DIN EN 15345-2008 Plastics - Recycled Plastics - Characterisation of Polypropylene (PP) recyclates English version of DIN EN 15345 2008-02《塑料 回收的塑料 聚丙烯(PP)回收材料的特征》.pdf

1、February 2008DEUTSCHE NORM English price group 9No part of this standard may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 13.030.50; 83.080.20!$

2、L=R“1412647www.din.deDDIN EN 15345Plastics Recycled Plastics Characterisation of Polypropylene (PP) recyclatesEnglish version of DIN EN 15345:2008-02Kunststoffe Kunststoff-Rezyklate Charakterisierung von Polypropylen (PP)-RezyklatenEnglische Fassung DIN EN 15345:2008-02www.beuth.deDocument comprises

3、 14 pagesDIN EN 15345:2008-02 2 National foreword This standard has been prepared by Technical Committee CEN/TC 249 “Plastics” (Secretariat: NBN, Belgium). The responsible German body involved in its preparation was the Normenausschuss Kunststoffe (Plastics Standards Committee), Technical Committee

4、NA 054-01-06 AA Kunststoffverwertung. EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN 15345December 2007ICS 13.030.50; 83.080.20English VersionPlastics - Recycled Plastics - Characterisation of Polypropylene(PP) recyclatesPlastiques - Plastiques recycls - Caractrisation desrecyclats de polypropyln

5、e (PP)Kunststoffe - Kunststoff-Rezyklate - Charakterisierung vonPolypropylen (PP)-RezyklatenThis European Standard was approved by CEN on 25 October 2007.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the stat

6、us of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A v

7、ersion in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, De

8、nmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATI

9、ONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2007 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 15345:2007: EEN 15345:2007 (E) 2 Contents Page Foreword3 Introduction .4 1 Scope 5 2 Normativ

10、e references 5 3 Terms, definitions and abbreviated terms 6 4 Characteristics of PP recyclates6 5 Quality Assurance .7 Annex A .9 Bibliography 12 DIN EN 15345:2008-02 EN 15345:2007 (E) 3 Foreword This document (EN 15345:2007) has been prepared by Technical Committee CEN/TC 249 “Plastics recyclate ch

11、aracterisation of PP”, the secretariat of which is held by NBN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by June 2008, and conflicting national standards shall be withdrawn at the latest by Ju

12、ne 2008. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This standard is one part of series of CEN publications on Plastics Recycling

13、 which is structured as follows: EN 15342 PlasticsRecycled PlasticsCharacterization of polystyrene (PS) recyclates EN 15343 PlasticsRecycled PlasticsPlastics recycling traceability and assessment of conformity and recycled content EN 15344 PlasticsRecycled PlasticsCharacterisation of Polyethylene (P

14、E) recyclates EN 15345 PlasticsRecycled PlasticsCharacterisation of Polypropylene (PP) recyclates EN 15346 PlasticsRecycled plasticsCharacterisation of poly(vinyl chloride) (PVC) recyclates EN 15347 Plastics Recycled Plastics Characterisation of plastics wastes EN 15348 PlasticsRecycled plasticsChar

15、acterization of poly(ethylene terephthalate) (PET) recyclates CEN/TR 15353 Plastics Recycled plastics Guidelines for the development of standards for recycled plastics According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to impl

16、ement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland

17、 and the United Kingdom. DIN EN 15345:2008-02 EN 15345:2007 (E) 4 Introduction Recycling of plastics waste is one type of material recovery process intended to save resources (virgin raw materials, water, and energy), while minimising harmful emissions into air, water and soil as well as any impacts

18、 on human health. The environmental impact of recycling has to be assessed over the whole life cycle of the recycling system (from the waste generation point to the disposal of final residues). To ensure that recycling constitutes the best environmental option for treating the available waste, some

19、prerequisites should preferably be met: recycling scheme being contemplated should generate lower environmental impacts than alternative recovery options; existing or potential market outlets should be identified that will secure a sustainable industrial recycling operation; collection and sorting s

