BS EN ISO 16558-1-2015 Soil quality Risk-based petroleum hydrocarbons Determination of aliphatic and aromatic fractions of volatile petroleum hydrocarbons using gas chromatography .pdf

1、BSI Standards PublicationBS EN ISO 16558-1:2015Soil quality Risk-basedpetroleum hydrocarbonsPart 1: Determination of aliphatic andaromatic fractions of volatile petroleumhydrocarbons using gas chromatography(static headspace method)BS EN ISO 16558-1:2015 BRITISH STANDARDNational forewordThis British

2、 Standard is the UK implementation of EN ISO 16558-1:2015.The UK participation in its preparation was entrusted to Technical Committee EH/4, Soil quality.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all

3、 the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2015.Published by BSI Standards Limited 2015ISBN 978 0 580 76245 1 ICS 13.080.10 Compliance with a British Standard cannot confer immunity from legal obligations.This British

4、 Standard was published under the authority of the Standards Policy and Strategy Committee on 30 September 2015.Amendments/corrigenda issued since publicationDate T e x t a f f e c t e dEUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 16558-1 September 2015 ICS 13.080.10 English Version Soil

5、 quality - Risk-based petroleum hydrocarbons - Part 1: Determination of aliphatic and aromatic fractions of volatile petroleum hydrocarbons using gas chromatography (static headspace method) (ISO 16558-1:2015) Qualit du sol - Hydrocarbures de ptrole risque - Partie 1: Dtermination des fractions alip

6、hatiques et aromatiques des hydrocarbures de ptrole volatiles par chromatographie en phase gazeuse (mthode par espace de tte statique) (ISO 16558-1:2015) Bodenbeschaffenheit - Minerallkohlenwasserstoffe fr die Risikobeurteilung - Teil 1: Bestimmung aliphatischer und aromatischer Fraktionen leicht fl

7、chtiger Minerallkohlenwasserstoffe mittels Gaschromatographie (statisches Headspace-Verfahren) (ISO 16558-1:2015) This European Standard was approved by CEN on 13 June 2015. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this Europ

8、ean Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions

9、 (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Bel

10、gium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switz

11、erland, Turkey andUnited Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national

12、 Members. Ref. No. EN ISO 16558-1:2015 EBS EN ISO 16558-1:2015EN ISO 16558-1:2015 (E) 3 European foreword This document (EN ISO 16558-1:2015) has been prepared by Technical Committee ISO/TC 190 “Soilquality” in collaboration with Technical Committee CEN/TC 345 “Characterization of soils” thesecretar

13、iat of which is held by NEN. This European Standard shall be given the status of a national standard, either by publication of anidentical text or by endorsement, at the latest by March 2016, and conflicting national standards shallbe withdrawn at the latest by March 2016. Attention is drawn to the

14、possibility that some of the elements of this document may be the subject ofpatent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patentrights. According to the CEN-CENELEC Internal Regulations, the national standards organizations of thefollowing countries

15、are bound to implement this European Standard: Austria, Belgium, Bulgaria,Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta,Netherlands, Norway, Poland, Por

16、tugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland,Turkey and the United Kingdom. Endorsement notice The text of ISO 16558-1:2015 has been approved by CEN as EN ISO 16558-1:2015 without anymodification. BS EN ISO 16558-1:2015ISO 16558-1:2015(E)Foreword ivIntroduction v1 Scope . 12 Normat

17、ive references 13 Terms and definitions . 24 Interferences 35 Principle 36 Reagents 37 Apparatus . 78 Sampling, preservation, and sample pretreatment . 88.1 General . 88.2 Sampling using vials pre-filled with methanol 88.3 Sampling using coring tube method . 99 Procedure. 99.1 Blank determination 99

18、.2 Extraction 99.3 Headspace-analysis . 99.4 Gas chromatographic analysis 109.4.1 General. 109.4.2 Calibration 109.4.3 Measurement . 1210 Calculation .1210.1 Calculation of the concentration in the spiked water sample .1210.1.1 Volatile aromatic hydrocarbon compounds with internal standard method .1

