1、June 2010 Translation by DIN-Sprachendienst.English price group 10No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 8
2、3.180!$i,(“1700905www.din.deDDIN EN 14294Adhesives for leather and footwear materials Preparation of bonded test pieces by moulding-on processesEnglish translation of DIN EN 14294:2010-06Klebstoffe fr Leder und Schuhwerkstoffe Herstellung von Verbund-Proben nach dem AnformverfahrenEnglische bersetzu
3、ng von DIN EN 14294:2010-06Adhsifs pour cuir et matriaux de la chaussure Prparation dprouvettes colles par moulage direct sur tigeTraduction anglaise de DIN EN 14294:2010-06SupersedesDIN EN 14294:2004-12www.beuth.deDocument comprises pagesIn case of doubt, the German-language original shall be consi
4、dered authoritative.1506.10 DIN EN 14294:2010-06 A comma is used as the decimal marker. National foreword This standard has been prepared by Technical Committee CEN/TC 193 “Adhesives” (Secretariat: AENOR, Spain). The responsible German body involved in its preparation was the Normenausschuss Materia
5、lprfung (Materials Testing Standards Committee), Working Committee NA 062-04-52 AA Schuhe. Amendments This standard differs from DIN EN 14294:2004-12 as follows: a) An environmental statement has been included (see clause 1). b) References to EN 522 and EN 1391 have been replaced with a reference to
6、 EN 15307. c) The range of reference footwear test adhesives now also includes PUD 1 and PUD 2. d) The bibliography has been dropped. Previous editions DIN EN 14294: 2004-12 2 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 14294 February 2010 ICS 83.180 Supersedes EN 14294:2004English Version
7、Adhesives for leather and footwear materials - Preparation of bonded test pieces by moulding-on processes Adhsifs pour cuir et matriaux de la chaussure - Prparation dprouvettes colles par moulage direct sur tige Klebstoffe fr Leder und Schuhwerkstoffe - Herstellung von Verbund-Proben nach dem Anform
8、verfahren This European Standard was approved by CEN on 28 December 2009. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliogr
9、aphical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of
10、a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Icelan
11、d, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue M
12、arnix 17, B-1000 Brussels 2010 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 14294:2010: EEN 14294:2010 (E) 2 Contents Page Foreword 3Introduction .41 Scope 52 Normative references 53 Terms and definitions .54 Procedure .65 Adhes
13、ives and materials .66 Apparatus .77 Test pieces .88 Preparation of moulded-on assemblies 99 Test report . 13DIN EN 14294:2010-06 EN 14294:2010 (E) 3 Foreword This document (EN 14294:2010) has been prepared by Technical Committee CEN/TC 193 “Adhesives”, the secretariat of which is held by AENOR. Thi
14、s European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by August 2010, and conflicting national standards shall be withdrawn at the latest by August 2010. Attention is drawn to the possibility that some of the
15、 elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 14294:2004. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the follo
16、wing countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slova
17、kia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. DIN EN 14294:2010-06 EN 14294:2010 (E) 4 Introduction EN 15307 and EN 1392 specify methods of testing and evaluation of adhesives for leather and footwear materials in “stuck-on“ assemblies. Most footwear produced in Europe is manufac
18、tured using stuck-on processes, but a significant proportion is produced by “moulding-on“ processes such as vulcanising, injection moulding and reaction moulding. This document specifies the preparation of bonded test pieces by moulding-on processes. The form and dimensions of the test pieces produc
19、ed allows testing according to the test methods specified in EN 1392, and evaluation of the bond strength obtained according to EN 15307. This document therefore complements the above mentioned series of documents, and together they allow the simulation, testing and evaluation of almost all bonds oc
20、curring in common footwear constructions. DIN EN 14294:2010-06 EN 14294:2010 (E) 5 1 Scope This European Standard specifies procedures for the preparation of test pieces comprising adhesive coated leather or other footwear upper material onto which a soling material is moulded directly. The procedur