20、chemes should be properly designed to deliver recyclable plastics waste fractions fitting reasonably well with the available recycling technologies and with the (changing) needs of the identified market outlets, preferably at minimum costs to society. This standard has been produced in accordance wi

21、th the guidance produced by CEN on Environmental Aspects and in accordance with CEN/TR 15353, Plastics Recycled plastics Guidelines for the development of standards for recycled plastics. NOTE CEN/TR 15353 considers the general environmental aspects which are specific to the recycling process. It is

22、 often impossible to trace back each individual product at the end user stage and to check whether the product has been used correctly through its life. Consequently products are out of industrial control for a period of time. It is possible that during this period contamination with other materials

23、 may occur that could affect the products suitability for recycling into the intended application. DIN EN 15345:2008-02 EN 15345:2007 (E) 5 1 Scope This European Standard defines a method of specifying delivery conditions for Polypropylene (PP) recyclates. It gives the most important characteristics

24、 and associated test methods for assessing a single batch of PP recyclates intended for use in the production of semi-finished/finished products. It is intended to support parties involved in the use of recycled PP to agree on specifications for specific and general applications. This standard does

25、not cover the characterisation of plastics wastes. See EN 15347. This standard is applicable without prejudice to any existing legislation. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited a

26、pplies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 12099, Plastics piping systems Polyethylene piping materials and components Determination of volatile content EN 15343, Plastics Recycled Plastics Plastics recycling traceability and

27、assessment of conformity and recycled content EN ISO 1133, Plastics Determination of the melt mass-flow rate (MFR) and the melt volume-flow rate (MVR) of thermoplastics (ISO 1133:2005) EN ISO 178, Plastics Determination of flexural properties (ISO 178:2001) EN ISO 179-1, Plastics Determination of Ch

28、arpy impact properties Part 1: Non-instrumented impact test (ISO 179-1:2000) EN ISO 179-2, Plastics Determination of Charpy impact properties Part 2: Instrumented impact test (ISO 179-2:1997) EN ISO 180, Plastics Determination of Izod impact strength (ISO 180:2000) EN ISO 472:2001, Plastics Vocabula

29、ry (ISO 472:1999) EN ISO 527-1, Plastics Determination of tensile properties Part 1: General principles (ISO 527-1:1993 including Corr 1:1994) EN ISO 527-2, Plastics Determination of tensile properties Part 2: Test conditions for moulding and extrusion plastics (ISO 527-2:1993 including Corr 1:1994)

30、 EN ISO 1183-1, Plastics Methods for determining the density of non-cellular plastics Part 1: Immersion method, liquid pyknometer method and titration method (ISO 1183-1:2004) EN ISO 3451-1, Plastics Determination of ash Part 1: General methods (ISO 3451-1:1997) CEN/TR 15353:2007 Plastics Recycled P

31、lastics Guidelines for the development of standards relating to recycled plastics DIN EN 15345:2008-02 EN 15345:2007 (E) 6 3 Terms, definitions and abbreviated terms For the purposes of this European Standard, the terms and definitions given in EN ISO 472:2001 and CEN/TR 15353:2007 apply. 4 Characte

32、ristics of PP recyclates A single batch is the quantity of recyclate that has homogenous characteristics within the specified tolerances. The characteristics of PP recyclates, given in Table 1, are divided into two types: Required characteristics needed to characterize PP recyclates in general and r

33、equired for specified recyclates. Optional characteristics needed to characterize PP recyclates according to customer specifications and applications. NOTE Polypropylene, or polypropylene-containing plastics wastes may contain a variety of propylene polymers such as homo- and co-polymers, isotatic,

34、syndiotatic and atatic, and be with or without fillers, fire retardants etc. The performance of recyclates derived from such wastes will depend on the relative proportions of these components. In order to be described as recycled polypropylene, the recyclate must contain polypropylene as the most im

35、portant polymeric component. These characteristics shall be assessed by using the test methods given in Table 1. Where possible, the supplier should provide information on the original application of the material. A Certificate of Analysis, providing the test results for each batch of recyclate shal

