DIN EN 14617-10-2012 Agglomerated stone - Test methods - Part 10 Determination of chemical resistance German version EN 14617-10 2012《烧结石料 试验方法 第10部分 耐化学性测定》.pdf

1、June 2012 Translation by DIN-Sprachendienst.English price group 8No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 91

2、.100.15!$|tl“1898173www.din.deDDIN EN 14617-10Agglomerated stone Test methods Part 10: Determination of chemical resistanceEnglish translation of DIN EN 14617-10:2012-06Knstlich hergestellter Stein Prfverfahren Teil 10: Bestimmung der chemischen BestndigkeitEnglische bersetzung von DIN EN 14617-10:2

3、012-06Pierre agglomre Mthodes dessai Partie 10: Dtermination de la rsistance chimiqueTraduction anglaise de DIN EN 14617-10:2012-06SupersedesDIN EN 14617-10:2005-06www.beuth.deDocument comprises 13 pagesIn case of doubt, the German-language original shall be considered authoritative.05.12 DIN EN 146

4、17-10:2012-06 2 A comma is used as the decimal marker. National foreword This standard has been prepared by Technical Committee CEN/TC 246 “Natural stones” (Secretariat: UNI, Italy). At present a DIN committee does not exist for this standard since the parties concerned have not shown any interest i

5、n work on the subject. The DIN Standard corresponding to the International Standard referred to in this document is as follows ISO 8486-2 DIN ISO 8486-2 Amendments This standard differs from DIN EN 14617-10:2005-06 as follows: a) in Subclause 4.3 the minimum size of test specimens has been changed;

6、b) the informative Annex A “Determination of the resistance to stains” is now a normative Annex; c) in Annex A a silicone ring is no longer used; d) the standard has been editorially revised. Previous editions DIN EN 14617-10: 2005-06 National Annex NA (informative) Bibliography DIN ISO 8486-2, Bond

7、ed abrasives Determination and designation of grain size distribution Part 2: Microgrits F230 to F2000 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 14617-10 April 2012 ICS 91.100.15 Supersedes EN 14617-10:2005English Version Agglomerated stone - Test methods - Part 10: Determination of chemi

8、cal resistance Pierre agglomre - Mthodes dessai - Partie 10: Dtermination de la rsistance chimique Knstlich hergestellter Stein - Prfverfahren - Teil 10: Bestimmung der chemischen Bestndigkeit This European Standard was approved by CEN on 9 March 2012. CEN members are bound to comply with the CEN/CE

9、NELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre

10、 or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the o

11、fficial versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania,

12、Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2012 CEN All rights of exploitation in any form and by any means reserv

13、ed worldwide for CEN national Members. Ref. No. EN 14617-10:2012: EEN 14617-10:2012 (E) 2 Contents Page Foreword 31 Scope 42 Normative references 43 Principle 44 Determination of the chemical resistance 44.1 Chemical reagents .44.2 Apparatus .44.3 Preparation of the specimens 54.4 Test procedure .54

14、.5 Expression of the results 54.6 Test report 6Annex A (normative) Determination of the resistance to stains 8A.1 Principle 8A.2 Staining agent 8A.3 Preparation of the specimens 8A.4 Test procedure .8A.5 Expression of the results 9A.6 Test report 9Bibliography . 11DIN EN 14617-10:2012-06 EN 14617-10

15、:2012 (E) 3 Foreword This document (EN 14617-10:2012) has been prepared by Technical Committee CEN/TC 246 “Natural stones”, the secretariat of which is held by UNI. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement,

16、at the latest by October 2012, and conflicting national standards shall be withdrawn at the latest by October 2012. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying a

17、ny or all such patent rights. This document supersedes EN 14617-10:2005. 4.3, 4.4, 4.5, A.3 and A.4 have been modified since the last edition of this European Standard. This European Standard is one of a series of standards for test methods for agglomerated stones which includes the following: EN 14

18、617-1, Agglomerated stone Test methods Part 1: Determination of apparent density and water absorption EN 14617-2, Agglomerated stone Test methods Part 2: Determination of flexural strength (bending) EN 14617-4, Agglomerated stone Test methods Part 4: Determination of the abrasion resistance EN 14617

19、-5, Agglomerated stone Test methods Part 5: Determination of freeze and thaw resistance EN 14617-6, Agglomerated stone Test methods Part 6: Determination of thermal shock resistance EN 14617-8, Agglomerated stone Test methods Part 8: Determination of resistance to fixing (dowel hole) EN 14617-9, Agg

20、lomerated stone Test methods Part 9: Determination of impact resistance EN 14617-10, Agglomerated stone Test methods Part 10: Determination of chemical resistance EN 14617-11, Agglomerated stone Test methods Part 11: Determination of linear thermal expansion coefficient EN 14617-12, Agglomerated sto

21、ne Test methods Part 12: Determination of dimensional stability EN 14617-13, Agglomerated stone Test methods Part 13: Determination of electrical resistivity EN 14617-15, Agglomerated stone Test methods Part 15: Determination of compressive strength EN 14617-16, Agglomerated stone Test methods Part

22、16: Determination of dimensions, geometric characteristics and surface quality of modular tiles According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cypru

23、s, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. DIN EN 14617-10:2012-06 EN 146

24、17-10:2012 (E) 4 1 Scope This European Standard specifies a method for determining the chemical resistance and the resistance to stains of agglomerated stones (see EN 14618) with a polished surface after a prolonged contact with chemical materials. NOTE It is to be remembered that agglomerated stone

25、s containing calcium carbonate aggregates are sensitive to any acid attack. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated re

26、ferences, the latest edition of the referenced document (including any amendments) applies. Not applicable. 3 Principle Resistance to a chemical attack is the characteristic which defines the behaviour of a floor/wall covering material in contact with chemically aggressive agents potentially able to

