BS EN ISO 16000-5-2007 Indoor air - Sampling strategy for volatile organic compounds (VOCs)《室内空气 挥发性有机化合物(VOCs)取样法》.pdf

1、 g49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58The European Standard EN ISO 16000-5:2007 has the status of a British StandardICS 13.040.20Indoor a

2、ir Part 5: Sampling strategy for volatile organic compounds (VOCs)BRITISH STANDARDBS EN ISO 16000-5:2007BS EN ISO 16000-5:2007This British Standard was published under the authority of the Standards Policy and Strategy Committee on 30 March 2007 BSI 2007ISBN 978 0 580 50343 6Amendments issued since

3、publicationAmd. No. Date Commentscontract. Users are responsible for its correct application.Compliance with a British Standard cannot confer immunity from legal obligations. National forewordThis British Standard was published by BSI. It is the UK implementation of EN ISO 16000-5:2007.The UK partic

4、ipation in its preparation was entrusted by Technical Committee EH/2, Air quality, to Subcommittee EH/2/3, Ambient atmospheres.A list of organizations represented on EH/2/3 can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a EURO

5、PEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN ISO 16000-5February 2007ICS 13.040.20English VersionIndoor air - Part 5: Sampling strategy for volatile organiccompounds (VOCs) (ISO 16000-5:2007)Air intrieur - Partie 5: Stratgie dchantillonnage pour lescomposs organiques volatils (COV) (ISO 16000-5:200

6、7)Innenraumluftverunreinigungen - Teil 5:Probenahmestrategie fr flchtige organischeVerbindungen (VOC) (ISO 16000-5:2007)This European Standard was approved by CEN on 13 January 2007.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving th

7、is EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (E

8、nglish, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria

9、, Cyprus, Czech Republic, Denmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATION

10、COMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2007 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN ISO 16000-5:2007: EForeword This document (EN ISO 16000-5:2007) h

11、as been prepared by Technical Committee ISO/TC 146 “Air quality“ in collaboration with Technical Committee CEN/TC 264 “Air quality“, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endo

12、rsement, at the latest by August 2007, and conflicting national standards shall be withdrawn at the latest by August 2007. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgiu

13、m, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Endorsement notice The t

14、ext of ISO 16000-5:2007 has been approved by CEN as EN ISO 16000-5:2007 without any modifications. EN ISO 16000-5:2007Reference numberISO 16000-5:2007(E)INTERNATIONAL STANDARD ISO16000-5First edition2007-02-01Indoor air Part 5: Sampling strategy for volatile organic compounds (VOCs) Air intrieur Par

15、tie 5: Stratgie dchantillonnage pour les composs organiques volatils (COV) EN ISO 16000-5:2007ii iiiContents Page Foreword iv Introduction . vi 1 Scope . 1 2 Normative references . 1 3 Definition of volatile organic compounds (VOCs). 1 4 Sources and occurrence 2 5 Measurement technique. 3 5.1 Genera

16、l. 3 5.2 Short-term measurements . 3 5.3 Long-term measurements 3 6 Sampling and measurement planning 3 6.1 General. 3 6.2 Measurement objective and environmental conditions 4 6.3 Time of sampling 6 6.4 Duration of sampling and frequency of measurement . 6 6.5 Sampling location. 8 6.6 Presentation o

17、f results and measurement uncertainty 8 6.7 Quality assurance. 9 Annex A (informative) Examples of organic chemicals detected in indoor air 10 Annex B (informative) Protocol for recording activities and boundary conditions during sampling . 12 Bibliography . 13 EN ISO 16000-5:2007iv Foreword ISO (th

18、e International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committ

19、ee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechn

20、ical standardization. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member

21、bodies for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying

22、any or all such patent rights. ISO 16000-5 was prepared by Technical Committee ISO/TC 146, Air quality, Subcommittee SC 6, Indoor air and by Technical Committee CEN/TC 264, Air quality in collaboration. ISO 16000 consists of the following parts, under the general title Indoor air: Part 1: General as

23、pects of sampling strategy Part 2: Sampling strategy for formaldehyde Part 3: Determination of formaldehyde and other carbonyl compounds Active sampling method Part 4: Determination of formaldehyde Diffusive sampling method Part 5: Sampling strategy for volatile organic compounds (VOCs) Part 6: Dete

24、rmination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TAsorbent, thermal desorption and gas chromatography using MS/FID Part 7: Sampling strategy for determination of airborne asbestos fibre concentrations Part 8: Determination of local mean ages of air i

25、n buildings for characterizing ventilation conditions Part 9: Determination of the emission of volatile organic compounds from building products and furnishing Emission test chamber method Part 10: Determination of the emission of volatile organic compounds from building products and furnishing Emis

26、sion test cell method Part 11: Determination of the emission of volatile organic compounds from building products and furnishing Sampling, storage of samples and preparation of test specimens Part 12: Sampling strategy for polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs),

27、polychlorinated dibenzofurans (PCDFs) and polycyclic aromatic hydrocarbons (PAHs) Part 13: Determination of total (gas and particle-phase) polychlorinated dioxin-like biphenyls and polychlorinated dibenzo-p-dioxins/dibenzofurans Collection on sorbent-backed filters EN ISO 16000-5:2007v Part 15: Samp

28、ling strategy for nitrogen dioxide (NO2) Part 16: Detection and enumeration of moulds Sampling by filtration Part 17: Detection and enumeration of moulds Culture-based method The following parts are under preparation: Part 14: Determination of total (gas and particle-phase) polychlorinated dioxin-li

29、ke biphenyls and polychlorinated dibenzo-p-dioxins/dibenzofurans Extraction, clean-up and analysis by high-resolution gas chromatography/mass spectrometry Part 18: Detection and enumeration of moulds Sampling of moulds by impaction Furthermore, ISO 16017-1 and ISO 16017-2 deal with VOC measurements.

