BS EN ISO 17294-2-2016 Water quality Application of inductively coupled plasma mass spectrometry (ICP-MS) Determination of selected elements including uranium isotopes《水质 电感耦合等离子体质.pdf

1、BS EN ISO 17294-2:2016W a t e r q u a l i t y A p p l i c a t i o nof inductively coupled plasmamass spectrometry (ICP-MS)Part 2: Determination of selected elementsincluding uranium isotopes (ISO 17294-2:2016)BSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06BS EN ISO

2、17294-2:2016 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN ISO17294-2:2016. It supersedes BS EN ISO 17294-2:2004 which iswithdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee EH/3/2, Physical chemical and biochemical methods.A l

3、ist of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2016.Published by BSI Standards Li

4、mited 2016ISBN 978 0 580 82291 9ICS 13.060.50Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 31 August 2016.Amendments/corrigenda issued since publicationDate T e

5、x t a f f e c t e dEUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 17294-2 August 2016 ICS 13.060.50 Supersedes EN ISO 17294-2:2004English Version Water quality - Application of inductively coupled plasma mass spectrometry (ICP-MS) - Part 2: Determination of selected elements including uran

6、ium isotopes (ISO 17294-2:2016) Qualit de leau - Application de la spectromtrie de masse avec plasma couplage inductif (ICP-MS) - Partie 2: Dosage des lments slectionns y compris les isotopes duranium (ISO 17294-2:2016) Wasserbeschaffenheit - Anwendung der induktiv gekoppelten Plasma-Massenspektrome

7、trie (ICP-MS) - Teil 2: Bestimmung von ausgewhlten Elementen einschlielich Uran-Isotope (ISO 17294-2:2016) This European Standard was approved by CEN on 28 February 2016. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European

8、 Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (E

9、nglish, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgiu

10、m, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerl

11、and, Turkey andUnited Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2016 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Me

12、mbers. Ref. No. EN ISO 17294-2:2016 EBS EN ISO 17294-2:2016EN ISO 17294-2:2016 (E) 3 European foreword This document (EN ISO 17294-2:2016) has been prepared by Technical Committee ISO/TC 147 “Water quality” in collaboration with Technical Committee CEN/TC 230 “Water analysis” the secretariat of whic

13、h is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by February 2017, and conflicting national standards shall be withdrawn at the latest by February 2017. Attention is drawn to the pos

14、sibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN ISO 17294-2:2004. According to the CEN-CENELEC Internal Regulations, the national stand

15、ards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Lu

16、xembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. Endorsement notice The text of ISO 17294-2:2016 has been approved by CEN as EN ISO 17294-2:2016 without any modification. BS EN ISO 17294-2:2016ISO 17294-2:

17、2016(E)Foreword ivIntroduction v1 Scope . 12 Normative references 23 Terms and definitions . 34 Principle 35 Interferences 35.1 General . 35.2 Spectral interferences . 45.2.1 General 45.2.2 Isobaric elemental 45.2.3 Polyatomic interferences 65.3 Non-spectral interferences . 66 Reagents 77 Apparatus

18、118 Sampling .129 Sample pre-treatment 129.1 Determination of the mass concentration of dissolved elements without digestion .129.2 Determination of the total mass concentration after digestion 1210 Procedure1310.1 General 1310.2 Calibration of the ICP-MS system . 1310.3 Measurement of the matrix so

19、lution for evaluation of the correction factors 1410.4 Measurement of the samples . 1411 Calculation .1412 Test report 15Annex A (normative) Determination of the mass concentration of uranium isotopes .16Annex B (informative) Description of the matrices of the samples used for the interlaboratory tr

20、ial 26Annex C (informative) Performance data .28Bibliography .31 ISO 2016 All rights reserved iiiContents PageBS EN ISO 17294-2:2016ISO 17294-2:2016(E)ForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work

21、 of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmen

22、tal, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.The procedures used to develop this document and those intended for its further maintenance are described in the

23、ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the different types of ISO documents should be noted. This document was drafted in accordance with the editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).Attention is drawn to the possibi

24、lity that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any patent rights identified during the development of the document will be in the Introduction and/or on the ISO list of p

