DIN EN 16523-1-2015 Determination of material resistance to permeation by chemicals - Part 1 Permeation by liquid chemical under conditions of continuous contact German version EN .pdf

1、April 2015 Translation by DIN-Sprachendienst.English price group 14No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS

2、13.340.01!%BEnglish version EN 16523-1:2015,English translation of DIN EN 16523-1:2015-04Bestimmung des Widerstands von Materialien gegen die Permeation von Chemikalien Teil 1: Permeation durch eine flssige Chemikalie unter Dauerkontakt;Englische Fassung EN 16523-1:2015,Englische bersetzung von DIN

3、EN 16523-1:2015-04Dtermination de la rsistance des matriaux la permation par des produitschimiques Partie 1: Permation par un produit chimique liquide dans des conditions de contactcontinu;Version anglaise EN 16523-1:2015,Traduction anglaise de DIN EN 16523-1:2015-04SupersedesDIN EN 374-3:2003-12 an

4、dDIN EN 374-3 Corrigendum1:2006-06www.beuth.deIn case of doubt, the German-language original shall be considered authoritative.Document comprises 30 pages 03.15 DIN EN 16523-1:2015-04 2 A comma is used as the decimal marker. Start of application The start of application of this standard is 2015-04-0

5、1. National foreword This standard includes safety requirements. This document (EN ISO 16523-1:2015) has been prepared by Technical Committee CEN/TC 162 “Protective clothing including hand and arm protection and lifejackets” (Secretariat: DIN, Germany). The responsible German body involved in its pr

6、eparation was the DIN-Normenausschuss Persnliche Schutzausrstung (DIN Standards Committee Personal Protective Equipment), Working Committee NA 075-05-13 AA Testverfahren fr Permeation von Chemikalien durch Materialien fr Schuhe, Handschuhe und Kleidung. Amendments This standard differs from DIN EN 3

7、74-3:2003-12 and DIN EN 374 Corrigendum 1: 2006-06 as follows: a) Clause 1 “Scope” has been revised; b) Clause 2 “Normative references” has been updated; c) Clause 3 “Terms and definitions” has been supplemented; d) the test procedure has been rendered more precise. Previous editions DIN 4841-1: 197

8、6-12, 1981-11, 1990-06 DIN 4841-2: 1979-05 DIN 4841-3: 1982-03 DIN 4841-5: 1987-01, 1987-04 DIN 23304: 1966-03 DIN 23314: 1966-03 DIN 23315: 1966-03 DIN 23316: 1966-03 DIN 23317: 1969-04 DIN 23324: 1969-04 DIN EN 374-3: 1994-04, 2003-12 DIN EN 374 Corrigendum 1: 2006-06 EUROPEAN STANDARD NORME EUROP

9、ENNE EUROPISCHE NORM EN 16523-1 February 2015 ICS 13.340.01 Supersedes EN 374-3:2003English Version Determination of material resistance to permeation by chemicals -Part 1: Permeation by liquid chemical under conditions of continuous contact Dtermination de la rsistance des matriaux la permation par

10、 des produits chimiques - Partie 1 : Permation par un produit chimique liquide dans des conditions de contact continu Bestimmung des Widerstands von Materialien gegen die Permeation von Chemikalien - Teil 1: Permeation durch eine flssige Chemikalie unter Dauerkontakt This European Standard was appro

11、ved by CEN on 5 December 2014. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national

12、 standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language

13、and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hun

14、gary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CEN

15、ELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2015 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 16523-1:2015 EEN 16523-1:2015 (E) 2 Contents Page Foreword 4 Introduction .5 1 Scope 6 2 Normative references 6 3 Terms

16、and definitions .6 4 Test principle 9 5 Collecting media 9 5.1 Gaseous collecting medium .9 5.2 Liquid collecting medium .9 5.3 Limitation due to collecting media.9 6 Apparatus 10 6.1 Permeation cells . 10 6.1.1 Standard permeation cell . 10 6.1.2 Alternative permeation cells 11 6.2 Temperature cont

