BS ISO 18263-2-2015 Plastics Mixtures of polypropylene (PP) and polyethylene (PE) recyclate derived from PP and PE used for flexible and rigid consumer packaging Preparation of tes.pdf

1、BSI Standards PublicationBS ISO 18263-2:2015Plastics Mixtures ofpolypropylene (PP) andpolyethylene (PE) recyclatederived from PP and PE usedfor flexible and rigid consumerpackagingPart 2: Preparation of test specimens anddetermination of propertiesBS ISO 18263-2:2015 BRITISH STANDARDNational forewor

2、dThis British Standard is the UK implementation of ISO 18263-2:2015.The UK participation in its preparation was entrusted to TechnicalCommittee PRI/82, Thermoplastic materials.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not p

3、urport to include all the necessaryprovisions of a contract. Users are responsible for its correctapplication. The British Standards Institution 2015.Published by BSI Standards Limited 2015ISBN 978 0 580 83015 0ICS 83.080.20Compliance with a British Standard cannot confer immunity fromlegal obligati

4、ons.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 30 November 2015.Amendments/corrigenda issued since publicationDate T e x t a f f e c t e dBS ISO 18263-2:2015 ISO 2015Plastics Mixtures of polypropylene (PP) and polyethylene (PE) recyclate

5、derived from PP and PE used for flexible and rigid consumer packaging Part 2: Preparation of test specimens and determination of propertiesPlastiques Recyclat mixte de polypropylne (PP) et polythylne (PE) Partie 2: Prparation des prouvettes et dtermination des propritsINTERNATIONAL STANDARDISO18263-

6、2First edition2015-11-01Reference numberISO 18263-2:2015(E)BS ISO 18263-2:2015ISO 18263-2:2015(E)ii ISO 2015 All rights reservedCOPYRIGHT PROTECTED DOCUMENT ISO 2015, Published in SwitzerlandAll rights reserved. Unless otherwise specified, no part of this publication may be reproduced or utilized ot

7、herwise in any form or by any means, electronic or mechanical, including photocopying, or posting on the internet or an intranet, without prior written permission. Permission can be requested from either ISO at the address below or ISOs member body in the country of the requester.ISO copyright offic

8、eCh. de Blandonnet 8 CP 401CH-1214 Vernier, Geneva, SwitzerlandTel. +41 22 749 01 11Fax +41 22 749 09 47copyrightiso.orgwww.iso.orgBS ISO 18263-2:2015ISO 18263-2:2015(E)Foreword iv1 Scope . 12 Normative references 13 Terms and definitions . 24 Preparation of test specimens 25 Conditioning of test sp

9、ecimens . 26 Determination of ratio of PP and PE 27 Determination of properties 2Annex A (informative) Determination of the ratio of PP and PE by the FTIR spectrometer 4Annex B (informative) The properties of the PP and PE mixture . 6Bibliography 9 ISO 2015 All rights reserved iiiContents PageBS ISO

10、 18263-2:2015ISO 18263-2:2015(E)ForewordISO (the International Organization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body intere

11、sted in a subject for which a technical committee has been established has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical

12、Commission (IEC) on all matters of electrotechnical standardization.The procedures used to develop this document and those intended for its further maintenance are described in the ISO/IEC Directives, Part 1. In particular the different approval criteria needed for the different types of ISO documen

13、ts should be noted. This document was drafted in accordance with the editorial rules of the ISO/IEC Directives, Part 2 (see www.iso.org/directives).Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible

14、for identifying any or all such patent rights. Details of any patent rights identified during the development of the document will be in the Introduction and/or on the ISO list of patent declarations received (see www.iso.org/patents).Any trade name used in this document is information given for the

15、 convenience of users and does not constitute an endorsement.For an explanation on the meaning of ISO specific terms and expressions related to conformity assessment, as well as information about ISOs adherence to the WTO principles in the Technical Barriers to Trade (TBT) see the following URL: For

16、eword - Supplementary informationThe committee responsible for this document is ISO/TC 61, Plastics, Subcommittee SC 9, Thermoplastic materials.ISO 18263 consists of the following parts, under the general title Plastics Mixtures of polypropylene (PP) and polyethylene (PE) recyclate derived from PP a

17、nd PE used for flexible and rigid consumer packaging: Part 1: Designation system and basis for specification Part 2: Preparation of test specimens and determination of propertiesiv ISO 2015 All rights reservedBS ISO 18263-2:2015INTERNATIONAL STANDARD ISO 18263-2:2015(E)Plastics Mixtures of polypropy

18、lene (PP) and polyethylene (PE) recyclate derived from PP and PE used for flexible and rigid consumer packaging Part 2: Preparation of test specimens and determination of properties1 ScopeThis part of ISO 18263 specifies methods of preparation of test specimens and the standard test methods to be us

