BS IEC 62899-202-2016 Printed electronics Materials Conductive ink《印刷电子技术 材料 导电油墨》.pdf

1、BSI Standards PublicationPrinted electronicsPart 202: Materials Conductive inkBS IEC 62899-202:2016National forewordThis British Standard is the UK implementation of IEC 62899-202:2016.The UK participation in its preparation was entrusted to TechnicalCommittee AMT/9, Printed Electronics.A list of or

2、ganizations represented on this committee can be obtained onrequest to its secretary.This publication does not purport to include all the necessary provisions ofa contract. Users are responsible for its correct application. The British Standards Institution 2016.Published by BSI Standards Limited 20

3、16ISBN 978 0 580 87173 3ICS 31.180; 87.080Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 31 March 2016.Amendments/corrigenda issued since publicationDate Text aff

4、ectedBRITISH STANDARDBS IEC 62899-202:2016IEC 62899-202 Edition 1.0 2016-02 INTERNATIONAL STANDARD Printed electronics Part 202: Materials Conductive inkINTERNATIONAL ELECTROTECHNICAL COMMISSION ICS 31.180; 87.080 ISBN 978-2-8322-3197-5 Registered trademark of the International Electrotechnical Comm

5、ission Warning! Make sure that you obtained this publication from an authorized distributor. BS IEC 62899-202:2016 2 IEC 62899-202:2016 IEC 2016 CONTENTS FOREW ORD . 4 INTRODUCTION . 6 1 Scope 7 2 Normative references. 7 3 Terms and definitions 8 4 Atmospheric conditions for evaluation and condition

6、ing 10 5 Evaluation of properties of conductive ink 10 5.1 Specimen 10 5.2 Contents . 10 5.2.1 Solid content 10 5.2.2 Non-volatile content . 10 5.2.3 Ash content 11 5.2.4 Foreign matter . 11 5.3 Physical properties 12 5.3.1 Density 12 5.3.2 Rheology . 12 5.3.3 Surface tension 13 5.3.4 Size of conduc

7、tive materials . 13 5.3.5 Flashpoint 15 5.3.6 Evaporation rate 15 6 Evaluation of the properties of a conductive layer . 16 6.1 Test piece . 16 6.1.1 General . 16 6.1.2 Substrate . 16 6.1.3 Conductive ink . 16 6.1.4 Dimensions of test piece 16 6.1.5 Preparation of test piece 16 6.2 Electrical proper

8、ties 16 6.2.1 Volume resistivity . 16 6.2.2 Surface resistivity 21 6.3 Optical properties 22 6.3.1 Overview . 22 6.3.2 Luminous transmittance . 22 6.3.3 Chromaticity. 22 6.3.4 Uniformity of colour 23 6.3.5 Haze 24 6.3.6 Refractive index . 25 7 Storage . 25 7.1 Storage conditions 25 7.2 Method for me

9、asuring aged deterioration . 25 7.3 Report of the results 25 Annex A (informative) Examples of the four-point probe for applying an appropriate weight 26 A.1 Internal structure . 26 A.2 Example of the general view 26 BS IEC 62899-202:2016IEC 62899-202:2016 IEC 2016 3 Annex B (informative) Equation o

10、f correction factor F . 27 B.1 General . 27 B.2 Conditions for correction factor F . 27 B.3 Equation of correction factor F . 28 Annex C (informative) Influence of the measuring position and the size of specimen on resistance . 29 C.1 Influence of the measuring position on resistance 29 C.2 Influenc

11、e of the size of the specimen on resistance29Bibliography . 31 Figure 1 Example of four-point probe measurement 17 Figure 2 Example of four-probe measurement equipment 17 Figure 3 Measuring positions of resistance (Type A) . 19 Figure 4 Measuring positions of resistance (Type B) . 19 Figure 5 Measur

12、ing positions of resistance (Type C) . 20 Figure A.1 Example of the internal structure of probe 26 Figure A.2 Example of the general view of the probe 26 Figure B.1 Schematic diagram of the geometry of the conductive layer and the configuration of probes A, B, C, and D 27 Figure C.1 Measurement mode

13、l for the influence of the measuring position on sheet resistance . 29 Figure C.2 Model measurement of the influence of the specimen size .30Table 1 Resistance range of the test piece and the applied current . 18Table 2 List of the size of the specimen 18 BS IEC 62899-202:2016 4 IEC 62899-202:2016 I

14、EC 2016 INTERNATIONAL ELECTROTECHNICAL COMMISSION _ _ _ _ _ _ _ _ _ _ _ _ PRINTED ELECTRONICS Part 202: Materials Conductive inkFOREW ORD 1) The International Electrotechnical Commission (IEC) is a worldwide organization for standardization comprising all national electrotechnical committees (IEC Na

