DIN EN 13205-2-2014 en 6898 Workplace exposure - Assessment of sampler performance for measurement of airborne particle concentrations - Part 2 Laboratory performance test based on.pdf

1、September 2014 Translation by DIN-Sprachendienst.English price group 17No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).

2、ICS 13.040.30!%:g_“2236860www.din.deDDIN EN 13205-2Workplace exposure Assessment of sampler performance for measurement of airborneparticle concentrations Part 2: Laboratory performance test based on determination of samplingefficiency;English version EN 13205-2:2014,English translation of DIN EN 13

3、205-2:2014-09Exposition am Arbeitsplatz Beurteilung der Leistungsfhigkeit von Sammlern fr die Messung der Konzentrationluftgetragener Partikel Teil 2: Laborprfung der Leistungsfhigkeit basierend auf der Bestimmung desProbenahmewirkungsgrads;Englische Fassung EN 13205-2:2014,Englische bersetzung von

4、DIN EN 13205-2:2014-09Exposition sur les lieux de travail valuation des performances des dispositifs de prlvement pour le mesurage desconcentrations de particules en suspension dans lair Partie 2: Essai de performances en laboratoire par dtermination de lefficacit deprlvement;Version anglaise EN 132

5、05-2:2014,Traduction anglaise de DIN EN 13205-2:2014-09Together with DIN EN 13205-1:2014-09, DIN EN 13205-4:2014-09, DIN EN 13205-5:2014-09 andDIN EN 13205-6:2014-09 supersedes DIN EN 13205:2002-04Supersedes: see belowwww.beuth.deIn case of doubt, the German-language original shall be considered aut

6、horitative.Document comprises 39 pages 07.14 DIN EN 13205-2:2014-09 2 A comma is used as the decimal marker. National foreword This document (EN 13205-2:2014) has been prepared by Technical Committee CEN/TC 137 “Assessment of workplace exposure to chemical and biological agents” (Secretariat: DIN, G

7、ermany). The responsible German body involved in its preparation was the Normenausschuss Sicherheitstechnische Grundstze (DIN Standards Committee Safety Design Principles), Working Group NA 095-03-01-01 AK Staub of Working Committee NA 095-03-01 AA Messstrategien und Anforderungen an Messverfahren.

8、Part 3 of this standards series has been published as Technical Report CEN/TR 13205-3:2014. A corres-ponding German-language Standard has not been published by DIN. Amendments This standard differs from DIN EN 13205:2002-04 as follows: a) the standard has been divided up into a six-part series (see

9、European foreword); b) the content of this Part 2 has been limited to the specification of a laboratory performance test for samplers, based on determining the sampling efficiency of a candidate sampler; c) the determination and expression of uncertainty in measurement has been revised and brought i

10、n line with ISO/IEC Guide 98-3:2008, Guide to the expression of uncertainty in measurement (GUM, corres-ponds to DIN V ENV 13005); d) the standard has been editorially revised. Previous editions DIN EN 13205: 2002-04 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 13205-2 June 2014 ICS 13.040.3

11、0 Supersedes EN 13205:2001English Version Workplace exposure - Assessment of sampler performance for measurement of airborne particle concentrations - Part 2: Laboratory performance test based on determination of sampling efficiency Exposition sur les lieux de travail - valuation des performances de

12、s dispositifs de prlvement pour le mesurage des concentrations de particules en suspension dans lair - Partie 2: Essai de performances en laboratoire par dtermination de lefficacit de prlvement Exposition am Arbeitsplatz - Beurteilung der Leistungsfhigkeit von Sammlern fr die Messung der Konzentrati

13、on luftgetragener Partikel - Teil 2: Laborprfung der Leistungsfhigkeit basierend auf der Bestimmung des Probenahmewirkungsgrads This European Standard was approved by CEN on 7 May 2014. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for givin

14、g this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three offic

15、ial versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of

16、Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, S

17、weden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2014 CEN All rights of exploitation in any form and by any means reserved worldwide for

18、 CEN national Members. Ref. No. EN 13205-2:2014 EEN 13205-2:2014 (E) 2 Contents Page Foreword 4 Introduction . 6 1 Scope 7 2 Normative references 7 3 Terms and definitions . 7 4 Symbols and abbreviations 8 4.1 Symbols 8 4.1.1 Latin 8 4.1.2 Greek . 10 4.2 Enumerating subscripts 10 4.3 Abbreviations .

