DIN EN 10245-4-2012 Steel wire and wire products - Organic coatings on steel wire - Part 4 Polyester coated wire German version EN 10245-4 2011《钢丝和线材产品 钢丝有机涂层 第4部分 聚酰胺涂层线材 德文版 EN 1.pdf

1、January 2012 Translation by DIN-Sprachendienst.English price group 9No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS

2、 25.220.60; 77.140.65!$y+W“1860852www.din.deDDIN EN 10245-4Steel wire and wire products Organic coatings on steel wire Part 4: Polyester coated wireEnglish translation of DIN EN 10245-4:2012-01Stahldraht und Drahterzeugnisse Organische Beschichtungen auf Stahldraht Teil 4: Polyester-beschichteter Dr

3、ahtEnglische bersetzung von DIN EN 10245-4:2012-01Fils et produits trfils en acier Revtements organiques sur fils dacier Partie 4: Fils revtement de polyesterTraduction anglaise de DIN EN 10245-4:2012-01SupersedesDIN EN 10245-4:2003-08www.beuth.deIn case of doubt, the German-language original shall

4、be considered authoritative.Document comprises 13 pages12.11 DIN EN 10245-4:2012-01 2 A comma is used as the decimal marker. National foreword This standard has been prepared by Technical Committee ECISS/TC 106 “Wire rod and wires” (Secretariat: AFNOR, France). The responsible German body involved i

5、n its preparation was the Normenausschuss Stahldraht und Stahl-drahterzeugnisse (Steel Wire and Wire Products Standards Committee), Working Committee NA 099-00-01 AA Stahldraht. Amendments This standard differs from DIN EN 10245-4:2003-08 as follows: a) normative references have been updated; b) the

6、 standard has been editorially revised. Previous editions DIN EN 10245-4: 2003-08 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 10245-4 October 2011 ICS 25.220.60; 77.140.65 Supersedes EN 10245-4:2003English Version Steel wire and wire products - Organic coatings on steel wire - Part 4: Polye

7、ster coated wire Fils et produits trfils en acier - Revtements organiques sur fils dacier - Partie 4: Fils revtement de polyester Stahldraht und Drahterzeugnisse - Organische Beschichtungen auf Stahldraht - Teil 4: Polyester- beschichteter Draht This European Standard was approved by CEN on 17 Septe

8、mber 2011. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be ob

9、tained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the

10、CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembour

11、g, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. Management Centre: Avenue Marnix 17, B-1000 Brussels 2011 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN

12、10245-4:2011: EEUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGEN 10245-4:2011 (E) 2 Contents Foreword 3Introduction .41 Scope 42 Normative references 53 Terms and definitions .64 Methods of application of polyester coatings 65 Requirements and testi

13、ng methods for polyester coating material .65.1 General 65.2 Composition and method of application .65.3 Consistency 65.4 Density 75.5 Hardness .75.6 Tensile strength .75.7 Elongation 76 Requirements and test methods for polyester coating on wire and wire products .76.1 General 76.2 Appearance 76.3

14、Colour .86.4 Gloss .86.5 Thickness .86.6 Elongation 86.7 Concentricity 86.8 Adherence 87 Performance requirements and tests for the polyester coating on the finished wire and wire products .97.1 General 97.2 Colour stability (accelerated weathering) .97.3 Kesternich test .97.4 Boiling water test 108

15、 Retests . 109 Inspection and quality assurance . 10Bibliography . 11DIN EN 10245-4:2012-01 EN 10245-4:2011 (E) 3 Foreword This document (EN 10245-4:2011) has been prepared by Technical Committee ECISS/TC 106 “Wire rod and wires”, the secretariat of which is held by AFNOR. This European Standard sha

16、ll be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by April 2012, and conflicting national standards shall be withdrawn at the latest by April 2012. Attention is drawn to the possibility that some of the elements of this documen

17、t may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 10245-4:2003. This standard is made up of the following parts: Part 1: General Rules; Part 2: PVC finished wire; Part 3: PE coated wire;

