CEN TS 17197-2018 Construction products Assessment of release of dangerous substances - Analysis of inorganic substances in digests and eluates - Analysis by Inductively Coupled Pl.pdf

1、BSI Standards PublicationWB11885_BSI_StandardCovs_2013_AW.indd 1 15/05/2013 15:06Construction products: Assessment of release of dangerous substances - Analysis of inorganic substances in digests and eluates - Analysis by Inductively Coupled Plasma - Optical Emission Spectrometry (ICP-OES)PD CEN/TS

2、17197:2018TECHNICAL SPECIFICATION SPCIFICATION TECHNIQUE TECHNISCHE SPEZIFIKATION CEN/TS 17197 July 2018 ICS 91.100.01 English Version Construction products: Assessment of release of dangerous substances - Analysis of inorganic substances in digests and eluates - Analysis by Inductively Coupled Plas

3、ma - Optical Emission Spectrometry (ICP-OES) Produits de construction: valuation des missions de substances dangereuses - Analyse des substances inorganiques dans les digestats et les luats - Partie 1: Analyse par plasma inductif coupl - Spectromtrie dmission optique (ICP-OES) Bauprodukte - Beurteil

4、ung der Freisetzung von gefhrlichen Stoffen - Analyse von anorganischen Stoffen in Aufschlusslsungen und Eluaten - Analyse mit induktiv gekoppeltem Plasma - Optische Emissionsspektralanalyse (ICP-OES) This Technical Specification (CEN/TS) was approved by CEN on 2 April 2018 for provisional applicati

5、on. The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit their comments, particularly on the question whether the CEN/TS can be converted into a European Standard. CEN members are required to announce the existence

6、of this CEN/TS in the same way as for an EN and to make the CEN/TS available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an E

7、N is reached. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands,

8、Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels 2018 CEN All

9、 rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. CEN/TS 17197:2018 ENational forewordThis Published Document is the UK implementation of CEN/TS 17197:2018. The UK participation in its preparation was entrusted to Technical Committee B/557, Co

10、nstruction products - Assessment of dangerous substances.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. The B

11、ritish Standards Institution 2018 Published by BSI Standards Limited 2018ISBN 978 0 580 85058 5ICS 91.100.01Compliance with a British Standard cannot confer immunity from legal obligations. This Published Document was published under the authority of the Standards Policy and Strategy Committee on 31

12、 July 2018.Amendments/corrigenda issued since publicationDate Text affectedPUBLISHED DOCUMENTPD CEN/TS 17197:2018TECHNICAL SPECIFICATION SPCIFICATION TECHNIQUE TECHNISCHE SPEZIFIKATION CEN/TS 17197 July 2018 ICS 91.100.01 English Version Construction products: Assessment of release of dangerous subs

13、tances - Analysis of inorganic substances in digests and eluates - Analysis by Inductively Coupled Plasma - Optical Emission Spectrometry (ICP-OES) Produits de construction: valuation des missions de substances dangereuses - Analyse des substances inorganiques dans les digestats et les luats - Parti

14、e 1: Analyse par plasma inductif coupl - Spectromtrie dmission optique (ICP-OES) Bauprodukte - Beurteilung der Freisetzung von gefhrlichen Stoffen - Analyse von anorganischen Stoffen in Aufschlusslsungen und Eluaten - Analyse mit induktiv gekoppeltem Plasma - Optische Emissionsspektralanalyse (ICP-O

15、ES) This Technical Specification (CEN/TS) was approved by CEN on 2 April 2018 for provisional application. The period of validity of this CEN/TS is limited initially to three years. After two years the members of CEN will be requested to submit their comments, particularly on the question whether th

16、e CEN/TS can be converted into a European Standard. CEN members are required to announce the existence of this CEN/TS in the same way as for an EN and to make the CEN/TS available promptly at national level in an appropriate form. It is permissible to keep conflicting national standards in force (in

17、 parallel to the CEN/TS) until the final decision about the possible conversion of the CEN/TS into an EN is reached. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France,

18、 Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCH

19、ES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels 2018 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. CEN/TS 17197:2018 EPD CEN/TS 17197:2018CEN/TS 17197:2018 (E) 2 Contents Page European fore

