DIN EN 1911-2010 Stationary source emissions - Determination of mass concentration of gaseous chlorides expressed as HCl - Standard reference method German version EN 1911 2010《固定源.pdf

1、December 2010 Translation by DIN-Sprachendienst.English price group 18No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).I

2、CS 13.040.40!$li“1735970www.din.deDDIN EN 1911Stationary source emissions Determination of mass concentration of gaseous chlorides expressedas HCl Standard reference methodEnglish translation of DIN EN 1911:2010-12Emissionen aus stationren Quellen Bestimmung der Massenkonzentration von gasfrmigen Ch

3、loriden, angegeben als HCl StandardreferenzverfahrenEnglische bersetzung von DIN EN 1911:2010-12Emissions de sources fixes Dtermination de la concentration massique en chlorures gazeux, exprime en HCl Mthode de rfrence normaliseTraduction anglaise de DIN EN 1911:2010-12SupersedesDIN EN 1911-1:1998-0

4、7,DIN EN 1911-2:1998-07 andDIN EN 1911-3:1998-07www.beuth.deDocument comprises pagesIn case of doubt, the German-language original shall be considered authoritative.This standard has been included in the VDI/DIN Handbook on air quality, Volume 5.4811.10 DIN EN 1911:2010-12 A comma is used as the dec

5、imal marker. National foreword This standard has been prepared by Technical Committee CEN/TC 264 “Air quality” (Secretariat: DIN, Germany), Working Group WG 3 “Determination of HCI emissions” (Secretariat: AFNOR, France). The responsible German body involved in its preparation was the Kommission Rei

6、nhaltung der Luft (KRdL) im VDI und DIN Normenausschuss (Commission on Air Pollution Prevention of VDI and DIN Standards Committee). Amendments This standard differs from DIN EN 1911-1:1998-07, DIN EN 1911-2:1998-07 and DIN EN 1911-3:1998-07 as follows: a) DIN EN 1911 is now a single document replac

7、ing the previous three-part edition covering the sampling and analysis of stationary source emissions for the determination of the mass concentration of gaseous chloride expressed as HCl; b) the requirements laid down in DIN EN 15259 are now to be taken into consideration (Clause 5); c) isokinetic s

8、ampling without any side stream is now described in addition to non isokinetic sampling and isokinetic sampling with a side stream; d) the temperature of the filter housing was the subject of much discussion and varying opinions. As a result, no particular value has been specified. Instead, the filt

9、er housing temperature is to be at least 20C above the dew point (Clause 5); e) performance characteristics and a maximum allowable overall uncertainty have been specified (Clause 8); f) an example of the evaluation of overall uncertainty of measurement is given (Annex C). Previous editions DIN EN 1

10、911-1: 1998-07 DIN EN 1911-2: 1998-07 DIN EN 1911-3: 1998-07 2 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 1911 August 2010 ICS 13.040.40 Supersedes EN 1911-1:1998, EN 1911-2:1998, EN 1911-3:1998English Version Stationary source emissions - Determination of mass concentration of gaseous chl

11、orides expressed as HCl - Standard reference method Emissions de sources fixes - Dtermination de la concentration massique en chlorures gazeux, exprime en HCl - Mthode de rfrence normalise Emissionen aus stationren Quellen - Bestimmung der Massenkonzentration von gasfrmigen Chloriden, angegeben als

12、HCl - Standardreferenzverfahren This European Standard was approved by CEN on 26 June 2010. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date

13、lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the

14、responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greec

15、e, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Managemen

16、t Centre: Avenue Marnix 17, B-1000 Brussels 2010 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 1911:2010: EEN 1911:2010 (E) 2 Contents Page Foreword 4Introduction .51 Scope 62 Normative references 63 Terms, definitions and abbrev

17、iations 63.1 Terms and definitions .63.2 Abbreviations .94 Principle . 115 Sampling 115.1 Sampling strategy . 115.1.1 General . 115.1.2 Non isokinetic sampling 125.1.3 Isokinetic sampling. 135.1.4 Losses of gaseous chlorides and side reactions during sampling 145.2 Sampling equipment 145.3 Sampling

