DIN EN 12911-2013 Products used for treatment of water intended for human consumption - Manganese greensand German version EN 12911 2013《人类生活用水用水处理剂 锰绿砂 德文版本EN 12911-2013》.pdf

1、July 2013 Translation by DIN-Sprachendienst.English price group 11No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 7

2、1.100.80!%English version EN 12911:2013,English translation of DIN EN 12911:2013-07Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch Mangangrnsand;Englische Fassung EN 12911:2013,Englische bersetzung von DIN EN 12911:2013-07Produits utiliss pour le traitement de leau destine la conso

3、mmation humaine Sable vert manganis;Version anglaise EN 12911:2013,Traduction anglaise de DIN EN 12911:2013-07SupersedesDIN EN 12911:2006-08www.beuth.deDocument comprises 20 pagesIn case of doubt, the German-language original shall be considered authoritative.06.13E DIN EN 12911:2013-07 2 A comma is

4、 used as the decimal marker. National foreword This document (EN 12911:2013) has been prepared by Technical Committee CEN/TC 164 “Water supply” (Secretariat: AFNOR, France). The responsible German body involved in its preparation was the Normenausschuss Wasserwesen (Water Practice Standards Committe

5、e), Working Committee NA 119-04-02 AA Wasseraufbereitung. Users of this standard are advised of the reservations stated in the Introduction of the European Standard and should note that national regulations exist in Germany dealing with water for human consumption, in particular the Trinkwasserveror

6、dnung (TrinkwV 2001) (German Drinking Water Ordinance). The DIN Standards corresponding to the International Standards referred to in this document are as follows, whereby EN ISO Standards are only listed below if these have not been published as DIN EN ISO Standards with the same number: EN ISO 369

7、6 DIN ISO 3696 Amendments This standard differs from DIN EN 12911:2006-08 as follows: a) the reference to Directive 67/548/EEC relating to the classification, packing and labelling of dangerous substances has been replaced by the reference to Regulation EC No 1272/2008. Previous editions DIN EN 1291

8、1: 1999-11, 2006-08 National Annex NA (informative) Bibliography DIN ISO 3696, Water for analytical laboratory use Specification and test methods Verordnung ber die Qualitt von Wasser fr den menschlichen Gebrauch (Trinkwasserverordnung TrinkwV 2001) (German Drinking Water Ordinance), as of 28 Novemb

9、er 2011 (BGBI. I, 2011, Nr. 61, S. 2370-2396), as amended by the second Ordinance amending the Trinkwasserverordnung (TrinkwVndV 2) (German Drinking Water Ordinance) of 5 December 2011 (BGBl. I, 2012, Nr. 58, S. 2562-2567)*)*)Obtainable from: Bundesministerium der Justiz (German Federal Ministry of

10、Justice) (Internet: http:/www.gesetze-im-internet.de). EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 12911 May 2013 ICS 71.100.80 Supersedes EN 12911:2006English Version Products used for treatment of water intended for human consumption - Manganese greensand Produits utiliss pour le traiteme

11、nt de leau destine la consommation humaine - Sable vert manganis Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch - Mangangrnsand This European Standard was approved by CEN on 14 March 2013. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate th

12、e conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard

13、 exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the nationa

14、l standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovak

15、ia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2013 CEN All rights of exploitation in any form and by any means reserved wor

16、ldwide for CEN national Members. Ref. No. EN 12911:2013: EEN 12911:2013 (E) 2 Contents Page Foreword 4 Introduction .5 1 Scope 6 2 Normative references 6 3 Terms and definitions and symbols 6 4 Description .6 4.1 Identification .6 4.1.1 Chemical name(s) 6 4.1.2 Synonym or common names 6 4.1.3 Chemic

17、al formula .6 4.1.4 CAS Registry Number .7 4.1.5 EINECS reference 7 4.2 Commercial form .7 5 Physical properties 7 5.1 Appearance 7 5.2 Particle size distribution .7 5.3 Density (bulk density loose) .8 6 Chemical properties 8 7 Specific properties.8 8 Test methods 8 8.1 Sampling .8 8.2 Analysis 9 8.

