BS EN ISO 14527-3-2000 Plastics - Urea-formaldehyde and urea melamine-formaldehyde powder moulding compounds (UF- and UF MF-PMCs) - Requirements for selected moulding compounds《塑料 .pdf

1、 | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | BRITISH STANDARD BS EN ISO 14527-3:2000 Th

2、e European Standard EN ISO 14527-3:1999 has the status of a British Standard ICS 83.080.10 NO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAW Plastics Urea-formaldehyde and urea/melamine- formaldehyde powder moulding compounds (UF- and UF/MF-PMCs) Part 3: Requirements for selecte

3、d moulding compoundsThis British Standard, having been prepared under the direction of the Sector Committee for Materials and Chemicals, was published under the authority of the Standards Committee and comes into effect on 15 January 2000 BSI 01-2000 ISBN 0 580 35878 X BS EN ISO 14527-3:2000 Amendme

4、nts issued since publication Amd. No. Date Comments National foreword This British Standard is the English language version of EN ISO 14527-3:1999. It is identical with ISO 14527-3:1999. The UK participation in its preparation was entrusted to Technical Committee PRI/42, Fibre reinforced thermosetti

5、ng plastics and prepregs, which has the responsibility to: aid enquirers to understand the text; present to the responsible international/European committee any enquiries on the interpretation, or proposals for change, and keep the UK interests informed; monitor related international and European de

6、velopments and promulgate them in the UK. A list of organizations represented on this committee can be obtained on request to its secretary. Cross-references Attention is drawn to the fact that CEN and CENELEC Standards normally include an annex which lists normative references to international publ

7、ications with their corresponding European publications. The British Standards which implement international or European publications referred to in this document may be found in the BSI Standards Catalogue under the section entitled “International Standards Correspondence Index”, or by using the “F

8、ind” facility of the BSI Standards Electronic Catalogue. A British Standard does not purport to include all the necessary provisions of a contract. Users of British Standards are responsible for their correct application. Compliance with a British Standard does not of itself confer immunity from leg

9、al obligations. Summary of pages This document comprises a front cover, an inside front cover, the EN ISO title page, the EN ISO foreword page, the ISO title page, pages ii and iii, a blank page, pages 1 to 4, an inside back cover and a back cover. The BSI copyright notice displayed in this document

10、 indicates when the document was last issued.EN ISO 14527-3:1999 Referencenumber ISO14527-3:1999(E) INTERNATIONAL STANDARD ISO 14527-3 Firstedition 1999-11-15 PlasticsUrea-formaldehydeand urea/melamine-formaldehydepowder mouldingcompounds(UF-and UF/MF-PMCs) Part3: Requirementsforselectedmoulding com

11、pounds Plastiques Poudres mouler base dure-formaldhyde et dure/mlamine-formaldhyde (UF- et UF/MF-PMC) Partie 3: Exigences relatives certaines poudres mouler EN ISO 14527-3:1999ISO-725413:(9991E) ISO9991 Allrgihtsresvrede.lnUesstorehwisescepfieid,noraptofthisilbupctaoinmaybeudorpercedorutziliedinnayf

12、ormorbynaysnaem,electnoric ormecinahcal,inclidungtohpociypongnadmicrfoilm,wituohteprmissioninwritingfromeitehrISOattherddaessleboworISOsmemebrydob inthectnuoryofthertseuqee.r ISOcirypohgtfofice aCsesoptale56 121-HC1veneGa20 leT.+41224790111 aFx+41223741097 E-mailcirypothgiso.ch Webwww.iso.ch ii DPFd

13、csilremia ihTsPDFfilemayctnoainemeddebdtyfepaces.InaccnadrocewithAebodslicensinglopicy,thisfilemaybepirntedorivewedubtslahlton beidetedlnuessthetyfepaceswhichareemeddebdraelicensedtonadintslaledonthecomputerfrepormingtheideting.Inodwlnidaongthis feli,trapiesaccepttierehnthesersnoptilibiyofontinfrnig

14、nigAebodslicsneniglopicy.hTeISOtneCarlSecterairatacceptsnollibaiityinthis .aera AbodeisatdaremarkofAbodeStsyemsInctaropro.de teDailsofthesfotwraepudorctsusedtocrtaeetihsPDFfilecanbefnuodintheGarenelInfolerativetothefile;theP-FDcerationrapamteers weretpoimizedforpirtning.Evreycraeahseebntakentoensrue

15、thatthefileissuitlbaeforusebyISOmemebridobse.Inthelnuikleyetnev tahtaplboremleratingtoitisfdnuo,lpaeseifnormthetneCarlSecterairatattheserddasgivenlebow. EN ISO 14527-3:1999ISO14527-3:1999(E)iii Foreword ISO(theInternationalOrganizationforStandardization)isaworldwidefederationofnationalstandardsbodie

16、s(ISO memberbodies).TheworkofpreparingInternationalStandardsisnormallycarriedoutthroughISOtechnical committees.Eachmemberbodyinterestedinasubjectforwhichatechnicalcommitteehasbeenestablishedhas therighttoberepresentedonthatcommittee.Internationalorganizations,governmentalandnon-governmental,in liais

