1、November 2016 English price group 17No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 91.100.10!%ub“2588263www.din.de
2、DIN EN 196-10Methods of testing cement Part 10: Determination of the watersoluble chromium (VI) content of cement;English version EN 19610:2016,English translation of DIN EN 196-10:2016-11Prfverfahren fr Zement Teil 10: Bestimmung des Gehaltes an wasserlslichem Chrom (VI) in Zement;Englische Fassung
3、 EN 19610:2016,Englische bersetzung von DIN EN 196-10:2016-11Mthodes dessais des ciments Partie 10: Dtermination de la teneur en chrome (VI) soluble dans leau des ciments;Version anglaise EN 19610:2016,Traduction anglaise de DIN EN 196-10:2016-11SupersedesDIN EN 19610:200610www.beuth.deDocument comp
4、rises 39 pagesDTranslation by DIN-Sprachendienst.In case of doubt, the German-language original shall be considered authoritative.11.16 DIN EN 196-10:2016-11 2 A comma is used as the decimal marker. National foreword This document (EN 196-10:2016) has been prepared by Technical Committee CEN/TC 51 “
5、Cement and building limes (Secretariat: NBN, Belgium). The responsible German body involved in its preparation was DIN-Normenausschuss Bauwesen (DIN Standards Committee Building and Civil Engineering), Working Committee NA 005-07-13 AA Zement (SpA zu Teilbereichen von CEN/TC 51 und ISO/TC 74). Amend
6、ments This standard differs from DIN EN 196-10:2006-10 as follows: a) Clause 2 “Normative references has been updated; b) the standard has been editorially revised. Previous editions DIN EN 196-10: 2006-10 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 196-10 May 2016 ICS 91.100.10 Supersedes
7、EN 196-10:2006English Version Methods of testing cement - Part 10: Determination of the water-soluble chromium (VI) content of cement Mthodes dessais des ciments - Partie 10 : Dtermination de la teneur en chrome (VI) soluble dans leau des ciments Prfverfahren fr Zement - Teil 10: Bestimmung des Geha
8、ltes an wasserlslichem Chrom (VI) in Zement This European Standard was approved by CEN on 20 December 2015. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alterat
9、ion. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made b
10、y translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
11、 Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey andUnited Kingdom. EUROPEAN COMMITTEE FOR STANDARDI
12、ZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2016 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 196-10:2016 E2 Contents Page European forewo
13、rd . 3 Introduction 4 1 Scope 5 2 Normative references 5 3 General requirements for testing 6 3.1 Number of tests 6 3.2 Repeatability and reproducibility 6 3.3 Expression of masses, volumes, factors and results . 6 3.4 Blank determinations 6 4 Reagents . 6 5 Apparatus . 7 6 Preparation of a test sam
14、ple of cement. 8 7 Extraction procedure . 9 7.1 Principle . 9 7.2 Preparation of mortar . 9 7.3 Filtration . 10 8 Determination of chromium (VI) . 10 8.1 General . 10 8.2 Measurement of absorbance without oxidation . 10 8.3 Measurement of absorbance with oxidation 11 9 Calculation and expression of
15、results . 12 9.1 Calculation 12 9.2 Expression of results . 13 10 Reporting of results . 13 11 Repeatability and reproducibility . 13 Annex A (normative) Evaluation of the compliance of cement with the regulatory limit in 47 to Annex XVII of Regulation (EC) No. 1907/2006 on water-soluble hexavalent
16、chromium content . 14 Annex B (informative) Guidance on the application of this European Standard to the determination of the water soluble chromium (VI) content of cement-containing preparations 24 Annex C (informative) Guidance on screening test method (1) using paste extraction - method based on
17、DS 1020 . 26 Annex D (informative) Guidance on screening test method (2) using paste extraction method based on TRGS 613 29 Annex E (informative) Guidance on the photometric determination of chromium reduction capacity in cements . 33 Bibliography . 37 EN 196-10:2016 (E) DIN EN 196-10:2016-11 3 Euro
18、pean foreword This document (EN 196-10:2016) has been prepared by Technical Committee CEN/TC 51 “Cement and building limes”, the secretariat of which is held by NBN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement,
19、 at the latest by November 2016, and conflicting national standards shall be withdrawn at the latest by November 2016. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN shall not be held responsible for identifying any or all su
20、ch patent rights. This document supersedes EN 196-10:2006. In comparison to EN 196-10:2006, the following changes have been made: In Clause 2, the normative references have been updated; The standard has been editorially revised. EN 196 consists of the following parts, under the general title Method
21、s of testing cement: Part 1: Determination of strength; Part 2: Chemical analysis of cement; Part 3: Determination of setting times and soundness; Part 4: Quantitative determination of constituents (CEN/TR 196-4); Part 5: Pozzolanicity test for pozzolanic cement; Part 6: Determination of fineness; P
22、art 7: Methods of taking and preparing samples of cement; Part 8: Heat of hydration - Solution method; Part 9: Heat of hydration - Semi-adiabatic method; Part 10: Determination of the water-soluble chromium (VI) content of cement. According to the CEN-CENELEC Internal Regulations, the national stand
23、ards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Lu
24、xembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. EN 196-10:2016 (E) DIN EN 196-10:2016-11 4 Introduction This European Standard specifies the reference method for the determination of water-soluble chromiu
25、m (VI) content of cement that consists of two stages, an extraction procedure and an analysis of the filtered extract. This European Standard test method has adopted the principle that extraction is carried out under conditions approximating as closely as possible to those during the commercial use
26、of cement. Consequently extraction is by standard mortar and subsequent filtration. Other extraction procedures based on paste extraction have traditionally been used and are included in Annexes C and D for use as screening tests, in factory production control or laboratories not having access to eq
27、uipment specified in EN 196-1 for the production of mortar. The use of paste extraction is outside the normal conditions of use of cement. This European Standard test method has adopted the principle of analysis by spectrophotometry. The procedures set down generally permit the analysis to be carrie
