DIN EN 14211-2012 Ambient air - Standard method for the measurement of the concentration of nitrogen dioxide and nitrogen monoxide by chemiluminescence German version EN 14211 2012.pdf

1、November 2012 Translation by DIN-Sprachendienst.English price group 31No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).I

2、CS 13.040.20!$N“1924394www.din.deDDIN EN 14211Ambient air Standard method for the measurement of the concentration of nitrogendioxide and nitrogen monoxide by chemiluminescence;English version EN 14211:2012,English translation of DIN EN 14211:2012-11Auenluft Messverfahren zur Bestimmung der Konzentr

3、ation von Stickstoffdioxid undStickstoffmonoxid mit Chemilumineszenz;Englische Fassung EN 14211:2012,Englische bersetzung von DIN EN 14211:2012-11Air ambiant Mthode normalise pour le mesurage de la concentration en dioxyde dazote etmonoxyde dazote par chimiluminescence;Version anglaise EN 14211:2012

4、,Traduction anglaise de DIN EN 14211:2012-11SupersedesDIN EN 14211:2005-06www.beuth.deDocument comprises pagesIn case of doubt, the German-language original shall be considered authoritative.10.12104 This standard has been included in the VDI/DIN Handbook on air quality, Volume 5.2 A comma is used a

5、s the decimal marker. National foreword This standard has been prepared by Technical Committee CEN/TC 264 “Air quality” (Secretariat: DIN, Germany), Working Group WG 12 “Reference method for determination of SO2/NO2/O3/CO in ambient air” (Secretariat: NEN, Netherlands). The responsible German body i

6、nvolved in its preparation was the Kommission Reinhaltung der Luft (KRdL) im VDI und DIN Normenausschuss (Commission on Air Pollution Prevention of VDI and DIN Standards Committee). Amendments This standard differs from DIN EN 14211:2005-06 as follows: a) Clause 1 “Scope”: the scope has been extende

7、d to include information for different groups of users; b) Subclause 6.3 “Sampling system” and former Annex A: the residence time is no longer calculated from reaction kinetics as prescribed in Annex A. This Annex has been deleted; c) Subclauses 8.1 and 8.3: normative references to EN 15267-1 and EN

8、 15267-2 have been included; d) Subclause 8.4.2.3, Table 4: the requirements for test gases have been modified; e) Subclauses 8.4.5 and 9.3: a formula for calculation of the detection limit of an analyser and information about its application have been inclulded; f) Subclause 8.4.11: the test of ozo

9、ne interference has been deleted as ozone is not an interferent. When testing the effect of interference of ammonia, the measured Noxconcentration is to be used instead of the NO concentration; g) Subclauses 9.4 and 9.6: the performance requirements for some performance characteristics in field oper

10、ation have been tightened. Additional performance criteria and tests have been introduced for repeatability at zero and span levels in field operation; h) Subclause 9.5: formulae for software adjustment of the raw analyser signal after calibration have been introduced; i) Subclause 9.6: formulae hav

11、e been introduced to calculate the average converter efficiency between checks and the resulting uncertainty of the average efficiency; j) Subclause 9.9 (new): general information on measurement uncertainty has been included; k) Clause 11: more stringent requirements have been specified for test rep

12、orts and documentation; DIN EN 14211:2012-11 3 l) the former Annex D has been replaced by the reference to Directive 2008/50/EC (Subclause 6.2); m) Annex F.3 (previously G.3): the model formula and the formulae for the calculation of the influence quantities have been modified; n) Annex F (previousl

13、y G) to Annex H (previously I): examples of calculations have been modified/supplemented. Previous editions DIN EN 14211: 2005-06 DIN EN 14211:2012-114 National Annex NA (informative) Bibliography VDI 2453 Part 2, Gaseous air pollution measurement Measurement of concentration of nitrogen monoxide an

14、d nitrogen dioxide Calibration of NO/NOxchemiluminescence analysers using gas phase titration VDI 2453 Part 3, Gaseous air pollution measurement Determination of the nitrogen monoxide and nitrogen dioxide concentration Preparation of the calibration gas mixtures and determination of their concentrat