19、210.1.2 Volatile aliphatic fractions 1210.2 Calculation of the concentration of a volatile compound or fraction in the soil sample 1310.3 Calculation of the concentration of volatile oil in the soil sample .1311 Expression of results .1312 Precision 1313 Test report 13Annex A (informative) Examples

20、of GC-MS chromatograms of fuels 14Bibliography .16 ISO 2015 All rights reserved iiiContents PageBS EN ISO 16558-1:2015ISO 16558-1:2015(E)ForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing

21、International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaiso

22、n with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.The procedures used to develop this document and those intended for its further maintenance are described in the ISO/IEC Direct

23、ives, Part 1. In particular the different approval criteria needed for the different types of ISO documents should be noted. This document was drafted in accordance with the editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).Attention is drawn to the possibility that some

24、 of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any patent rights identified during the development of the document will be in the Introduction and/or on the ISO list of patent declarat

25、ions received (see www.iso.org/patents).Any trade name used in this document is information given for the convenience of users and does not constitute an endorsement.For an explanation on the meaning of ISO specific terms and expressions related to conformity assessment, as well as information about

26、 ISOs adherence to the WTO principles in the Technical Barriers to Trade (TBT) see the following URL: Foreword - Supplementary Information The committee responsible for this document is ISO/TC 190, Soil quality, Subcommittee SC 3, Chemical methods and soil characteristics.ISO 16558 consists of the f

27、ollowing parts, under the general title Soil quality Risk-based petroleum hydrocarbons: Part 1: Determination of aliphatic and aromatic fractions of volatile petroleum hydrocarbons using gas chromatography (static headspace method) Part 2: Determination of aliphatic and aromatic fractions of semi-vo

28、latile petroleum hydrocarbons using gas chromatography with flame ionization detection (GC/FID) Technical Specificationiv ISO 2015 All rights reservedBS EN ISO 16558-1:2015ISO 16558-1:2015(E)IntroductionISO 11504 establishes a basis for the choice of fractions and individual compounds when carrying

29、out analysis for petroleum hydrocarbons in soils and soil-like materials including sediments. It provides guidance for the appropriate use of the analytical results in risks assessment. This part of ISO 16558 specifies methods for the quantitative determination of the appropriate fractions of alipha

30、tic and aromatic compounds. The methods described are based on existing standards mineral oil (ISO 16703) and volatile hydrocarbons (ISO 22155).The general use and relation between the two different parts of this International Standard is given in Figure 1.KeyaFlorisilbclean-up: Only to be applied i

31、n case the test according to ISO 16703 is carried out. If the aliphatic and aromatic fractions have to be analysed, florisil clean-up should not be carried out. Florisil is a trade name for a prepared diatomaceous substance mainly consisting of anhydrous magnesium silicate.bFlorisil is an example of

32、 a suitable product available commercially. This information is given for the convenience of users of this International Standard and does not constitute an endorsement by ISO of this product.Figure 1 Use of different analytical International Standards during risk assessment of petroleum hydrocarbon

33、s ISO 2015 All rights reserved vBS EN ISO 16558-1:2015BS EN ISO 16558-1:2015Soil quality Risk-based petroleum hydrocarbons Part 1: Determination of aliphatic and aromatic fractions of volatile petroleum hydrocarbons using gas chromatography (static headspace method)1 ScopeThis part of ISO 16558 spec

34、ifies a method for the quantitative determination of the total extractable volatile, the volatile aliphatic, and aromatic fractions of petroleum hydrocarbon content in field moist soil samples by gas chromatography with mass spectrometric detection. The aromatic fractions are determined by the sum o

35、f individual aromatic compounds.The sum of the volatile aliphatic (C5to C10) and aromatic (C6to C10) fractions can be referred to as “volatile oil”.The results of the test carried out can be used for risk assessment studies related to contaminations with petroleum hydrocarbons.This part of ISO 16558

36、 provides a method applicable to petroleum hydrocarbon contents from about 5 mg/kg soil expressed as dry matter for the whole aliphatic fraction C5to C10and about 5 mg/kg soil expressed as dry matter for the aromatic fraction in the boiling range of C6to C10.With this method, all hydrocarbons with a