18、procedure . 185.3.1 Preparation and installation of equipment . 185.3.2 Sampling procedure . 195.3.3 Validation of results . 206 Analysis . 216.1 Introduction . 216.2 Reagents and samples to be analysed . 226.2.1 Reagents for analysis . 226.2.2 Samples to be analysed . 226.3 Silver titration: potent

19、iometric method 226.3.1 Apparatus 226.3.2 Reagents and solutions . 236.3.3 Procedure 236.3.4 Interferences . 236.3.5 Calculations . 246.4 Mercuric-thiocyanate spectrophotometry 246.4.1 Warning 246.4.2 Apparatus 246.4.3 Reagents 246.4.4 Procedure 256.4.5 Interferences . 256.4.6 Calculations . 266.5 I

20、on-exchange chromatography . 267 Expression of results . 278 Determination of the characteristics of the method: sampling and analysis. 288.1 General . 288.2 Relevant performance characteristics of the method and performance criteria . 288.2.1 General . 288.2.2 Sampling procedure . 288.2.3 Analyse p

21、rocedure 298.3 Establishment of the uncertainty budget . 309 Measurement report . 31DIN EN 1911:2010-12 EN 1911:2010 (E) 3 Annex A (informative) Examples of absorbers 32Annex B (informative) Comparison between mercuric-thiocyanate spectrophotometry and ion exchange chromatography method (methods B a

22、nd C) . 34Annex C (informative) Example of assessment of compliance of the reference method for chlorides . 35C.1 General . 35C.2 Process of uncertainty estimation . 35C.3 Specific conditions in the field 36C.4 Performance characteristics of the method . 37C.5 Calculation of standard uncertainty of

23、concentration measured. 38C.6 Calculation of the overall (or expanded) uncertainty 41C.7 Uncertainty associated to the mass concentration of gaseous chlorides at O2reference concentration . 41Annex D (informative) Performance characteristics of the whole measurement method 43D.1 Analytical detection

24、 limit of the method . 43D.2 Repeatability and reproducibility of the method in the field . 43Annex E (informative) Significant technical changes . 45Bibliography 46DIN EN 1911:2010-12 EN 1911:2010 (E) 4 Foreword This document (EN 1911:2010) has been prepared by Technical Committee CEN/TC 264 “Air q

25、uality”, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by February 2011, and conflicting national standards shall be withdrawn at the latest by February 201

26、1. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 1911-1:1998, EN 1911-2:1998 and EN 1911-3:1998. Annex E

27、 provides details of significant technical changes between this European Standard and the previous edition. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cr

28、oatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. DIN EN 1911:2010-12 EN 191

29、1:2010 (E) 5 Introduction This European Standard describes the Standard Reference Method (SRM) with three alternative analytical techniques for determining gaseous chlorides content emitting to atmosphere from ducts and stacks. The specific components and the requirements for the measuring system ar

30、e described. A number of performance characteristics with associated minimum performance criteria are specified for the measuring system (see Tables 1 and 2 in 8.2). This European Standard can be used as an SRM provided the overall uncertainty of the method is less than 30,0 % relative at the daily

31、Emission Limit Value (ELV) for incineration and large combustion plants or at the ELV prescribed by the specific regulations for other plants. An Alternative Method to this SRM may be used provided that the user can demonstrate equivalence according to CEN/TS 14793. DIN EN 1911:2010-12 EN 1911:2010

32、(E) 6 1 Scope The method described in this European Standard determines the concentration of chlorinated compounds in a flue gas that after passage of the sampling system including a particle filter give Cl-ions in the absorption solution. This Standard Reference Method has been evaluated during fie

33、ld tests on waste incineration. The method applies to waste gases in which chlorides concentration expressed as HCl may vary between 1 mgm-3and 5 000 mgm-3under normal pressure and temperature conditions (see Note 1), and according to emission limit values laid down, for example, in the Council Dire

