CEN TS 16516-2013 Construction products - Assessment of release of dangerous substances - Determination of emissions into indoor air《建筑产品 危险物质释放的评估 室内空气排放测定》.pdf

1、BSI Standards PublicationConstruction products Assessment of release of dangerous substances Determination of emissions into indoor airPD CEN/TS 16516:2013National forewordThis Published Document is the UK implementation of CEN/TS 16516:2013.The UK participation in its preparation was entrusted to T

2、echnicalCommittee B/557, Construction products - Assessment of dangerous substances.A list of organizations represented on this committee can be obtained onrequest to its secretary.This publication does not purport to include all the necessary provisions ofa contract. Users are responsible for its c

3、orrect application. The British Standards Institution 2013.Published by BSI Standards Limited 2013ISBN 978 0 580 57317 0ICS 13.040.20; 91.100.01Compliance with a British Standard cannot confer immunity fromlegal obligations.This Published Document was published under the authority of theStandards Po

4、licy and Strategy Committee on 31 October 2013.Amendments/corrigenda issued since publicationDate Text affectedPUBLISHED DOCUMENTPD CEN/TS 16516:2013TECHNICAL SPECIFICATION SPCIFICATION TECHNIQUE TECHNISCHE SPEZIFIKATION CEN/TS 16516 October 2013 ICS 13.040.20; 91.100.01 English Version Construction

5、 products - Assessment of release of dangerous substances - Determination of emissions into indoor air Produits de construction - Dtermination des missions de substances dangereuses - Dtermination des missions dans lair intrieur Bauprodukte - Bewertung der Freisetzung von gefhrlichen Stoffen - Besti

6、mmung von Emissionen in die InnenraumluftThis Technical Specification (CEN/TS) was approved by CEN on 25 May 2013 for provisional application. The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit their comments, par

7、ticularly on the question whether the CEN/TS can be converted into a European Standard. CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS available promptly at national level in an appropriate form. It is permissible to keep conflic

8、ting national standards in force (in parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yug

9、oslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPE

10、N DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2013 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. CEN/TS 16516:2013: EPD CEN/TS 16516:2013CEN/TS 16516:2013 (E) 2 Co

11、ntents Page Introduction .5 1 Scope 7 2 Normative references 7 3 Terms, definitions and abbreviations 7 3.1 Terms relating to sampling and products .8 3.2 Terms relating to emissions into indoor air and associated laboratory testing 10 3.3 Terms relating to determination of emitted substances. 13 3.

12、4 Abbreviations 14 4 Intended conditions of use, emission scenarios and European reference room 15 4.1 Intended conditions of use and emission scenario 15 4.2 Reference room and emission scenario 15 4.3 Time schedule of emission(s) determination 16 5 Product sampling and transport to the laboratory

13、17 5.1 Introduction . 17 5.2 Objective of sampling 17 5.3 Preparation of a sampling plan and sampling strategy 17 5.4 Information from the testing laboratory needed to complement the product sampling plan 19 5.5 Packaging and transport of laboratory sample . 19 5.6 Sample description, marking of lab

14、oratory sample and sampling report 20 5.7 Chain of custody report . 20 5.8 Dispatch of product samples, time schedule 20 6 Handling of product samples in the laboratory . 21 6.1 Storage of sample in the testing laboratory 21 6.2 Preparation of the test specimen 21 7 Test chamber conditions . 22 7.1

15、Principles . 22 7.2 Dimensions of test specimen 22 7.3 Loading factor . 22 7.4 Ventilation 22 7.5 Air velocity . 23 7.6 Cleanliness of test chamber 23 7.7 Testing climate (temperature, relative humidity of supply air) 23 7.8 Storage of test specimen . 23 7.9 Large bulk products . 23 7.10 Volume of t

