DIN EN 16849-2016 Bitumen and bituminous binders - Determination of water content in bituminous emulsions - Method using a drying balance German version EN 16849 2016《沥青和沥青粘合剂 沥青乳胶.pdf

1、December 2016 English price group 7No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 75.140; 91.100.50!%7“2599120www.

2、din.deDIN EN 16849Bitumen and bituminous binders Determination of water content in bituminous emulsions Method using a drying balance;English version EN 16849:2016,English translation of DIN EN 16849:2016-12Bitumen und bitumenhaltige Bindemittel Bestimmung des Wassergehaltes von Bitumenemulsionen Ve

3、rfahren mittels Trocknungswaage;Englische Fassung EN 16849:2016,Englische bersetzung von DIN EN 16849:2016-12Bitumes et liants bitumineux Dtermination de la teneur en eau des mulsions de bitume Mthode par vaporation la balance dessiccatrice;Version anglaise EN 16849:2016,Traduction anglaise de DIN E

4、N 16849:2016-12www.beuth.deDocument comprises 10 pagesDTranslation by DIN-Sprachendienst.In case of doubt, the German-language original shall be considered authoritative.12.16 DIN EN 16849:2016-12 2 A comma is used as the decimal marker. National foreword This document (EN 16849:2016) has been prepa

5、red by Technical Committee CEN/TC 336 “Bituminous binders” (Secretariat: AFNOR, France). The responsible German bodies involved in its preparation were DIN-Normenausschuss Materialprfung (DIN Standards Committee Materials Testing) and DIN-Normenausschuss Bauwesen (DIN Standards Committee Building an

6、d Civil Engineering), Joint Committee NA 062-03-32 GA Bitumen; Prfverfahren und Anforderungen fr die Bindemittel. The DIN Standard corresponding to the International Standard referred to in this document is as follows: ISO 5725-2 DIN ISO 5725-2 National Annex NA (informative) Bibliography DIN ISO 57

7、25-2, Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 16849 October 2016 ICS 75.140; 91.100.50 English Version Bi

8、tumen and bituminous binders - Determination of water content in bituminous emulsions - Method using a drying balance Bitumes et liants bitumineux - Dtermination de la teneur en eau des mulsions de bitume - Mthode par vaporation la balance dessiccatrice Bitumen und bitumenhaltige Bindemittel - Besti

9、mmung des Wassergehaltes von Bitumenemulsionen - Verfahren mittels Trocknungswaage This European Standard was approved by CEN on 29 July 2016. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard the status of a na

10、tional standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, French, German). A v

11、ersion in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus

12、, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingd

13、om. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2016 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 16849:20

14、16 EEN 16849:2016 (E) 2 Contents Page European foreword . 3 1 Scope 4 2 Normative references 4 3 Terms and definitions . 4 4 Principle . 5 5 Reagents and material . 5 6 Apparatus . 5 7 Sampling . 5 8 Procedure. 5 8.1 Control of the apparatus . 5 8.2 Test temperature and stop criterion . 5 8.3 Test .

15、 5 9 Calculation . 6 10 Expression of results 6 11 Precision . 6 11.1 Repeatability . 6 11.2 Reproducibility 7 12 Test report . 7 Bibliography 8 DIN EN 16849:2016-12 EN 16849:2016 (E) 3 European foreword This document (EN 16849:2016) has been prepared by Technical Committee CEN/TC 336 “Bituminous bi

16、nders”, the secretariat of which is held by AFNOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by April 2017, and conflicting national standards shall be withdrawn at the latest by April 2017. At

17、tention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN/CENELEC Internal Regulations, the national standards organizations

18、of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Ne

19、therlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. DIN EN 16849:2016-12 EN 16849:2016 (E) 4 1 Scope This European Standard specifies a quick method for determining, by evaporation, the water content of bituminous road emulsion

20、s, with or without polymer added. For bituminous emulsions without flux oil, bituminous emulsions containing vegetal flux oil, and bituminous emulsions containing up to 1,5 % mass of mineral flux oil in the emulsion, this European Standard, according to the selected operating conditions, is consider

21、ed as an alternative method to the reference methods EN 1428 1 and EN 1431 2. Above a mineral flux oil content of 1,5 % by mass, depending on the volatility of the flux oil: the present method can be used if the user can prove its reliability in comparison to EN 1428 or EN 1431. the present method c

22、an only be used by correcting the result by means of a previously established correlation with the reference method EN 1428 or EN 1431. NOTE Polymer modified emulsions can behave differently in the test than unmodified emulsions; in case of doubt, the method is checked against EN 1428 or EN 1431. In

23、 case of dispute, the water content should be determined according to EN 1428 or EN 1431. WARNING The use of this European Standard can involve hazardous materials, operations and equipment. This European Standard does not purport to address all of the safety problems associated with its use. It is

24、the responsibility of the user of this European Standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and a

25、re indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 58, Bitumen and bituminous binders Sampling bituminous binders EN 12594, Bitumen and bituminous bin

26、ders Preparation of test samples 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 water content percentage in mass of water determined according to the test conditions described in this European Standard 3.2 mineral flux flux which may be of c

