DIN EN 16070-2014 Products used for treatment of water intended for human consumption - Natural zeolite German version EN 16070 2014《人类消费用水处理产品 天然沸石》.pdf

1、June 2014 Translation by DIN-Sprachendienst.English price group 11No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 7

2、1.100.80!%2c+“2156408www.din.deDDIN EN 16070Products used for treatment of water intended for human consumption Natural zeolite;English version EN 16070:2014,English translation of DIN EN 16070:2014-06Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch Natrlicher Zeolith;Englische Fass

3、ung EN 16070:2014,Englische bersetzung von DIN EN 16070:2014-06Produits utiliss pour le traitement de leau destine la consommation humaine Zolite naturelle;Version anglaise EN 16070:2014,Traduction anglaise de DIN EN 16070:2014-06www.beuth.deDocument comprises 20 pagesIn case of doubt, the German-la

4、nguage original shall be considered authoritative.05.14DIN EN 16070:2014-06 2 A comma is used as the decimal marker. National foreword This document (EN 16070:2014) has been prepared by Technical Committee CEN/TC 164 “Water supply” (Secretariat: AFNOR, France). The responsible German body involved i

5、n its preparation was the Normenausschuss Wasserwesen (Water Practice Standards Committee), Working Committee NA 119-04-02 AA Wasseraufbereitung. Users of this standard are advised of the reservations stated in the Introduction of the European Standard and should note that national regulations exist

6、 in Germany dealing with water for human consumption, in particular the Trinkwasserverordnung (TrinkwV 2001) (German Drinking Water Ordinance). The DIN Standards corresponding to the International Standards referred to in this document are as follows, whereby EN ISO Standards are only listed below i

7、f these have not been published as DIN EN ISO Standards with the same number: EN ISO 3696 DIN ISO 3696 National Annex NA (informative) Bibliography DIN ISO 3696, Water for analytical laboratory use Specification and test methods Verordnung ber die Qualitt von Wasser fr den menschlichen Gebrauch (Tri

8、nkwasserverordnung TrinkwV 2001) (German Drinking Water Ordinance), as of 02 August 2013 (BGBI. (German Federal Law Gazette) I, 2013, no. 46, p. 2977-3004), as amended by Article 4, Paragraph 22 of the Act of 07 August 2013 (BGBI. I, no. 48, p. 3154-3211)*)*)Obtainable from: Bundesministerium der Ju

9、stiz (German Federal Ministry of Justice) (Internet: http:/www.gesetze-im-internet.de). EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 16070 March 2014 ICS 71.100.80 English Version Products used for treatment of water intended for human consumption - Natural zeolite Produits utiliss pour le t

10、raitement de leau destine la consommation humaine - Zolite naturelle Produkte zur Aufbereitung von Wasser fr den menschlichen Gebrauch - Natrlicher Zeolith This European Standard was approved by CEN on 6 February 2014. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which s

11、tipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This Europe

12、an Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are

13、the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Roma

14、nia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2014 CEN All rights of exploitation in any form and by

15、 any means reserved worldwide for CEN national Members. Ref. No. EN 16070:2014 EEN 16070:2014 (E) 2 Contents PageForeword 3 Introduction .3 1 Scope 5 2 Normative references 5 3 Terms, definitions and symbols .5 4 Description .5 4.1 Identification .5 4.2 Commercial form .6 4.3 Types of natural zeolit

16、es .6 5 Physical properties 6 5.1 Appearance 6 5.2 Particle size distribution .6 5.3 Density (bulk density loose) .7 6 Chemical and mineralogical properties 7 6.1 General 7 6.2 Capacity 8 7 Test methods 8 7.1 Sampling .8 7.2 Analysis 8 8 Labelling, transportation and storage 11 8.1 Means of delivery

17、 11 8.2 Labelling according to the EU legislation . 11 8.3 Transportation regulations and labelling . 11 8.4 Marking 11 8.5 Storage . 11 Annex A (informative) General information on natural zeolites 12 A.1 Origin . 12 A.2 Typical properties . 12 A.3 Use . 16 A.4 Hydraulic characteristics . 16 A.5 Ru