19、 11 5 Principle 11 6 Test method 11 6.1 General 11 6.2 Test conditions 11 6.3 Test variables . 12 6.3.1 General 12 6.3.2 Particle size 14 6.3.3 Wind speed . 14 6.3.4 Wind direction 14 6.3.5 Aerosol composition . 14 6.3.6 Sampled or internally separated mass 14 6.3.7 Aerosol charge . 14 6.3.8 Specime

20、n variability 15 6.3.9 Excursion from the nominal flow rate . 15 6.3.10 Surface treatments 15 7 Experimental requirements 15 8 Calculation of sampler bias and expanded uncertainty 17 8.1 General 17 8.2 Determination of the sampling efficiency . 18 8.3 Calculation of sampler bias 18 8.3.1 Calculation

21、 of the sampled aerosol concentration 18 8.3.2 Calculation of the ideal sampled aerosol concentration . 20 8.3.3 Calculation of the sampler bias 21 8.4 Calculation of the expanded uncertainty of the sampler 21 8.4.1 General 21 8.4.2 Calibration of sampler test system 22 8.4.3 Estimation of sampled c

22、oncentration . 23 8.4.4 Bias relative to the sampling convention 23 8.4.5 Individual sampler variability . 24 8.4.6 Excursion from the nominal flow rate . 24 8.4.7 Combined uncertainty (of measurement) . 28 8.4.8 Expanded uncertainty . 31 9 Test report 31 9.1 General 31 DINEN 13205-2:2014-09EN 13205

23、-2:2014 (E) 3 9.2 Testing laboratory details and sponsoring organisation 31 9.3 Description of the candidate sampler . 31 9.4 Critical review of sampling process 32 9.5 Laboratory methods used 32 9.6 Details of experimental design 33 9.7 Presentation of experimental results 33 9.8 Data analysis 33 9

24、.9 Candidate sampler performance . 33 9.10 Report of workplace comparison 33 9.11 Summary and information for the user of the sampler . 33 Bibliography 36 DIN EN 13205-2:2014-09 EN 13205-2:2014 (E) 4 Foreword This document (EN 13205-2:2014) has been prepared by Technical Committee CEN/TC 137 “Assess

25、ment of workplace exposure to chemical and biological agents”, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by December 2014 and conflicting national stand

26、ards shall be withdrawn at the latest by December 2014. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document together with EN

27、 13205-1, CEN/TR 13205-3, EN 13205-4, EN 13205-5 and EN 13205-6 supersedes EN 13205:2001. EN 13205, Workplace exposure Assessment of sampler performance for measurement of airborne particle concentrations, consists of the following parts: Part 1: General requirements; Part 2: Laboratory performance

28、test based on determination of sampling efficiency (the present document); Part 3: Analysis of sampling efficiency data Technical Report; Part 4: Laboratory performance test based on comparison of concentrations; Part 5: Aerosol sampler performance test and sampler comparison carried out at workplac

29、es; Part 6: Transport and handling tests. Significant technical changes from the previous edition, EN 13205:2001: This part of EN 13205 is based on Annex A of the previous edition, EN 13205:2001. The scope has been limited to aerosol samplers, and the current version of the standard is not (directly

30、) applicable to other types of aerosol instruments. As this is now a standard in its own right, a clause on symbols used has been added. Almost all definitions are now given either in EN 1540, Workplace exposure Terminology or in Part 1 of this standard. The method of calculating the uncertainty of

31、a sampler or a measuring procedure has been revised in order to comply with ENV 13005. The concept of “accuracy” is no longer used, instead the concept of “expanded uncertainty” is used. The five major sources of uncertainty due to aspects of the sampling performance of an aerosol sampler (calibrati

