DIN EN 1965-1-2011 en 4612 Structural adhesives - Corrosion - Part 1 Determination and classification of corrosion to a copper substrate German version EN 1965-1 2011《结构粘胶剂 腐蚀 第1部分.pdf

1、July 2011 Translation by DIN-Sprachendienst.English price group 6No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 77

2、.060; 83.180!$sK“1805840www.din.deDDIN EN 1965-1Structural adhesives Corrosion Part 1: Determination and classification of corrosion to a coppersubstrateEnglish translation of DIN EN 1965-1:2011-07Strukturklebstoffe Korrosion Teil 1: Bestimmung und Klassifikation der Korrosion eines KupfermaterialsE

3、nglische bersetzung von DIN EN 1965-1:2011-07Adhsifs structuraux Corrosion Partie 1: Dtermination et classification de la corrosion dun substrat en cuivreTraduction anglaise de DIN EN 1965-1:2011-07SupersedesDIN EN 1965-1:2001-12www.beuth.deDocument comprises pagesIn case of doubt, the German-langua

4、ge original shall be considered authoritative.806.11 DIN EN 1965-1:2011-07 National foreword is standard has been prepared by Technical Committee CEN/TC 193 “Adhesives” (Secretariat: AENOR, Spain). ThThe responsible German body involved in its preparation was the Normenausschuss Materialprfung (Mate

5、rials Testing Standards Committee), Working Committee NA 062-04-55 AA Prfung von Konstruktionsklebstoffen, -klebverbindungen und Kernverbunden. Amendments This standard differs from DIN EN 1965-1:2001-12 as follows: a) a safety statement and an environmental statement have been included; b) normativ

6、e references have been updated; c) it has been specified that the solvent should be able to dissolve the uncured adhesive; d) the standard has been editorially revised. Previous editions DIN V ENV 1965-1: 1995-09 DIN EN 1965-1: 2001-12 2 EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 1965-1 Ma

7、y 2011 ICS 77.060; 83.180 Supersedes EN 1965-1:2001English Version Structural adhesives Corrosion Part 1: Determination and classification of corrosion to a copper substrate Adhsifs structuraux Corrosion Partie 1: Dtermination et classification de la corrosion dun substrat en cuivre Strukturklebstof

8、fe Korrosion Teil 1: Bestimmung und Klassifikation der Korrosion eines Kupfermaterials This European Standard was approved by CEN on 10 March 2011. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of

9、a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German).

10、 A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cy

11、prus, Czech Republic, Denmark, Estonia,Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland,Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION CO

12、MIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2011 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 1965-1:2011: EEN 1965-1:2011 (E) 2 Contents Page Foreword 31 Scop

13、e 42 Normative references 43 Terms and definitions .44 Principle 45 Products and materials .46 Procedure .56.1 General 56.2 Preparation of the copper substrate 56.3 Determination .57 Discolouration/corrosion 68 Report .6DIN EN 1965-1:2011-07 EN 1965-1:2011 (E) 3 Foreword This document (EN 1965-1:201

14、1) has been prepared by Technical Committee CEN/TC 193 “Adhesives”, the secretariat of which is held by AENOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by November 2011, and conflicting nation

15、al standards shall be withdrawn at the latest by November 2011. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersed

16、es EN 1965-1:2001. SAFETY STATEMENT Persons using this document should be familiar with the normal laboratory practice, if applicable. This document does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user to establish appropriate

17、safety and health practices and to ensure compliance with any regulatory conditions. ENVIRONMENTAL STATEMENT It is understood that some of the material permitted in this standard may have negative environmental impact. As technological advantages lead to acceptable alternatives for these materials,

18、they will be eliminated from this standard to the extent possible. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, E

19、stonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. DIN EN 1965-1:2011-07 EN 1965-1:2011 (E) 4 1 Scope This European St

20、andard describes a method to determine the ability of a liquid adhesive to corrode a copper substrate under heat ageing conditions. Temperatures and ageing periods are chosen to ensure the maximum differentiation between the corrosivity of different adhesives and are not intended to represent any pa

21、rticular service condition. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies

22、. EN 923:2005+A1:2008, Adhesives Terms and definitions ISO 6958, Wrought copper and copper alloys Drawn rectangular bars Dimensions and form tolerances 3 Terms and definitions For the purposes of this document, the terms and definitions given in EN 923:2005+A1:2008 and the following apply. 3.1 corro