18、les for safe handling and use . 16 A.6 Emergency procedures 16 Bibliography . 18 DIN EN 16070:2014-06 EN 16070:2014 (E) 3 Foreword This document (EN 16070:2014) has been prepared by Technical Committee CEN/TC 164 “Water supply”, the secretariat of which is held by AFNOR. This European Standard shall

19、 be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by September 2014 and conflicting national standards shall be withdrawn at the latest by September 2014. Attention is drawn to the possibility that some of the elements of this do

20、cument may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard

21、: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain,

22、 Sweden, Switzerland, Turkey and the United Kingdom. DIN EN 16070:2014-06 EN 16070:2014 (E) 4 Introduction In respect of potential adverse effects on the quality of water intended for human consumption, caused by the product covered by this European Standard: a) this European Standard provides no in

23、formation as to whether the product may be used without restriction in any of the Member States of the EU or EFTA; b) it should be noted that, while awaiting the adoption of verifiable European criteria, existing national regulations concerning the use and/or the characteristics of this product rema

24、in in force. NOTE Conformity with this European Standard does not confer or imply acceptance or approval of the product in any of the Member States of the EU or EFTA. The use of the product covered by this European Standard is subject to regulation or control by National Authorities. DIN EN 16070:20

25、14-06 EN 16070:2014 (E) 5 1 Scope This European Standard is applicable to natural zeolites used for treatment of water intended for human consumption. It describes the characteristics of natural zeolites and specifies the requirements and the corresponding test methods for natural zeolites. It gives

26、 information on their use in water treatment. The natural zeolites included in this standard are clinoptilolite, chabasite and phillipsite/analcime. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its applicat

27、ion. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 12901:1999, Products used for treatment of water intended for human consumption - Inorganic supporting and filtering materials - Def

28、initions EN 12902:2004, Products used for treatment of water intended for human consumption - Inorganic supporting and filtering materials - Methods of test EN ISO 3696, Water for analytical laboratory use - Specification and test methods (ISO 3696) EN ISO 14911, Water quality - Determination of dis

29、solved Li+, Na+, NH4+, K+, Mn2+, Ca2+, Mg2+, Sr2+ and Ba2+ using ion chromatography - Method for water and waste water (ISO 14911) 3 Terms, definitions and symbols For the purposes of this document, the terms, definitions and symbols given in EN 12901:1999 apply. 4 Description 4.1 Identification 4.1

30、.1 Chemical name(s) Crystalline hydrated aluminosilicate. 4.1.2 Synonym or common names Zeolite; Hydrated sodium, potassium, calcium, magnesium aluminosilicate. 4.1.3 Chemical formula General formula: MxDyAlx+2ySizO2x+4y+2z n H2O where M = Na, K, Li; D = Ca, Mg; x/y/z = 1 to 6; DIN EN 16070:2014-06

31、EN 16070:2014 (E) 6 n = 1 to 6. 4.1.4 CAS Registry number 1)1318-02-1 12173-10-3 12271-42-0 12251-32-0 61027-84-7 1318-10-1 4.1.5 EINECS reference 2)215-283-8 4.2 Commercial form Natural zeolites are dry granular products, available in different particle sizes. 4.3 Types of natural zeolites There ar

32、e over 200 different zeolites with about 30 natural zeolites. However, not all natural zeolites can be used in the treatment of water intended for human consumption. Given the particular characteristics needed for this type of application, only three species are identified: clinoptilolite, chabazite

33、 and phillipsite/analcime. These zeolites are available in large quantities in Europe, with no trace of hazardous or toxic elements. 5 Physical properties 5.1 Appearance The product consists of dry, free flowing granules. The product has a granular shape and a rough texture. The product shall be gen

34、erally homogeneous and shall be visibly free of extraneous matter. 5.2 Particle size distribution The particle size distribution shall be determined on samples taken at the point of manufacture using the method of test given in EN 12902. NOTE 1 The particle size can decrease during transportation an

35、d handling. The particle size distribution shall be described by either: a) effective size: (d10) with a maximum deviation of 5 %; median size: (d50) with a maximum deviation of 5 %; 1)Chemical Abstracts Service Registry Number. 2)European Inventory of Existing Commercial Chemical Substances. DIN EN

