dilution solvent 57.4 Marker compound 58 Sampling 59 Procedure. 59.1 Density . 59.2 Water content . 69.3 Gas-chromatographic conditions 69.4 Qualitative analysis of product 69.5 Calibration 69.6 Sample preparation 79.7 Quantitative determination of comp

19、ound content 710 Calculation 810.1 General . 810.2 Method 1: VOC content, as a percentage by mass, of the product “ready for use” . 810.3 Method 2: VOC content, in grams per litre, of the product “ready for use” 910.4 Method 3: VOC content, in grams per litre, of the product “ready for use” less wat

20、er . 910.5 Method 4: VOC content, in grams per litre, of the product “ready for use” less water and less exempt compounds (only required if national legislation applies) 1011 Expression of results .1012 Precision 1012.1 General 1012.2 Repeatability limit r . 1012.3 Reproducibility limit R 1113 Test

21、report 11Annex A (normative) Required supplementary information 12Annex B (informative) Examples of gas-chromatographic conditions .13BS EN ISO 11890-2:2013ISO 11890-2:2013(E)iv ISO 2013 All rights reservedBibliography .17BS EN ISO 11890-2:2013ISO 11890-2:2013(E)ForewordISO (the International Organi

22、zation for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been establishe

23、d has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.I

24、nternational Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publi

25、cation as an International Standard requires approval by at least 75 % of the member bodies casting a vote.Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent ri

26、ghts.ISO 11890-2 was prepared by Technical Committee ISO/TC 35, Paints and varnishes.This third edition cancels and replaces the second edition (ISO 11890-2:2006), of which it constitutes a minor revision to correct the numerator of the fraction in Equation (6) in 10.5.ISO 11890 consists of the foll

27、owing parts, under the general title Paints and varnishes Determination of volatile organic compound (VOC) content: Part 1: Difference method Part 2: Gas-chromatographic method ISO 2013 All rights reserved vBS EN ISO 11890-2:2013BS EN ISO 11890-2:2013Paints and varnishes Determination of volatile or

28、ganic compound (VOC) content Part 2: Gas-chromatographic method1 ScopeThis part of ISO 11890 is one of a series of standards dealing with the sampling and testing of paints, varnishes and related products.It specifies a method for the determination of the volatile organic compound (VOC) content of p

29、aints, varnishes and their raw materials. This part is preferred if the expected VOC content is greater than 0,1 % by mass and less than about 15 % by mass. When the VOC content is greater than about 15 % by mass, the less complicated method given in ISO 11890-1 may be used.This method assumes that

30、the volatile matter is either water or organic. However, other volatile inorganic compounds can be present and might need to be quantified by another suitable method and allowed for in the calculations.2 Normative referencesThe following documents, in whole or in part, are normatively referenced in

31、this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.ISO 760, Determination of water Karl Fischer method (General method)ISO 1513, Paints

32、 and varnishes Examination and preparation of test samplesISO 2811-1, Paints and varnishes Determination of density Part 1: Pyknometer methodISO 2811-2, Paints and varnishes Determination of density Part 2: Immersed body (plummet) methodISO 2811-3, Paints and varnishes Determination of density Part

33、3: Oscillation methodISO 2811-4, Paints and varnishes Determination of density Part 4: Pressure cup methodISO 15528, Paints, varnishes and raw materials for paints and varnishes Sampling3 Terms and definitionsFor the purposes of this document, the following terms and definitions apply.3.1volatile or

34、ganic compoundVOCany organic liquid and/or solid that evaporates spontaneously at the prevailing temperature and pressure of the atmosphere with which it is in contactNote 1 to entry: As to current usage of the term VOC in the field of coating materials, see volatile organic compound content (VOC co

35、ntent).INTERNATIONAL STANDARD ISO 11890-2:2013(E) ISO 2013 All rights reserved 1BS EN ISO 11890-2:2013ISO 11890-2:2013(E)Note 2 to entry: Under US government legislation, the term VOC is restricted solely to those compounds that are photochemically active in the atmosphere (see ASTM D3960). Any othe