20、word . 4 Introduction 5 1 Scope 6 2 Normative references 6 3 Terms and definitions . 6 4 Symbols and abbreviations . 8 5 Principle . 8 6 Interferences 9 7 Reagents 10 8 Apparatus 12 9 Procedure 12 9.1 Test sample 12 9.2 Test portion 13 9.3 Instrument set up . 13 9.3.1 General requirements 13 9.3.2 I

21、nter-element correction . 13 9.3.3 Internal standard . 13 9.3.4 Instrument performance check 13 9.4 Calibration 14 9.4.1 Linear calibration function . 14 9.4.2 Non-linear calibration function 14 9.4.3 Standard addition calibration . 14 9.5 Sample measurement . 14 10 Calculation 15 10.1 Calculation f

22、or digests of construction products 15 10.2 Calculation for eluates of construction products . 15 11 Expression of results . 15 12 Performers characteristics . 16 12.1 General . 16 12.2 Blank . 16 12.3 Calibration check . 16 12.4 Interference . 16 12.5 Recovery 16 12.6 Precision 16 13 Test report 17

23、 Annex A (informative) Wavelengths, spectral interferences and estimated method detection limits . 19 Annex B (informative) Method detection limit (MDL) and precision data for soil, sludge and biowaste 23 Annex C (informative) Inter element correction (IEC) 27 PD CEN/TS 17197:2018CEN/TS 17197:2018 (

24、E) 3 Annex D (normative) Determination of arsenic, antimony and selenium using hydride-generation ICP-OES 29 D.1 Scope . 29 D.2 Principle . 29 D.3 Apparatus 29 D.4 Reagents and solutions . 30 D.5 Procedure 31 Bibliography . 33 PD CEN/TS 17197:2018CEN/TS 17197:2018 (E) 4 European foreword This docume

25、nt (CEN/TS 17197:2018) has been prepared by Technical Committee CEN/TC 351 “Construction Products - Assessment of release of dangerous substances”, the secretariat of which is held by NEN. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent r

26、ights. CEN shall not be held responsible for identifying any or all such patent rights. This document has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association. Two similar documents have been developed for drinking water, surface water and was

27、te water and different types of waste respectively, see Annex B. According to the CEN/CENELEC Internal Regulations, the national standards organisations of the following countries are bound to announce this Technical Specification: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark

28、, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. PD CEN/TS

29、 17197:2018CEN/TS 17197:2018 (E) 5 Introduction Following an extended evaluation of available methods for content and eluate analysis in construction products (CEN/TR 16045 1) it was concluded that multi element analysis methods have preference over methods developed for single elements or small gro

30、ups of elements. This implies that for inorganic substances ICP methods are preferred for the analysis of extracts obtained from digestion or eluates obtained from leaching. This document has been adopted from the work carried out in the context of CEN/TC 400 (project HORIZONTAL) and is very similar

31、 to EN 16170:2016, Sludge, treated biowaste and soil - Determination of elements using inductively coupled plasma optical emission spectrometry (ICP-OES) 2. This Technical Specification is part of a modular horizontal approach which was adopted in CEN/TC 351. Horizontal means that the methods can be

32、 used for a wide range of materials and products with certain properties. Modular means that a test standard developed in this approach concerns a specific step in assessing a property and not the whole chain of measurement (from sampling to analyses). Beneficial features of this approach are that m

33、odules can be replaced by better ones without jeopardizing the standard chain and duplication of work of in different Technical Committees for Products can be avoided as far as possible. The modules that relate to the standards developed in CEN/TC 351 are specified in CEN/TR 16220:2011, Construction

34、 products: Assessment of release of dangerous substances Complement to sampling 3 which distinguishes between the modules. This Technical Specification belongs to the analytical step. The use of modular horizontal standards implies the drawing of test schemes as well. Before executing a test on a ce

35、rtain construction product to determine certain characteristics it is necessary to draw up a protocol in which the adequate modules are selected and together form the basis for the entire test procedure. PD CEN/TS 17197:2018CEN/TS 17197:2018 (E) 6 1 Scope This Technical Specification specifies the m