25、atent declarations received (see www.iso.org/patents).Any trade name used in this document is information given for the convenience of users and does not constitute an endorsement.For an explanation on the meaning of ISO specific terms and expressions related to conformity assessment, as well as inf

26、ormation about ISOs adherence to the World Trade Organization (WTO) principles in the Technical Barriers to Trade (TBT) see the following URL: www.iso.org/iso/foreword.htmlThe committee responsible for this document is ISO/TC 147, Water quality, Subcommittee SC 2, Physical, chemical and biochemical

27、methods.This second edition cancels and replaces the first edition (ISO 17294-2:2003), which has been technically revised.ISO 17294 consists of the following parts, under the general title Water quality Application of inductively coupled plasma mass spectrometry (ICP-MS): Part 1: General guidelines

28、Part 2: Determination of selected elements including uranium isotopesiv ISO 2016 All rights reservedBS EN ISO 17294-2:2016ISO 17294-2:2016(E)IntroductionWhen applying this part of ISO 17294, it is necessary in each case, depending on the range to be tested, to determine if and to what extent additio

29、nal conditions are to be established. ISO 2016 All rights reserved vBS EN ISO 17294-2:2016BS EN ISO 17294-2:2016Water quality Application of inductively coupled plasma mass spectrometry (ICP-MS) Part 2: Determination of selected elements including uranium isotopesWARNING Persons using this part of I

30、SO 17294 should be familiar with normal laboratory practice. This part of ISO 17294 does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user to establish appropriate safety and health practices and to ensure compliance with any nat

31、ional regulatory conditions.IMPORTANT It is absolutely essential that tests, conducted in accordance with this part of ISO 17294, be carried out by suitably qualified staff.1 ScopeThis part of ISO 17294 specifies a method for the determination of the elements aluminium, antimony, arsenic, barium, be

32、ryllium, bismuth, boron, cadmium, caesium, calcium, cerium, chromium, cobalt, copper, dysprosium, erbium, gadolinium, gallium, germanium, gold, hafnium, holmium, indium, iridium, iron, lanthanum, lead, lithium, lutetium, magnesium, manganese, mercury, molybdenum, neodymium, nickel, palladium, phosph

33、orus, platinum, potassium, praseodymium, rubidium, rhenium, rhodium, ruthenium, samarium, scandium, selenium, silver, sodium, strontium, terbium, tellurium, thorium, thallium, thulium, tin, tungsten, uranium and its isotopes, vanadium, yttrium, ytterbium, zinc and zirconium in water (for example, dr

34、inking water, surface water, ground water, waste water and eluates).Taking into account the specific and additionally occurring interferences, these elements can also be determined in digests of water, sludges and sediments (for example, digests of water as described in ISO 15587-1 or ISO 15587-2).T

35、he working range depends on the matrix and the interferences encountered. In drinking water and relatively unpolluted waters, the limit of quantification (xLQ) lies between 0,002 g/l and 1,0 g/l for most elements (see Table 1). The working range typically covers concentrations between several pg/l a

36、nd mg/l depending on the element and pre-defined requirements.The quantification limits of most elements are affected by blank contamination and depend predominantly on the laboratory air-handling facilities available on the purity of reagents and the cleanliness of glassware.The lower limit of quan

37、tification is higher in cases where the determination suffers from interferences (see Clause 5) or memory effects (see ISO 17294-1:2004, 8.2).INTERNATIONAL STANDARD ISO 17294-2:2016(E) ISO 2016 All rights reserved 1BS EN ISO 17294-2:2016ISO 17294-2:2016(E)Table 1 Lower limits of quantification ( xLQ

38、) for unpolluted waterElement Isotope often usedLimit of quantificationaElement Isotope often usedLimit of quantificationaElement Isotope often usedLimit of quantificationag/l g/l g/lAg107Ag 0,5 Hf178Hf 0,1 Ru102Ru 0,1109Ag 0,5 Hg202Hg 0,05Sb121Sb 0,2Al27Al 1 Ho165Ho 0,1123Sb 0,2As75Asc0,1 In115In 0