15、ion VDI 4202 Part 1, Performance criteria for performance tests of automated ambient air measuring systems Point-related measurement methods for gaseous and particulate air pollutants VDI 4203 Part 1, Testing of automated measuring systems General concepts VDI 4203 Part 3, Testing of automated measu

16、ring systems Test procedures for point-related ambient air measuring systems for gaseous and particulate air pollutants DIN EN 14211:2012-11 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 14211 August 2012 ICS 13.040.20 Supersedes EN 14211:2005English Version Ambient air - Standard method for

17、the measurement of the concentration of nitrogen dioxide and nitrogen monoxide by chemiluminescence Air ambiant - Mthode normalise pour le mesurage de la concentration en dioxyde dazote et monoxyde dazote par chimiluminescence - Messverfahren zur Bestimmung der Konzentration von Stickstoffdioxid und

18、 Stickstoffmonoxid mit Chemilumineszenz This European Standard was approved by CEN on 10 May 2012. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-t

19、o-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by transla

20、tion under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland,

21、 Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION C

22、OMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2012 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 14211:2012: EAuenluft2 Contents Contents . 2Foreword 41 Scope 52

23、 Normative references 63 Terms and definitions 64 Abbreviated terms . 115 Principle 115.1 General 115.2 Measuring principle . 115.3 Type approval test . 125.4 Field operation and quality control 126 Sampling . 136.1 General 136.2 Sampling location 136.3 Sampling system 136.4 Control and regulation o

24、f sample flow rate . 146.5 Sampling pump for the manifold 157 Analyser equipment . 157.1 General 157.2 Converter 157.3 Ozone generator. 167.4 Reaction chamber 167.5 Optical filter 167.6 Detector . 167.7 Ozone removal device . 167.8 Sampling pump for the analyser 167.9 Particle filter . 168 Type appr

25、oval of nitrogen dioxide and nitrogen monoxide analysers 168.1 General 168.2 Relevant performance characteristics and performance criteria . 178.3 Design change 198.4 Procedures for determination of the performance characteristics during the laboratory test . 208.5 Determination of the performance c

26、haracteristics during the field test 328.6 Type approval and uncertainty calculation . 359 Field operation and ongoing quality control . 369.1 General 369.2 Suitability evaluation . 369.3 Initial installation 389.4 Ongoing quality assurance/quality control . 399.5 Calibration of the analyser 419.6 C

27、hecks 439.7 Maintenance . 489.8 Data handling and data reports 489.9 Measurement uncertainty . 4910 Expression of results 4911 Test reports and documentation 5011.1 Type approval test . 5011.2 Field operation . 51DIN EN 14211:2012-11 EN 14211:2012 (E) 3 Annex A (normative) Test of lack of fit . 53An

28、nex B (informative) Sampling equipment. 55Annex C (informative) Types of chemiluminescence analysers 57Annex D (informative) Manifold testing 60Annex E (normative) Type approval 62Annex F (informative) Calculation of uncertainty in field operation at the hourly limit value 81Annex G (informative) Ca

29、lculation of uncertainty in field operation at the annual limit value . 89Annex H (informative) Significant technical changes . 99Bibliography 100DIN EN 14211:2012-11 EN 14211:2012 (E) 4 Foreword This document (EN 14211:2012) has been prepared by Technical Committee CEN/TC 264 “Air quality”, the sec

30、retariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by February 2013, and conflicting national standards shall be withdrawn at the latest by February 2013. Attention is

31、drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 14211:2005. The technical changes made since EN 14211:2005 are listed i

32、n Annex H of this European Standard. According to the CEN/CENELEC Internal Regulations, the national standards organisations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugosl

33、av Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. DIN EN 14211:2012-11 EN 14211:2012 (E) 5 1 Scope T