15、tional Committees). The object of IEC is to promote international co-operation on all questions concerning standardization in the electrical and electronic fields. To this end and in addition to other activities, IEC publishes International Standards, Technical Specifications, Technical Reports, Pub

16、licly Available Specifications (PAS) and Guides (hereafter referred to as “ IEC Publication(s)” ). Their preparation is entrusted to technical committees; any IEC National Committee interested in the subject dealt with may participate in this preparatory work. International, governmental and non-gov

17、ernmental organizations liaising with the IEC also participate in this preparation. IEC collaborates closely with the International Organization for Standardization (ISO) in accordance with conditions determined by agreement between the two organizations. 2) The formal decisions or agreements of IEC

18、 on technical matters express, as nearly as possible, an international consensus of opinion on the relevant subjects since each technical committee has representation from all interested IEC National Committees. 3) IEC Publications have the form of recommendations for international use and are accep

19、ted by IEC National Committees in that sense. W hile all reasonable efforts are made to ensure that the technical content of IEC Publications is accurate, IEC cannot be held responsible for the way in which they are used or for any misinterpretation by any end user. 4) In order to promote internatio

20、nal uniformity, IEC National Committees undertake to apply IEC Publications transparently to the maximum extent possible in their national and regional publications. Any divergence between any IEC Publication and the corresponding national or regional publication shall be clearly indicated in the la

21、tter. 5) IEC itself does not provide any attestation of conformity. Independent certification bodies provide conformity assessment services and, in some areas, access to IEC marks of conformity. IEC is not responsible for any services carried out by independent certification bodies. 6) All users sho

22、uld ensure that they have the latest edition of this publication. 7) No liability shall attach to IEC or its directors, employees, servants or agents including individual experts and members of its technical committees and IEC National Committees for any personal injury, property damage or other dam

23、age of any nature whatsoever, whether direct or indirect, or for costs (including legal fees) and expenses arising out of the publication, use of, or reliance upon, this IEC Publication or any other IEC Publications. 8) Attention is drawn to the Normative references cited in this publication. Use of

24、 the referenced publications is indispensable for the correct application of this publication. 9) Attention is drawn to the possibility that some of the elements of this IEC Publication may be the subject of patent rights. IEC shall not be held responsible for identifying any or all such patent righ

25、ts. International Standard IEC 62899-2-1 has been prepared by IEC technical committee 119: Printed electronics. The text of this standard is based on the following documents: FDIS Report on voting 119/ 88/ FDIS 119/ 101A/ RVD Full information on the voting for the approval of this standard can be fo

26、und in the report on voting indicated in the above table. This publication has been drafted in accordance with the ISO/ IEC Directives, Part 2. A list of all parts in the IEC 62899 series, published under the general title Printed electronics, can be found on the IEC website. BS IEC 62899-202:2016IE

27、C 62899-202:2016 IEC 2016 5 The committee has decided that the contents of this publication will remain unchanged until the stability date indicated on the IEC website under “ http:/ / webstore.iec.ch“ in the data related to the specific publication. At this date, the publication will be reconfirmed

28、, withdrawn, replaced by a revised edition, or amended. A bilingual version of this publication may be issued at a later date. BS IEC 62899-202:2016 6 IEC 62899-202:2016 IEC 2016 INTRODUCTION The IEC 62899-20x series relates mainly to evaluation methods for materials of printed electronics. The seri

29、es also include storage methods, packaging and marking, and transportation conditions. The IEC 62899-20x series is divided into parts for each material. Each part is prepared as a generic specification containing fundamental information for the area of printed electronics. The IEC 62899-20x series c

30、onsists of the following parts: Part 201: Materials Substrates Part 202: Materials Conductive ink Part 203: Materials Semiconductor ink1(Subsequent parts will be prepared for other materials.) Furthermore, sectional specifications, blank detail specifications, and detail specifications of each mater

31、ial will follow these parts. This part of IEC 62899 is prepared for conductive materials used in printed electronics and contains the test conditions, the evaluation methods and the storage conditions. _ _ _ _ _ _ _ _ _ _ _ _ _ 1Under consideration. BS IEC 62899-202:2016IEC 62899-202:2016 IEC 2016 7

32、 PRINTED ELECTRONICS Part 202: Materials Conductive ink 1 Scope This part of IEC 62899 defines the terms and specifies the standard methods for characterisation and evaluation. This International Standard is applicable to conductive inks and conductive layer that are made from conductive inks. 2 Nor

