DIN EN 14662-3-2016 Ambient air - Standard method for the measurement of benzene concentrations - Part 3 Automated pumped sampling with in situ gas chromatography German version EN.pdf

1、February 2016 English price group 27No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 13.040.20!%LF“2413558www.din.de

2、DIN EN 14662-3Ambient air Standard method for the measurement of benzene concentrations Part 3: Automated pumped sampling with in situ gas chromatography;English version EN 14662-3:2015,English translation of DIN EN 14662-3:2016-02Auenluft Messverfahren zur Bestimmung von Benzolkonzentrationen Teil

3、3: Automatische Probenahme mit einer Pumpe und gaschromatographische In-situ-Bestimmung;Englische Fassung EN 14662-3:2015,Englische bersetzung von DIN EN 14662-3:2016-02Qualit de lair ambiant Mthode normalise pour le mesurage de la concentration en benzne Partie 3: Prlvement par pompage automatique

4、avec analyse chromatographique en phase gazeuse sur site;Version anglaise EN 14662-3:2015,Traduction anglaise de DIN EN 14662-3:2016-02SupersedesDIN EN 14662-3:2005-08www.beuth.deDocument comprises 74 pagesDTranslation by DIN-Sprachendienst.In case of doubt, the German-language original shall be con

5、sidered authoritative.01.16This standard has been included in the VDI/DIN Handbook on air quality, Volume 5.DIN EN 14662-3:2016-02 2 A comma is used as the decimal marker. National foreword This document (EN 14662-3:2015) has been prepared by Technical Committee CEN/TC 264 “Air quality” (Secretariat

6、: DIN, Germany), Working Group WG 12 “Reference method for determination of SO2/NO2/O3/CO in ambient air” (Secretariat and Convenership: NEN, Netherlands). The responsible German body involved in its preparation was the Kommission Reinhaltung der Luft im VDI und DIN Normenausschuss KRdL (Commission

7、on Air Pollution Prevention of VDI and DIN Standards Committee KRdL). Amendments This standard differs from DIN EN 14662-3:2005-08 as follows: a) Clause 8 has been brought in line with other standards dealing with type approval of gas analysers; b) in 9.4 and 9.6, performance requirements have been

8、modified or removed and additional performance criteria and tests have been introduced for repeatability at span level; c) in 9.5, a formula for software adjustment of the raw analyser signal after calibration has been introduced; d) in Annexes E and F, uncertainty calculations have been modified to

9、 be in conformity with EN ISO 14956. Previous editions DIN 33963-1: 1997-02 DIN 33963-2: 1997-02 DIN EN 14662-3: 2005-08 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 14662-3 November 2015 ICS 13.040.20 Supersedes EN 14662-3:2005English Version Ambient air - Standard method for the measuremen

10、t of benzene concentrations - Part 3: Automated pumped sampling with in situ gas chromatography Qualit de lair ambiant - Mthode normalise pour le mesurage de la concentration en benzne - Partie 3: Prlvement par pompage automatique avec analyse chromatographique en phase gazeuse sur site Auenluft - M

11、essverfahren zur Bestimmung von Benzolkonzentrationen - Teil 3: Automatische Probenahme mit einer Pumpe und gaschromatographische In-situ-Bestimmung This European Standard was approved by CEN on 17 July 2015. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate t

12、he conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standar

13、d exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the nation

14、al standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slova

15、kia, Slovenia, Spain, Sweden, Switzerland, Turkey andUnited Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of exploitation in any form and by any means

16、reserved worldwide for CEN national Members. Ref. No. EN 14662-3:2015 EEN 14662-3:2015 (E) 2 Contents Page European foreword . 4 1 Scope 5 2 Normative references 6 3 Terms and definitions . 6 4 Abbreviated terms . 11 5 Principle 12 5.1 General . 12 5.2 Measuring principle 12 5.3 Type approval test .

