DIN 67510-1-2009 Phosphorescent pigments and products - Part 1 Measurement and marking at the producer《磷光颜料及产品 第1部分 生产商处的测量和标记》.pdf

1、November 2009DEUTSCHE NORM Normenausschuss Lichttechnik (FNL) im DINDIN-SprachendienstEnglish price group 10No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sa

2、le for German Standards (DIN-Normen).ICS 13.200; 87.060.10!%$Yp“2015477www.din.deDDIN 67510-1Phosphorescent pigments and products Part 1: Measurement and marking at the producer,English translation of DIN 67510-1:2009-11Langnachleuchtende Pigmente und Produkte Teil 1: Messung und Kennzeichnung beim

3、Hersteller,Englische bersetzung von DIN 67510-1:2009-11Produits et pigments phosphorescents Partie 1: Lessai de qualit et marquage chez le producteur,Traduction anglaise de DIN 67510-1:2009-11SupersedesDIN 67510-1:2002-10www.beuth.deDocument comprises 16 pages01.14 DIN 67510-1:2009-11 2 A comma is u

4、sed as the decimal marker. Contents Page Foreword 3 1 Scope 4 2 Normative references 4 3 Terms and definitions .4 4 Measurement 5 4.1 Measured objects.5 4.1.1 General 5 4.1.2 Phosphorescent pigments 6 4.1.3 Phosphorescent products 6 4.1.4 Reference sample 7 4.2 Requirements for the excitation appara

5、tus 7 4.3 Measurement and excitation 7 4.3.1 Temperature .7 4.3.2 Illuminance measuring instrument 7 4.3.3 Procedure .7 4.4 Measurement of light decay .7 4.4.1 Luminance 7 4.4.2 Effect of stray light 9 4.4.3 Number of measured values .9 4.5 Determination of the decay time 9 4.6 Determination of the

6、colour of phosphorescence .9 4.7 Measurement record .9 Annex A (informative) Mathematical method for approximate determination of the decay time 11 A.1 Application 11 A.2 Procedure 11 A.3 Example of linear extrapolation 12 A.4 Example of parabolic extrapolation 13 Annex B (informative) Determination

7、 of the complete and relative saturating excitation 15 B.1 Complete saturating excitation . 15 B.2 Relative saturating excitation 15 Bibliography . 16 DIN 67510-1:2009-11 3 Foreword This standard has been prepared by Working Committee NA 058-00-19 AA Leuchtfarben of the Normenausschuss Lichttechnik

8、(FNL) (Lighting Technology Standards Committee). DIN 67510 consists of the following parts, under the general title Phosphorescent pigments and products: Part 1: Measurement and marking at the producer Part 2: Measurement of phosphorescent products on site Part 3: Low location lighting system Part 4

9、: Products for phosphorescent escape route systems Markings and applications Amendments This standard differs from DIN 67510-1:2002-10 as follows: a) the scope has been restricted to measurement and classification by the manufacturer; b) the word “photoluminescent” has been replaced with “phosphores

10、cent” in the title; c) the concept of saturating excitation has been added; d) Clause 5 “Marking of phosphorescent properties” has been omitted without replacement. Previous editions DIN 67510: 1958-07, 1974-11 DIN 67510-1: 2002-10, 1992-01 DIN 67510-1:2009-11 4 1 Scope This standard applies to the

11、measurement and classification by the manufacturer of phosphorescent pigments and the phosphorescent products made from them, for example for marking escape routes and hazards, in buildings, underground thoroughfares, on aircraft and ships, for marking equipment, fittings, utensils, working clothing

12、 and safety clothing. This standard specifies a series of conditions for testing the change in luminance over time and for identifying the tested phosphorescent products. This standard does not apply to radioluminescent pigments as described in DIN 5043-1 and DIN 5043-2. 2 Normative references The f

13、ollowing referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced documents (including any amendments) applies. DIN 5031-3, Optical radiation physics and illuminatin

14、g engineering Quantities, symbols and units of illuminating engineering DIN 5031-7, Optical radiation physics and illuminating engineering Terms for wavebands DIN 5032-7, Photometry Classification of illuminance meters and luminance meters DIN 5033-4, Colorimetry Spectrophotometric method DIN 5033-6

15、, Colorimetry Tristimulus method DIN 5033-7, Colorimetry Measuring conditions for object colours DIN 55943, Colouring materials Terms and definitions DIN EN 13032-1, Light and lighting Measurement and presentation of photometric data of lamps and luminaires Part 1: Measurement and file format DIN EN

