1、February 2008DEUTSCHE NORM English price group 11No part of this standard may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 13.030.50; 83.080.20!
2、$L=M“1412642www.din.deDDIN EN 15344Plastics Recycled Plastics Characterisation of Polyethylene (PE) recyclatesEnglish version of DIN EN 15344:2008-02Kunststoffe Kunststoff-Rezyklate Charakterisierung von Polyethylen (PE)-RezyklatenEnglische Fassung DIN EN 15344:2008-02www.beuth.deDocument comprises
3、17 pagesDIN EN 15344:2008-02 2 National foreword This standard has been prepared by Technical Committee CEN/TC 249 “Plastics” (Secretariat: NBN, Belgium). The responsible German body involved in its preparation was the Normenausschuss Kunststoffe (Plastics Standards Committee), Technical Committee N
4、A 054-01-06 AA Kunststoffverwertung. EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN 15344December 2007ICS 13.030.50; 83.080.20English VersionPlastics - Recycled Plastics - Characterisation of Polyethylene(PE) recyclatesPlastiques - Plastiques recycls - Caractrisation desrecyclats de polythylne (P
5、E)Kunststoffe - Kunststoff-Rezyklate - Charakterisierung vonPolyethylen (PE)-RezyklatenThis European Standard was approved by CEN on 25 October 2007.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of
6、 a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A versio
7、n in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark
8、, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUR
9、OPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2007 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 15344:2007: EEN 15344:2007 (E) 2 Contents Foreword3 Introduction .4 1 Scope 5 2 Normative referenc
10、es 5 3 Terms, definitions and abbreviated terms 6 4 Characterisation of PE recyclates6 5 Quality assurance7 Annex A (normative) Method for the determination of contaminants .9 A.1 General9 A.2 Principle9 A.3 Apparatus .9 A.3.1 Method A.9 A.3.2 Method B.9 A.3.3 Method C.9 A.3.4 Device for visual exam
11、ination 9 A.4 Procedure .10 A.4.1 Method A.10 A.4.2 Method B.10 A.4.3 Method C.10 A.5 Expression of results 10 A.6 Test report 11 Annex B (normative) Test Method for the determination of bulk density.12 B.1 Scope 12 B.2 Material .13 B.3 Apparatus .13 B.4 Preparation of test sample13 B.5 Procedure .1
12、3 B.6 Expression of results 13 B.7 Test report 14 Bibliography 15 DIN EN 15344:2008-02 Page EN 15344:2007 (E) 3 Foreword This document (EN 15344:2007) has been prepared by Technical Committee CEN/TC 249 “Plastics”, the secretariat of which is held by NBN. This European Standard shall be given the st
13、atus of a national standard, either by publication of an identical text or by endorsement, at the latest by June 2008, and conflicting national standards shall be withdrawn at the latest by June 2008. Attention is drawn to the possibility that some of the elements of this document may be the subject
14、 of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This standard is one part of a series of CEN publications on Plastics Recycling which is structured as follows: EN 15342 PlasticsRecycled PlasticsCharacterization of polystyrene (PS) re
15、cyclates EN 15343 PlasticsRecycled PlasticsPlastics recycling traceability and assessment of conformity and recycled content EN 15344 PlasticsRecycled PlasticsCharacterisation of Polyethylene (PE) recyclates EN 15345 PlasticsRecycled PlasticsCharacterisation of Polypropylene (PP) recyclates EN 15346
16、 PlasticsRecycled plasticsCharacterisation of poly(vinyl chloride) (PVC) recyclates EN 15347 Plastics Recycled Plastics Characterisation of plastics wastes EN 15348 PlasticsRecycled plasticsCharacterization of poly(ethylene terephthalate) (PET) recyclates CEN/TR 15353 Plastics Recycled plastics Guid
17、elines for the development of standards for recycled plastics According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finlan
18、d, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. DIN EN 15344:2008-02 EN 15344:2007 (E) 4 Introduction Recycling plastics waste is
19、 one type of material recovery process intended to save resources (virgin raw materials, water, and energy), while minimising harmful emissions into air, water and soil as well as any impacts on human health. The environmental impact of recycling has to be assessed over the whole life cycle of the r