37、 boiling range of 36 C to 184 C, n-alkanes between C5H12to C10H22, isoalkanes, cycloalkanes, BTEX, and di- and tri-alkyl benzenes compounds are determined as total volatile petroleum hydrocarbons C5to C10. In addition, volatile aliphatic and aromatic fractions are specified.For the determination of

38、semi-volatile aliphatic and aromatic fractions of petroleum hydrocarbons in soil samples, see ISO/TS 16558-2.NOTE The sub-fractions proposed in this part of ISO 16558 have shown to be suitable for risk assessment studies. However, other sub-fractions between C5H12to C10H22can be determined in confor

39、mity with this part of ISO 16558.On the basis of the peak pattern of the gas chromatogram and of the boiling points of the individual n-alkanes listed in Annex A, the approximate boiling range of the mineral oil and some qualitative information on the composition of the contamination can be achieved

40、.2 Normative referencesThe following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amend

41、ments) applies.ISO 8466-1, Water quality Calibration and evaluation of analytical methods and estimation of performance characteristics Part 1: Statistical evaluation of the linear calibration functionISO 10381-1, Soil quality Sampling Part 1: Guidance on the design of sampling programmesISO 10381-2

42、, Soil quality Sampling Part 2: Guidance on sampling techniquesINTERNATIONAL STANDARD ISO 16558-1:2015(E) ISO 2015 All rights reserved 1BS EN ISO 16558-1:2015ISO 16558-1:2015(E)ISO 11465, Soil quality Determination of dry matter and water content on a mass basis Gravimetric methodISO 18512, Soil qua

43、lity Guidance on long and short term storage of soil samplesISO 22155, Soil quality Gas chromatographic determination of volatile aromatic and halogenated hydrocarbons and selected ethers Static headspace methodISO 22892, Soil quality Guidelines for the identification of target compounds by gas chro

44、matography and mass spectrometry3 Terms and definitionsFor the purposes of this document, the following terms and definitions apply.3.1total content of volatile petroleum hydrocarbon fractions by gas chromatographysum of compounds extractable with methanol that can be measured by headspace gas chrom

45、atography with a mass spectrometric detector and eluted on a non-polar capillary column with retention times between those of n-pentane (C5H12) EC 5 and hexane (C6H14) EC 6, between EC 6 and n-octane (C8H18) EC 8, and between EC 8 and 1,2-diethylbenzene (C10H14) EC 10Note 1 to entry: Substances that

46、 comply with that definition are mainly short chain or branched, olefenic, alicyclic, aliphatic hydrocarbons, and BTEX or alkyl substituted aromatic hydrocarbons.3.2volatile aromatic compounds and fraction between EC numbers 9 to 10 of petroleum hydrocarbonssingle mono-aromatic BTEX compounds and th

47、e fraction between EC numbers 9 to 10 containing di- and tri-alkylated aromatic compounds which can be measured by headspace gas chromatography with a mass spectrometric detectorNote 1 to entry: For example compounds, see Table 1.3.3volatile aliphatic fractions of petroleum hydrocarbonsquantitative

48、values for the aliphatic fractions of the volatile petroleum hydrocarbons (olefenic, alicyclic branched, and paraffinic short hydrocarbons) between EC numbers 5 to 6, 6 to 8, and 8 to 10 which can be measured with headspace gas chromatography with a mass spectrometric detectorNote 1 to entry: For ex

49、ample compounds, see Table 1.Table 1 EC number ranges and respective example aliphatic and aromatic compoundsStructure typeEC number range Carbon number of n-alkanesBoiling rangeCExample compoundsAliphatic compounds5 to 6 36 to 69 Pentane, 2- and 3-methylpentane, 2,2- and 2,3-dimethylbutane, cyclopentane, 2,3-dimethyl-butadiene, hexane 6 to 8 69 to 128 Cyclohexane, methylcyclopentane, dimethyl-cyclopentane, methyl- and dimethyl-cyclohexane, branched C7- and C8-alkane 8 to 10 128 to 175 n-nonane, 2-methylnonan