16、 ISO 15528, Paints, varnishes and raw materials for paints and varnishes Sampling (ISO 15528:2000) 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 phosphorescent pigments pigments1)that can be charged using ultraviolet or visible light radiat

17、ion2)and then continue to emit light without further excitation 3.2 phosphorescent products products made using phosphorescent pigments, such as paints and varnishes, films, enamels, and polymers, as well as signs, operating controls and paints made from them 1) See DIN 55943 for definition. 2) See

18、DIN 5031-7 for definitions.DIN 67510-1:2009-11 5 3.3 excitation of phosphorescent pigments and products effect of ultraviolet or visible light radiation on a phosphorescent pigment or product that is capable of producing phosphorescence 3.4 luminance luminance L is the quotient of the luminous flux

19、passing through (or striking) an area A in a certain direction () and the product of the solid angle of radiation and the projection of the area A cos onto a plane perpendicular to the angle of view DIN 5031-3 3.5 decay decrease in luminance over time of phosphorescent pigments or products after exc

20、itation has ceased 3.6 decay time time after the end of excitation in which the luminance of a phosphorescent pigment or product has decreased to a specified value 3.7 chromaticity coordinates of phosphorescence in colour region chromaticity coordinates of phosphorescence after excitation has ceased

21、 NOTE DIN 5033-2 describes how colours for the 2 standard observer are determined. 3.8 saturating excitation excitation at which the luminance of a phosphorescent pigment or product can no longer be increased by changing the excitation conditions 4 Measurement 4.1 Measured objects 4.1.1 General Meas

22、ured objects are: a) phosphorescent pigments; b) products made with phosphorescent pigments. DIN 67510-1:2009-11 6 4.1.2 Phosphorescent pigments Phosphorescent pigments can be measured in cuvettes with the following geometric dimensions: shape: round; diameter: 50 mm; depth: 5 mm. The material from

23、which the cuvette is made shall not affect the spectral characteristics of the radiation used for excitation or the radiation emitted by the phosphorescent pigment. When filling the cuvette, compact the phosphorescent pigment by tapping it repeatedly and smoothing it flat. DIN EN ISO 15528 applies w

24、hen taking samples of phosphorescent pigments for testing from one or more containers. Phosphorescent pigments can also be tested in transparent carriers such as printing ink binding agents or casting resin, or with a specified coated area, on a white, diffusely reflective surface. The conditions fo

25、r making the specimens shall be stated. 4.1.3 Phosphorescent products 4.1.3.1 Granules The requirements in 4.1.2 apply, but the cuvettes shall be 80 mm deep. When filling the cuvette, the granules shall be compacted so that individual particles do not move during the measurement. NOTE The larger the

26、 particles, the less reproducible the measurements. In the case of larger particles, it is therefore advisable to perform several measurements and use the average results. 4.1.3.2 Films, plates, enamels and signs 4.1.3.2.1 Sampling Samples are to be taken from each production batch. A distinction is

27、 made between the following cases: for batches of fewer than 50 units or less than 50 m2, one measurement shall be performed, for batches of fewer than 150 units or less than 150 m2, one measurement shall be made at the beginning and one at the end, for batches of more than 150 units or more than 15

28、0 m2, a measurement shall be made for every 200 units or 200 m2in addition to the measurements at the beginning and the end. 4.1.3.2.2 Backing on reverse side In order to measure the luminance of phosphorescent films it is essential that the phosphorescent layer has a white backing on the reverse si

29、de. However, because the pigment on these products is often not completely opaque and there are also applications without the white backing layer, films shall be provided with a backing of white, diffusely reflecting material with a reflectivity of 90 % for the measurement. For translucent materials

30、, a measurement shall also be carried out on a black background with a reflectivity 50 mm; d) uniformity within the area of the measured object to be evaluated: g2= Emin/Emax 1/1,1; e) excitation time: 5 min. The saturating excitation (see Annex B) may not have been reached. The sample shall have be

31、en kept in the dark so that its phosphorescence has decreased to 0,3 mcd/m2before excitation. 4.3 Measurement and excitation 4.3.1 Temperature The temperature shall be (22 3) C. 4.3.2 Illuminance measuring instrument The level and uniformity of illuminance shall be determined using an illuminance me

32、asuring instrument, which shall meet the following requirements: a) measurement range of at least 10 lx to 10 klx; b) diameter of the light aperture of the photometer head 80 % of the measured surface; c) other parameters according to class B as specified in DIN 5032-7. 4.3.3 Procedure To measure th