21、es described simulate direct vulcanising of rubber, injection moulding of thermoplastics and reaction moulding of polyurethane. The prepared test pieces are suitable for the test procedures described in EN 1392, to meet the requirements of EN 15307. SAFETY STATEMENT Persons using this document shoul
22、d be familiar with the normal laboratory practice, if applicable. This document does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user to establish appropriate safety and health practices and to ensure compliance with any regulat
23、ory conditions. ENVIRONMENTAL STATEMENT It is understood that some of the material permitted in this standard may have negative environmental impact. As technological advantages lead to acceptable alternatives for these materials, they will be eliminated from this standard to the extent possible. At
24、 the end of the test, the user of the standard should take care to carry out an appropriate disposal of the wastes, according to local regulation. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition
25、cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 923:2005, Adhesives Terms and definitions EN 1392:2006, Adhesives for leather and footwear materials Solvent-based and dispersion adhesives Testing of bond strength under speci
26、fied conditions EN 15307, Adhesives for leather and footwear materials Sole-upper bonds Minimum strength requirements EN ISO 868, Plastics and ebonite Determination of indentation hardness by means of a durometer (Shore hardness) (ISO 868:2003) 3 Terms and definitions For the purposes of this docume
27、nt, the terms and definitions given in EN 923:2005 and EN 1392:2006 and the following apply. 3.1 moulding-on process process for soling footwear in which the soling material is directly moulded onto the bottom of the shoe in a mould closed by the shoe upper or other footwear component NOTE The other
28、 footwear component can be an outsole or midsole onto which another soling layer is to be moulded. 3.2 vulcanising moulding process in which uncured rubber is inserted or extruded into the mould and is shaped and crosslinked by heat and pressure DIN EN 14294:2010-06 EN 14294:2010 (E) 6 3.3 injection
29、 moulding moulding process in which molten thermoplastic material is injected into the mould and sets on cooling 3.4 reaction moulding moulding process in which reactive chemicals are poured or injected into the mould and polymerise and crosslink by chemical reaction 4 Procedure The surface of the l
30、eather, other footwear upper material or other footwear component material used is treated in a manner specific to the nature of the material. Strips of specified length and width are cut from the treated material. One or more of these strips are coated with adhesive and attached, with the bonding s
31、urface uppermost, to the bottom plate of a mould. Soling material is introduced to fill the mould and allowed to cure or set as appropriate to produce an assembly of soling bonded to upper material. The moulded assembly, and test pieces cut from it, are stored under specified conditions before testi
32、ng. 5 Adhesives and materials 5.1 Footwear adhesives The adhesive used shall be identified in the report, in particular note name and/or designation, manufacturer, date of manufacture or supply and/or lot number, main polymer and colour. For two-part adhesives the nature of the crosslinking agent an
33、d the mixing ratio of the components shall be identified. Reference footwear test adhesives are one- or two-part adhesives with specified properties (e.g. Test adhesive CR 1, Test adhesive CR 2, Test adhesive PU 1, Test adhesive PU 2, Test adhesive PUD 1, Test adhesive PUD 2). If a reference footwea
34、r test adhesive in accordance with EN 15307 is used, record its designation in the report. NOTE For direct vulcanising processes, and injection moulding processes with styrene-butadiene-styrene thermoplastic rubber (SBSR), special types of adhesive are required. 5.2 Footwear materials 5.2.1 General
35、Identify all footwear materials used in the report. 5.2.2 Upper materials (or other footwear materials) Record the name and/or designation, manufacturer, date of manufacture or supply and type of leather, other footwear upper material (or other footwear material) used. For leathers list colour, thic