18、2.1 Particle size distribution .9 8.2.2 Bulk density loose .9 8.2.3 Mass loss at 150 C .9 8.2.4 Ignition loss at 650 C .9 8.2.5 Manganese content 10 8.2.6 Oxidation capacity 11 9 Labelling, transportation and storage 13 9.1 Means of delivery 13 9.2 Labelling according to the EU legislation 13 9.3 Tr

19、ansportation regulations and labelling . 13 9.4 Marking 13 9.5 Storage . 13 9.5.1 Long-term stability 13 9.5.2 Storage incompatibility 13 Annex A (informative) General information on manganese greensand . 14 A.1 Origin . 14 A.1.1 Raw material 14 A.1.2 Manufacturing process 14 A.2 Typical properties

20、. 14 A.2.1 Chemical composition . 14 A.2.2 Mechanical strength . 15 A.2.3 Density . 15 A.2.4 Porosity of particles . 15 A.3 Use . 16 E DIN EN 12911:2013-07 EN 12911:2013 (E) 3 A.3.1 Function 16 A.3.2 Specific amount . 16 A.3.3 Means of application . 16 A.3.4 Secondary effects 16 A.4 Hydraulic charac

21、teristics 16 A.4.1 Interstitial volume 16 A.4.2 Head loss in filtration 16 A.4.3 Expansion during up-flow washing . 17 A.5 Rules for safe handling and use 17 A.6 Emergency procedures . 17 A.6.1 First aid . 17 A.6.2 Spillage . 17 A.6.3 Fire 17 Bibliography 18 E DIN EN 12911:2013-07 EN 12911:2013 (E)

22、4 Foreword This document (EN 12911:2013) has been prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest

23、 by November 2013, and conflicting national standards shall be withdrawn at the latest by November 2013. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all s

24、uch patent rights. This document supersedes EN 12911:2006. Significant technical difference between this edition and EN 12911:2006 is as follows: Updating of subclause 9.2 in line with current legislation. According to the CEN-CENELEC Internal Regulations, the national standards organisations of the

25、 following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherla

26、nds, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. E DIN EN 12911:2013-07 EN 12911:2013 (E) 5 Introduction In respect of potential adverse effects on the quality of water intended for human consumption caused by the product covered

27、by this European Standard, the following statements apply: This European Standard provides no information as to whether the product may be used without restriction in any of the Member States of the EU or EFTA. It should be noted that, while awaiting the adoption of verifiable European criteria, exi

28、sting national regulations concerning the use and/or the characteristics of this product remain in force. NOTE Conformity with this European Standard does not confer or imply acceptance or approval of the product in any of the Member States of the EU or EFTA. Use of the product covered by this Europ

29、ean Standard is subject to regulation or control by National Authorities. E DIN EN 12911:2013-07 EN 12911:2013 (E) 6 1 Scope This European Standard is applicable to manganese greensand used for the treatment of water intended for human consumption. It describes the characteristics of manganese green

30、sand and specifies the requirements and the corresponding test methods for manganese greensand. It gives information on its use in water treatment. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its applicati

31、on. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 12901:1999, Products used for treatment of water intended for human consumption Inorganic supporting and filtering materials Definiti

32、ons EN 12902, Products used for treatment of water intended for human consumption Inorganic supporting and filtering materials Methods of test EN ISO 3696, Water for analytical laboratory use Specification and test methods (ISO 3696) ISO 6333, Water quality Determination of manganese Formaldoxime sp

33、ectrometric method ISO 9682-1:2009, Iron ores Determination of manganese content Part 1: Flame atomic absorption spectrometric method 3 Terms and definitions and symbols For the purposes of this document, the terms and definitions and symbols given in EN 12901:1999 apply. 4 Description 4.1 Identific

34、ation 4.1.1 Chemical name(s) Manganese oxide coated zeolite (glauconite). NOTE The product is a preparation. 4.1.2 Synonym or common names Manganese greensand, manganese zeolite, ferro-sand, greensand. 4.1.3 Chemical formula Not applicable. E DIN EN 12911:2013-07 EN 12911:2013 (E) 7 4.1.4 CAS Regist