34、ctive 2000/76/EC on waste incineration plants. NOTE 1 The limit values of this European Standard are expressed in mgHCl/m3, on dry basis, at the reference conditions of 273 K and 101,3 kPa and at the reference O2concentration. NOTE 2 The required uncertainty results from the capacity of the method t

35、ested in the field (Annex D) and in the laboratory (see performance characteristics in Tables 1 and 2 and Annex C). 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated refe

36、rences, the latest edition of the referenced document (including any amendments) applies. EN 13284-1:2001, Stationary source emissions Determination of low range mass concentration of dust Part 1: Manual gravimetric method ENV 13005, Guide to the expression of uncertainly in measurement EN 15259:200

37、7, Air quality Measurement of stationary source emissions Requirements for measurement sections and sites and for the measurement objective, plan and report EN ISO 3696:1995, Water for analytical laboratory use Specification and test methods (ISO 3696:1987) EN ISO 10304-1, Water quality Determinatio

38、n of dissolved anions by liquid chromatography of ions Part 1: Determination of bromide, chloride, fluoride, nitrate, nitrite, phosphate and sulfate (ISO 10304-1:2007) EN ISO 14956, Air quality Evaluation of the suitability of a measurement procedure by comparison with a required measurement uncerta

39、inty (ISO 14956:2002) 3 Terms, definitions and abbreviations 3.1 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1.1 absorber device in which gaseous chloride is absorbed into an absorption solution 3.1.2 chemical blank chloride ion content of an

40、 unexposed sample of the absorption solution, plus reagents that are added to the solution before analysis if necessary DIN EN 1911:2010-12 EN 1911:2010 (E) 7 3.1.3 analytical detection limit DLconcentration value of the measurand below which there is at least 95 % level of confidence that the measu

41、red value corresponds to a sample free of that measurand 3.1.4 field blank value determined by a specific procedure used to ensure that no significant contamination has occurred during all steps of the measurement and to check that the operator can achieve a quantification level adapted to the task

42、3.1.5 isokinetic sampling sampling at a rate such that the velocity and direction of the gas entering the sampling nozzle is the same as that of the gas in the duct at the sampling point EN 13284-1:2001 3.1.6 measurand particular quantity subject to measurement ISO/IEC Guide 99:2007, 2.6 3.1.7 measu

43、rement series several successive measurements carried out on the same sampling plane and at the same process operating conditions EN 13284-1:2001 3.1.8 performance characteristic one of the quantities (described by values, tolerances, range, etc.) assigned to equipment in order to define its perform

44、ance 3.1.9 analytical repeatability closeness of the agreement between the results of successive measurements of the same measurand carried out under the same conditions of measurement NOTE 1 Analytical repeatability conditions include: the same measurement procedure; the same laboratory; the same s

45、ampling equipment, used under the same conditions and at the same location; repetition over a short period of time. NOTE 2 Analytical repeatability may be expressed quantitatively in terms of the dispersion characteristics of the results. ISO/IEC Guide 99:2007, 3.6 NOTE 3 In this European Standard t

46、he analytical repeatability is expressed as a value with a level of confidence of 95 %. DIN EN 1911:2010-12 EN 1911:2010 (E) 8 3.1.10 repeatability in the field closeness of the agreement between the results of simultaneous measurements of the same measurand carried out with two sets of equipment un

47、der the same conditions of measurement NOTE 1 These conditions include: the same measurement procedure; two sets of equipment, the performances of which are fulfilling the requirements of the reference method, used under the same conditions; the same location; implemented by the same laboratory; typ

48、ically calculated over short periods of time in order to avoid the effect of changes of influence parameters (e.g. 30 min). NOTE 2 Repeatability may be expressed quantitatively in terms of the dispersion characteristics of the results. NOTE 3 In this European Standard the repeatability under field conditions is expressed as a value with a level of confidence of 95 %. 3.1.11 reproducibility in the field closeness of the agreement between the results of simultaneous measurements of the same measurand carried out with several sets of equipment under the same conditions of mea