27、 react with the surface itself, and thereby either corrode it, penetrate it permanently or alter the visible aspect in some manner. The deteriorating action of the aggressive chemical can generate two different effects: a real chemical action, according to which the alteration of the surface is due

28、to the chemical reaction between the aggressive agent and some constituents of the surface itself; a physical absorbing action, according to which the aggressive agent is able to penetrate the surface so that the removal is either extremely difficult or impossible. Both these actions can involve a m

29、odification of the visible appearance of the surface of the chemically attacked material, but only in the first case can the damage also introduce a modification in the physical and mechanical properties of the material itself. 4 Determination of the chemical resistance 4.1 Chemical reagents 4.1.1 W

30、ater solution containing hydrochloric acid solution, 50 % (V/V), prepared from N hydrochloric acid solution. 4.1.2 Sodium hydroxide in a 50 % (V/V) water solution, prepared from a normal water sodium hydroxide non-carbonated solution. 4.2 Apparatus Glossmeter, able to measure with an accuracy and pr

31、ecision of 10 %, the brightness degree of the surface. The glossmeter shall measure the reflection of a light ray incident on a surface. The reflection degree is given by the amount of light specularly reflected in a point of the surface in relationship to the amount of light DIN EN 14617-10:2012-06

32、 EN 14617-10:2012 (E) 5 reflected by the standard glass plate. A light source representing average daylight shall be used, such as the source CIE1D 65, with the lighting intensity allowed by the glossmeter calibration. The glossmeter shall be equipped with at least two optical systems placed at 60 a

33、nd 20 angles. This allows for an efficient measurement of the different reflection directions: the 60 angle covers a range of reflection degrees from low to high, while the 20 angle lends greater accuracy to the measurement of the higher reflection directions (see Annex A). 4.3 Preparation of the sp

34、ecimens For each type of material to be tested four samples shall be prepared with a polished surface2of at least 300 mm 300 mm onto which a containing ring (at least 100 mm diameter) is glued. The ring is made of chemically resistant material such as silicone. The surface to be measured shall be fl

35、at in order to permit the positioning of the instrument sensor in contact with the material to be tested. Before testing, the surface shall be cleaned of any possible wax, other finishes or treatment layers using ketone or another appropriate solvent. 4.4 Test procedure The procedure consists of pos

36、itioning the instrument sensor in contact with the surface to be measured, and of reading the number reported on the display which defines the reflection degree as a reference value of the examined surface. The test shall be carried out at an ambient temperature of (23 5) C. On each of the four spec

37、imens, it is necessary to carry out the reflection measurement on at least five different points, and to then calculate the average value (M1) of each specimen. On two specimens placed horizontally within the ring, pour 10 ml to 15 ml of hydrochloric acid solution (4.1.1), avoiding any possible over

38、flowing. Repeat this operation on the other two specimens using the sodium hydroxide solution (4.1.2). Keep the specimens, protected with a polyethylene film, on a table for all the time requested for the test. After 1 h 5 min draw out one specimen containing hydrochloric acid and one containing sod

39、ium hydroxide respectively; wash them carefully with water and remove the ring. Finally, dry them with soft cellulose paper. After 8 h 30 min draw out the two other specimens and perform the same washing and drying procedure. Repeat the reflection measurement on at least in 5 points on each of the f

40、our specimens, and then calculate the average value for each specimen and the standard deviation of the 5 values. The reflection measurements are to be carried out with the glossmeter under an incident light positioned at 60. 4.5 Expression of the results a) The effects of the chemical attack are ex

41、pressed as the loss of the reference reflection value. This loss is calculated as a percentage of reflection of the material tested with respect to the reference value. A class of resistance to acids and alkali shall be attributed as follows: 1Commission Internationale de lEclairage (Central Bureau,

42、 Kagelpasse 27, A-1030 Vienna-AT). 2Obtained by polishing with abrasive grit, grain size F500, according to ISO 8486-2:2007, Bonded abrasives Determination and designation of grain size distribution: Part 2: Microgrits F230 to F2000. DIN EN 14617-10:2012-06 EN 14617-10:2012 (E) 6 C4: materials, whic

43、h keep at least 80 % of the reflection reference value after 8 h 30 min of acid and basic attack (or if only in one specimen the attack is between 60 % and 80 %); C3: materials, which keep between 60 % and 80 % of the reflection reference value after 8 h 30 min of acid and basic attack; C2: material

44、s, which keep between 60 % and 80 % of the reflection reference value after 1 h 30 min of acid and basic attack; C1: materials, which keep less than 60 % of the reflection reference values after 1 h 30 min of basic and acid attack. b) The values are calculated on the basis of 5 measurements and the

45、dispersion is declared. 4.6 Test report The test report shall contain the following information: a) unique identification number of the report; b) number and year of issue of this European Standard, i.e. EN 14617-10:2012; c) name and address of the test laboratory and the address where the test was

46、carried out if different from the test laboratory; d) name and address of the client; e) it is the responsibility of the client to supply the following information: name of the supplier; name of the person or organization which carried out the sampling; surface finish of the specimens (if relevant t

47、o the test); nature of the binders; f) date of delivery of the sample or of the specimens; g) date when the specimens were prepared (if relevant) and the date of testing; h) number of specimens in the sample; i) dimensions of the specimens; j) water solutions preparation and concentration and chemic

48、al agents used; k) type of glossmeter used and the kind and intensity of the light source; l) reflection directions of the light; m) results obtained, using the following table: DIN EN 14617-10:2012-06 EN 14617-10:2012 (E) 7 Table 1 Results Chemical resistance Sample N Reference value Class - Hydrochloric acid solution - Sodium hydroxide solution n) statement on measurement uncertainty (where appr