DIN EN ISO 10426-5-2006 Petroleum and natural gas industries - Cements and materials for well cementing - Part 5 Determination of shrinkage and expansion of well cement formulation.pdf

1、Februar 2006DEUTSCHE NORM Normenausschuss Erdl- und Erdgasgewinnung (NG) im DINPreisgruppe 11DIN Deutsches Institut fr Normung e.V. Jede Art der Vervielfltigung, auch auszugsweise, nur mit Genehmigung des DIN Deutsches Institut fr Normung e.V., Berlin, gestattet.ICS 75.020; 91.100.10!,e4“9661798www.

2、din.deDDIN EN ISO 10426-5Erdl- und Erdgasindustrie Zemente und Materialien fr die Zementation von Tiefbohrungen Teil 5: Bestimmung der Schrumpfung und Quellung vonBohrloch-Zementmischungen bei atmosphrischem Druck(ISO 10426-5:2004);Englische Fassung EN ISO 10426-5:2005Petroleum and natural gas indus

3、tries Cements and materials for well cementing Part 5: Determination of shrinkage and expansion of well cement formulations atatmospheric pressure (ISO 10426-5:2004);English version EN ISO 10426-5:2005Industries du ptrole et du gaz naturel Ciments et matriaux pour la cimentation des puits Partie 5:

4、Dtermination du retrait et de lexpansion la pression atmosphrique desformulations de ciments pour puits (ISO 10426-5:2004);Version anglaise EN ISO 10426-5:2005Alleinverkauf der Normen durch Beuth Verlag GmbH, 10772 Berlinwww.beuth.deGesamtumfang 19 SeitenB55EB1B3E14C22109E918E8EA43EDB30F09CC9B7EF8DD

5、9NormCD - Stand 2007-03 DIN EN ISO 10426-5:2006-02 2 Nationales Vorwort Diese Europische Norm wurde vom Technischen Komitee CEN/TC 12 Materialien, Ausrstungen und Offshore-Bauwerke fr die Erdl-, petrochemische und Erdgasindustrie“ (Sekretariat: Frankreich) erstellt. Es handelt sich dabei um die unve

6、rnderte bernahme von ISO 10426-5:2004, erarbeitet von ISO/TC 67 Materials, equipment and offshore structures for petroleum, petrochemical and natural gas industries“, Subkomitee SC 3 Drilling and completion fluids, and well cements“. Fr Deutschland hat hieran der Arbeitskreis NG 12/67 AK 3 Bohrsplun

7、g und Zemente“ im Normen-ausschuss Erdl- und Erdgasgewinnung (NG) mitgearbeitet. Diese Europische Norm enthlt unter Bercksichtigung des DIN-Prsidialbeschlusses 13/1983 nur die englische Originalfassung der ISO-Norm. Es wird ausdrcklich darauf hingewiesen, dass die Anwendung der in dieser Norm aufgef

8、hrten Einheit in“ in Deutschland im nationalen amtlichen und geschftlichen Verkehr aufgrund des Gesetzes ber Einheiten im Messwesen (vom 1985-02-22 sowie der Ausfhrungsverordnung vom 1985-12-13 gendert durch Verordnung vom 2001-10-29 und Verordnung vom 2003-11-25) nicht zulssig ist. ISO 10426 besteh

9、t unter dem gemeinsamen Haupttitel Erdl- und Erdgasindustrie Zemente und Materialien fr die Zementation von Tiefbohrungen aus folgenden Teilen: Teil 1: Anforderungen Teil 2: Prfung von Bohrloch-Zemente Teil 3: Prfung von Unterwasser-Bohrlochzement Teil 4: Vorbereitung und Prfung von Schaumzementbrhe

10、n unter atmosphrischen Bedingungen Teil 5: Bestimmung der Schrumpfung und Quellung von Bohrloch-Zementmischungen bei atmosph-rischem Druck B55EB1B3E14C22109E918E8EA43EDB30F09CC9B7EF8DD9NormCD - Stand 2007-03 EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMOctober 2005ICS 91.100.10; 75.020English Vers

11、ionPetroleum and natural gas industries - Cements and materialsfor well cementing - Part 5: Determination of shrinkage andexpansion of well cement formulations at atmospheric pressure(ISO 10426-5:2004)Industries du ptrole et du gaz naturel - Ciments etmatriaux pour la cimentation des puits - Partie

12、5:Dtermination du retrait et de lexpansion la pressionatmosphrique des formulations de ciments pour puits (ISOErdl- und Erdgasindustrie - Zemente und Materialien frdie Zementation von Tiefbohrungen - Teil 5: Bestimmungder Schrumpfung und Quellung von Bohrloch-Zementmischungen bei atmosphrischem Druc

13、k (ISO10426-5:2004)This European Standard was approved by CEN on 30 September 2005.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and

14、bibliographical references concerning such nationalstandards may be obtained on application to the Central Secretariat or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility

15、of a CEN member into its own language and notified to the Central Secretariat has the same status as the officialversions.CEN members are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, La