33、mative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments

34、) applies. ISO 5-2, Photography and graphic technology Density measurements Part 2: Geometric conditions for transmittance density ISO 5-3, Photography and graphic technology Density measurements Part 3: Spectral conditions ISO 124, Latex, rubber Determination of total solids content ISO 291, Plasti

35、cs Standard atmospheres for conditioning and testing ISO 304, Surface active agents Determination of surface tension by drawing up liquid films ISO 489:1999, Plastics Determination of refractive index ISO 758, Liquid chemical products for industrial use Determination of density at 20 degrees C ISO 1

36、183-1, Plastics Methods for determining the density of non-cellular plastics Part 1: Immersion method, liquid pyknometer method and titration method ISO 2555, Plastics Resins in the liquid state or as emulsions or dispersions Determination of apparent viscosity by the Brookfield Test method ISO 2592

37、, Determination of flash and fire points Cleveland open cup method ISO 2719, Determination of flash point Pensky-Martens closed cup method ISO 2811-1, Paints and varnishes Determination of density Part 1: Pyknometer method ISO 2811-2, Paints and varnishes Determination of density Part 2: Immersed bo

38、dy (plummet) method BS IEC 62899-202:2016 8 IEC 62899-202:2016 IEC 2016 ISO 2884-1, Paints and varnishes Determination of viscosity using rotary viscometers Part 1: Cone-and-plate viscometer operated at a high rate of shear ISO 3219, Plastics Polymers/resins in the liquid state or as emulsions or di

39、spersions Determination of viscosity using a rotational viscometer with defined shear rate ISO 3451-1, Plastics Determination of ash Part 1: General methods ISO 3664, Graphic technology and photography Viewing conditions ISO 3679, Determination of flash no-flash and flash point Rapid equilibrium clo

40、sed cup method ISO 4576, Plastics Polymer dispersions Determination of sieve residue (gross particle and coagulum content) ISO 9276-6, Representation of results of particle size analysis Part 6: Descriptive and quantitative representation of particle shape and morphology ISO 13319, Determination of

41、particle size distributions Electrical sensing zone method ISO 13320, Particle size analysis Laser diffraction methods ISO 13321, Particle size analysis Photon correlation spectroscopy ISO 13322-1, Particle size analysis Image analysis methods Part 1: Static image analysis methods ISO 13468-1:1996,

42、Plastics Determination of the total luminous transmittance of transparent materials Part 1: Single beam instrument ISO 13468-2:1999, Plastics Determination of the total luminous transmittance of transparent materials Part 2: Double-beam instrument ISO 13655, Graphic technology Spectral measurement a

43、nd colorimetric computation for graphic arts images ISO 14488, Particulate materials Sampling and sample splitting for the determination of particulate properties ISO 14782, Plastics Determination of haze for transparent materials ISO 14887, Sample preparation Dispersing procedures for powers in liq

44、uids ISO 20998-1, Measurement and characterization of particles by acoustic methods Part 1: Concepts and procedures in ultrasonic attenuation spectroscopy 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. NOTE The terms in italic font are those def

45、ined in Clause 3. BS IEC 62899-202:2016IEC 62899-202:2016 IEC 2016 9 3 .1 conductive material ingredient of a printing or coating material, which itself is electrically conductive or becomes electrically conductive by post treatment such as heating 3 .2 conductive ink fluid in which one or more smal

46、l molecules, polymers, or particles are dissolved or dispersed, and which becomes an electrically conductive layer (3.3) by post treatment such as heating 3 .3 conductive layer film-like electrically conductive body made of conductive ink (3.2), which is printed or coated on a substrate, followed as

47、 necessary by post treatment such as heating 3 .4 conductive film substrate (sheet or roll) with conductive layer (3.3) 3 .5 solid content mass fraction of an ingredient which effectively functions as a conductive substance, in conductive ink (3.2) 3 .6 non-volatile content mass fraction of residue

48、obtained by evaporation of the volatile solvent under specific conditions, in conductive ink (3.2) 3 .7 ash content mass fraction of residue excluding ingredients which are combusted or carbonised by pyrolysis, in conductive ink (3.2) 3 .8 foreign matter substances and/ or particles of aggregated gr

49、ains, filmed ink and ingredients which do not function as a part of conductive ink (3.2) 3 .9 spherical particle particle with three approximately equal dimensions of length, width and height 3 .10 rod substance with thin elongated cylindrical shape 3 .11 wire substance with thin long fibre-like shape having electrically conductive or semi-conductive property 3 .12 tube substance with fiber-like