19、ed in determining the properties of mixtures of polypropylene (PP) and polyethylene (PE) recyclate derived from PP and PE used for flexible and rigid consumer packaging for moulding and extrusion. Recyclate from packaging used for the transport, handling, or storage of hazardous goods is not to be u

20、sed. Since it is impossible to get the information about stabilizer levels of recyclate, it is necessary to add stabilizer as needed. Requirements for handling test material and for conditioning both the test material before moulding and the specimens before testing are given in this part of ISO 182

21、63.2 Normative referencesThe following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any ame

22、ndments) applies.ISO 178, Plastics Determination of flexural propertiesISO 179-1, Plastics Determination of Charpy impact properties Part 1: Non-instrumented impact testISO 179-2, Plastics Determination of Charpy impact properties Part 2: Instrumented impact testISO 291, Plastics Standard atmosphere

23、s for conditioning and testingISO 472, Plastics VocabularyISO 527-1, Plastics Determination of tensile properties Part 1: General principlesISO 527-2, Plastics Determination of tensile properties Part 2: Test conditions for moulding and extrusion plasticsISO 1133-1, Plastics Determination of the mel

24、t mass-flow rate (MFR) and melt volume-flow rate (MVR) of thermoplastics Part 1: Standard methodISO 1183-1, Plastics Methods for determining the density of non-cellular plastics Part 1: Immersion method, liquid pyknometer method and titration methodISO 1183-2, Plastics Methods for determining the de

25、nsity of non-cellular plastics Part 2: Density gradient column methodISO 1183-3, Plastics Methods for determining the density of non-cellular plastics Part 3: Gas pyknometer methodISO 1873-2, Plastics Polypropylene (PP) moulding and extrusion materials Part 2: Preparation of test specimens and deter

26、mination of properties ISO 2015 All rights reserved 1BS ISO 18263-2:2015ISO 18263-2:2015(E)ISO 10350-1, Plastics Acquisition and presentation of comparable single-point data Part 1: Moulding materialsISO 15270, Plastics Guidelines for the recovery and recycling of plastics wasteISO 18263-1, Plastics

27、 Mixtures of polypropylene (PP) and Polyethylene (PE) recyclate derived from PP and PE used for flexible and rigid consumer packaging Part 1: Designation system and basis for specificationsISO 20753, Plastics Test specimens3 Terms and definitionsFor the purposes of this document, the terms and defin

28、itions given in ISO 472 and ISO 15270 apply.4 Preparation of test specimensThe test specimens shall be prepared in accordance with ISO 1873-2 and shall be tested in accordance with each test method indicated in Table 1. It is essential that specimens are always prepared by the same procedure using t

29、he same processing conditions.5 Conditioning of test specimensTest specimens for the determination of mechanical properties and density shall be conditioned in accordance with ISO 291 for 40 h to 96 h at 23 C 2 C.6 Determination of ratio of PP and PEThe ratio of PP and PE shall be determined in acco

30、rdance with traceable documents from the supplier.NOTE In regard to the procedures etc. needed for the traceable documents on the recycled plastics, it is recommended to use EN 15343 or ISO/IEC 17050-1 and ISO/IEC 17050-2 as references. It is known that the ratio of PP and PE can be determined by FT

31、IR spectrometer, but sufficient precision data, especially including other materials, is not yet available (see Annex A).7 Determination of propertiesIn the determination of properties and the presentation of data, the standards, supplementary instructions, and notes given in ISO 10350-1 shall be ap

32、plied. All tests shall be carried out in the standard atmosphere of 23 C 2 C, unless specifically stated otherwise in Table 1 and Table 2.Table 1 is compiled from ISO 10350-1 and the properties listed are those which are appropriate for the mixtures of PP and PE recyclate for moulding and extrusion

33、materials. These properties are those considered useful for comparisons of data generated for different thermoplastics.Table 2 contains those properties which are in wide use or of particular significance in the practical characterization of mixtures PP and PE recyclate for moulding and extrusion ma

34、terials.NOTE This recyclate is derived from PP and PE used for flexible and rigid consumer packaging for moulding and extrusion. Therefore, there is no information about a stabilizer of recyclate and it may be necessary to add a stabilizer as needed.2 ISO 2015 All rights reservedBS ISO 18263-2:2015I

35、SO 18263-2:2015(E)Table 1 General properties and test conditions (selected from ISO 10350-1)Property Unit StandardSpecimen type (dimensions in mm)Test conditions and supplementary instructionRheological propertiesMelt mass-flow rate (MFR)g/10 minISO 1133-1 Moulding compoundTemperature 230 C, load 2,

36、16 kgMechanical propertiesTensile yield stress MPaISO 527-1 ISO 527-2Injection-moulded type A1 test specimen as defined in ISO 20753Test speed 50 mm/minTensile stress at break%Test speed 5 mm/min Only to be quoted if strain at break is under 10 %Flexural modulus MPaISO 178Injection-moulded type B2 t