16、est chamber . 23 7.11 Placement of test specimen in test chamber . 24 8 Determination of volatile organic compounds in test chamber air . 24 8.1 Common requirements 24 8.2 Determination of VOCs and SVOCs in test chamber air 24 8.3 Determination of formaldehyde and some other volatile carbonyl compou

17、nds in test chamber air 27 8.4 Quality control External references . 27 9 Calculation of specific emission rates and expression of results at the reference room 28 10 Reporting for the horizontal reference method . 31 10.1 General . 31 10.2 Sampling 31 10.3 Handling of samples in the laboratory, pre

18、paration of test specimen 31 10.4 Test chamber conditions . 31 PD CEN/TS 16516:2013CEN/TS 16516:2013 (E) 3 10.5 Determination of vapour-phase organic compounds in test chamber air 31 10.6 Calculation and reporting of test results 32 11 Indirect methods 32 Annex A (informative) Repeatability . 33 Ann

19、ex B (informative) Examples of indirect methods (also called simplified, screening, secondary, derived or alternative methods) . 34 Annex C (informative) Information on very volatile organic compound (VVOC) testing. 36 Annex D (informative) Key concepts for product sampling . 37 Annex E (informative

20、) Example of a form for the sampling report 49 Annex F (informative) Example form for a chain of custody report 50 Annex G (informative) Benzene artefact generation on Tenax 51 Annex H (informative) Information on regulations concerning the emission into indoor air of dangerous substances from const

21、ruction products . 52 Bibliography 54 PD CEN/TS 16516:2013CEN/TS 16516:2013 (E) 4 Foreword This document (CEN/TS 16516:2013) has been prepared by Technical Committee CEN/TC 351 “Construction products - Assessment of release of dangerous substances”, the secretariat of which is held by NEN. Attention

22、 is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document has been prepared under a mandate given to CEN by the European Commission and the

23、 European Free Trade Association. According to the CEN-CENELEC Internal Regulations, the national standards organisations of the following countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugo

24、slav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. PD CEN/TS 16516:2013CEN/TS 16516:2013 (E) 5 Intr

25、oduction This Technical Specification was developed in the frame of the Mandate M/366 “Development of horizontal standardized assessment methods for harmonised approaches relating to dangerous substances under the Construction Products Regulation (CPR)“ addressing the preparation of horizontal measu

26、rement/test methods for the determination of emission of regulated dangerous substances from construction products into indoor air. This mandate is a complement to the product mandates granted by the European Commission to CEN under the Construction Products Regulation. The harmonised products stand

27、ards (hEN) developed in CEN under mandates from the European Commission specify construction product(s) as put on the market and address their intended conditions of use. This Technical Specification has gone through a robustness validation for identifying how small changes in specific testing param

28、eters can influence the test result. This study also delivered data on repeatability within one testing laboratory (see Annex A). It is planned to convert the TS into an EN standard immediately after publication of this TS taking into account any relevant information provided during that process. Th

29、is may include data from further round robin tests. It is vital that such information is clearly linked to a specified product in a product standard. The responsibility of product specification is with the product TCs, as described in CEN/TR 16496. This determination of emission into indoor air is t

30、o be carried out on products under their intended conditions of use. The intended use of a construction product is generally specified in the corresponding harmonised product standard. The specific emission rates determined using this Technical Specification are associated with application of the pr

31、oduct in a defined European Reference Room under specified climate (temperature and humidity) and ventilation conditions. A reference room is needed since it is not possible to evaluate emissions by testing in all possible use scenarios. The reference room dimensions, resulting product loading facto

32、rs, as well as climate and ventilation conditions are selected to represent the general indoor environment (see Clause 4). Based on the huge amount of available European experience, it was possible to identify one emission scenario and one reference room and associated set of product loading factors

33、 to be used. This Technical Specification specifies the horizontal reference method for testing the emission (release) of dangerous substances from construction products into indoor air. This method uses a test chamber in which emissions are generated under conditions which are kept constant during