36、ethod for the determination of major, minor and trace elements in aqua regia and nitric acid digests and in eluates of construction products by Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES). It refers to the following 44 elements: Aluminium (Al), antimony (Sb), arsenic (As), bar

37、ium (Ba), beryllium (Be), bismuth (Bi), boron (B), cadmium (Cd), calcium (Ca), cerium (Ce), chromium (Cr), cobalt (Co), copper (Cu), iron (Fe), lanthanum (La), lead (Pb), lithium (Li), magnesium (Mg), manganese (Mn), mercury (Hg), molybdenum (Mo), neodymium (Nd), nickel (Ni), phosphorus (P), potassi

38、um (K), praseodymium (Pr), samarium (Sm), scandium (Sc), selenium (Se), silicon (Si), silver (Ag), sodium (Na), strontium (Sr), sulphur (S), tellurium (Te), thallium (Tl), thorium (Th), tin (Sn), titanium (Ti), tungsten (W), uranium (U), vanadium (V), zinc (Zn), and zirconium (Zr). For the determina

39、tion of low levels of As, Se and Sb, hydride generation may be applied. This method is described in Annex D. NOTE Construction products include e.g. mineral-based products (S); bituminous products (B); metals (M); wood-based products (W); plastics and rubbers (P); sealants and adhesives (A); paints

40、and coatings (C), see also CEN/TR 16045 1. The method in this Technical Specification is applicable to construction products and validated for the product types listed in Annex D. 2 Normative references The following documents are referred to in the text in such a way that some or all of their conte

41、nt constitutes requirements of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. CEN/TS 16637-2, Construction products Assessment of release of dangerous substances Part 2: Ho

42、rizontal dynamic surface leaching test CEN/TS 16637-3, Construction products Assessment of release of dangerous substances Part 3: Horizontal up-flow percolation test EN 17087: 1, Construction products: Assessment of release of dangerous substances Preparation of test portions from the laboratory sa

43、mple for testing of release and analysis of content CEN/TS 17196, Construction products Assessment of release of dangerous substances Digestion by aqua regia for subsequent analysis of the major, minor and trace elements EN ISO 3696:1995, Water for analytical laboratory use Specification and test me

44、thods (ISO 3696:1987) EN ISO/IEC 17025, General requirements for the competence of testing and calibration laboratories (ISO/IEC 17025) 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. ISO and IEC maintain terminological databases for use in stand

45、ardization at the following addresses: 1Under preparation. Stage at the time of publication: prEN 17087:2017. PD CEN/TS 17197:2018CEN/TS 17197:2018 (E) 7 IEC Electropedia: available at http:/www.electropedia.org/ ISO Online browsing platform: available at http:/www.iso.org/obp 3.1 digest solution re

46、sulting from acid digestion of a sample SOURCE: EN 16687:2015, 3.2.8 3.2 eluate solution obtained from a leaching test SOURCE: EN 16687:2015, 4.2.7 3.3 analyte determinand element, ion or substance to be determined by an analytical method SOURCE: EN 16687:2015, 4.1.11 3.4 sample portion of material

47、selected from a larger quantity of material Note 1 to entry: The manner of selection of the sample should be prescribed in a sampling plan. Note 2 to entry: The term “sample” is often accompanied by a prefix (e.g. laboratory sample, test sample) specifying the type of sample and/or the specific step

48、 in the sampling process to which the obtained material relates. SOURCE: EN 16687:2015, 3.1.5 3.5 test sample analytical sample sample, prepared from the laboratory sample, from which test portions are removed for testing or for analysis SOURCE: EN 16687:2015, 3.2.2 3.6 test portion analytical porti

49、on amount of the test sample taken for testing/ analysis, usually of known weight or volume EXAMPLE 1 A bag of aggregates is delivered to the laboratory (the laboratory sample). For test purposes a certain amount of the aggregate is dried, the result is the test sample. Afterwards the column for a percolation test is filled with a test portion of dried aggregate. EXAMPLE 2 A piece of flooring is delivered to the laboratory (the laboratory sample). For the purpose of digestion a certain amount is size reduced, t