DIN EN 15078-2013 Chemicals used for treatment of swimming pool water - Sulfuric acid German version EN 15078 2013《用于处理游泳池水的化学品 硫酸 德文版本EN 15078-2013》.pdf

1、August 2013 Translation by DIN-Sprachendienst.English price group 11No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS

2、 71.100.80!%(25“2051518www.din.deDDIN EN 15078Chemicals used for treatment of swimming pool water Sulfuric acid;English version EN 15078:2013,English translation of DIN EN 15078:2013-08Produkte zur Aufbereitung von Schwimm- und Badebeckenwasser Schwefelsure;Englische Fassung EN 15078:2013,Englische

3、bersetzung von DIN EN 15078:2013-08Produits chimiques utiliss pour le traitement de leau des piscines Acide sulfurique;Version anglaise EN 15078:2013,Traduction anglaise de DIN EN 15078:2013-08SupersedesDIN EN 15078:2006-08www.beuth.deDocument comprises pagesIn case of doubt, the German-language ori

4、ginal shall be considered authoritative.1507.13 DIN EN 15078:2013-08 2 A comma is used as the decimal marker. National foreword This document (EN 15078:2013) has been prepared by Technical Committee CEN/TC 164 “Water supply” (Secretariat: AFNOR, France). The responsible German body involved in its p

5、reparation was the Normenausschuss Wasserwesen (Water Practice Standards Committee), Working Committee NA 119-04-02 AA Wasseraufbereitung. Amendments This standard differs from DIN EN 15078:2006-08 as follows: a) specifications concerning hazard and safety related symbols have been brought in line w

6、ith the “Globally Harmonized System of Classification, Labelling and Packaging of Chemicals (GHS)” (Global harmonisiertes System zur Einstufung und Kennzeichnung von Chemikalien). b) requirements for the composition of the commercial product have been brought in line with DIN EN 899. Previous editio

7、ns DIN EN 15078: 2006-08 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 15078 May 2013 ICS 71.100.80 Supersedes EN 15078:2006English Version Chemicals used for treatment of swimming pool water - Sulfuric acid Produits chimiques utiliss pour le traitement de leau des piscines - Acide sulfurique

8、 Produkte zur Aufbereitung von Schwimm- und Badebeckenwasser - Schwefelsure This European Standard was approved by CEN on 21 March 2013. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national

9、 standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version

10、 in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czec

11、h Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EU

12、ROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2013 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 15078:2013: EEN 15078:2013

13、 (E) 2 Contents Page Foreword . 3 Introduction 4 1 Scope 5 2 Normative reference . 5 3 Description . 5 3.1 Identification . 5 3.2 Commercial forms 6 3.3 Physical properties 6 3.4 Chemical properties . 7 4 Purity criteria 7 4.1 General . 7 4.2 Composition of commercial product . 8 4.3 Chemical parame

14、ters and indicator parameters . 8 5 Test methods 8 6 Labelling Transportation Storage 8 6.1 Means of delivery . 8 6.2 Labelling according to EU legislation 9 6.3 Transportation regulations and labelling 9 6.4 Marking . 10 6.5 Storage . 10 Annex A (informative) General information on sulfuric acid .

15、11 A.1 Origin 11 A.2 Use 11 Annex B (normative) General rules relating to safety . 12 B.1 Rules for safe handling and use 12 B.2 Emergency procedures 12 Bibliography 13 DIN EN 15078:2013-08 EN 15078:2013 (E) 3 Foreword This document (EN 15078:2013) has been prepared by Technical Committee CEN/TC 164

16、 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by November 2013, and conflicting national standards shall be withdrawn at the latest by No

17、vember 2013. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 15078:2006. Significant technical differences

18、 between this edition and EN 15078:2006 are as follows: Replacement of warning and safety precautions notes by labelling according to Regulation (EC) No 1272/2008 2. According to the CEN-CENELEC Internal Regulations, the national standards organisations of the following countries are bound to implem

19、ent this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania,

20、Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. DIN EN 15078:2013-08 EN 15078:2013 (E) 4 Introduction In respect of potential adverse effects on the quality of water intended for swimming pools, caused by the product covered by this European Standard: a) this European