18、Part 4: Polyester coated wire; Part 5: Polyamide coated wire. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estoni

19、a, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. DIN EN 10245-4:2012-01 EN 10245-4:2011 (E) 4 Introduction This European

20、Standard for organic coatings for steel wire covers the requirements of a general nature and applies also to coatings for which no specific requirements have been established in the subsequent parts of this standard. The subsequent parts of this standard deal more specifically with clearly defined c

21、oatings or groups of coatings. These coatings may have their own particular methods of application and their individual requirements which are specified in these parts of this standard, in other standards or in manufacturers data sheets. Because the standard specifies requirements and tests not only

22、 for the coating but also for the coating material, it has proved not practical to put all the requirements in one clause and all the tests in another one. Following structure has been chosen in order to limit complexity and to facilitate the use. In writing this series of standards consideration ha

23、s been given to the nomenclature and transformation of organic coating materials as applied to steel wire products. These organic coating materials may, on application to wire and by their integration into the finished wire product, change their characteristics and properties. This standard specifie

24、s characteristics and tests not only for the organic coating but also for the coating materials both before and after their application to steel wire and wire products. In addition it specifies the requirements for performance levels and testing methods on organic coating material which have become

25、an integral and permanent part of the finished wire product. Therefore it has proven not to be practical to put all requirements in one clause and all the tests in another one. To aid continuity and in order to limit complexity, the following structure has been chosen for this standard: Clause 5 dea

26、ls with the characteristics and testing methods of organic coating material as supplied by the manufacturer for the purposes of its application to the wire product. Tests described in this section are intended to be carried out by the organic coating material manufacturer or the applicator before th

27、e coating operation. Clause 6 relates to the characteristics and testing methods for the “organic coating“ when the organic coating material has been applied to and has become an integral part of the finished wire. Consequently tests are intended to be in the main carried out by the coating “applica

28、tors“. Clause 7 defines the performance requirements and testing methods on the “organic coating“ of the finished wire product, and where this is not possible, tests will be carried out on “coated“ panels Scope 1 Scope Complementary to EN 10245-1, this European Standard specifies the characteristics

29、 and requirements for steel wire and wire products coated with polyester. It covers both thermoplastic and thermosetting polyester. DIN EN 10245-4:2012-01 EN 10245-4:2011 (E) 5 2 Normative references The following referenced documents are indispensable for the application of this document. For dated

30、 references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 10021, General technical delivery conditions for steel products EN 10245-1, Steel wire and wire products Organic coatings on steel wire Part 1: Ge

31、neral rules EN ISO 527-3, Plastics Determination of tensile properties Part 3: Test conditions for films and sheets (ISO 527-3:1995) EN ISO 868, Plastics and ebonite Determination of indentation hardness by means of a durometer (Shore hardness) (ISO 868:2003) EN ISO 1183-1, Plastics Methods for dete

32、rmining the density of non-cellular plastics Part 1: Immersion method, liquid pyknometer method and titration method (ISO 1183-1:2004) EN ISO 1183-2, Plastics Methods for determining the density of non-cellular plastics Part 2: Density gradient column method (ISO 1183-2:2004) EN ISO 1183-3, Plastics

33、 Methods for determining the density of non-cellular plastics Part 3: Gas pyknometer method (ISO 1183-3:1999) EN ISO 2813, Paints and varnishes Determination of specular gloss of non-metallic paint films at 20, 60 and 85 (ISO 2813:1994, including Technical Corrigendum 1:1997) EN ISO 2815, Paints and

34、 varnishes Buchholz indentation test (ISO 2815:2003) EN ISO 3231, Paints and varnishes Determination of resistance to humid atmospheres containing sulfur dioxide (ISO 3231:1993) EN ISO 3668, Paints and varnishes Visual comparison of the colour of paints (ISO 3668:1998) EN ISO 4892-1, Plastics Method

