BS ISO 12000-2014 Plastics rubber Polymer dispersions and rubber lattices (natural and synthetic) Definitions and review of test methods《塑料 橡胶 聚合物的分散体及橡胶乳(天然的和合成的)的清析度 试验方法的确定和复审》.pdf

1、BSI Standards PublicationBS ISO 12000:2014Plastics/rubber Polymerdispersions and rubber latices(natural and synthetic) Definitions and review of testmethodsBS ISO 12000:2014 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of ISO 12000:2014. Itsupersedes BS ISO 12000:2

2、000 which is withdrawn.The UK participation in its preparation was entrusted to TechnicalCommittee PRI/21, Testing of plastics.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of

3、a contract. Users are responsible for its correctapplication. The British Standards Institution 2014. Published by BSI StandardsLimited 2014ISBN 978 0 580 74666 6ICS 83.040.10; 83.060Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published u

4、nder the authority of theStandards Policy and Strategy Committee on 30 September 2014.Amendments issued since publicationDate Text affectedBS ISO 12000:2014 ISO 2014Plastics/rubber Polymer dispersions and rubber latices (natural and synthetic) Definitions and review of test methodsPlastiques/caoutch

5、ouc Dispersions de polymres et latex de caoutchouc (naturel et synthtique) Dfinitions et revue des mthodes dessaiINTERNATIONAL STANDARDISO12000Third edition2014-10-01Reference numberISO 12000:2014(E)BS ISO 12000:2014ISO 12000:2014(E)ii ISO 2014 All rights reservedCOPYRIGHT PROTECTED DOCUMENT ISO 201

6、4All rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized otherwise in any form or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior written permission. Permission can be requeste

7、d from either ISO at the address below or ISOs member body in the country of the requester.ISO copyright officeCase postale 56 CH-1211 Geneva 20Tel. + 41 22 749 01 11Fax + 41 22 749 09 47E-mail copyrightiso.orgWeb www.iso.orgPublished in SwitzerlandBS ISO 12000:2014ISO 12000:2014(E) ISO 2014 All rig

8、hts reserved iiiContents PageForeword iv1 Scope . 12 Normative references 13 Terms and definitions . 34 Sampling 35 Conditioning 36 Test methods . 37 Precision of the test methods used 58 Test report . 5BS ISO 12000:2014ISO 12000:2014(E)ForewordISO (the International Organization for Standardization

9、) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established has the right to be repr

10、esented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization.The procedures used to deve

11、lop this document and those intended for its further maintenance are described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the different types of ISO documents should be noted. This document was drafted in accordance with the editorial rules of the ISO

12、/IEC Directives, Part 2 (see www.iso.org/directives).Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rights. Details of any patent rights identified during t

13、he development of the document will be in the Introduction and/or on the ISO list of patent declarations received (see www.iso.org/patents).Any trade name used in this document is information given for the convenience of users and does not constitute an endorsement.For an explanation on the meaning

14、of ISO specific terms and expressions related to conformity assessment, as well as information about ISOs adherence to the WTO principles in the Technical Barriers to Trade (TBT) see the following URL: Foreword - Supplementary informationThe committee responsible for this document is ISO/TC 61, Plas

15、tics, Subcommittee SC 9, Thermoplastic materials in collaboration with ISO/TC 45, Rubber and rubber products.This third edition cancels and replaces the second edition (ISO 12000:2000), which has been technically revised to update the references to the test methods and change dated references to und

16、ated references.iv ISO 2014 All rights reservedBS ISO 12000:2014INTERNATIONAL STANDARD ISO 12000:2014(E)Plastics/rubber Polymer dispersions and rubber latices (natural and synthetic) Definitions and review of test methods1 ScopeThis International Standard gives definitions relative to polymer disper

17、sions and latices and identifies the test methods applicable for determining the properties of polymer dispersions, comprising products of synthetic or natural origin including synthetic and natural rubber latices. Some of the test methods apply only to polymer dispersions or latices of specific che

18、mical composition or to those to be used for specific applications.NOTE When they are not the subject of an existing International Standard, the test methods to be used for investigation of an individual polymer dispersion or latex are intended to be the subject of an agreement between the intereste

19、d parties.2 Normative referencesThe following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including

20、any amendments) applies.ISO 35, Natural rubber latex concentrate Determination of mechanical stabilityISO 123, Rubber latex SamplingISO 124, Latex, rubber Determination of total solids contentISO 125, Natural rubber latex concentrate Determination of alkalinityISO 126, Natural rubber latex concentra

