BS ISO 105-G04-2016 Textiles Tests for colour fastness Colour fastness to nitrogen oxides in the atmosphere at high humidities《纺织品 色牢度试验 耐高湿氮氧化物色牢度》.pdf

1、BS ISO 105-G04:2016T e x t i l e s T e s t s f o r c o l o u rfastnessPart G04: Colour fastness to nitrogenoxides in the atmosphere at high humiditiesBSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06BS ISO 105-G04:2016 BRITISH STANDARDNational forewordThis British Sta

2、ndard is the UK implementation of ISO 105-G04:2016.The UK participation in its preparation was entrusted to TechnicalCommittee TCI/81, Colour fastness and colour measurement oftextiles.A list of organizations represented on this committee can beobtained on request to its secretary.This publication d

3、oes not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2016.Published by BSI Standards Limited 2016ISBN 978 0 580 84753 0ICS 59.080.01Compliance with a British Standard cannot confer immunity fromlegal

4、 obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 30 June 2016.Amendments/corrigenda issued since publicationDate T e x t a f f e c t e dBS ISO 105-G04:2016 ISO 2016Textiles Tests for colour fastness Part G04: Colour fastness to nit

5、rogen oxides in the atmosphere at high humiditiesTextiles Essais de solidit des coloris Partie G04: Solidit des coloris aux oxydes dazote en atmosphre tauxdhumidit levsINTERNATIONAL STANDARDISO105-G04Second edition2016-06-01Reference numberISO 105-G04:2016(E)BS ISO 105-G04:2016ISO 105-G04:2016(E)ii

6、ISO 2016 All rights reservedCOPYRIGHT PROTECTED DOCUMENT ISO 2016, Published in SwitzerlandAll rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on

7、 the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below or ISOs member body in the country of the requester.ISO copyright officeCh. de Blandonnet 8 CP 401CH-1214 Vernier, Geneva, SwitzerlandTel. +41 22 749 01 11Fax +41 22 749 0

8、9 47copyrightiso.orgwww.iso.orgBS ISO 105-G04:2016ISO 105-G04:2016(E)Foreword ivIntroduction v1 Scope . 12 Normative references 13 Principle 14 Apparatus and reagents 15 Conditioning 36 Test specimens 37 Procedure. 38 Test report . 49 Notes on humidity for testing 4Annex A (normative) Test apparatus

9、 . 5Bibliography 7 ISO 2016 All rights reserved iiiContents PageBS ISO 105-G04:2016ISO 105-G04:2016(E)ForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally

10、 carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the w

11、ork. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.The procedures used to develop this document and those intended for its further maintenance are described in the ISO/IEC Directives, Part 1. In particular the dif

12、ferent approval criteria needed for the different types of ISO documents should be noted. This document was drafted in accordance with the editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).Attention is drawn to the possibility that some of the elements of this document m

13、ay be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any patent rights identified during the development of the document will be in the Introduction and/or on the ISO list of patent declarations received (see www.iso.org/pate

14、nts).Any trade name used in this document is information given for the convenience of users and does not constitute an endorsement.For an explanation on the meaning of ISO specific terms and expressions related to conformity assessment, as well as information about ISOs adherence to the WTO principl

15、es in the Technical Barriers to Trade (TBT) see the following URL: Foreword - Supplementary information.The committee responsible for this document is ISO/TC 38, Textiles, Subcommittee SC 1, Tests for coloured textiles and colorants.This second edition cancels and replaces the first edition (ISO 105

16、-G04:1989), which has been technically revised. The main technical changes are the following:a) delete the test-control fabric dyed with Disperse Blue 3;b) add the test-control fabric dyed with Disperse Violet 1 and the test-control fabric dyed with Disperse Blue 56.ISO 105 consists of the many part

17、s designated by a part letter and a two-digit serial number (e.g. A01), under the general title Textiles Tests for colour fastness. A complete list of these is given in ISO 105-A01.iv ISO 2016 All rights reservedBS ISO 105-G04:2016ISO 105-G04:2016(E)IntroductionThis method is based on a test (AATCC

18、164-1987), developed by AATCC in response to a specific need in the USA for the determination of fading in the presence of nitrogen oxide at high relative humidities. Such conditions are prevalent along the Gulf of Mexico coast of the USA and in Southern California. Fading of some dyes on certain ma