39、,1 Sc45Sc 5Au197Au 0,5 Ir193Ir 0,1Se77Sec1B10B 1 K39KC578Sec0,111B 1 La139La 0,182Se 1Ba137Ba 3Li6Li 10 Sm147Sm 0,1138Ba 0,57Li 1Sn118Sn 1Be9Be 0,1 Lu175Lu 0,1120Sn 1Bi209Bi 0,5Mg24Mg 1Sr86Sr 0,5Ca43Ca 10025Mg 1088Sr 0,344Ca 50 Mn55Mn 0,1 Tb159Tb 0,140Ca 10Mo95Mo 0,5 Te126Te 2Cd111Cd 0,198Mo 0,3 Th2

40、32Th 0,1114Cd 0,5 Na23Na 10Tl203Tl 0,2Ce140Ce 0,1 Nd146Nd 0,1205Tl 0,1Co59Co 0,2Ni58Nic0,1 Tm169Tm 0,1Cr52Crc0,160Nic0,1U238U 0,153Cr 5 P31P 5235U 10-4Cs133Cs 0,1Pb206Pbb0,2234U 10-5Cu63Cu 0,1207Pbb0,2 V51Vc0,165Cu 0,1208Pbb0,1W182W 0,3Dy163Dy 0,1 Pd108Pd 0,5184W 0,3Er166Er 0,1 Pr141Pr 0,1 Y89Y 0,1F

41、e56Fec5 Pt195Pt 0,5Yb172Yb 0,2Ga69Ga 0,3 Rb85Rb 0,1174Yb 0,271Ga 0,3Re185Re 0,1Zn64Zn 1Gd157Gd 0,1187Re 0,166Zn 1158Gd 0,1 Rh103Rh 0,168Zn 1Ge74Ge 0,3 Ru101Ru 0,2 Zr90Zr 0,2aDepending on the instrumentation, significantly lower limits can be achieved.bIn order to avoid incorrect results due to the v

42、arying isotop ratios in the environment, the signal intensities of 206Pb, 207Pb and 208Pb shall be added.cIn order to reach these limits, depending on interferences, the use of a collision/reaction cell is recommended2 Normative referencesThe following documents, in whole or in part, are normatively

43、 referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.ISO 3696, Water for analytical laboratory use Specification and test

44、methodsISO 5667-1, Water quality Sampling Part 1: Guidance on the design of sampling programmes and sampling techniquesISO 5667-3, Water quality Sampling Part 3: Preservation and handling of water samples2 ISO 2016 All rights reservedBS EN ISO 17294-2:2016ISO 17294-2:2016(E)ISO 8466-1, Water quality

45、 Calibration and evaluation of analytical methods and estimation of performance characteristics Part 1: Statistical evaluation of the linear calibration functionISO 15587-1, Water quality Digestion for the determination of selected elements in water Part 1: Aqua regia digestionISO 15587-2, Water qua

46、lity Digestion for the determination of selected elements in water Part 2: Nitric acid digestionISO 17294-1:2004, Water quality Application of inductively coupled plasma mass spectrometry (ICP-MS) Part 1: General guidelines3 Terms and definitionsFor the purposes of this document, the terms and defin

47、itions given in ISO 17294-1 and the following apply.3.1limit of applicationlowest concentration of an analyte that can be determined with a defined level of accuracy and precision4 PrincipleMulti-element determination of selected elements, including uranium isotopes, by inductively coupled plasma ma

48、ss spectrometry (ICP-MS) consists of the following steps: introduction of a measuring solution into a radiofrequency plasma (for example, by pneumatic nebulization) where energy transfer processes from the plasma cause desolvation, decomposition, atomization and ionization of elements; as an additio

49、nal option, collision and reaction cell technology may be to overcome several interferences (see 5.1); extraction of the ions from plasma through a differentially pumped vacuum interface with integrated ion optics and separation on the basis of their mass-to-charge ratio by a mass spectrometer (for instance a quadrupole MS); transmission of the ions through the mass separation unit (for instance, a quadrupole) and detection, usually by a continuous dynode electron multiplier assembly, and ion informat