BS EN ISO 16396-2-2017 Plastics Polyamide (PA) moulding and extrusion materials Preparation of test specimens and determination of properties《塑料 聚酰胺(PA)模制和挤出材料 试样制备和性能测定》.pdf

1、BS EN ISO 16396-2:2017Plastics Polyamide (PA) moulding and extrusion materialsPart 2: Preparation of test specimens and determination of properties (ISO 16396-2:2017)BSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06BS EN ISO 16396-2:2017 BRITISH STANDARDNational forew

2、ordThis British Standard is the UK implementation of EN ISO 16396-2:2017. It supersedes BS EN ISO 1874-2:2012 which iswithdrawn.The UK participation in its preparation was entrusted to Technical Committee PRI/82, Thermoplastic materials.A list of organizations represented on this committee can be ob

3、tained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2017.Published by BSI Standards Limited 2017ISBN 978 0 580 88548 8 ICS 83.080.20 Compliance

4、 with a British Standard cannot confer immunity from legal obligations.This British Standard was published under the authority of the Standards Policy and Strategy Committee on 31 March 2017.Amendments/corrigenda issued since publicationDate T e x t a f f e c t e dEUROPEAN STANDARD NORME EUROPENNE E

5、UROPISCHE NORM EN ISO 16396-2 March 2017 ICS 83.080.20 Supersedes EN ISO 1874-2:2012English Version Plastics - Polyamide (PA) moulding and extrusion materials - Part 2: Preparation of test specimens and determination of properties (ISO 16396-2:2017) Plastiques - Matriaux polyamides (PA) pour moulage

6、 et extrusion - Partie 2: Prparation des prouvettes et dtermination des proprits (ISO 16396-2:2017) Kunststoffe - Polyamid-(PA)-Formmassen fr das Spritzgieen und die Extrusion - Teil 2: Herstellung von Probekrpern und Bestimmung von Eigenschaften (ISO 16396-2:2017) This European Standard was approve

7、d by CEN on 3 February 2017. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national s

8、tandards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language an

9、d notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hunga

10、ry, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG C

11、EN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2017 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 16396-2:2017 EBS EN ISO 16396-2:2017EN ISO 16396-2:2017 (E) 3 European foreword This document (EN ISO 16396-2:

12、2017) has been prepared by Technical Committee ISO/TC 61 “Plastics” in collaboration with Technical Committee CEN/TC 249 “Plastics” the secretariat of which is held by NBN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endor

13、sement, at the latest by September 2017 and conflicting national standards shall be withdrawn at the latest by September 2017. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for id

14、entifying any or all such patent rights. This document supersedes EN ISO 1874-2:2012. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech R

15、epublic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Ki

16、ngdom. Endorsement notice The text of ISO 16396-2:2017 has been approved by CEN as EN ISO 16396-2:2017 without any modification. BS EN ISO 16396-2:2017ISO 16396-2:2017(E)Foreword iv1 Scope . 12 Normative references 13 Terms and definitions . 24 Preparation of test specimens 24.1 Treatment of the mat

17、erial before moulding or laser sintering . 24.2 Injection moulding . 34.3 Laser sintering. 35 Conditioning of test specimens . 55.1 Conditioning states of the test specimen . 55.2 Dry-as-moulded (DAM) state 55.3 Moist state . 66 Determination of properties 6Annex A (normative) Specimen preparation u

18、sing laser sintering 9Bibliography .10 ISO 2017 All rights reserved iiiContents PageBS EN ISO 16396-2:2017ISO 16396-2:2017(E)ForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing Internationa

19、l Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO,

20、also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.The procedures used to develop this document and those intended for its further maintenance are described in the ISO/IEC Directives, Part 1

21、. In particular the different approval criteria needed for the different types of ISO documents should be noted. This document was drafted in accordance with the editorial rules of the ISO/IEC Directives, Part 2 (see www .iso .org/ directives).Attention is drawn to the possibility that some of the e

22、lements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any patent rights identified during the development of the document will be in the Introduction and/or on the ISO list of patent declarations rece

23、ived (see www .iso .org/ patents).Any trade name used in this document is information given for the convenience of users and does not constitute an endorsement.For an explanation on the meaning of ISO specific terms and expressions related to conformity assessment, as well as information about ISOs

24、adherence to the World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see the following URL: www .iso .org/ iso/ foreword .html.This document was prepared by Technical Committee ISO/TC 61, Plastics, Subcommittee SC 9, Thermoplastic materials.This first edition of ISO 16

25、396-2 cancels and replaces ISO 1874-2:2012, which has been technically revised.A list of all parts in the ISO 16396 series can be found on the ISO website.iv ISO 2017 All rights reservedBS EN ISO 16396-2:2017INTERNATIONAL STANDARD ISO 16396-2:2017(E)Plastics Polyamide (PA) moulding and extrusion mat

26、erials Part 2: Preparation of test specimens and determination of properties1 ScopeThis document specifies the methods of preparation of test specimens and the test methods to be used in determining the properties of polyamide moulding and extrusion materials. Requirements for handling test material

27、 and for conditioning both the test material before moulding and the specimens before testing are given.Procedures and conditions for the preparation of test specimens and procedures for measuring properties of the materials from which these specimens are made are given. Properties and test methods

28、that are suitable and necessary to characterize polyamide moulding and extrusion materials are listed.The properties have been selected from the general test methods in ISO 10350-1. Other test methods in wide use for, or of particular significance to, these moulding and extrusion materials are also

29、included in this document, as are the designatory properties viscosity number and tensile modulus of elasticity given in ISO 16396-1.2 Normative referencesThe following documents are referred to in the text in such a way that some or all of their content constitutes requirements of this document. Fo

