BS ISO 12219-2-2012 Interior air of road vehicles Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Ba.pdf

1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS ISO 12219-2:2012Interior air of road vehiclesPart 2: Screening method for thedetermination of the emissions of volatileorganic compounds from vehicle interiorparts and materia

2、ls Bag methodBS ISO 12219-2:2012 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of ISO 12219-2:2012.The UK participation in its preparation was entrusted to TechnicalCommittee EH/2/3, Ambient atmospheres.A list of organizations represented on this committee can beobt

3、ained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2012. Published by BSI StandardsLimited 2012ISBN 978 0 580 72177 9ICS 13.040.20; 43.020Complia

4、nce with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 30 June 2012.Amendments issued since publicationDate Text affectedBS ISO 12219-2:2012 ISO 2012Interior air of road vehicle

5、s Part 2: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Bag methodAir intrieur des vhicules routiers Partie 2: Mthode de criblage pour la dtermination des missions de composs organiques volatils des parties et des matr

6、iaux intrieurs des vhicules Mthode du sacINTERNATIONAL STANDARDISO12219-2First edition2012-06-15Reference numberISO 12219-2:2012(E)BS ISO 12219-2:2012ISO 12219-2:2012(E)ii ISO 2012 All rights reservedCOPYRIGHT PROTECTED DOCUMENT ISO 2012All rights reserved. Unless otherwise specified, no part of thi

7、s publication may be reproduced or utilized in any form or by any means, electronic or mechanical, including photocopying and microfilm, without permission in writing from either ISO at the address below or ISOs member body in the country of the requester.ISO copyright officeCase postale 56 CH-1211

8、Geneva 20Tel. + 41 22 749 01 11Fax + 41 22 749 09 47E-mail copyrightiso.orgWeb www.iso.orgPublished in SwitzerlandBS ISO 12219-2:2012ISO 12219-2:2012(E) ISO 2012 All rights reserved iiiContents PageForeword ivIntroduction v1 Scope 12 Normative references . 13 Terms and definitions . 14 Principle . 2

9、5 Apparatus and materials . 26 Test conditions . 46.1 General . 46.2 Test specimen size 46.3 Curing conditions (storage period and storage conditions) . 46.4 Heating temperature . 46.5 Heating time 46.6 Gas amount to be filled in a sampling bag . 47 Verification of test conditions 57.1 Monitoring of

10、 test conditions . 57.2 Recovery rate . 58 Test method 58.1 Test equipment . 58.2 Preparation for testing . 58.3 Emission test 58.4 Gas collection . 69 Analytical procedures 69.1 Analysis of VOCs . 69.2 Analysis of formaldehyde and other carbonyl compounds 610 Calculation of sampling bag values . 71

11、1 Test report . 712 Quality assurance/quality control . 8Annex A (informative) General procedures for preparation and storage of test specimens . 11Annex B (informative) Additional information on test report and recovery rate .12Bibliography .14BS ISO 12219-2:2012ISO 12219-2:2012(E)ForewordISO (the

12、International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee

13、 has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnic

14、al standardization.International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2.The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodi

15、es for voting. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote.Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any o

16、r all such patent rights.ISO 12219-2 was prepared by Technical Committee ISO/TC 146, Air quality, Subcommittee SC 6, Indoor air, in collaboration with Technical Committee ISO/TC 22, Road vehicles.ISO 12219 consists of the following parts, under the general title Interior air of road vehicles: Part 1

17、: Whole vehicle test chamber Specification and method for the determination of volatile organic compounds in cabin interiors Part 2: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Bag method Part 3 Screening method for

18、the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Micro-scale chamber method Part 4: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Small chamber methodThe follow

19、ing part is under preparation: Part 5: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materials Static chamber methodiv ISO 2012 All rights reservedBS ISO 12219-2:2012ISO 12219-2:2012(E)IntroductionVolatile organic compounds (VOC

20、s) are widely used in industry and may be emitted by many everyday products and materials. They have attracted much attention in recent years because of their impact on indoor air quality. After homes and workplaces, people spend a lot of time in their vehicles. It is important to determine the mate