35、ry Number1)Glauconite: 90387-66-9. Manganese oxide: 1313-13-9. 4.1.5 EINECS reference2)Glauconite: 291-341-6. Manganese oxide: 215-202-6. 4.2 Commercial form Manganese greensand is a granular product available in only one particle size range. 5 Physical properties 5.1 Appearance The product comprise

36、s dry, sand-like, free flowing black granules. The particles are coated with a black manganese dioxide coating. The product has a granular shape, dense crystalline structure and a rough texture. The product shall be generally homogeneous and shall be visibly free of extraneous matter. 5.2 Particle s

37、ize distribution The particle size distribution shall be determined on samples taken at the point of manufacture using the test method given in EN 12902. NOTE 1 The particle size can decrease during transportation and handling. The particle size distribution shall be described by either: a) effectiv

38、e size: (d10) 0,30 mm to 0,35 mm with a maximum deviation of 0,03 mm; 1) uniformity coefficient: (U) shall be less than 1,6; 2) minimum size: (d1) shall be at least 0,25 mm; 3) maximum size: shall not exceed 1,25 mm; or b) by particle size range and by mass fraction of oversize and undersize particl

39、es. The maximum permitted mass fractions of oversize and undersize are 5 %. NOTE 2 Other values might be necessary for certain applications. 1)Chemical Abstracts Service Registry Number. 2)European Inventory of Existing Commercial Chemical Substances. E DIN EN 12911:2013-07 EN 12911:2013 (E) 8 5.3 D

40、ensity (bulk density loose) The bulk density loose shall be at least 1 300 kg/m3. 6 Chemical properties This European Standard specifies the minimum purity requirements for manganese greensand used for the treatment of water intended for human consumption. Limits are given for impurities commonly pr

41、esent in the product. Depending on the raw material and the manufacturing process, other impurities may be present and, if so, the user, and when necessary the relevant authorities, shall be notified. Users of this product should check the national regulations in order to clarify whether it is of ap

42、propriate purity for treatment of water intended for human consumption, taking into account raw water quality, contents of other impurities and additives used in the product not stated in this product standard. Limits have been given for impurities and chemical parameters where these are likely to b

43、e present in significant quantities from the current production process and raw materials. If the production process or raw materials lead to the presence of significant amounts of impurities, by-products or additives being present, the user shall be notified. The composition of the commercial produ

44、ct shall conform to Table 1. Table 1 Composition of commercial product Parameters Limit in mass fraction % Manganese oxides (as Mn)a0,2 to 0,8 Mass loss at 150 C max. 6 Ignition loss at 650 C max. 8 aThe manganese in the product is present as a mixture of different oxides. NOTE 1 Acid-soluble materi

45、al is not a relevant parameter for this product, which is not stable to acids and which will react with hydrochloric acid releasing chlorine gas. After filling, washing and commissioning of a filter system producing drinking water, manganese greensand should not increase the concentrations of chemic

46、al parameters (see 1). NOTE 2 Water extractable substances, determined in accordance with the method for granular materials given in EN 12902, can be used to estimate the leaching of the chemicals specified in EN 12902. 7 Specific properties The oxidation capacity of manganese greensand (regenerated

47、 form), expressed as grams of Mn per litre of packed product, shall be at least 0,7 g/l. 8 Test methods 8.1 Sampling Prepare the laboratory sample(s) required by the relevant procedures described in EN 12902. E DIN EN 12911:2013-07 EN 12911:2013 (E) 9 8.2 Analysis 8.2.1 Particle size distribution Th

48、e particle size distribution shall be determined in accordance with EN 12902. 8.2.2 Bulk density loose The bulk density loose shall be determined in accordance with EN 12902. 8.2.3 Mass loss at 150 C 8.2.3.1 General The mass loss shall be determined by the method for water content, heating to 150 C,

49、 in accordance with EN 12902. 8.2.3.2 Precision The absolute difference between two single test results, obtained under repeatability conditions, shall not exceed the repeatability limit, r, in more than one in twenty cases. 107,0 Xr =(1) where X1is the measured value. 8.2.4 Ignition loss at 650 C 8.2.4.1 Principle The sample is heated to constant mass at 650 C. It is assumed that water, including chemically bound water, is the only material present in the manganese greensand that is volatile at this temperature.