17、onwithISO,alsotakepartinthework.ISOcollaboratescloselywiththeInternationalElectrotechnical Commission(IEC)onallmattersofelectrotechnicalstandardization. InternationalStandardsaredraftedinaccordancewiththerulesgivenintheISO/IECDirectives,Part3. DraftInternationalStandardsadoptedbythetechnicalcommitte

18、esarecirculatedtothememberbodiesforvoting. PublicationasanInternationalStandardrequiresapprovalbyatleast75%ofthememberbodiescastingavote. AttentionisdrawntothepossibilitythatsomeoftheelementsofthispartofISO14527maybethesubjectof patentrights.ISOshallnotbeheldresponsibleforidentifyinganyorallsuchpate

19、ntrights. InternationalStandardISO14527-3waspreparedbyTechnicalCommitteeISO/TC61, Plastics, Subcommittee SC12, Thermosetting materials. Afteratransitionperiodof,atthemost,fouryears,thethreepartsofISO14527(seebelow),togetherwiththe threepartsofISO14528,willreplaceISO2112:1990,ofwhichtheyconstituteate

20、chnicalrevision. ISO14527consistsofthefollowingparts,underthegeneraltitle Plastics Urea-formaldehyde and urea/melamine-formaldehyde powder moulding compounds (UF- and UF/MF-PMCs): Part 1: Designation system and basis for specifications Part 2: Preparation of test specimens and determination of prope

21、rties Part 3: Requirements for selected moulding compounds AnnexAofthispartofISO14527isforinformationonly. EN ISO 14527-3:1999EN ISO 14527-3:1999INTERNATIONAL STANDARD ISO 14527-3:1999(E) ISO 9991 All irhgts seredevr 1 Plastics Urea-formaldehyde and urea/melamine-formaldehyde powder moulding compoun

22、ds (UF- and UF/MF-PMCs) Part 3: Requirements for selected moulding compounds 1 Scope This part of ISO 14527 specifies the requirements for the physical and chemical properties of urea-formaldehyde and urea/melamine-formaldehyde powder moulding compounds (UF- and UF/MF-PMCs) and compression- or injec

23、tion-moulded test specimens produced from them. It is limited to those powder moulding compounds whose composition and properties are significantly different. It is further limited to those moulding compounds which are of general technical and/or economic importance. The properties which are used to

24、 characterize the moulding compounds, the test methods and the test conditions are selected from those given in ISO 14527-2. The moulding compounds are divided into types according to their composition and properties. The various types are designated using the designation system defined in ISO 14527

25、1. 2 Normative references The following normative documents contain provisions which, through reference in this text, constitute provisions of this part of ISO 14527. For dated references, subsequent amendments to, or revisions of, any of these publications do not apply. However, parties to agreeme

26、nts based on this part of ISO 14527 are encouraged to investigate the possibility of applying the most recent editions of the normative documents indicated below. For undated references, the latest edition of the normative document referred to applies. Members of ISO and IEC maintain registers of cu

27、rrently valid International Standards. ISO 472:1999, Plastics Vocabulary. ISO 2112:1990, Plastics Urea-formaldehyde moulding materials Specification. ISO 14527-1:1999, Plastics Urea-formaldehyde and urea/melamine-formaldehyde powder moulding compounds (UF- and UF/MF-PMCs) Part 1: Designation system

28、and basis for specifications. ISO 14527-2:1999, Plastics Urea-formaldehyde and urea/melamine-formaldehyde powder moulding compounds (UF- and UF/MF-PMCs) Part 2: Preparation of test specimens and determination of properties. 3 Terms and definitions For the purposes of this part of ISO 14527, the term

29、s and definitions given in ISO 472, ISO 14527-1 and ISO 14527-2 apply. EN ISO 14527-3:1999 1ISO -725413:(9991E) 2 ISO 9991 All irhgts seredevr 4 Requirements 4.1 Property values In order for a urea-formaldehyde or urea/melamine-formaldehyde powder moulding compound to be considered as complying with

30、 this part of ISO 14527, it shall meet the requirements given in Table 1. Table 1 gives the mean value obtained for the set of test specimens used to determine a particular property. Individual values of properties 2.1, 2.2, 2.3 and 2.4 shall be within 10 % of the mean value, and individual values o

31、f properties 3.1 and 3.2 shall be within 5 C of the mean value. No specific limits are placed on rheological and processing properties. However, suitable rheological and processing properties are essential for the satisfactory use of a moulding compound. The test methods and test conditions used sha

32、ll be as agreed between the interested parties. In addition, for some applications, it may be useful for information to be made available on other properties, for example: cure time; particle size; moisture content. If this is so, these properties and test methods, as well as the test conditions to

33、be used, shall be as agreed between the interested parties. 4.2 Filler/reinforcement type and content In order for a phenolic powder moulding compound to be considered as complying with this part of ISO 14527, the nature, form and content by mass of its filler/reinforcement shall be as given in the