21、rial emissions of interior parts and to reduce them to an acceptable level, if required. Therefore it is necessary to obtain comprehensive and reliable information about the types of organic compounds in the interior air of vehicles and also their concentrations.This part of ISO 12219 outlines the s

22、ampling bag test method for the screening of VOCs, formaldehyde and other carbonyl compounds which diffuse from vehicle interior parts into the air inside road vehicles.Measuring VOCs from vehicle interior parts can be performed in several ways and the approach selected depends upon the desired outc

23、ome and the material type. For example, to obtain diffusion data from complete assemblies (e.g. instrument panel, seat etc.) it is necessary to employ chambers / bags that have sufficient volume to house the complete assembly. Meanwhile, to obtain diffusion data from representative samples of homoge

24、neous vehicle interior materials, the micro-scale chamber method can be chosen.Each measurement method such as bag/micro-scale chamber/small-chamber sampling offers a complementary approach.ISO 16000-3, ISO 16000-5,2ISO 16000-6, ISO 16000-9,3ISO 16000-10,4ISO 16000-11,5ISO 16000-24,6ISO 16000-25,7as

25、 well as ISO 16017-1 and ISO 16017-28also focus on VOC measurements. ISO 2012 All rights reserved vBS ISO 12219-2:2012BS ISO 12219-2:2012Interior air of road vehicles Part 2: Screening method for the determination of the emissions of volatile organic compounds from vehicle interior parts and materia

26、ls Bag methodWARNING It is the responsibility of the user of this part of ISO 12219 to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. National regulations for precautions shall be followed.1 ScopeThis part of ISO 12219 specif

27、ies the sampling bag test method for measuring volatile organic compounds (VOCs), formaldehyde and other carbonyl compounds which may diffuse from vehicle interior parts into the air inside road vehicles. This method is intended for evaluating and screening new vehicle interior parts and materials s

28、uch as seats, the instrument panel, ceiling materials and so on.The test method specified in this part of ISO 12219 specifies a procedure for screening of VOCs, formaldehyde and other carbonyl compounds using sampling bags.This part of ISO 12219 provides third party test laboratories and manufacturi

29、ng industry with a cost-effective approach for:a) evaluating and screening prototype, “low-diffusion” materials or products during development;b) comparing diffusions from products within a range (e.g. different colours or patterns).This part of ISO 12219 specifies the design, construction, performa

30、nce, evaluation, and use of sampling bags for testing vapour-phase organic emissions diffused from vehicle interior parts.2 Normative referencesThe following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated

31、 references, the latest edition of the referenced document (including any amendments) applies.ISO 16000-3, Indoor air Part 3: Determination of formaldehyde and other carbonyl compounds in indoor air and test chamber air Active sampling methodISO 16000-6:2011, Indoor air Part 6: Determination of vola

32、tile organic compounds in indoor and test chamber air by active sampling on Tenax TAsorbent, thermal desorption and gas chromatography using MS or MS-FID sorbent, thermal desorption and gas-chromatography using MS or MS-FIDISO 16017-1, Indoor, ambient and workplace air Sampling and analysis of volat

33、ile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 1: Pumped sampling3 Terms and definitionsFor the purposes of this document, the following terms and definitions apply.INTERNATIONAL STANDARD ISO 12219-2:2012(E) ISO 2012 All rights reserved 1BS ISO 12219-2:201

34、2ISO 12219-2:2012(E)3.1vehicle interior partpart which is used in the interior of a vehicle including related materials such as adhesives and coating materials3.2sampling bag valueconcentration increment of a subject gas component due to the diffusion of VOCs, formaldehyde and other carbonyl compoun

35、ds from a test specimen, multiplied by the total amount of the gas filling the sampling bag3.3test specimencomponent part or representative sample of material cut out from vehicle interior parts which are to be tested3.4volatile organic compoundVOCorganic compound whose boiling point is in the range

36、 from (50 C to 100 C) to (240 C to 260 C)ISO 16000-6:2011, 3.23.5total volatile organic compoundTVOCsum of volatile organic compounds sampled on Tenax TA1)and eluting between and including n-hexane and n-hexadecane, detected with a flame ionization detector (TVOCFID) or mass spectrometric detector (