34、his European Standard specifies a continuous measurement method for the determination of the concentrations of nitrogen dioxide and nitrogen monoxide present in ambient air based on the chemiluminescence measuring principle. This standard describes the performance characteristics and sets the releva

35、nt minimum criteria required to select an appropriate chemiluminescence analyser by means of type approval tests. It also includes the evaluation of the suitability of an analyser for use in a specific fixed site so as to meet the data quality requirements as specified in Annex I of Directive 2008/5

36、0/EC 1 and requirements during sampling, calibration and quality assurance for use. The method is applicable to the determination of the concentration of nitrogen dioxide present in ambient air up to 500 g/m3. This concentration range represents the certification range for NO2for the type approval t

37、est. The method is applicable to the determination of the concentration of nitrogen monoxide present in ambient air up to 1 200 g/m3. This concentration range represents the certification range for NO for the type approval test. NOTE 1 It is possible to use other ranges depending on the levels prese

38、nt in ambient air. NOTE 2 When this European Standard is used for other purposes than for measurements required by Directive 2008/50/EC, the ranges and uncertainty requirements may not apply. The method covers the determination of ambient air concentrations of nitrogen dioxide and nitrogen monoxide

39、in zones classified as rural areas, urban-background areas and traffic-orientated locations and locations influenced by industrial sources. The results are expressed in g/m3(at 20 C and 101,3 kPa). NOTE 3 500 g/m3 of NO2corresponds to 261 nmol/molof NO2at 20 C and 101,3 kPa. 1 200 g/m3 of NO corresp

40、onds to 962 nmol/mol of NO at 20 C and 101,3 kPa. This standard contains information for different groups of users. Clauses 5 to 7 and Annexes B and C contain general information about the principles of NOxmeasurement by chemiluminescence analyser and sampling equipment. Clause 8 and Annex E are spe

41、cifically directed towards test houses and laboratories that perform type-approval testing of NOxanalysers. These sections contain information about: Type-approval test conditions, test procedures and test requirements; Analyser performance requirements; Evaluation of the type-approval test results;

42、 Evaluation of the uncertainty of the measurement results of the NOxanalyser based on the type-approval test results. Clauses 9 to 11 and Annexes F and G are directed towards monitoring networks performing the practical measurements of NOxin ambient air. These sections contain information about: Ini

43、tial installation of the analyser in the monitoring network and acceptance testing; Ongoing quality assurance/quality control; Calculation and reporting of measurement results; Evaluation of the uncertainty of measurement results under practical monitoring conditions. DIN EN 14211:2012-11 EN 14211:2

44、012 (E) 6 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including

45、 any amendments) applies. EN 15267-1, Air quality Certification of automated measuring systems Part 1: General principles EN 15267-2, Air quality Certification of automated measuring systems Part 2: Initial assessment of the AMS manufacturers quality management system and post certification surveill

46、ance for the manufacturing process EN ISO 6142, Gas analysis Preparation of calibration gas mixtures Gravimetric method (ISO 6142) EN ISO 6143, Gas analysis Comparison methods for determining and checking the composition of calibration gas mixtures (ISO 6143) EN ISO 6144, Gas analysis Preparation of

47、 calibration gas mixtures Static volumetric methods (ISO 6144) EN ISO 6145-6, Gas analysis Preparation of calibration gas mixtures using dynamic volumetric methods Part 6: Critical orifices (ISO 6145-6) EN ISO 6145-7, Gas analysis Preparation of calibration gas mixtures using dynamic volumetric meth

48、ods Part 7: Thermal mass-flow controllers (ISO 6145-7) EN ISO 6145-10, Gas analysis Preparation of calibration gas mixtures using dynamic volumetric methods Part 10: Permeation method (ISO 6145-10) EN ISO 14956, Air quality Evaluation of the suitability of a measurement procedure by comparison with a required measurement uncertainty (ISO 14956) EN ISO/IEC 17025, General requirements for the competence of testing and calibration laboratories (ISO/IEC 17025) ENV 13005:1999, Guide to the expression of uncertainty in measurement 3 Terms and definitions For the purposes of this document,