17、rolled room, cabinet or water bath . 12 6.3 Supply of gas for gaseous collecting medium (dry air or nitrogen) . 12 6.4 Liquid pump and stirrer (in case of a liquid collecting medium) . 12 6.5 Equipment for the quantitative determination of the challenge chemical or its components in the collecting m

18、edium . 12 6.6 Time measuring device 12 7 Test specimens . 12 8 Procedure 13 8.1 Calibration . 13 8.2 Preparation of test specimens and apparatus . 13 8.3 Test procedure 13 8.4 Calculation of results . 15 8.4.1 Open loop system: Permeation rate (PR) . 15 8.4.2 Closed loop system Permeation rate (PR)

19、 . 15 8.5 Expression of results . 16 8.6 Uncertainty of measurement . 16 9 Test report . 16 Annex A (informative) Types of permeation behaviour 18 Annex B (informative) Physical assessment of the samples. 20 B.1 General . 20 B.2 Visual appearance 20 B.3 Thickness 20 B.4 Mass . 20 B.5 Hardness 20 Ann

20、ex C (informative) Examples of appropriate techniques for the detection of chemicals. 21 Annex D (informative) Examples of appropriate techniques to assess flow and stirring for permeation with liquid collecting medium . 22 DIN EN 16523-1:2015-04 EN 16523-1:2015(E)3 D.1 For the open loop system . 22

21、 D.2 For open and closed loop system . 22 D.3 For open and close loop system . 23 Annex E (informative) Example of permeation cell . 24 Annex F (informative) Results of the interlaboratory trials 26 Annex ZA (informative) Relationship between this European Standard and the Essential Requirements of

22、EU Directive 89/686/EEC on PPE 27 Bibliography 28 DINEN 16523-1:2015-04EN 16523-1:2015 (E) 4 Foreword This document (EN 16523-1:2015) has been prepared by Technical Committee CEN/TC 162 “Protective clothing including hand and arm protection and lifejackets”, the secretariat of which is held by DIN.

23、This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by August 2015 and conflicting national standards shall be withdrawn at the latest by August 2015. Attention is drawn to the possibility that some of t

24、he elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document supersedes EN 374-3:2003. In comparison with EN 374-3:2003, the entire document has been revised. This document has been pre

25、pared under a mandate given to CEN by the European Commission and the European Free Trade Association, and supports essential requirements of EU Directive(s). For relationship with EU Directive(s), see informative Annex ZA, which is an integral part of this document. EN 16523, Determination of mater

26、ial resistance to permeation by chemicals, is composed with the following parts: Part 1: Permeation by liquid chemical under conditions of continuous contact the present document; Part 2: Permeation by gaseous chemical under conditions of continuous contact. NOTE CEN/TC 162 WG 13 has foreseen to wor

27、k on other test methods in the future that will spread in several standard parts: Permeation by solid chemical under conditions of continuous contact; Permeation by chemical under conditions of intermittent contact; Permeation by chemical of seams, joins, assemblages and closers; Permeation by chemi

28、cal in a form of droplets; Guide on testing and interpretation. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Esto

29、nia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. DIN EN 16523-1:2015-04

30、EN 16523-1:2015(E)5 Introduction Users involved in the production, use, transportation, and emergency response with liquid chemicals can be exposed to numerous compounds capable of causing harm upon contact with the human body. The harmful effects of these chemicals can range from acute trauma such

31、as skin irritation and burn to chronic degenerative disease, such as cancer. Since engineering controls may not eliminate all possible exposures, attention is often placed on reducing the potential for direct skin contact through the use of personal protective equipment (PPE) that resists permeation

32、, penetration and degradation. The test method described in this part of EN 16523 is intended to be used to evaluate the barrier effectiveness of materials used for protective clothing, gloves and footwear materials against permeation by liquid chemicals. This method does not assess the chemical deg