36、 16070:2014-06 EN 16070:2014 (E) 7 uniformity coefficient: (U) shall be less than 1,5; minimum size: (d1) with a maximum deviation of 5 %; or b) by particle size range and by mass fraction of oversize and undersize particles (see A.2.2.1). The maximum permitted mass fractions of oversize and undersi

37、ze are 5 %. NOTE 2 Other values might be necessary for certain applications. 5.3 Density (bulk density loose) The bulk density loose shall be in the range of: 800 kg/m3to 1 100 kg/m3for a clinoptilolite type zeolite; 700 kg/m3to 850 kg/m3for a chabazite type zeolite; 1 000 kg/m3to 1 100 kg/m3for a p

38、hillipsite/analcime type zeolite. 6 Chemical and mineralogical properties 6.1 General This European Standard specifies the minimum purity requirements for natural zeolite used for the treatment of water intended for human consumption. Limits are given for impurities commonly present in the product.

39、Depending on the raw material and the manufacturing process, other impurities may be present and, if so, this shall be notified to the user and when necessary to relevant authorities. Users of this product should check the national regulations in order to clarify whether it is of appropriate purity

40、for treatment of water intended for human consumption, taking into account raw water quality, contents of other impurities and additives used in the product not stated in this product standard. Limits have been given for impurities and chemical parameters where these are likely to be present in sign

41、ificant quantities from the current production process and raw materials. If the production process or raw materials lead to significant quantities of impurities, by-products or additives being present, this shall be notified to the user. The composition of the commercial product shall conform to Ta

42、ble 1. Table 1 null Composition of commercial product Parameters Limit in mass fraction % Mass loss at 150 C max. 7 Ignition loss at 650 C max. 14 After filling, washing and commissioning of a filter system producing drinking water, natural zeolite should not increase the concentrations of chemical

43、parameters (see1). NOTE Water extractable substances, determined in accordance with the method for granular materials given in EN 12902, can be used to estimate the leaching of the chemicals specified in EN 12902. DIN EN 16070:2014-06 EN 16070:2014 (E) 8 6.2 Capacity The cations that maintain the el

44、ectronic neutrality of the zeolite structure can be exchanged. This is a selective cation exchange according to the zeolite affinity for the replacing cation. The total cation exchange capacity and the selectivity are specific to each type of zeolite. This property makes the zeolites especially usef

45、ul and efficient for cation elimination or to achieve control of their concentration in water. Ammonium can be used as a quality standard to determine the Cation Exchange Capacity (CEC) of a natural zeolite. The total CEC shall be not less than 1,2 mg of ammonium per gram zeolite. 7 Test methods 7.1

46、 Sampling Prepare the laboratory sample(s) required by the relevant procedures described in EN 12902. 7.2 Analysis 7.2.1 Particle size distribution The particle size distribution shall be determined in accordance with EN 12902. 7.2.2 Bulk density loose The bulk density loose shall be determined in a

47、ccordance with EN 12902. 7.2.3 Mass loss at 150 C It is assumed that water is the only material present in the natural zeolite that is volatile at this temperature. The mass loss shall be determined by the method for water content, heating to 150 C, in accordance with EN 12902. 7.2.4 Precision - rep

48、eatability limit The absolute difference between two single test results, obtained under repeatability conditions, shall not exceed the repeatability limit, r, in more than 1 in 20 cases. 107,0 Xr = (1)where X1is the measured value. 7.2.5 Ignition loss at 650 C 7.2.5.1 Principle Heat the sample to c

49、onstant mass at 650 C. It is assumed that water, including chemically bound water and carbon dioxide produced from carbonates, are the only materials present in natural zeolite that are volatile at this temperature. At 650 C, the loss of water is practically complete. DIN EN 16070:2014-06 EN 16070:2014 (E) 9 7.2.5.2 Apparatus Ordinary laboratory apparatus and glassware together with the following. 7.2.5.2.1 Muffle furnace, capable of being controlled at (650 25) C. 7.2.5.2.2 High temperature metal or ceramic crucible wit