17、 13 5.4 Field operation and quality control. 14 6 Sampling equipment . 14 6.1 General . 14 6.2 Sampling location . 14 6.3 Sampling system . 14 6.4 Control and regulation of sample volume . 15 6.5 Sampling pump for the manifold 15 7 Analyser equipment 16 7.1 General . 16 7.2 Sampling trap 16 7.3 Samp

18、ling device 16 7.4 Thermal desorption unit . 16 7.5 Separation unit 16 7.6 Detector . 16 7.7 Data processing system . 17 8 Type approval of benzene analysers . 17 8.1 General . 17 8.2 Relevant performance characteristics and performance criteria 18 8.3 Design changes (EN 15267-1 and EN 15267-2) . 19

19、 8.4 Procedures for determination of the performance characteristics during the laboratory test . 19 8.5 Determination of the performance characteristics during the field test. 27 8.6 Expanded uncertainty calculation for type approval . 31 9 Field operation and ongoing quality control . 31 9.1 Gener

20、al . 31 9.2 Suitability evaluation 32 9.3 Initial installation 33 9.4 Ongoing quality assurance/quality control 34 9.5 Calibration of the analyser . 36 9.6 Checks . 37 9.7 Maintenance . 41 9.8 Data handling and data reports 41 9.9 Measurement uncertainty 42 10 Expression of results . 42 DIN EN 14662

21、-3:2016-02 EN 14662-3:2015 (E) 3 11 Test reports and documentation 42 11.1 Type approval test 42 11.2 Field operation 44 Annex A (normative) Test of lack of fit 45 Annex B (informative) Sampling equipment 47 Annex C (informative) Components and applications of benzene analysers . 48 Annex D (informa

22、tive) Manifold testing equipment . 50 Annex E (normative) Type approval . 52 Annex F (informative) Calculation of uncertainty in field operation at the annual limit value 65 Bibliography . 72 DIN EN 14662-3:2016-02 EN 14662-3:2015 (E) 4 European foreword This document (EN 14662-3:2015) has been prep

23、ared by Technical Committee CEN/TC 264 “Air quality”, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2016, and conflicting national standards shall be

24、 withdrawn at the latest by May 2016. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 14662-3:2005. This d

25、ocument has been prepared under a mandate given to CEN by the European Commission and the European Free Trade Association and supports Essential Requirements of the Council Directive 2008/50/EC 1. Details of significant technical changes between this European Standard and the previous edition are: C

26、lause 8 has been brought in line with other Standards dealing with type approval of gas analysers; In 9.4 and 9.6, performance requirements have been modified or removed and additional performance criteria and tests have been introduced for repeatability at span level; In 9.5, formulae have been int

27、roduced for software adjustment of the raw analyser signal after calibration; In Annexes E and F, uncertainty calculations have been modified to be in conformity with EN ISO 14956. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are

28、bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Port

29、ugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. DIN EN 14662-3:2016-02 EN 14662-3:2015 (E) 5 1 Scope This European Standard specifies a semi-continuous measurement method for the determination of the concentration of benzene present in ambient air based

30、on automated sampling and analysis by gas chromatography. This European Standard describes the performance characteristics and sets the relevant minimum criteria required to select an appropriate automated gas chromatograph (GC) by means of type approval tests. It also includes the evaluation of the

31、 suitability of an analyser for use in a specific fixed site so as to meet the data quality requirements as specified in Annex I of Directive 2008/50/EC 1 and requirements during sampling, calibration and quality assurance for use. The method is applicable to the determination of the mass concentrat

32、ion of benzene present in ambient air in the range up to 50 g/m3benzene. This concentration range represents the certification range for the type approval test. Other ranges may be used depending on the levels present in ambient air. NOTE 1 When the standard is used for other purposes than for measu

33、rements required by Directive 2008/50/EC, the ranges and uncertainty requirements may not apply. The method covers the determination of ambient air concentrations of benzene in zones classified as rural areas, urban-background areas and traffic-orientated locations and locations influenced by indust

34、rial sources. The results are expressed in g/m3(at 20 C and 101,3 kPa). NOTE 2 50 g/m3of benzene corresponds to 15,4 nmol/mol of benzene. This European Standard contains information for different groups of users. Clauses 5 to 7 and Annexes C and D contain general information about the principles of