19、n-made fibres, particularly on carpets, was observed to be quite severe under such conditions. The development of this test method enabled dye manufacturers, fibre producers and textile manufacturers to select dye/fibre combinations which were resistant to fading in the presence of nitrogen oxide at

20、 high relative humidities. The same fabrics, when tested at low humidities, showed little or no fading. ISO 2016 All rights reserved vBS ISO 105-G04:2016BS ISO 105-G04:2016Textiles Tests for colour fastness Part G04: Colour fastness to nitrogen oxides in the atmosphere at high humidities1 ScopeThis

21、part of ISO 105 specifies a method for determining the resistance of the colour of textiles to the action of nitrogen oxide in the atmosphere at elevated temperatures and high relative humidities.For testing at lower humidities, see ISO 105-G01.2 Normative referencesThe following documents, in whole

22、 or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.ISO 105-A02, Textiles Tests for colour fa

23、stness Part A02: Grey scale for assessing change in colourISO 105-C10, Textiles Tests for colour fastness Part C10: Colour fastness to washing with soap or soap and sodaISO 105-D01, Textiles Tests for colour fastness Part D01: Colour fastness to drycleaning using perchloroethylene solventISO 139, Te

24、xtiles Standard atmospheres for conditioning and testing3 PrincipleA test specimen and a piece of test-control fabric are simultaneously exposed to nitrogen oxide in an atmosphere which is maintained at 87,5 % 2,5 % relative humidity and a temperature of 40 C 1 C until the test-control fabric shows

25、a colour change-corresponding to that of a standard of fading.The exposure/measurement cycle is repeated until the test specimen shows a definite colour change or for a prescribed number of cycles.4 Apparatus and reagents4.1 Exposure chamber, see Annex A.4.2 Test-control fabric4.2.1 Test-control fab

26、ric dyed with Disperse Violet 1A woven filament acetate is uniformly dyed in an open-width dyeing machine with 0,4 % (on mass of fabric) Cl Disperse Violet 1 (Colour Index, Third Edition) in a dye-bath containing 1 g/l of a dispersing agent at a liquor ratio of 10:1.INTERNATIONAL STANDARD ISO 105-G0

27、4:2016(E) ISO 2016 All rights reserved 1BS ISO 105-G04:2016ISO 105-G04:2016(E)The fabric construction has both a taffeta and a satin side; for this test procedure, only the taffeta side will be considered.The resistance of the test-control fabric to the action of nitrogen oxides should not be varied

28、 between the new lots. The supplier should confirm the performance of the new lot.1)4.2.2 Test-control fabric dyed with Disperse Blue 56A woven filament acetate is uniformly dyed in an open-width dyeing machine with 0,8 % (on mass of fabric) CI Disperse Blue 56 (Colour Index, Third Edition) in a dye

29、-bath containing 0,5 ml/l of a dispersing agent at a liquor ratio of 42:1.The fabric construction has both a taffeta and a satin side; for this test procedure, only the taffeta side will be considered.The resistance of the test-control fabric to the action of nitrogen oxide should not be varied betw

30、een the new lots. The supplier should confirm the performance of the new lot.2)4.3 Standard of fading4.3.1 Standard fading fabric for test-control fabric dyed with Disperse Violet 1The regenerated cellulose woven taffeta is a fabric of similar appearance to the test-control fabric (4.2.1), dyed to m

31、atch an average of faded test-control fabric.3)4.3.2 Standard of fading for test-control fabric dyed with Disperse Blue 56It is considered that the standard of fading is completed when a faded test-control fabric (4.2.2) is observed to have a contrast equal to grade 3-4 on the in grey scale.4.4 Grey

32、 scale for assessing change in colour, complying with ISO 105-A02.4.5 Nitrogen oxideUse bottled gas which contains approximately 1 % nitrogen dioxide in nitrogen, in cylinders equipped with the proper reducing valves. For safety, chain the cylinders to a wall so that they cannot fall or be knocked d

33、own.WARNING Nitrogen oxide in high concentrations are injurious to health and should be exhausted to the atmosphere or trapped in water and neutralized with a 10 % (m/m) solution of sodium hydroxide or sodium hydrogen carbonate. The maximum concentration in a work area should not exceed 9,57 mg/m3.4

34、.6 Urea after treatmentThe use of this treatment is optional.Experience has shown that colour change after removal of test specimens from the exposure chamber is negligible. The urea treatment itself will often cause a colour change in test specimens. Therefore, if 1) Test-control fabric dyed with D