28、d out without the need for an oxidation step. On rare occasions some cements may contain reducing species, not controlled by the routine method, that interfere with the analysis and require an oxidation step. Inter-laboratory testing has demonstrated that it is necessary to include an initial assess
29、ment test in order to observe the effects on the analysis. By comparing the results obtained from the method with and without the oxidation step, it can be determined whether, for that cement, the reference method should include the oxidation step. Other instrumental procedures may be used for the a
30、nalysis of the filtered extract provided they are calibrated against the analysis of the filtered extract using the reference procedure. In case of dispute or failure to comply with a regulatory limit only the reference method shall be used. This European Standard test method has drawn heavily on th
31、e Danish Standard DS 1020 and the extraction procedure developed by the French cement industry association ATILH. Careful consideration has been given to the details of the German TRGS 613 method developed by Germanys Hazardous Materials Committee in support of Industrial Regulations for Hazardous M
32、aterials. Notice was also taken of the British Cement Association inherent colour method; the draft method produced by CEN/TC 193/WG1, reference N680, for cement-based adhesives; European Standard method EN 420 for protective gloves; and to the method, reference ID-215, developed by the Occupational
33、 Safety and Health Administration, Salt Lake City, UT, USA. The USA Portland Cement Association, Research and Development report Serial No. 2554 “Review and evaluation of analytical methods for the determination of hexavalent chromium in hydraulic cements and clinker” by Waldemar A. Klemm was found
34、to be most helpful in resolving technical issues. CEN/TR 14589 confirmed that chromium species and solubilities are sensitive to pH and redox conditions and care has been taken to address these in this European Standard by controlling sample exposure to air, by adding the indicator to the alkaline f
35、iltered extract and by precisely specifying the pH for the analytical procedure. This European Standard test method was developed in order to provide a reference test method for use in the evaluation of compliance of cement with the requirements in entry 47 to Annex XVII of Regulation (EC) 1907/2006
36、1of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH). A system for the evaluation of compliance of cement is set out in Annex A. 1Note that Regulation (EC) No 1907/2006 is impacted by Commission
37、 Regulation (EU) No 126/2013 of 13 February 2013 amending Annex XVII to Regulation (EC) No 1907/2006 of the European Parliament and of the Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH). EN 196-10:2016 (E) DIN EN 196-10:2016-11 5 1 Scope This part of EN 1
38、96 specifies the method for the determination of the water-soluble chromium (VI) content of cement. A reference method is described consisting of two stages, an extraction procedure and an analysis of the filtered extract. Guidance on other extraction procedures, suitable for screening tests, for fa
39、ctory production control or other purposes, is given but in case of dispute or failure to comply with a regulatory limit only the reference method is used. The reference method has alternatives whereby the filtered extract may be subjected to an oxidation step or not. The criteria by which the appro
40、priate procedure is selected are set down. Other instrumental procedures may be used for the analysis of the filtered extract provided they are calibrated against the analysis of the filtered extract using the reference procedure. In the case of a dispute, only the reference method is used. Annex A
41、sets out a normative procedure to be followed in case this test method is used as the basis for evaluation of conformity of a cement with the regulatory limit in Regulation (EC) 1907/20062. This part of EN 196 describes a method that applies to cements. It may have wider applicability but this would
42、 need to be verified by testing on a product-by-product basis. Guidance in the possible application of this European Standard to the determination of the water-soluble chromium (VI) content of cement-containing preparations is given in Annex B. Annexes C and D provide information on other test proce
43、dures based on paste extraction and thus depart from the performance of cement in its normal conditions of use. They may be carried out with or without the oxidation process. Users should be aware that results using these methods might be significantly different to those obtained by the reference me
44、thod. In the case of dispute or failure to comply with the regulatory limit only the reference method is used. Annex E provides guidance on a method for determination of the excess reducing agent content of cement as used in the factory internal control system of some countries. Manufacturers using
45、such an internal control method should ensure themselves of the relevance of results in comparison with testing by the reference method. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dat
46、ed references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 196-1, Methods of testing cement - Part 1: Determination of strength EN 196-7, Methods of testing cement - Part 7: Methods of taking and prepari
47、ng samples of cement EN ISO/IEC 17020, Conformity assessment - Requirements for the operation of various types of bodies performing inspection (ISO/IEC 17020) EN ISO/IEC 17025, General requirements for the competence of testing and calibration laboratories (ISO/IEC 17025) EN ISO/IEC 17065, Conformit
48、y assessment - Requirements for bodies certifying products, processes and services (ISO/IEC 17065) 2Note that Regulation (EC) No 1907/2006 is impacted by Commission Regulation (EU) No 126/2013 of 13 February 2013 amending Annex XVII to Regulation (EC) No 1907/2006 of the European Parliament and of t
49、he Council on the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH). EN 196-10:2016 (E) DIN EN 196-10:2016-11 6 3 General requirements for testing 3.1 Number of tests Determination of water-soluble chromium (VI) content of cement, where the determination is not part of a series subject to statistical control, shall be carried out in duplicate. Where the determination is one of a series subject to statistical control, a si
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