34、designation of the moulding compound (see ISO 14527-1:1999, subclause 4.2). EN ISO 14527-3:1999 2ISO -725413:(9991E) ISO 9991 All irhgts seredevr 3 Table 1 Property requirements for UF- and UF/MF-PMCs containing (LD+MD), (WD+MD) or (LD+S) as filler 1234 Type: PMC ISO 14527-. . . Property Unit Pro- c

35、ess- ing a Max. or min. UF (LD10+MD30),X,E to (LD20+MD20),X,E UF (LD10+MD30) to (LD20+MD20) UF (WD30+MD20) to (WD40+MD10) UF/MF (LF20+S10) to (LF30+S20) 1 Rheological and processing properties 1.1 To be agreed between the interested parties 2 Mechanical properties 2.1 Stress at break, B MPa Q M W W

36、45 55 45 55 35 40 b 2.2 Flexural strength, fM MPa Q M W W 80 100 80 1000 70 80 80 2.3 Charpy impact strength, a cU kJ/m 2 Q M W W 5,0 7,5 5,0 7,5 4,5 5,0 6,5 2.4 Charpy notched impact strength, a cA kJ/m 2 Q M W W 1,1 1,3 1,1 1,3 1,0 1,0 1,5 3 Thermal properties 3.1 Temperature of deflection under l

37、oad, T f 1,8 C Q/M W 130 130 130 130 3.2 Temperature of deflection under load, T f 8,0 C Q/M W 90 90 90 80 3.3 Flammability (glow bar), BH Q / Mu BH 2-10 BH 2-10 BH 2-10 b 4 Electrical properties 4.1 Dissipation factor, tan 100 Q / Mu 0 , 1 4.2 Volume resistivity, e cm Q/M W 10 12 1 0 10 4.3 Surface

38、 resistivity, e Q/M W 10 11 10 11 10 11 10 10 4.4 Proof tracking index, PTI Q/M W 600 600 600 500 5 Other properties 5.1 mg u 150 150 200 100 5.2 Water absorption, W w 24 %b y mass Q/M u a Q = Compression moulding M = Injection moulding b Limit will be inserted when agreed on within TC61/SC12. NOTE

39、1 See ISO 14527-2:1999, Tables 3 and 4, columns 3, 4, and 7, for the methods to be used for the preparation of test specimens and the determination of properties. NOTE 2 In view of the differences between the property-value limits for compression-moulding and injection-moulding materials, the likely

40、 variations in test results and the wide range of properties covered, it should not be assumed that materials having the same designation are exactly equivalent. EN ISO 14527-3:1999 3ISO -725413:(9991E) 4 ISO 9991 All irhgts seredevr Annex A (informative) Comparison of designations Table A.1 Compari

41、son of designations used for UF- and UF/MF-PMCs in national and international standards 1234 National or international standard Type: PMC ISO 14527-. . . ISO 14527-3:1999 UF (LD10+MD30),X,E to (LD20+MD20),X,E UF (LD10+MD30) to (LD20+MD20) UF (WD30+MD20) to (WD40+MD10) UF/MF (LF20+S10) to (LF30+S20)

42、ISO 2112:1990 UF A10 UF A11 UF A20 ASTM D 705-81 BS 1322:1992 UF A10 UF A11 UF A20 DIN 7708-3:1975 131.5 131 (130) a JIS K 6916:1995 UM-E UM-G NF a Former DIN type (not included in DIN 7708-3:1975). EN ISO 14527-3:1999 4BS EN ISO 14527-3:2000 BSI 389 Chiswick High Road London W4 4AL | | | | | | | |

43、 | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | | BSI British Standards Institution BSI is the independent natio

44、nal body responsible for preparing British Standards. It presents the UK view on standards in Europe and at the international level. It is incorporated by Royal Charter. Revisions British Standards are updated by amendment or revision. Users of British Standards should make sure that they possess th

45、e latest amendments or editions. It is the constant aim of BSI to improve the quality of our products and services. We would be grateful if anyone finding an inaccuracy or ambiguity while using this British Standard would inform the Secretary of the technical committee responsible, the identity of w

46、hich can be found on the inside front cover. Tel: 020 8996 9000. Fax: 020 8996 7400. BSI offers members an individual updating service called PLUS which ensures that subscribers automatically receive the latest editions of standards. Buying standards Orders for all BSI, international and foreign sta

47、ndards publications should be addressed to Customer Services. Tel: 020 8996 9001. Fax: 020 8996 7001. In response to orders for international standards, it is BSI policy to supply the BSI implementation of those that have been published as British Standards, unless otherwise requested. Information o

48、n standards BSI provides a wide range of information on national, European and international standards through its Library and its Technical Help to Exporters Service. Various BSI electronic information services are also available which give details on all its products and services. Contact the Info

49、rmation Centre. Tel: 020 8996 7111. Fax: 020 8996 7048. Subscribing members of BSI are kept up to date with standards developments and receive substantial discounts on the purchase price of standards. For details of these and other benefits contact Membership Administration. Tel: 020 8996 7002. Fax: 020 8996 7001. Copyright Copyright subsists in all BSI publications. BSI also holds the copyright, in the UK, of the publications of the inte