35、isperse Violet 1 is commercially available from Testfabrics, Inc. This information is given for the convenience of users of this document and does not constitute an endorsement by ISO this product.2) Test-control fabric dyed with Disperse Blue 56 is commercially available from the Japanese Standards

36、 Association This information is given for the convenience of users of this document and does not constitute an endorsement by ISO this product.3) The standard fading fabric is commercially available from Testfabrics, Inc. This information is given for the convenience of users of this document and d

37、oes not constitute an endorsement by ISO this product.2 ISO 2016 All rights reservedBS ISO 105-G04:2016ISO 105-G04:2016(E)this procedure is used, it is essential that both the exposed and unexposed test-control fabric be treated in an identical manner.Use urea solution containing 10 g/l of urea (NH2

38、CONH2), buffered to pH 7 by the addition of 0,4 g/l of sodium dihydrogen orthophosphate dehydrate (NaH2PO42H2O), and 2,5 g/l of disodium hydrogen orthophosphate dodecahydrate (Na2HPO412H2O), and containing 0,1 g/l or less of a rapid-wetting surface-active agent; for example, sodium dioctyl sulfosucc

39、inate.5 ConditioningThe standard temperate atmosphere for testing textiles (see ISO 139), i.e. a relative humidity of (65 4) % and temperature of (20 2) C, shall be used for conditioning.6 Test specimensCut out test specimens measuring at least 60 mm 60 mm. For subsequent colour comparison, the unex

40、posed sample shall be kept in an airtight container away from light to avoid further colour changesIf the test involves the effect of nitrogen oxide on laundered or dry-cleaned material, use laundered or dry-cleaned material for both the control and test exposure. For the preparation of test specime

41、ns for testing after laundering or dry cleaning, follow the procedures described in ISO 105-C10 and/or ISO 105-D01. While laundering or dry-cleaning before testing, the size of the test specimens also meets at least 60 mm 60 mm.7 Procedure7.1 Suspend the test specimens and piece of test-control fabr

42、ic (4.2.1 or 4.2.2) in the exposure chamber (4.1) which should produce a cycle of fade within 5 h to 15 h of exposure.7.2 Examine the test-control fabric periodically until its colour corresponds to that of the standard of fading. This constitutes one cycle. An alternative method of determining one

43、cycle of fade is to terminate the exposure cycle when the test-control fabric exhibits a colour change of (16,5 1,5) CIELAB units (see ISO 105-J01).7.3 Remove those test specimens which exhibit a noticeable colour change at the end of one cycle. One cycle will generally produce a measurable colour c

44、hange in samples which are sensitive to nitrogen oxide.7.4 Suspend a fresh piece of test-control fabric (4.2.1 or 4.2.2) for each additional cycle of fade until the required number of cycles has been completed.Test specimens exposed to nitrogen oxide may continue to change colour after removal from

45、the test chamber. The colour may be stabilized by plunging them into a buffered urea solution (see 4.6) for 5 min, squeezing them out, thoroughly rinsing them in clean water and drying them in air at a temperature not above 60 C. Do not treat with the urea solution any test specimen that is to be re

46、turned to the test chamber for additional exposure.7.5 At the end of each cycle, immediately assess the change in colour of the test specimen using the grey scale for assessing change in colour (4.4).7.6 Classify the effect on colour of test specimens after the specified number of cycles, using the

47、grey scale for assessing change in colour (4.4). ISO 2016 All rights reserved 3BS ISO 105-G04:2016ISO 105-G04:2016(E)8 Test reportThe test report shall include the following:a) the date of test;b) the number and year of publication of this part of ISO 105, i.e. ISO 105-G04:2016;c) all details necess

48、ary for the identification of the test specimen tested;d) the type of the test-control fabric used;e) the numerical rating for the change in colour of each test specimen using the grey scale;f) the number of cycles of exposure;g) the temperature and relative humidity at which the test was performed.

49、9 Notes on humidity for testingThe fading of dyes by nitrogen oxide on some fibres, such as polyamide and acetate, is altered greatly by relatively small variations in relative humidity at high humidities. Therefore, to achieve reproducibility and good interlaboratory correlation in test results, close control of temperature and relative humidity is required.4 ISO 2016 All rights reservedBS ISO 105-G04:2016ISO 105-G04:2016(E)Annex A (normative) Test apparatusSuitable test apparatus is shown in Figu