21、Standard provides no information as to whether the product may be used without restriction in any of the Member States of the EU or EFTA; b) it should be noted that, while awaiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the characteristi

22、cs of this product remain in force. NOTE Conformity with this European Standard does not confer or imply acceptance or approval of the product in any of the Member States of the EU or EFTA. The use of the product covered by this European Standard is subject to regulation or control by National Autho

23、rities. DIN EN 15078:2013-08 EN 15078:2013 (E) 5 1 Scope This European Standard is applicable to sulfuric acid used directly or for the production of formulations for the treatment of water for swimming pools. It describes the characteristics and specifies the requirements and the corresponding test

24、 methods for sulfuric acid. It gives information on its use for treatment of water for swimming pools. It also determines the rules relating to safe handling and use (see Annex B). 2 Normative reference The following documents, in whole or in part, are normatively referenced in this document and are

25、 indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 899, Chemicals used for treatment of water intended for human consumption Sulfuric acid 3 Description

26、 3.1 Identification 3.1.1 Chemical name Sulfuric acid. 3.1.2 Synonym or common name Oil of vitriol. 3.1.3 Relative molecular mass 98. 3.1.4 Empirical formula H2SO4. 3.1.5 Chemical formula H2SO4. 3.1.6 CAS Registry Number 1)7664-93-9. 3.1.7 EINECS reference 2)231-639-5. 1) Chemical Abstracts Service

27、Registry Number. 2) European Inventory of Existing Commercial Chemical Substances.DIN EN 15078:2013-08 EN 15078:2013 (E) 6 3.2 Commercial forms Sulfuric acid is available as aqueous solutions. NOTE For some water treatment applications, diluted acid can be used. 3.3 Physical properties 3.3.1 Appeara

28、nce The product is clear or slightly turbid, colourless liquid. 3.3.2 Density 1,84 g/ml for sulfuric acid concentration of mass fraction of 96 % at 20 C. 1,71 g/ml for sulfuric acid concentration of mass fraction of 78 % at 20 C. 1,18 g/ml for sulfuric acid concentration of mass fraction of 25 % at

29、20 C. 3.3.3 Solubility in water At all concentrations, the product is miscible with water. 3.3.4 Vapour pressure Below 0,000 01 kPa for sulfuric acid concentration of mass fraction of 96 % at 20 C. Below 0,1 kPa for sulfuric acid concentration of mass fraction of 78 % at 20 C. Below 1,9 kPa for sulf

30、uric acid concentration of mass fraction of 25 % at 20 C. 3.3.5 Boiling point at 100 kPa 3)+ 310 C for sulfphuric acid concentration of mass fraction of 96 %. Approximately + 200 C for sulfuric acid concentration of mass fraction of 78 %. + 106,5 C for sulfuric acid concentration of mass fraction of

31、 25 %. 3.3.6 Melting point + 5 C for sulfuric acid concentration of mass fraction of 98 %. - 10 C for sulfuric acid concentration of mass fraction of 96 %. - 11 C for sulfuric acid concentration of mass fraction of 78 %. - 22 C for sulfuric acid concentration of mass fraction of 25 %. 3.3.7 Specific

32、 heat 1,465 kJ/(kg.K) for sulfuric acid concentration of mass fraction of 96 % at 20 C. 3) 100 kPa = 1 bar. DIN EN 15078:2013-08 EN 15078:2013 (E) 7 3.3.8 Viscosity (dynamic) 22 mPa.s for sulfuric acid concentration of mass fraction of 96 % at 20 C. 16,7 mPa.s for sulfuric acid concentration of mass

33、 fraction of 78 % at 20 C. 3.3.9 Critical temperature Not applicable. 3.3.10 Critical pressure Not applicable. 3.3.11 Physical hardness Not applicable. 3.4 Chemical properties Concentrated sulfuric acid reacts violently: with bases or with water (exothermic reaction); with reducing agents due to oxi

34、dising properties; with combustible materials due to oxidising and dehydrating properties. The concentrated acid is a strong oxidising agent and can cause ignition in contact with organic materials. Sulfuric acid (of sulfuric acid content less than a mass fraction of 70 %) attacks most common metals