21、te Determination of dry rubber contentISO 127, Rubber, natural latex concentrate Determination of KOH numberISO 291, Plastics Standard atmospheres for conditioning and testingISO 472, Plastics VocabularyISO 506, Rubber latex, natural, concentrate Determination of volatile fatty acid numberISO 705, R

22、ubber latex Determination of density between 5 C and 40 CISO 706, Rubber latex Determination of coagulum content (sieve residue)ISO 976, Rubber and plastics Polymer dispersions and rubber latices Determination of pHISO 1147, Plastics/rubber Polymer dispersions and synthetic rubber latices Freeze-tha

23、w cycle stability testISO 1409, Plastics/rubber Polymer dispersions and rubber latices (natural and synthetic) Determination of surface tension by the ring methodISO 1652, Rubber latex Determination of apparent viscosity by the Brookfield test methodISO 1656, Rubber, raw natural, and rubber latex, n

24、atural Determination of nitrogen content ISO 2014 All rights reserved 1BS ISO 12000:2014ISO 12000:2014(E)ISO 1657, Rubber, raw and rubber latex Determination of iron content 1,10-Phenanthroline photometric methodISO 1802, Natural rubber latex concentrate Determination of boric acid contentISO 2005,

25、Rubber latex, natural, concentrate Determination of sludge contentISO 2006-1, Rubber latex, synthetic Determination of mechanical stability Part 1: High-speed methodISO 2006-2, Rubber latex, synthetic Determination of mechanical stability Part 2: Moderate-speed method under loadISO 2115, Plastics Po

26、lymer dispersions Determination of white point temperature and minimum film-forming temperatureISO 23529, Rubber General procedures for preparing and conditioning test pieces for physical test methodsISO 2555, Plastics Resins in the liquid state or as emulsions or dispersions Determination of appare

27、nt viscosity by the Brookfield Test methodISO 2811-1, Paints and varnishes Determination of density Part 1: Pyknometer methodISO 2811-3, Paints and varnishes Determination of density Part 3: Oscillation methodISO 3136, Rubber latex Styrene-butadiene Determination of bound styrene contentISO 3219, Pl

28、astics Polymers/resins in the liquid state or as emulsions or dispersions Determination of viscosity using a rotational viscometer with defined shear rateISO 3251, Paints, varnishes and plastics Determination of non-volatile-matter contentISO 3899, Rubber Nitrile latex Determination of residual acry

29、lonitrile contentISO 3900, Rubber Nitrile latex Determination of bound acrylonitrile contentISO 4576, Plastics Polymer dispersions Determination of sieve residue (gross particle and coagulum content)ISO 4655, Rubber Reinforced styrene-butadiene latex Determination of total bound styrene contentISO 7

30、143, Binders for paints and varnishes Methods of test for characterizing water-based bindersISO 7780, Rubbers and rubber latices Determination of manganese content Sodium periodate photometric methodsISO 8053, Rubber and latex Determination of copper content Photometric methodISO 9252, Synthetic rub

31、ber latex Microbiological examinationISO 13741-1, Plastics/rubber Polymer dispersions and rubber latices (natural and synthetic) Determination of residual monomers and other organic components by capillary-column gas chromatography Part 1: Direct liquid injection methodISO 13741-2, Plastics/rubber P

32、olymer dispersions and rubber latices (natural and synthetic) Determination of residual monomers and other organic components by capillary-column gas chromatography Part 2: Headspace methodISO 13773, Rubber Polychloroprene latex Determination of alkalinityISO 23529, Rubber General procedures for pre

33、paring and conditioning test pieces for physical test methodsNOTE Where individual standards overlap, it is intended that they will be harmonized by the Technical Committees responsible for them, ISO/TC 45 and ISO/TC 61.2 ISO 2014 All rights reservedBS ISO 12000:2014ISO 12000:2014(E)3 Terms and defi

34、nitionsFor the purposes of this document, the following terms and definitions apply.3.1dispersionheterogeneous system in which a finely divided material is distributed in another materialSOURCE: ISO 4723.2polymer dispersionliquid to semi-liquid material, usually milky-white, containing the polymeric

35、 material in a stable condition finely dispersed in a continuous liquid phase, normally water3.3latexcolloidal aqueous dispersion of a polymeric materialSOURCE: ISO 472Note 1 to entry: Frequently, “latex” is also used as a synonym for polymer dispersions in general.Note 2 to entry: Polymer dispersio