34、the test. These conditions are selected so that the test results can be expressed in terms of chemical concentrations in the air of the reference room (see Clause 7 and Clause 9). It is to be noted that the test chamber is defined in terms of performance requirements. This responds to the requiremen

35、t of Mandate M/366 for a horizontal approach but still maintains sufficient flexibility on chamber dimensions to ensure representative samples of different materials can be accommodated (see Clause 5). Clause 8 of this Technical Specification specifies how emitted regulated dangerous substances shou

36、ld be analysed. This Technical Specification also addresses separately (see Clause 11 and Annex B) indirect methods that provide, within their specific field of application, a result that is comparable or that correlates with the result of the reference method. Such methods may be easier to apply an

37、d/or be cheaper. They are in accordance with mandate M/366 provided that their comparability or correlation to the reference test method has been demonstrated in their specific field of application. They are especially suitable for Factory Production Control testing (FPC). The selection of one emiss

38、ion scenario and one reference room for evaluating emissions to indoor air is in general accordance with the approach taken in existing European national regulations and voluntary schemes relating to emissions from construction products into indoor air. It also accords with the horizontal requiremen

39、ts of mandate M/366. The aim of this Technical Specification is not to develop a new testing method but to combine by normative references the use of existing standards complemented, when necessary, with additional and/or modified requirements so that according to the horizontal concept specified in

40、 mandate M/366 construction products can be evaluated under comparable conditions with regard to emissions into indoor air. PD CEN/TS 16516:2013CEN/TS 16516:2013 (E) 6 In summary, the horizontal test method specified in this Technical Specification determines the specific emission rate of volatile o

41、rganic compounds from a construction product into indoor air. This can be converted into a concentration in the air of the reference room by calculation. This Technical Specification has not been evaluated for the determination of steady state concentration of formaldehyde. NOTE A European Standard

42、(EN 717-1) exists for the determination of formaldehyde emissions from wood-based panels, in terms of steady state concentration. PD CEN/TS 16516:2013CEN/TS 16516:2013 (E) 7 1 Scope This Technical Specification specifies a horizontal reference method for the determination of emissions of regulated d

43、angerous substances from construction products into indoor air. This method is applicable to volatile organic compounds, semi-volatile organic compounds, and volatile aldehydes. It is based on the use of a test chamber and subsequent analysis of the organic compounds by GC-MS or HPLC. NOTE 1 Supplem

44、ental information is given on indirect test methods (Annex B) and on measuring very volatile organic compounds (see informative Annex C). NOTE 2 This Technical Specification describes the overall procedure and makes use of existing standards mainly by normative reference, complemented when necessary

45、 with additional or modified normative requirements. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest ed

46、ition of the referenced document (including any amendments) applies. CEN/TR 16220:2011, Construction products Assessment of release of dangerous substances Complement to sampling CEN/TR 16496:2013, Construction Products Assessment of release of dangerous substances Use of harmonised horizontal asses

47、sment methods EN ISO 13137, Workplace atmospheres Pumps for personal sampling of chemical and biological agents Requirements and test methods EN ISO 16000-9:2006, Indoor air Part 9: Determination of the emission of volatile organic compounds from building products and furnishing Emission test chambe

48、r method (ISO 16000-9:2006) EN ISO 16000-11:2006, Indoor air Part 11: Determination of the emission of volatile organic compounds from building products and furnishing Sampling, storage of samples and preparation of test specimens (ISO 16000-11:2006) EN ISO 16017-1, Indoor, ambient and workplace air

49、 Sampling and analysis of volatile organic compounds by sorbent tube/thermal desorption/capillary gas chromatography Part 1: Pumped sampling (ISO 16017-1) ISO 554, Standard atmospheres for conditioning and/or testing Specifications ISO 16000-3:2011, Indoor air Part 3: Determination of formaldehyde and other carbonyl compounds in indoor air and test chamber air Active sampling method ISO 16000-6:2011, Indoor air Part 6: Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TA