35、, e.g. iron, zinc, liberating the flammable gas hydrogen. WARNING Mixing with water produces a marked temperature rise. Therefore ALWAYS ADD THE ACID TO THE WATER (NEVER THE REVERSE), slowly and agitating continuously. 4 Purity criteria 4.1 General This European Standard specifies the minimum purity

36、 requirements for sulfuric acid used for the treatment of water for swimming pools. Limits are given for impurities commonly present in the product. Depending on the raw material and the manufacturing process, other impurities may be present and, if so, this shall be notified to the user and, when n

37、ecessary, to the relevant authorities. Users of this product should check the national regulations in order to clarify whether it is of appropriate purity for treatment of water for swimming pools, taking into account raw water quality, contents of other impurities and additives used in the products

38、 not stated in the product standard. Limits have been given for impurities and chemicals parameters where these are likely to be present in significant quantities from the current production process and raw materials. If the production process or raw materials lead to significant quantities of impur

39、ities, by-products or additives being present, this shall be notified to the user. DIN EN 15078:2013-08 EN 15078:2013 (E) 8 4.2 Composition of commercial product The usual commercial concentrations of sulfuric acid available have a mass fraction of 96 % or 98 %. Other concentrations of sulfuric acid

40、 between a mass fraction of 25 % and 80 % are also available. If sold as concentrated acid, the mass fraction of sulfuric acid shall be in the range of 92 % to 98 %. The concentration of sulfuric acid shall be within a mass fraction of 1 % of the manufacturers declared value. 4.3 Chemical parameters

41、 and indicator parameters The product shall conform to the requirements specified in Table 1. Table 1 Chemical parameters and indicator parameters Parameter Limit of H2SO4mg/kg Sulfur dioxide (SO2) max. 100 Iron (Fe) max. 100 Arsenic (As) max. 0,4 Cadmium (Cd) max. 0,1 Chromium (Cr) max. 4 Mercury (

42、Hg) max. 0,1 Nickel (Ni) max. 4 Lead (Pb) max. 4 Antimony (Sb) max. 1 Selenium (Se) max. 1 NOTE For chemical parameter values of trace metals in drinking water, see 1. 5 Test methods The sampling and the analytical methods are those described in EN 899. 6 Labelling Transportation Storage 6.1 Means o

43、f delivery Sulfuric acid shall be delivered in containers made of, or lined with, one of the materials given in EN 899, depending on the temperature and concentration of the acid. In order that the purity of the product is not affected, the means of delivery shall not have been used previously for a

44、ny different product or it shall have been specially cleaned and prepared before use. DIN EN 15078:2013-08 EN 15078:2013 (E) 9 6.2 Labelling according to EU legislation 4)The following labelling requirements shall apply to sulfuric acid at the date of publication of this European Standard. Figure 1

45、GHS 05 Signal word: Danger Classification and hazard statement: H 314 Causes severe skin burns and eye damage The regulation 2, and its amendments for the purposes of its adaptation to technical and scientific progress, contains a list of substances classified by the EU. Substances not listed in thi

46、s regulation should be classified on the basis of their intrinsic properties according to the criteria in the regulation by the person responsible for the marketing of the substance. 6.3 Transportation regulations and labelling Sulfuric acid of concentration greater than a mass fraction of 51 % is l

47、isted as UN number 5)1830. RID 6) /ADR 7): class 8, classification code C1, packing group II. IMDG 8): class 8, packing group II. IATA 9): class 8, packing group II. 4) See 2. 5) United Nations Number. 6) Regulations concerning International carriage of Dangerous goods by rail. 7) European Agreement

48、 concerning the international carriage of Dangerous goods by Road. 8) International Maritime transport of Dangerous Goods. 9) International Air Transport Association. DIN EN 15078:2013-08 EN 15078:2013 (E) 10 6.4 Marking The marking shall include the following information: name “sulfuric acid“, trade name and mass fraction; net mass; name and address of supplier and/or manufacturer; statement “this product conforms to EN 15078“. 6.5 Storage 6.5.1 Long term stability The product is sta