36、l be provided by the supplier to the purchaser on request. To secure the legal use of the recyclate, the supplier shall provide the necessary information about the material composition of the recyclates, as specified by the purchaser. DIN EN 15345:2008-02 EN 15345:2007 (E) 7 Table 1 Characterisation

37、 of PP recyclates Characteristic Unit Test Method Comment Required Colour Visual inspection Density Kg/m3EN ISO 1183-1 Method A Impact Strength KJ/m2EN ISO 179-1, EN ISO 179-2 or EN ISO 180 Melt Flow Rate g/10min EN ISO 1133 Condition M Shape Visual inspectionaOptional Ash Content % EN ISO 3451-1 Bu

38、lk Density Kg/m3See Annex A Extraneous Polymers % Thermal/Infra-red Analyses Flexural Properties MPa EN ISO 178 Filtration Level Mesh Size Provide information on mesh size. Recycled Content % EN 15343 Tensile stress at yield MPa EN ISO 527-1 EN ISO 527-2 Tensile strain at break % EN ISO 527-1 EN ISO

39、 527-2 Volatile Content % EN 12099bor other aFor example, ground, micronised, pellets, flakes. bAlthough the scope of EN 12099 is limited, it is considered relevant. Other tests may be carried out by agreement between the purchaser and the supplier and the results reported. 5 Quality Assurance In or

40、der that the purchaser of the recyclate may have confidence in the quality of the product, the supplier shall maintain records of the quality control carried out, including incoming materials, processes and finished products. A quality management system certified to EN ISO 9001 may be a suitable gua

41、rantee of consistent recyclate quality. The specification and the standard deviation or range of values within and between batches of material shall be agreed between the supplier and the purchaser. Where a statement of recycled content, or the previous history of the material, is requested, documen

42、tary evidence shall be provided, where there is no analytical method available to supply such information. These records should be available to the purchaser on request. DIN EN 15345:2008-02 EN 15345:2007 (E) 8 Where a recyclate has been produced via a melt process, the supplier may choose to state

43、the level of filtration applied during that process. This will determine the maximum size of any non-melting contaminants present in the recyclate. The statement of filtration level shall include details of the filter. Recyclates which have not passed through a melt process cannot be quantified in t

44、he same way, and the supplier may state this. NOTE EN 15343 describes a qualified recycling process and gives details of traceability and the assessment of recycled content. DIN EN 15345:2008-02 EN 15345:2007 (E) 9 Annex A (Normative) Test Method for the determination of bulk density A.1 Scope This

45、test method specifies a method for determining the bulk density, i.e. the mass per unit of volume of loose material (powder or granular material), that can be poured from a funnel of specific design. When the method is applied to relatively coarse materials, rather variable results may be obtained,

46、owing to the error introduced when a straightedge blade is drawn across the top of the cylinder. A knowledge of bulk density is of limited value in estimating the relative fluffiness or bulk of moulding materials, unless their densities in the moulded condition are approximately the same. It therefo

47、re gives a fairly good idea of stability of mixing, presence of humidity and stability between batches (consistency). Key 1 Volume of approximately 2 500 ml, Diameter of hole at base 55 mm 0,25 mm 2 Inner height: 200 mm 0,2mm, Inner diameter: 113 mm 0,2mm, Volume: 2 000 ml 3 Angle approximately 65 4

48、 Diameter of hole approximately 60 mm 5 Distance of 100 mm 0,5 mm Figure A.1 Typical apparatus DIN EN 15345:2008-02 EN 15345:2007 (E) 10 A.2 Material Powder or granular material. A.3 Apparatus A.3.1 Balance, accurate to 0,1 g. A.3.2 Measuring cylinder, smoothly finished inside, which shall be constr

49、ucted of metal, of a capacity of 2 000 ml (Inner height of 200 mm and an inner diameter of 113 mm). A.3.3 Conical funnel, of the form and dimensions shown in Figure A1, of a capacity of 2 500 ml, internal diameter at base 55 mm, equipped with a metal trap plate for the lower orifice. Diameter of orifice in trap plate 60 mm. A.4 Preparation of test sample Mix the sample before testing. A.5 Procedure A.5.1 Support the funnel (A.3.3) vertically with its lower orifice 10