37、TVOCMS), and quantified by converting the total area of the chromatogram in that analytical window to toluene equivalentsNOTE Adapted from ISO 16000-6:2011, 3.4.4 PrincipleThe test method specified in this part of ISO 12219 is a procedure for calculating sampling bag values of VOCs, formaldehyde, an

38、d other carbonyl compounds which may diffuse from vehicle interior parts.One or multiple test specimens put in a sampling bag are heated to a specified temperature, then a fraction of the gas in the sampling bag is collected to measure the test concentrations. By comparing the test concentrations wi

39、th the corresponding blank concentrations, the sampling bag values of VOCs, formaldehyde, and other carbonyl compounds diffusing from one test specimen can be calculated (see Clause 10).The analytical part of the overall measurement procedure is based on the use of sorbent tubes with subsequent ther

40、mal desorption and gas chromatographic analysis for VOCs (according to ISO 16000-6) and the use of 2,4-dinitrophenylhydrazine (DNPH) sorbent tubes, followed by high performance liquid chromatography (HPLC) analysis with ultraviolet absorption for the determination of formaldehyde and other carbonyl

41、compounds (according to ISO 16000-3).The specified analytical procedure is valid for the determination of VOCs ranging in concentration from sub-microgram per metre cubed to several milligrams per metre cubed. The method is applicable to the measurement of non-polar and slightly polar VOCs ranging i

42、n volatility from n-C6to n-C16.The specified analytical procedure for formaldehyde and other carbonyl compounds is valid for the determination of carbonyl compounds within the concentration range of approximately 1 g/m3to 1 mg/m3.5 Apparatus and materials5.1 General. The test apparatus and materials

43、 necessary for determining the sampling bag values of VOCs, formaldehyde and other carbonyl compounds diffusing from vehicle interior parts are mainly as follows:1) Tenax TA is the trade name of a product supplied by Buchem. This information is given for the convenience of users of this document and

44、 does not constitute an endorsement by ISO of the product named. Equivalent products may be used if they can be shown to lead to the same results.2 ISO 2012 All rights reservedBS ISO 12219-2:2012ISO 12219-2:2012(E) sampling bag; nitrogen gas or air (filling gas); thermostatic oven; pumps; integratin

45、g flow meter; gas analyser; sorbent tube and DNPH cartridge.5.2 Sampling bag.5.2.1 General. Sampling bags used in this part of ISO 12219 shall be in accordance with 5.2.2, 5.2.3, 5.2.4 and 7.2.5.2.2 Material and capacity. The sampling bag material shall be inert, impermeable, and non-sorbing e.g. fl

46、uorinated resins, such as poly(vinyl fluoride) (PVF) or perfluoro(ethylene/propylene) plastic and shall meet the performance characteristics specified in 7.2. The bag capacity shall be at least 10 l.5.2.3 Airtightness. Sampling bags shall be sealed securely with low-emitting tape or heat bonded so a

47、s to be isolated from the uncontrolled ambient air.5.2.4 Blank concentration. Blank concentrations (background artefacts) which are observed when a sampling bag is heated to test temperature (65 C) without any sample present, shall be as low as possible (e.g. below 0,075 g/bag for formaldehyde and o

48、ther carbonyl compounds and below 0,05 g/bag for VOCs) so that they do not interfere with the test results.5.3 Purity of the gas. The nitrogen gas or air introduced to the sampling bag shall be pure and dry. The concentrations of VOCs, formaldehyde and other carbonyl compounds shall be as low as pos

49、sible so that they do not adversely affect the test results.The purity of the gas or air shall fulfil the requirements of ISO 16000-3 and ISO 16000-6.5.4 Thermostatic oven. Temperature shall be controlled in an oven which is capable of maintaining a constant and homogeneous temperature.The thermostatic oven where a sampling bag is heated shall be capable of uniformly controlling temperatures within 1 C.5.5 Pumps. Vacuum pumps or other apparatus which can be used to evacuate sampling