30、r dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.ISO 62, Plastics Determination of water absorptionISO 75-2, Plastics Determination of temperature of deflection under load Part 2: Plastics and

31、 eboniteISO 179-1, Plastics Determination of Charpy impact properties Part 1: Non-instrumented impact testISO 179-2, Plastics Determination of Charpy impact properties Part 2: Instrumented impact testISO 294-1, Plastics Injection moulding of test specimens of thermoplastic materials Part 1: General

32、principles, and moulding of multipurpose and bar test specimensISO 294-4, Plastics Injection moulding of test specimens of thermoplastic materials Part 4: Determination of moulding shrinkageISO 307, Plastics Polyamides Determination of viscosity numberISO 527-2, Plastics Determination of tensile pro

33、perties Part 2: Test conditions for moulding and extrusion plasticsISO 1110, Plastics Polyamides Accelerated conditioning of test specimensISO 1133-2, Plastics Determination of the melt mass-flow rate (MFR) and melt volume-flow rate (MVR) of thermoplastics Part 2: Method for materials sensitive to t

34、ime-temperature history and/or moisture ISO 2017 All rights reserved 1BS EN ISO 16396-2:2017ISO 16396-2:2017(E)ISO 1183-1, Plastics Methods for determining the density of non-cellular plastics Part 1: Immersion method, liquid pyknometer method and titration methodISO 1183-2, Plastics Methods for det

35、ermining the density of non-cellular plastics Part 2: Density gradient column methodISO 1183-3, Plastics Methods for determining the density of non-cellular plastics Part 3: Gas pyknometer methodISO 3451-4, Plastics Determination of ash Part 4: PolyamidesISO 8256, Plastics Determination of tensile-i

36、mpact strengthISO 11357-3, Plastics Differential scanning calorimetry (DSC) Part 3: Determination of temperature and enthalpy of melting and crystallizationISO 15512, Plastics Determination of water contentISO 16396-1, Plastics Polyamide (PA) moulding and extrusion materials Part 1: Designation syst

37、em, marking of products and basis for specificationsISO 20753, Plastics Test specimens.ISO 27547-1, Plastics Preparation of test specimens of thermoplastic materials using mouldless technologies Part 1: General principles, and laser sintering of test specimensIEC 60093, Methods of test for volume re

38、sistivity and surface resistivity of solid electrical insulating materialsIEC 60112, Method for the determination of the proof and the comparative tracking indices of solid insulating materialsIEC 60243-1, Electric strength of insulating materials Test methods Part 1: Tests at power frequenciesIEC 6

39、0250, Recommended methods for the determination of the permittivity and dielectric dissipation factor of electrical insulating materials at power, audio and radio frequencies including metre wavelengthsIEC 60296, Fluids for electrotechnical applications Unused mineral insulating oils for transformer

40、s and switchgearIEC 60695-11-10, Fire hazard testing Part 11-10: Test flames 50 W horizontal and vertical flame test methods3 Terms and definitionsNo terms and definitions are listed in this document.ISO and IEC maintain terminological databases for use in standardization at the following addresses:

41、 IEC Electropedia: available at h t t p :/ www .electropedia .org/ ISO Online browsing platform: available at h t t p :/ www .iso .org/ obp4 Preparation of test specimens4.1 Treatment of the material before moulding or laser sinteringBefore processing, the material sample shall have reached room tem

42、perature. Before processing, the moisture content of the material sample shall not exceed 0,2 % (mass fraction) in the case of PAs having a viscosity number 200 ml/g and not exceed 0,1 % (mass fraction) in the case of PAs having a viscosity 2 ISO 2017 All rights reservedBS EN ISO 16396-2:2017ISO 163

43、96-2:2017(E)number 200 ml/g. For PA46, PA6T/66, PA6T/XT, PA6T/6I/66, PA6T/6I, PA6I/6T and PA NDT/INDT, the moisture content shall be less than 0,1 % (mass fraction).The moisture content of filled or reinforced materials shall be expressed as a percentage of the total mass of the compound. The moistu

44、re content shall be determined in accordance with ISO 15512 and the viscosity number in accordance with ISO 307.To ensure that the moisture content remains low, it is recommended that the sample material in the feed hopper of the injection-moulding machine be blanketed with a suitable gas (for examp

45、le, dried air, nitrogen or argon).Better results may be obtained using a dehumidifier hopper drier.If test specimens are to be prepared by laser sintering (see 4.3 and Annex A), follow the instructions given in Annex A for treatment of the material before processing.4.2 Injection mouldingFor the acq

46、uisition and presentation of comparable data, injection-moulded specimens are used so that valid comparisons between materials can be made. These data represent the most basic approach to the designation of the properties of materials.Injection-moulded specimens shall be prepared in accordance with

47、ISO 294-1, using the conditions specified in Table 1. Such specimens shall be prepared by injection moulding from dry granules. It is essential that the specimens are always prepared by the same procedure using the same processing conditions. The material shall be kept in sealed, moisture-proof cont

48、ainers until it is required for use.NOTE The ISO 294 series will be revised, defining only the injection-moulding conditions and will refer to ISO 20753 for the dimensions of the specimens. Other International Standards that have hitherto used different designations for the same specimen type will a

49、lso be revised to bring the designations into line with those in ISO 20753. Many test standards, specifying test specimen or referring to other standards as ISO 3167 and the ISO 294 series, will be revised in due time and also refer to ISO 20753.Besides injection moulding, other methods are also used to manufacture PA parts, e.g. extrusion, blow moulding and methods using mouldless technologies. Different methods of manufacture can lead to significantly different pro