35、benzene measurement by automated gas chromatography and sampling equipment. Clause 8 and Annex E are specifically directed towards test houses and laboratories that perform type-approval testing of benzene analysers. These sections contain information about: type-approval test conditions, test proce

36、dures and test requirements; analyser performance requirements; evaluation of the type-approval test results; evaluation of the uncertainty of the measurement results of the benzene analyser based on the type-approval test results. Clauses 9 to 11 and Annex F are directed towards monitoring networks

37、 performing the practical measurements of benzene in ambient air. These sections contain information about: initial installation of the analyser in the monitoring network and acceptance testing; ongoing quality assurance/quality control; calculation and reporting of measurement results; evaluation o

38、f the uncertainty of measurement results under practical monitoring conditions. DIN EN 14662-3:2016-02 EN 14662-3:2015 (E) 6 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated reference

39、s, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 15267-1, Air quality Certification of automated measuring systems Part 1: General principles EN 15267-2, Air quality Certification of automated measuring sy

40、stems Part 2: Initial assessment of the AMS manufacturers quality management system and post certification surveillance for the manufacturing process EN ISO 6142, Gas analysis Preparation of calibration gas mixtures Gravimetric method (ISO 6142) EN ISO 6143, Gas analysis Comparison methods for deter

41、mining and checking the composition of calibration gas mixtures (ISO 6143) EN ISO 6144, Gas analysis Preparation of calibration gas mixtures Static volumetric method (ISO 6144) EN ISO 6145-4, Gas analysis Preparation of calibration gas mixtures using dynamic volumetric methods Part 4: Continuous syr

42、inge injection method (ISO 6145-4) EN ISO 6145-6, Gas analysis Preparation of calibration gas mixtures using dynamic volumetric methods Part 6: Critical orifices (ISO 6145-6) EN ISO 6145-7, Gas analysis Preparation of calibration gas mixtures using dynamic volumetric methods Part 7: Thermal mass-flo

43、w controllers (ISO 6145-7) EN ISO 6145-8, Gas analysis Preparation of calibration gas mixtures using dynamic volumetric methods Part 8: Diffusion method (ISO 6145-8) EN ISO 6145-9, Gas analysis Preparation of calibration gas mixtures using dynamic volumetric methods Part 9: Saturation method (ISO 61

44、45-9) EN ISO 6145-10, Gas analysis Preparation of calibration gas mixtures using dynamic volumetric methods Part 10: Permeation method (ISO 6145-10) EN ISO 14956, Air quality Evaluation of the suitability of a measurement procedure by comparison with a required measurement uncertainty (ISO 14956) IS

45、O/IEC Guide 98-3:2008, Uncertainty of measurement Part 3: Guide to the expression of uncertainty in measurement (GUM:1995) 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 adjustment set of operations carried out on a measuring system so that

46、it provides prescribed indications corresponding to given values of a quantity to be measured Note 1 to entry: Types of adjustment of a measuring system include zero adjustment of a measuring system, offset adjustment, and span adjustment (sometimes called gain adjustment). DIN EN 14662-3:2016-02 EN

47、 14662-3:2015 (E) 7 Note 2 to entry: Adjustment of a measuring system should not be confused with calibration, which is a prerequisite for adjustment. Note 3 to entry: In the context of this European Standard, adjustment is performed on measurement data rather than on the analyser. SOURCE: JCGM 200:

48、2012 (VIM), Note 3 to entry has been modified, 2 3.2 ambient air outdoor air in the troposphere, excluding workplaces as defined by Directive 89/654/EEC where provisions concerning health and safety at work apply and to which members of the public do not have regular access SOURCE: 2008/50/EC 1 3.3

49、analyser analytical instrument that provides an output signal which is a function of the concentration, partial pressure, flow or temperature of one or more components of a gas mixture 3.4 availability of the analyser fraction of the total time period for which valid measuring data of the ambient air concentration is available from an analyser 3.5 calibration operation that, under specified conditions, in a first step, establishes a relation between the quantity value