30、 EN ISO 16000-5:2007vi Introduction In ISO 16000-1, general requirements relating to the measurement of indoor air pollutants and the important conditions to be observed before or during the sampling of individual pollutants or groups of pollutants are described. This part of ISO 16000 describes bas

31、ic aspects to be considered when working out a sampling strategy for the measurements of volatile organic compounds (VOCs) in indoor air. It is intended to be a link between ISO 16000-1, Indoor air, General aspects of sampling strategy, the analytical procedures described in ISO 16000-6, Indoor air,

32、 Determination of volatile organic compounds in indoor air and test chamber air by active sampling on Tenax TAsorbent, thermal desorption and gas chromatography using MS/FID, and the more generic ISO 16017-1, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by so

33、rbent tube/thermal desorption/capillary gas chromatography Part 1: Pumped sampling and ISO 16017-2, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 2: Diffusive sampling. This part of ISO 16000

34、 presupposes knowledge of ISO 16000-1. The sampling strategy procedure described in this part of ISO 16000 is based on Guideline VDI 4300 Part 61. EN ISO 16000-5:20071Indoor air Part 5: Sampling strategy for volatile organic compounds (VOCs) 1 Scope This part of ISO 16000 is intended as an aid to pl

35、anning volatile organic compound (VOC) indoor pollution measurements. In the case of indoor air measurements, the careful planning of sampling and the entire measurement strategy are of particular significance since the result of the measurement may have far-reaching consequences, for example, with

36、regard to the need for remedial action or the success of such an action. An inappropriate measurement strategy may contribute to the complete uncertainty of the measurement result in a larger extent than the measurement procedure itself. This part of ISO 16000 uses the definition for indoor environm

37、ent defined in ISO 16000-1. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies

38、. ISO 16000-1:2004, Indoor air General aspects of sampling strategy ISO 16000-6, Indoor air Part 6: Determination of volatile organic compounds in indoor air and test chamber air by active sampling on Tenax TAsorbent, thermal desorption and gas chromatography using MS/FID ISO 16000-8, Indoor air Par

39、t 8: Determination of local mean ages of air in buildings for characterizing ventilation conditions ISO 16017-1, Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 1: Pumped sampling ISO 16017-2,

40、Indoor, ambient and workplace air Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 2: Diffusive sampling 3 Definition of volatile organic compounds (VOCs) Numerous organic compounds are present in indoor environments. Depending

41、on volatility, these are present in the gas phase or are bound to suspended particulate matter or deposited dust. A working group of the World Health Organization WHO2classified organic compounds based on boiling point (see Table 1). EN ISO 16000-5:20072 Table 1 Classification of organic pollutants

42、of indoor air2Description Abbreviation aBoiling point range Saturation vapour pressuresExamples of sampling media afrom C to C kPa Very volatile organic compounds VVOC 15 Activated carbon, cooled sampling media, molecular sieves, canister method Volatile organic compounds VOC 50 to 100 240 to 260 10

43、2Tenax 1), graphitized carbon or activated carbon Semi-volatile organic compounds SVOC 240 to 260 380 to 400 102to 108PUF bor XAD-2 1)Particulate organic matter POM 380 Filters aThe WHO information has been supplemented. bPolyurethane foam. This classification, based primarily on the boiling point,

44、takes into account aspects of the analysis, especially gas chromatography. Since the transition points are fluid here, it is not useful to specify sharp limits for the boiling point ranges and the sampling media to be selected. NOTE 1 Boiling points of some compounds are difficult or impossible to d

45、etermine because they decompose before they boil at atmospheric pressure. Vapour pressure is another criterion for classification of compound volatility that may be used for classification of organic chemicals3. NOTE 2 TVOC (total volatile organic compounds) is defined in ISO 16000-6. 4 Sources and

46、occurrence Several hundred VOCs have been detected in indoor air, stemming from various sources. These sources may be present in the room continuously or intermittently. The most important continuous sources are all kinds of building products, furniture, and room textiles. Intermittent sources inclu

47、de household products and products for renovation, as well as the occupants and a number of their activities, such as smoking and hobby work. Ambient air shall also be considered as a source although its contribution to indoor air pollution by VOCs is generally less important. The various types of s

48、ources mentioned in the preceding paragraph emit a wide range of different VOCs into the indoor air. They also have different emission profiles. As the goal of most indoor air analyses is to provide as representative information as possible on the air pollution status of a room, taking into account

49、the emission characteristics, it is important to develop a sound measurement strategy. In addition, it shall be considered that VOC concentrations in indoor air vary from room to room and are also subject to change over time. It is difficult to establish a comprehensive list of which VOCs are emitted from which sources because of the ongoing variation in the production of products and the resulting change in the composition o