23、sion destructive attack on metals which can be chemical or electrochemical in nature NOTE The described method measures essentially only the chemical attack. The electrochemical contribution is eliminated as far as possible by ensuring that there is no electrolyte and that the copper substrate is, a

24、s far as practicable, free from metallic impurities which can result in the formation of a galvanic cell. 4 Principle An abraded and polished copper substrate is coated with a thin film of the liquid adhesive and then aged for 24 h in dry heat at 50 C or 100 C. Following this the surface is examined

25、 and the extent of tarnishing and/or corrosion on the basis of discolouration. 5 Products and materials 5.1 Solvent. Any sulfur free, and water free, hydrocarbon based solvent, which has been shown to cause no discolouration of the abraded copper substrate at 50 C is suitable. The solvent should be

26、able to dissolve the uncured adhesive 5.2 Copper substrate, plate. Recommended cross section 12 mm 2 mm, ISO 6958 E-Cu F30, produced by electrolysis. DIN EN 1965-1:2011-07 EN 1965-1:2011 (E) 5 5.3 Abrasive cloth or emery paper. Grade P2401)silicon carbide. 5.4 Liquid abrasive. (Silicon carbide) grad

27、e 1501). 5.5 Stainless steel tweezers. 5.6 Cotton wool. 6 Procedure 6.1 General Use a minimum of three copper plates for each evaluation. 6.2 Preparation of the copper substrate Lay the abrasive cloth or emery paper on a flat surface and wet it with the solvent. Place the copper plate on top on this

28、 and cover with the filter paper, to ensure that the copper surface is protected from contamination by fingers. Rub the copper plate in a criss-cross pattern against the abrasive material until a uniform abraded surface is achieved. It is necessary to abrade all six plane surfaces of the test plate

29、beginning with the edges and finishing with the faces. Following this abrasion, store the copper plate in solvent. 6.3 Determination Remove the copper plate from the solvent, handling only with the tweezers, and place on a clean glass plate. Coat the copper plate with the liquid abrasive and abrade

30、with a piece of cotton wool which has been moistened with a drop of solvent. Finally, polish vigorously with clean, dry, cotton wool, repeating the polishing with fresh pieces of cotton wool until one remains clean and white following polishing. On completion of the final abrasion, immediately immer

31、se the copper plate in a shallow dish of the adhesive, again handling with tweezers, and place in a oven at 50 C or 100 C for 24 h. Remove the copper plate from the dish with the tweezers and carefully wash in solvent to remove uncured material, then dry it with the filter paper. It is essential tha

32、t the test is repeated if, during any of the above procedures or testing, the copper plate: a) is touched by fingers; b) comes into contact with water; or c) comes into contact with any other material; d) or if the appearance of the edge of the plate is significantly different from that of the face.

33、 1) Grade defined by Fdration Europenne des Fabricants de Produits Abrasifs (FEPA-43).DIN EN 1965-1:2011-07 EN 1965-1:2011 (E) 6 7 Discolouration/corrosion The discolouration/corrosion is graded as in Table 1, on examination of the copper surface using normal vision. Table 1 Classification of discol

34、ouration/corrosion Corrosion grade Significance Description 0 No tarnish or corrosion Unchanged 1 Light tarnish Weak/pale orange, hardly changed when compared with a lightly polished copper substrate, can also be dark orange. 2 Moderate tarnish Wine-red, lavender-blue, a lot of lavender-blue and/or

35、silver with a red-wine covering. Silver. Brass coloured or golden. 3 Heavy tarnish Magenta with a brass coloured surface. A lot of red and green shimmer (Butterfly) but no grey. 4 Corrosion Transparent black or dark grey or brown with the “Butterfly“ with a slight green shimmer. Graphite black or du

36、ll black. Shiny or pitch black. 8 Report The test report shall include: a) a reference to this European Standard, i.e. EN 1965-1; b) type and designation of the product tested; c) description of the copper plate preparation procedure; d) description of the type and thickness of the copper plates; e) corrosion/discolouration grade ranking; f) details of any operations not specified in this European Standard together with details of any events likely to have had had an effect on the results. DIN EN 1965-1:2011-07