20、ecycling system (from the waste generation point to the disposal of final residues). To ensure that recycling constitutes the best environmental option for treating the available waste, some prerequisites should preferably be met: recycling scheme being contemplated should generate lower environment
21、al impacts than alternative recovery options; existing or potential market outlets should be identified that will secure a sustainable industrial recycling operation; collection and sorting schemes should be properly designed to deliver recyclable plastics waste fractions fitting reasonably well wit
22、h the available recycling technologies and with the (changing) needs of the identified market outlets, preferably at minimum costs to society. This standard has been produced in accordance with the guidance produced by CEN on Environmental Aspects and in accordance with CEN/TR 15353, Plastics Recycl
23、ed plastics Guidelines for the development of standards for recycled plastics. NOTE CEN/TR 15353 considers the general environmental aspects which are specific to the recycling process. It is often impossible to trace back each individual product at the end user stage and to check whether the produc
24、t has been used correctly through its life. Consequently products are out of industrial control for a period of time. It is possible that during this period contamination with other materials may occur that could affect the products suitability for recycling into the intended application. DIN EN 153
25、44:2008-02 EN 15344:2007 (E) 5 1 Scope This European Standard defines a method of specifying delivery conditions for polyethylene (PE) recyclates. It gives the most important characteristics and associated test methods for assessing PE recyclates intended for use in the production of semi-finished/f
26、inished products. It is intended to support parties involved in the use of recycled PE to agree on specifications for specific and generic applications. This standard is applicable without prejudice to any existing legislation. This standard does not cover the characterisation of plastics wastes. Se
27、e EN 15347. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 12099, Plas
28、tics piping systems Polyethylene piping materials and components Determination of volatile content EN 15348:2007, PlasticsRecycled plasticsCharacterization of poly(ethylene terephthalate) (PET) recyclates EN ISO 179-1, Plastics Determination of Charpy impact properties Part 1: Non-instrumented impac
29、t test (ISO 179-1:2000) EN ISO 180, Plastics Determination of Izod impact strength (ISO 180:2000) EN ISO 472:2001, Plastics Vocabulary (ISO 472:1999) EN ISO 527-1, Plastics Determination of tensile properties Part 1: General principles (ISO 527-1:1993 including Corr 1:1994) EN ISO 527-2, Plastics De
30、termination of the tensile properties Part 2: Test conditions for moulding and extrusion plastics (ISO 527-2:1993 including Corr 1:1994) EN ISO 1043-1:2001, Plastics Symbols and abbreviated terms Part 1: Basic polymers and their special characteristics (ISO 1043-1:2001) EN ISO 1133, Plastics Determi
31、nation of the melt mass flow-rate (MFR) and the melt-volume flow rate (MVR) of thermoplastics (ISO 1133:2005) EN ISO 1183-1, Plastics - Methods for determining the density of non-cellular plastics - Part 1: Immersion method, liquid pyknometer method and titration method (ISO 1183-1:2004) EN ISO 3451
32、-1, Plastics Determination of ash Part 1: General methods (ISO 3451-1:1997) ISO 3534-2, Statistics Vocabulary and symbols - Part 2: Applied statistics ISO 22498, Plastics Vinyl chloride homopolymer and copolymer resins Particle size determination by mechanical sieving CEN/TR 15353:2007, Plastics Rec
33、ycled plastics Guidelines for the development of standards for recycled plastics DIN EN 15344:2008-02 EN 15344:2007 (E) 6 3 Terms, definitions and abbreviated terms For the purposes of this European Standard, the terms and definitions given in EN ISO 472:2001 and CEN/TR 15353:2007 apply. The abbrevi
34、ated terms related to recyclates are given in EN ISO 1043-1:2001. 4 Characterisation of PE recyclates A single batch is the quantity of PE recyclate that has homogeneous characteristics within the specified tolerances. The characteristics of PE recyclates, which shall be determined for every batch (
35、see ISO 3534-2) of recyclate, are given in Table 1, and are divided into two types: Required characteristics, needed to define PE recyclates in general, and required for all recyclates. Optional characteristics, needed to define PE recyclates according to customer specifications and applications. NO