33、e level and distribution of illuminance in the plane of the evaluated area of the measured object, the light aperture of the photometer head shall be mounted in this plane. The illuminance shall be measured in the centre of the evaluated area of the measured object. The measurement of light decay sh

34、all begin within 10 s of the end of excitation. 4.4 Measurement of light decay 4.4.1 Luminance 4.4.1.1 General The luminance can be either measured directly or determined using an illuminance measurement. DIN 67510-1:2009-11 8 4.4.1.2 Measurement of luminance If luminance is to be measured directly,

35、 a luminance meter that meets the following requirements shall be used: a) measurement range of at least 105cd/m2to 10 cd/m2; b) a display with at least 3 digits; minimum value: 0,001 102, maximum value: 1,999 10; c) other parameters according to class A as specified in DIN 5032-7. The distance betw

36、een the luminance meter and the measured object, and the aperture angle of the luminance meter shall be chosen so that an area of the measured object with a diameter of 35 mm to 50 mm is evaluated. If the shape of the measured object means that different areas are measured, this shall be noted in th

37、e measurement record. 4.4.1.3 Determining the luminance by measuring illuminance 4.4.1.3.1 Principle The luminance of phosphorescent pigments and products can be determined using an illuminance measurement. The relationship between luminance and illuminance is defined by Equation (1): L = / p(1) whe

38、re L is the mean luminance of the measured object being examined; is the illuminance at a defined reference point on the light aperture of the photometer head (see DIN EN 13032-1); pis the projected solid angle which the evaluated area of the measured object makes with the centre of the light apertu

39、re of the photometer head. The projected solid angle pis calculated from Equation (2): p = (1 + (r/R)2)1 0(2) where 0 is the standard solid angle: 0= 1 sr; r is the distance of the light aperture of the photometer head from the measured object; R is the radius of the plane of the evaluated area of t

40、he measured object. 4.4.1.3.2 Measurement geometry The measurements shall be made using the following measurement geometry: a) diameter of the evaluated area of the measured object: 35 mm to 50 mm; b) distance between the measured object and the light aperture of the photometer head, equal to the di

41、ameter of the evaluated area. DIN 67510-1:2009-11 9 If the shape of the measured objects means that different areas are measured, this shall be noted in the measurement record. 4.4.1.3.3 Illuminance measuring instrument The illuminance measuring instrument shall meet the following requirements: a) m

42、easurement range when converting the display to luminance: 105cd/m2to 10 cd/m2; b) display with at least 3 digits; minimum value: 0,001 102; maximum value: 1,999 10; c) other parameters according to class A as specified in DIN 5032-7 with the exception of the cos evaluation (f2), for which there are

43、 no requirements. NOTE An analogue output and/or a computer interface (e.g. in accordance with DIN 66348-1) is recommended for recording purposes. 4.4.2 Effect of stray light Stray light entering the light aperture of the photometer head or the surface of the phosphorescent product shall be prevente

44、d as far as possible during the measurement, or its effects shall be corrected. NOTE Stray light occurs when artificial light or daylight is incident on the measured object and is reflected or transmitted by it, causing the luminance of the measured object to appear greater than that which is actual

45、ly produced by phosphorescence. Stray light can also occur when artificial light or daylight is incident on the light aperture of the photometer head used for the measurement. 4.4.3 Number of measured values Luminance readings in mcd/m2shall be taken at the end of excitation, after (2 0,1) min, (10

46、0,1) min, (30 0,2) min, (60 0,3) min and (120 0,5) min. 4.5 Determination of the decay time To determine the decay time, the luminance over time shall be measured as described in 4.4. If the value does not fall below (0,3 0,03) mcd/m2 after (120 1) min, the decay time can be determined using a suita

47、ble mathematical method (see Annex A). 4.6 Determination of the colour of phosphorescence To determine the colour of phosphorescence, colorimetric instruments using the trichromatic or spectral method (see DIN 5033-4 and DIN 5033-6) are used. The phosphorescent pigments or products are charged using

48、 equipment as described in 4.2, but in addition to Xe lamps, all other lamps whose spectral power distribution corresponds to the standard illuminant D65 can be used (see DIN 5033-7). The colour of phosphorescence is measured within 5 min of the end of excitation for the 2 standard observer. If a spectroradiometer is used to measure the colour of phosphorescence, a very fast or simultaneously measuring spectrometer should be used due to the changing colours o