27、arbochemical, petrochemical or petroleum origin or a mixture of those 3.3 vegetal flux type of bio-flux derived exclusively from plant based (vegetal) product DIN EN 16849:2016-12 EN 16849:2016 (E) 5 4 Principle The water contained in the emulsion is evaporated by regulated heating. The sample being

28、 directly placed on a balance integrated to the apparatus, the weight loss is automatically determined until a constant mass is obtained. 5 Reagents and material Solvents appropriate for the cleaning of the laboratory material used. 6 Apparatus Usual laboratory material and glassware, together with

29、the following: 6.1 Drying balance, of sufficient capacity, capable of weighing to the nearest 0,001 g, equipped with a regulated heating device able to maintain a temperature at an accuracy 5 C in the range of 110 C to 150 C, around the sample during the test. 6.2 Drying cups, in a material not affe

30、cting the behaviour of bituminous emulsions. 6.3 Absorbing glass fibre filter(s), to enable a homogeneous repartition of the sample and to avoid skinning effect. 7 Sampling The product submitted to the test shall be sampled according to EN 58 and shall be prepared according to EN 12594. 8 Procedure

31、8.1 Control of the apparatus Each new apparatus shall be calibrated for temperature and weighing accuracy before its first use. Once in service, an apparatus shall be calibrated at least yearly. 8.2 Test temperature and stop criterion Test temperature shall be set at: 110 C for mineral flux emulsion

32、s with up to 1,5 % by mass of flux and emulsions with 5 % by mass or more of vegetal flux; 130 C for vegetal fluxed emulsions with less than 5 % by mass of flux; 150 C for non-fluxed emulsions. The stop of the test can be defined automatically or manually. The stop criterion shall be set at a value

33、closest to about 1 mg/50 s. 8.3 Test 8.3.1 Switch on the drying balance (6.1). Set up the heating temperature and stop criterion at the desired values (see 8.2). DIN EN 16849:2016-12 EN 16849:2016 (E) 6 8.3.2 Place the absorbing filter (6.3) on the drying cup (6.2) and tare the balance. 8.3.3 Remove

34、 the absorbing filter and weigh (4,0 0,5) g of emulsion, 0m in the drying cup to the nearest 0,001 g. Distribute the emulsion uniformly on the cup surface in less than 30 s. Place the same absorbing filter (8.3.2) on top of the emulsion sample in order to ensure an even drying of the test sample. NO

35、TE To enable easy cleaning and re-use of the drying cup, it is also possible to pour the emulsion sample in-between two glass fibre filters. 8.3.4 Start up the apparatus for test. 8.3.5 The test is considered finished when the mass of the dehydrated binder is constant. The mass is considered constan

36、t when the stop criterion is satisfied (8.2). Record the final mass fm to the nearest 0,001 g. Before any new measurement, open the balance and let it cool down to ambient temperature 9 Calculation The water content (w) of the sample tested, expressed in percentage by mass, is calculated using the f

37、ollowing formula: 10000=mmmwfwhere 0mis the initial mass of emulsion (8.3.3); fm is the final mass (8.3.5). NOTE some apparatus automatically calculates the water content and/or binder content when the test is finished. 10 Expression of results Express the water content as a percentage by mass to th

38、e nearest 0,1 %. 11 Precision NOTE The precision of the method was evaluated in the frame of a Round Robin test program conducted by TC336/WG2 3 in accordance with ISO 5725-2 4. 11.1 Repeatability The difference between two test results obtained by the same operator with the same apparatus under con

39、stant operating conditions on identical test material would, in the long run, in the normal and correct operation of the test method, exceed 0,6 % by mass in absolute value, in only one case in twenty 3. DIN EN 16849:2016-12 EN 16849:2016 (E) 7 11.2 Reproducibility The difference between two single

40、and independent test results obtained by different operators working in different laboratories on identical test material would, in the long run, in the normal and correct operation of the test method, exceed 1,8 % by mass in absolute value, in only one case in twenty 3. 12 Test report The test repo

41、rt shall contain at least the following information: a) a reference to this European Standard; b) the type and complete identification of the sample under test; c) test temperature and stop criterion d) the test result (see Clause 10); if used, the corrected water content according to the correlatio

42、n with the reference method EN 1428 1 or EN 1431 2; e) any deviation, by agreement or otherwise, from the procedure specified; f) the date of the test. DIN EN 16849:2016-12 EN 16849:2016 (E) 8 Bibliography 1 EN 1428, Bitumen and bituminous binders Determination of water content in bituminous emulsio

43、ns Azeotropic distillation method 2 EN 1431, Bitumen and bituminous binders Determination of residual binder and oil distillate from bitumen emulsions by distillation 3 CEN TC336/WG2, Round Robin on bituminous emulsions, B. Eckmann, F. Le Cunff, M. Cresnar, S. Collins in the name of TC336/WG2 6th Eurasphalt & Eurobitume Congress, Paper 100, Prague 2016 4 ISO 5725-2, Accuracy (trueness and precision) of measurement methods and results Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method DIN EN 16849:2016-12