37、est specimen as defined in ISO 20753 (80 10 4)Test speed 2 mm/minFlexural strength MPaCharpy unnotched impact strengthkJ/m2ISO 179-1ISO 179-2Injection-moulded type B2 test specimen as defined in ISO 20753 (80 10 4)Edgewise impact Also record type of failure (see ISO 179-1)Charpy notched impact stren

38、gthTable 2 Additional properties and test conditionProperty Unit Standard Specimen typeTest conditions and supplementary instructionBasic propertiesPP/PE composition (by mass)% ISO 18263-1Moulding compoundSee Clause 6Density g/cm3ISO 1183-1, ISO 1183-2, or ISO 1183-3Strand after measured MFRThe meth

39、ods specified in ISO 1183-1, ISO 1183-2 and ISO 1183-3 are regarded as equivalent for the purposes of this part of ISO 18263Colour ISO 18263-1Moulding compoundVisual inspection specified in ISO 18263-1Form ISO 18263-1Moulding compoundVisual inspection specified in ISO 18263-1 ISO 2015 All rights res

40、erved 3BS ISO 18263-2:2015ISO 18263-2:2015(E)Annex A (informative) Determination of the ratio of PP and PE by the FTIR spectrometerA.1 GeneralThis annex shows the relationship between the ratio of IR absorbance at 1 370 cm1and 1 464 cm1and a PP and PE blend ratio of the mixture of virgin PP and PE o

41、btained by using FTIR. This relationship is useful for presuming the ratio of PP and PE in a recyclate.NOTE Since the recyclate included a PP/PE copolymer etc., the PP/PE ratio calculated from this relationship is just a reference and it cannot be used for deciding the composition indicated in Table

42、 2.A.2 SamplesThe samples were blended by test roll machine under about 200 C.PE-LLD: MFR = 1,0 g/10 min, density = 0,926 g/cm3PP (Homo-PP): MFR = 7,7 g/10 minTable A.1 Prepared samplesmass %No. 1 No. 2 No. 3 No. 4 No. 5 No. 6 No. 7 No. 8 No. 9 No. 10 No. 11PE 100 95 90 85 75 50 25 15 10 5 0PP 0 5 1

43、0 15 25 50 75 85 90 95 100A.3 IR measurementsAll samples were measured by the FTIR with the following condition.ATR method: Using Zn-Se crystalWave number regions: 4 000 650 cm1Cumulated number: 64 timesResolution: 4 cm1A.4 ResultPlot the ratio of A (1 370 cm1)/A (1 464 cm1) against the ratio of PP

44、and PE (see Figure A.1).A.5 Estimation of ratio of PP and PECalculate the ratio of PP and PE using the formula in Figure A.1.4 ISO 2015 All rights reservedBS ISO 18263-2:2015ISO 18263-2:2015(E)y = 0,0195x + 0,031R = 0,99262,00001,80000 10 20 30 40 50 60 70 80 90 100A(1 370 cm )/A(1 464 cm )-1-11,600

45、01,40001,20001,00000,80000,60000,40000,20000,0000Figure A.1 Relationship between A (1 370 cm1)/A (1 464 cm1) and PP content for PP and PE blend ISO 2015 All rights reserved 5BS ISO 18263-2:2015ISO 18263-2:2015(E)Annex B (informative) The properties of the PP and PE mixtureB.1 GeneralThis annex shows

46、 the relationship between PP/PE blend ratio of mixture and tensile properties (strength and elongation) or morphology using mixture of virgin PP and PE. From this diagram, it is useful for estimation of the tensile properties of a recyclate. This annex shows the relationships schematically. Therefor

47、e, these data shall not be used for calculating the composition of the recyclates.B.2 Preparation of samplesPP and PE were melt blended in a laboratory twin screw type batch mixer at the compositions 0 %, 30 %, 50 %, 70 %, and 100 % of PE by mass. Sheets of 150 mm 150 mm 0,5 mm were prepared by comp

48、ression moulding. Pre heat: 220 C, 5 min Press: 220 C, 10 MPa, 5 min Cooling: 30 C, 10 MPa, 5 minPE-HD: MFR = 0,36 g/10 min (at 190 C 2,16 kg), density = 0,956 g/cm3PP: MFR = 3,1 g/10 min (at 230 C 2,16 kg), Homo-PPTable B.1 Prepared samplesmass %No1 2 3 4 5MaterialsPE 100 70 50 30 0PP 0 30 50 70 10

49、0The tensile test specimens, ISO 527-3 Type 2 (width = 15 mm), were prepared by cutting from each blend sheet. The specimens for tensile test were conditioning at (23 2) C for at least 4 h.B.3 Tensile testB.3.1 Test conditionsTest speed: 50 mm/minInitial distance between grips: 100 mmTest condition: (23 2) C6 ISO 2015 All rights reservedBS ISO 18263-2:2015ISO 18263-2:2015(E)B.3.2 Result