36、ns and latices are often further explained by adding the designation of the base polymer by name or by abbreviation, for instance polyacrylate dispersion, SBR latex.4 SamplingSampling shall be carried out in accordance with ISO 123 (rubber latex).Representative samples of polymer dispersions and of

37、latices are a prerequisite for reliable and reproducible results from the test methods. Therefore the material to be tested shall be uniform.5 ConditioningThe conditioning and testing atmosphere shall comply with the specified test method or referring standard, as applicable. If there are no such re

38、quirements, then samples shall be conditioned and tests carried out in one of the standard atmospheres specified in either ISO 291 for polymer dispersions or ISO 23529 for latices, as appropriate.6 Test methodsTest methods shall be selected from those given in Table 1 for rubber latices, and those i

39、n Table 2 for polymer dispersions, as appropriate. ISO 2014 All rights reserved 3BS ISO 12000:2014ISO 12000:2014(E)Table 1 Test methods developed by ISO/TC 45Property Units Test method CommentsPhysical and physico-chemical propertiesMechanical stability s ISO 35 Natural rubber latex onlyTotal solids

40、 content % (m/m) ISO 124 Alkalinity g/100 g of latexISO 125 Natural rubber latex onlyDry rubber content % (m/m) ISO 126 Natural rubber latex onlyDensity Mg/m3ISO 705 Natural rubber latex onlyCoagulum content (sieve residue) % (m/m) ISO 706apH pH-units ISO 976aSurface tension mN/m ISO 1409 Viscosity

41、mPa s ISO 1652 Apparent viscositySludge content % (m/m) ISO 2005 Natural rubber latex onlyHigh-speed mechanical stability % (m/m) ISO 2006 Synthetic rubber latex onlyMicrobiological examination ISO 9252 Chemical propertiesKOH number ISO 127 Natural rubber latex onlyVolatile fatty acid number ISO 506

42、 Natural rubber latex onlyNitrogen content % (m/m) ISO 1656 Natural rubber latex onlyIron content (1,10-phenanthroline photo-metric method)ppm (m/m) ISO 1657 Boric acid content % (m/m) ISO 1802 Natural rubber latex onlyBound styrene content % (m/m) ISO 3136 Styrene-butadiene latexResidual acrylonitr

43、ile content % (m/m) ISO 3899 Nitrile latexBound acrylonitrile content % (m/m) ISO 3900 Nitrile latexTotal bound styrene content % (m/m) ISO 4655 Reinforced styrene-butadiene latexManganese content (sodium periodate photometric method)mg/kg ISO 7780 Copper content (photometric method) mg/kg ISO 8053

44、Synthetic rubber latex onlyAlkalinity mmol HCl per 100 gISO 13773 GeneralSampling ISO 123aTest methods for polymer dispersions used as raw materials for paints are specified in ISO 7143.4 ISO 2014 All rights reservedBS ISO 12000:2014ISO 12000:2014(E)Table 2 Test methods developed by ISO/TC 61Propert

45、y Units Test method CommentsPhysical and physico-chemical propertiesNon-volatile matter at specified tempera-tures% (m/m) ISO 3251bApparent viscosity by Brookfield Test method (general procedure)Pa s ISO 2555 Density g/ml ISO 2811-1bISO 2811-3bViscosity using rotational viscometer at defined shear r

46、atePa s ISO 3219 aGross particle content by sieve analysis % (m/m) ISO 4576 aResidue on sieve(s) substantially larger than average particle sizeChemical propertiesResidual monomers and other organic constituents by capillary-column gas chromatographymg/kgISO 13741-1aISO 13741-2aDirect liquid injecti

47、on method Headspace methodGeneralFreezethaw cycle stability White point temperature and minimum film-forming temperaturenumber of cycles CISO 1147 ISO 2115Generally, applicable only to poly-mer dispersionsaTest methods for polymer dispersions used as raw materials for paints are specified in ISO 714

48、3.bDeveloped by ISO/TC 35.7 Precision of the test methods usedDetails of the precision of the test method used shall be given in a “Precision” clause. If the experimental data on which the stated precision is based are included in the standard, this may be placed in an informative annex. The precisi

49、on shall be expressed as a percentage of the results in terms of the following:a) repeatability;b) reproducibility.8 Test reportThe results of the individual tests performed on a polymer dispersion/latex shall be recorded in a test report. This shall comply with the requirements of the particular International Standard in question, but shall include at least the following information:a) a refer