32、on of sampler test system, estimation of sampled concentration, bias relative to the sampling convention, individual sampler variability and excursion from nominal flow rate) are described with equations on how to incorporate these uncertainties into the expanded uncertainty of a sampler. CEN/TR 132

33、05-3 gives recommendations how these entities may be calculated from measured sampling efficiency data. The list of the particle size distributions (per sampling convention) to be used for the evaluation of sampler performance has been restricted at the lower end to reflect that particles with an ae

34、rodynamic DIN EN 13205-2:2014-09 EN 13205-2:2014(E)5 diameter less than 0,5 m are not sampled due to aerodynamic forces. In the current version, an additional requirement on the size distributions is that at least 84 % of the aerosol mass consists of particles exceeding 0,5 m. According to the CEN-C

35、ENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary,

36、 Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. DIN EN 13205-2:2014-09 EN 13205-2:2014 (E) 6 Introduction EN 481 defines sampling conventions for the particl

37、e size fractions to be collected from workplace atmospheres in order to assess their impact on human health. Conventions are defined for the inhalable, thoracic and respirable aerosol fractions. These conventions represent target specifications for aerosol samplers, giving the ideal sampling efficie

38、ncy as a function of particle aerodynamic diameter. In general, the sampling efficiency of real aerosol samplers will deviate from the target specification, and the aerosol mass collected will therefore differ from that which an ideal sampler would collect. In addition, the behaviour of real sampler

39、s is influenced by many factors such as external wind speed. In many cases there is an interaction between the influence factors and fraction of the airborne particle size distribution of the environment in which the sampler is used. EN 13205 (all parts) enables manufacturers and users of aerosol sa

40、mplers to adopt a consistent approach to sampler validation, and provide a framework for the assessment of sampler performance with respect to EN 481 and EN 482. It is the responsibility of the manufacturer of aerosol samplers to inform the user of the sampler performance under the laboratory condit

41、ions1)specified in this part of EN 13205. It is the responsibility of the user to ensure the actual conditions of intended use are within what the manufacturer specifies as acceptable conditions according to the performance test. 1) The inhalable convention is undefined for particle sizes in excess

42、of 100 m or for wind speeds greater than 4 m/s. The tests required to assess performance are therefore limited to these conditions. If such large particle sizes or wind speeds actually existed at the time of sampling, it is possible that different samplers meeting this document give different result

43、s. DIN EN 13205-2:2014-09 EN 13205-2:2014 (E) 7 1 Scope This European Standard specifies a laboratory performance test for samplers for the inhalable, thoracic and respirable aerosol fractions, based on determining the sampling efficiency curve of a candidate sampler at a minimum of nine particle si

44、zes. It specifies methods for testing aerosol samplers under prescribed laboratory conditions in order to test whether the performance of a candidate sampler fulfils the requirements of EN 13205-1:2014. This part of EN 13205 is applicable to all samplers used for the health-related sampling of parti

45、cles in workplace air. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced docume

46、nt (including any amendments) applies. EN 1540, Workplace exposure Terminology EN 13205-1:2014, Workplace exposure Assessment of sampler performance for measurement of airborne particle concentrations Part 1: General requirements CEN/TR 13205-3:2014, Workplace exposure Assessment of sampler performa

47、nce for measurement of airborne particle concentrations Part 3: Analysis of sampling efficiency data EN 13205-5:2014, Workplace exposure Assessment of sampler performance for measurement of airborne particle concentrations Part 5: Aerosol sampler performance test and sampler comparison carried out a

48、t workplaces EN ISO 13137, Workplace atmospheres Pumps for personal sampling of chemical and biological agents - Requirements and test methods (ISO 13137) 3 Terms and definitions For the purpose of this document, the terms and definitions given in EN 1540, EN 13205-1:2014 and the following apply. NOTE With regard to EN 1540, in particular, the following terms are used in this document: total airborne particles, respirable fraction, sampling efficiency, static sampler, thoracic fra