36、r compound is then defined as being an exempt compound.Note 3 to entry: Under European legislation, EU Directive 2004/42/EC, the term VOC refers to volatile organic compounds with boiling points up to 250 C, measured at a standard pressure of 101,3 kPa.SOURCE: ISO 4618:2006, modified Note 3 to entry

37、 has been added.3.2volatile organic compound contentVOC contentmass of the volatile organic compounds present in a coating material, as determined under specified conditionsNote 1 to entry: The properties and the amounts of the compounds to be taken into account will depend on the field of applicati

38、on of the coating material. For each field of application, the limiting values and the methods of determination or calculation are stipulated by regulations or by agreement.Note 2 to entry: If the term VOC refers to compounds with a defined maximum boiling point (see Note 3 to 3.1), the compounds co

39、nsidered to be part of the VOC content are those with boiling points below that limit, and compounds with higher boiling points are considered to be non-volatile organic compounds.SOURCE: ISO 4618:2006, modified Note 2 to entry has been added.3.3exempt compoundorganic compound that does not particip

40、ate in atmospheric photochemical reactionsNote 1 to entry: See Note 2 to entry and Note 3 to entry in 3.1)3.4ready for usestate of a product when it is mixed in accordance with the manufacturers instructions in the correct proportions and thinned if required using the correct thinners so that it is

41、ready for application by the approved method4 PrincipleAfter preparation of the sample, the VOCs are separated by a gas-chromatographic technique. Either a hot or a cold sample injection system is used, depending on the sample type. Hot injection is the preferred method. After the compounds have bee

42、n identified, they are quantified from the peak areas using an internal standard. Depending on the equipment used, it might also be possible to determine the water content by this method. A calculation is then performed to give the VOC content of the sample.5 Required supplementary informationFor an

43、y particular application, the test method specified in this part of ISO 11890 needs to be completed by supplementary information. The items of supplementary information are given in Annex A.6 Apparatus6.1 Gas chromatographThe apparatus shall be set up and used in accordance with the manufacturers in

44、structions. All of the instrumental parts coming into contact with the test sample shall be made of a material (e.g. glass) which is resistant to the sample and will not change it chemically.2 ISO 2013 All rights reservedBS EN ISO 11890-2:2013ISO 11890-2:2013(E)6.2 Sample injection system6.2.1 Gener

45、alUse one of the two types specified in 6.2.2 and 6.2.3.6.2.2 Hot-injection system with sample splitter (preferred system)The instrument shall have a variable-temperature injection block with a sample splitter. The injection temperature shall be capable of being set to an accuracy of 1 C. The split

46、ratio shall be adjustable and capable of being monitored. The sample splitter insert shall contain silanized glass wool to retain non-volatile constituents, and shall be cleaned and provided with new glass wool packing or replaced as required to rule out errors due to residues of binder or pigment (

47、i.e. adsorption of compounds). The occurrence of adsorption is revealed by peak tailing, in particular with components of low volatility.6.2.3 Cold-injection system with sample splitterThe cold-injection system shall be provided with temperature programming for heating from ambient to 300 C and shal

48、l have a sample splitter inlet which is made of an inert material such as glass. The sample splitter shall be provided with silanized glass wool packing and shall be maintained as specified in 6.2.2. The split ratio shall be adjustable and capable of being monitored.Method precision will be increase

49、d if the injection system, especially the hot-injection system, is coupled to an auto-injector. The manufacturers instructions shall be followed when an auto-injector is used.6.2.4 Selection of sample injection systemThe choice between hot-injection and cold-injection will depend on the type of product under test. It will be necessary to use the cold-injection system for products which, at high temperature, release substances which interfere with the determination.Indications of cleavage or decomposition reactions can