36、kness and type of tannage (if known). If reference test material Leather 1 is used in accordance with EN 15307, record its designation. 5.2.3 Soling moulding materials 5.2.3.1 General The soling moulding material required depends on the moulding-on process to be simulated. DIN EN 14294:2010-06 EN 14
37、294:2010 (E) 7 5.2.3.2 Direct vulcanising materials Record the name and/or designation, manufacturer, date of manufacture or supply, colour, polymer base and Shore hardness in accordance with EN ISO 868 of the material used. NOTE Uncured compounds of acrylonitrile-butadiene (nitrile) rubber (NBR) or
38、 styrene-butadiene rubber (SBR) are mainly used. 5.2.3.3 Injection moulding materials Record the name and/or designation, manufacturer, date of manufacture or supply, colour, polymer base and Shore hardness in accordance with EN ISO 868 of the material used. NOTE PVC compounds or styrene-butadiene-s
39、tyrene thermoplastic rubber (SBSR) compounds are mainly used. 5.2.3.4 Reaction moulding materials Record the name and/or designation, manufacturer, date of manufacture or supply, colour, chemical nature of the reactive constituents and the catalysts used, if any. NOTE Polyurethane chemicals are main
40、ly used, consisting of a prepolymer and a resin which are mixed in the appropriate proportions before moulding. If a catalyst is also required, this can be added to the resin prior to the weighing out of the constituents. 6 Apparatus 6.1 General The items required depend on the types of material use
41、d and the type of moulding-on process. 6.2 Cutting knife, sharp for cutting test pieces in accordance with 7.1. The angle between the inner and outer cutting surface shall be approximately 20. 6.3 Adhesive applicator, brush, roller or coating machine for applying a uniform coat of the adhesive under
42、 test. 6.4 Platen press, a heated platen press suitable for direct vulcanisation of rubber, capable of: a) maintaining platen temperatures of (105 5) C for the bottom platen and (180 5) C for the top platen; b) applying a pressure up to 5 MPa to the mould. 6.5 Rectangular mould, of approximate dimen
43、sions 150 mm 100 mm 5 mm for direct vulcanisation. The wall of the mould base should include a 10 mm wide shelf all round, half way up, to accept excess rubber displaced from the cavity. 6.6 Surface pyrometer, suitable for measuring the operating temperatures of the press platens. 6.7 Oven, capable
44、of maintaining a temperature of (75 5) C to pre-heat the rubber prior to moulding. 6.8 Gloves, heat resistant, suitable for handling the hot mould. 6.9 Injection moulding machine, fitted with a mould of approximate dimensions 150 mm 100 mm 5 mm for the preparation of flat test plaques. A commercial
45、single station low pressure screw injection moulder is suitable. 6.10 Mould, for polyurethane reaction moulding, having: a) flat rigid base with a rectangular cavity of approximate dimensions 300 mm 200 mm 6,5 mm; DIN EN 14294:2010-06 EN 14294:2010 (E) 8 b) rigid hinged lid which can be held in plac
46、e, for example by two wing nuts; c) rebate a few millimetres deep across the two corners of the base away from the hinge. This provides a gap which can assist in opening of the mould. 6.11 Oven, capable of maintaining a temperature of (50 5) C to heat the mould prior to moulding. 6.12 Mould release
47、agent, suitable for polyurethanes. 6.13 Solvent, such as 2-butanone (MEK), suitable for removing mould release agent. 6.14 General purpose balance, reading up to 300 g with an accuracy of 0,1 g. 6.15 Metal mixing cans, of approximate volume 400 cm3 capable of holding about 300 g of the polyurethane
48、constituents in liquid form. 6.16 Paper weighing cups, of approximate volume 200 cm3, to weigh the polyurethane prepolymer prior to mixing. 6.17 High speed stirrer, suitable for mixing the viscous polyurethane constituents in a metal can. A stirrer with a mixing head comprising a horizontal spoked m
49、etal wheel with rectangular teeth around the edge is suitable. 6.18 Polyethylene gloves. 6.19 Safety goggles. 6.20 Adhesive tape, double side adhesive tape. 7 Test pieces 7.1 General The form and dimensions of the test pieces prepared from the moulded-on assemblies shall comply with the requirements for test pieces for peel tests at (23 2) C, and test pieces for peel tests under constant load and at a constant elevated temperature (“creep test“) in EN 1392. 7.2 Number of test piece
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