35、s of exposure to laboratory light sources Part 1: General guidance (ISO 4892-1:1999) EN ISO 4892-2, Plastics Methods of exposure to laboratory light sources Part 2: Xenon-arc lamps (ISO 4892-2:2006) ISO 4582, Plastics Determination of changes in colour and variations in properties after exposure to

36、daylight under glass, natural weathering or laboratory light sources ISO 7724-1, Paints and varnishes Colorimetry Part 1: Principles ISO 7724-2, Paints and varnishes Colorimetry Part 2: Colour measurement ISO 7724-3, Paints and varnishes Colorimetry Part 3: Calculation of colour differences DIN EN 1

37、0245-4:2012-01 EN 10245-4:2011 (E) 6 3 Terms and definitions For the purposes of this document, the terms and definitions given in EN 10245-1 and the following apply. 3.1 polyester organic material which is the result of a polycondensation reaction of a polyhydroxy compound with di- or polycarbon ac

38、ids NOTE There are two main classes of polyester: the linear polyesters and the crosslinked polyesters. Linear polyesters generally are thermoplastic, whereas crosslinked polyester is thermosetting and is hard. 3.2 polyethyleneglycoltereftalate (PET) one of the most commonly used linear polyesters N

39、OTE PET is only the abbreviation of polyethyleneglycoltereftalate. The designation of other types of polyester by PET is not correct and is to be avoided. 4 Methods of application of polyester coatings The most commonly used method for polyester coating on wire is by extrusion and for coating of wir

40、e products is by powder coating. The coating may be applied directly on the surface of the wire or wire product or after applying a primer. Where appropriate other methods may be used. 5 Requirements and testing methods for polyester coating material 5.1 General Unless otherwise specified the test m

41、ethods for polyester coating material shall be in accordance with EN 10245-1. 5.2 Composition and method of application The coating material shall be free of lead (Pb), cadmium (Cd) and benzoin. Other requirements for the composition shall be agreed between manufacturer and applicator and shall take

42、 account of this method of application. However, the polyester coating material shall fulfil the requirements of this standard. The processing of the polyester coating material shall be at the manufacturers discretion. The requirements for the polyester intended for extrusion are those for PET. For

43、other coating material other requirements may be agreed between the parties. 5.3 Consistency The manufacturer shall ensure that the organic coating material composition and its characteristics shall remain constant from batch to batch and unchanged from that as agreed at the time of inquiry and orde

44、ring. The manufacturer shall immediately notify the applicator of any subsequent change in the type and quantity of the constituent parts of the composition once this has been agreed between the two parties. At the request of the supplier or purchaser the presence of certain elements may be limited.

45、 In any case, the compound composition shall be cadmium-free. DIN EN 10245-4:2012-01 EN 10245-4:2011 (E) 7 5.4 Density Unless otherwise agreed between the applicator and the coating material supplier the density of the coating material, when tested in accordance with EN ISO 1183- 1 to -3, shall be i

46、n accordance with Table 1. Where the apparent density of the supplied powder is specified, requirements and test methods shall be agreed between the parties. 5.5 Hardness When measured in accordance with EN ISO 868 the Shore hardness D shall be in accordance with Table 1. If so agreed between the pa

47、rties the Bucholtz hardness, when measured in accordance with EN ISO 2815, shall be in accordance with Table 1. 5.6 Tensile strength When tested in accordance with EN ISO 527-3 the minimum tensile strength shall be in accordance with Table 1. 5.7 Elongation When tested in accordance with EN ISO 527-

48、3 the elongation shall be in accordance with Table 1. Table 1 Requirements and tests for the coating material Characteristics Requirements for Test method Thermoplastics materials Thermosetting materials Density (kg/dm3) Neutral, uncoloured: 1,30 1,40 aWhite: 1,50 1,70 0,05 aEN ISO 1183-1 to -3 Green: 1,45 1,65 0,05 Shore hardness D Min. 76 not applicable EN ISO 868 Bucholtz hardness Not applicable