33、radation or penetration of the material. Resistance to penetration by liquid chemicals can be determined by using for example ISO 6530 10 while resistance to penetration by liquid chemicals under pressure can be determined by using for example ISO 13994 11. Resistance to chemical degradation can be

34、determined by EN 374-4 2 for gloves and EN 13832-1:2006, 4.2 3 for footwear. This method provides tests results in terms of breakthrough time. This parameter is a key measure of the effectiveness of a material to act as a barrier to the challenge chemical. Such information is used in the comparison

35、of the performances of PPE materials during the process of selecting PPE for protection from hazardous chemicals. Long breakthrough times are characteristic of high permeation resistance. Breakthrough time does not provide a correlation between protection and the toxicity of the chemicals tested, on

36、ly cumulative permeation can provide this information. It has been assumed in the drafting of this part of EN 16523 that the execution of its provisions will be entrusted to appropriately qualified and experienced people with a sound understanding of analytical chemistry. Appropriate precautions sho

37、uld be taken when carrying out this type of testing in order to avoid injury to health and contamination of the environment. A future part of EN 16523 will explain the use of the series of standards EN 16523. DINEN 16523-1:2015-04EN 16523-1:2015 (E) 6 1 Scope This European Standard specifies a test

38、method for the determination of the resistance of protective clothing, gloves and footwear materials to permeation by potential hazardous liquid chemicals under the condition of continuous contact. This test method is applicable to the assessment of protection against liquid chemicals that can be co

39、llected only by liquid or gaseous collecting media. This test method is not adapted for the assessment of chemical mixtures, except for aqueous solutions. This standard is used with the specifications given in the products standards (for example EN 374-1 for gloves) where the following information i

40、s defined: any pre-conditioning; precise sampling (place, size, number); associated levels of performance. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the editio

41、n cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 374-1, Protective gloves against chemicals and micro-organisms - Part 1: Terminology and performance requirements 3 Terms and definitions For the purposes of this document, t

42、he following terms and definitions apply. 3.1 analytical technique method of identifying and quantifying the amount of permeated chemical in the collection medium Note 1 to entry: Such methods are often specific to individual chemical and collection-medium combinations. EXAMPLE Applicable analytical

43、 techniques can include ultraviolet (UV) or infrared (IR) spectrophotometry, mass spectrometry, pH measurement, ion chromatography, conductimetry, colourimetry, atmospheric analytical detector tubes and radionuclide tagging/detection counting. Although liquid and/or gas chromatography are separation

44、 techniques rather than detection methods they can be used in conjunction with suitable detectors to quantify the amount of permeated chemical in the collection medium (see Annex C). 3.2 liquid challenge chemical liquid chemical that is used to challenge the protective clothing, gloves and footwear

45、material specimen 3.3 collecting medium liquid or gas on the inner “clean” side of the test sample in which any permeated chemical is collected 3.4 response time time between the actual arrival of the challenge chemical on the collecting side of the specimen and the time when the analytical instrume

46、ntation responds to it DIN EN 16523-1:2015-04 EN 16523-1:2015 (E) 7 3.5 limit of quantification minimum quantity of a substance which can be measured Note 1 to entry: It is the value where the uncertainty of measurement is equal to 50 % of the determined value. 3.6 loop 3.6.1 closed loop system in w

47、hich the collecting medium is re-circulated or stirred through the sampling compartments of the test cell Note 1 to entry: Closed loop systems are not commonly used with gaseous collection media. 3.6.2 open loop system where the collecting medium passes through the sampling compartment of the test c

48、ell without re-circulation Note 1 to entry: Open loop systems may be used with either liquid or gaseous collection media. 3.7 minimum detectable permeation rate MDPR lowest rate of permeation that is measurable with the complete permeation-test system Note 1 to entry: This value is not necessarily the intrinsic limit of detection for the analytical instrument. Note 2 to entry: MDPR is usually based upon 3 times the average background noise. Note 3 to entry: Useful information can be found on the following webs