36、TE 1 Polyethylene plastics waste originate from different types or grades of PE containing additives to modify characteristics. Polyethylene is generally classified as PE-HD (high density polyethylene), PE-LD (low density polyethylene), PE-LLD (linear low density polyethylene) and others of less com
37、mon use. The properties and performance of recyclates derived from such wastes may depend on the type or relative proportions of blends of PE, but it is not in the scope of this Standard to investigate such relations. These characteristics shall be assessed by using the test methods given in Table 1
38、. Where possible the supplier should provide information on the original applications. A certificate of analysis, giving the test results for each batch of recyclate shall be provided by the supplier to the purchaser upon request. To secure the legal use of the recyclate, the supplier shall provide
39、the necessary information about the material composition of the recyclate, as specified by the purchaser. NOTE 2 In this European Standard, PE (R) is composed of: - Polymeric matrix, consisting of polyethylene (PE content); - Fillers, pigments and additives; - Impurities or contamination in a quanti
40、ty which do not compromise the workability characteristics of PE (R); - Polymers compatible with the polymeric matrix. DIN EN 15344:2008-02 EN 15344:2007 (E) 7 Table 1 Characterisation of PE recyclates Characteristics Unit Tests method Comments Required Bulk density kg/m3ANNEX B Test may be used for
41、 powder or granulates ASTM D 1895-96 may be used for powder Colour Visual inspection Particle size mm ISO 22498aFor powder used for rotomoulding (particle size distribution also required). For flakes or regrind the Annex A of EN 15348:2007 and Annex E of EN 15346:2007 draft standards may be used. AS
42、TM D 1921-01 may also be used Melt mass flow rate (MFR) g/10 min EN ISO 1133 190 C-2,16 kg for density 0,945 kg/dm3190 C-5 kg for density 0,945 kg/dm3Shape Visual inspection Typical shape are pellets, flakes, regrind, powder and agglomeratedOptional Ash content % EN ISO 3451-1 With this method, any
43、organic pigments are destroyed Density kg/m3EN ISO 1183-1 Pycnometer, parties to agree on method A or B Contaminants Number ANNEX A Method A, B or C Parties to agree on which method Filtration level m Mesh size Only finest filter. Alternatively dimension of net passage. Izod impact strength or Charp
44、y impact strength kJ/m2EN ISO 180 EN ISO 179-1 Temperature conditions agreed between the interested parties Residual humidity % EN 12099b Weight loss, 105 C Tensile stress at yield MPa EN ISO 527-1 EN ISO 527-2 Test speed and at the temperature conditions agreed between the interested parties Test s
45、pecimen 1 A Tensile strain at break % EN ISO 527-1 EN ISO 527-2 Test speed and at the temperature conditions agreed between the interested parties Test specimen 1 A X: required characteristics to be quantified. O: optional characteristics to be quantified. a Although ISO 22498 is specific to PVC, it
46、 is considered relevant to PP. bAlthough the scope of EN 12099 is limited, it is considered relevant. 5 Quality assurance In order that the purchaser of the recyclate may have confidence in the quality of the product, the supplier shall maintain records of the quality control carried out, including
47、incoming materials, processes and finished products. DIN EN 15344:2008-02 EN 15344:2007 (E) 8 NOTE A quality management system certified to EN ISO 9001 may be a suitable guarantee of consistent recyclate quality. The specification and the standard deviation or range of values within and between batc
48、hes of material shall be agreed between the supplier and the purchaser. Where a statement of recycled content, or the previous history of the material is requested, documentary evidence shall be provided, where there is no analytical method available to supply such information. These records should
49、be available to the purchaser on request. Where a recyclate has been produced via a melt process, the supplier may choose to state the level of filtration applied during that process. This will determine the maximum size of any non-melting contaminants present in the recyclate. The statement of filtration level shall include details of the filter. Recyclates which have not passed through a melt process cannot be quantified in the same way, and the
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