16、tvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia,Slovenia, Spain, Sweden, Switzerland and United Kingdom.Management Centre: rue de Stassart, 36 B-1050 Brussels 2005 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Membe

17、rs.Ref. No. EN ISO 10426-5:2005: E10426-5:2004)EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNG EN ISO 10426-5B55EB1B3E14C22109E918E8EA43EDB30F09CC9B7EF8DD9NormCD - Stand 2007-03 Contents Page1 2 3 4 5 Determination of shrinkage or expansion under c

18、onditions of free access of water at 6 Determination of bulk shrinkage or expansion under impermeable condition and Introduction . 4 Foreword3 EN ISO 10426-5:2005 (E)2Scope.5 Normative references 5 Terms and definitions5 Bibliography 17 atmospheric pressure Membrane test 13 atmospheric pressure Annu

19、lar ring test.6 Sampling .6 B55EB1B3E14C22109E918E8EA43EDB30F09CC9B7EF8DD9NormCD - Stand 2007-03 Foreword The text of ISO 10426-5:2004 has been prepared by Technical Committee ISO/TC 67 “Materials, equipment and offshore structures for petroleum and natural gas industries” of the International Organ

20、ization for Standardization (ISO) and has been taken over as EN ISO 10426-5:2005 by Technical Committee CEN/TC 12 “Materials, equipment and offshore structures for petroleum, petrochemical and natural gas industries“, the secretariat of which is held by AFNOR. This European Standard shall be given t

21、he status of a national standard, either by publication of an identical text or by endorsement, at the latest by April 2006, and conflicting national standards shall be withdrawn at the latest by April 2006. According to the CEN/CENELEC Internal Regulations, the national standards organizations of t

22、he following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Slovakia, Slovenia, Spain

23、, Sweden, Switzerland and United Kingdom. Endorsement noticeThe text of ISO 10426-5:2004 has been approved by CEN as EN ISO 10426-5:2005 without any modifications. EN ISO 10426-5:2005 (E)3B55EB1B3E14C22109E918E8EA43EDB30F09CC9B7EF8DD9NormCD - Stand 2007-03 Introduction Dimensional changes in oil- an

24、d gas-well cements after placement, phenomena often referred to as shrinkage, (when the dimensional change corresponds to a decrease in cement volume) have often been used to explain various wellbore phenomena including a microannulus, leading to a bad bond as demonstrated by the bond log; interzona

25、l communication, resulting in costly remedial operations; lack of a hydraulic seal when utilizing cement inflatable packers. Attempts have been made to find additives that decrease cement shrinkage (shrinkage being a fundamental characteristic of Portland cement) The best solution for shrinkage thus

26、 far has been the identification of additives that favour the expansion of the cement. However, even if cement expands dimensionally, it will still shrink internally. In this case, the bulk expansion of the cement sample is simply superimposed on an inner shrinkage that will affect the porosity of t

27、he sample. Shrinkage and expansion in cement result from the formation of hydration products having a density different from the compounded density of the reaction components. This can result in the following: change in pore volume; change in pore pressure; change in sample dimensions; change in int

28、ernal stress. In a closed cell with a non-deformable boundary, the volume of hydrates produced during the chemical reaction is less than the volume of dry compounds plus water. The change in volume of hydrates will be referred to as inner hydration shrinkage. The change in the sample dimensions will

29、 be referred to as bulk shrinkage or expansion. Bulk shrinkage and expansion of cement refer to the result of the measurement of linear dimensional change or volume change. The volume to which all volume changes are related is the volume of the slurry immediately after mixing and emplacement in the

30、experimental equipment. In this part of ISO 10426, units are given as SI, and where practical, U.S. Customary units are included in brackets for information. Users of this part of ISO 10426 should be aware that further or differing requirements might be needed for individual applications. This part

31、of ISO 10426 is not intended to inhibit a vendor from offering, or the purchaser from accepting, alternative equipment or engineering solutions for the individual application. This can be particularly applicable where there is innovative or developing technology. Where an alternative is offered, the

32、 vendor should identify any variations from this International Standard and provide details. This part of ISO 10426 is based on API Technical Report 10TR 21.EN ISO 10426-5:2005 (E)4B55EB1B3E14C22109E918E8EA43EDB30F09CC9B7EF8DD9NormCD - Stand 2007-03 1 Scope This part of ISO 10426 provides the method

33、s for the testing of well cement formulations to determine the dimension changes during the curing process (cement hydration) at atmospheric pressure only. This is a base document, because under real well cementing conditions shrinkage and expansion take place under pressure and different boundary c

34、onditions. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 10426-2:200

35、3, Petroleum and natural gas industries Cements and materials for well cementing Part 2: Testing of well cements3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1bulk expansion increase in the external volume or dimensions of a cement sample 3.2

36、bulk shrinkage decrease in the external volume or dimensions of a cement sample 3.3hydration shrinkage difference in the volume between the hydration products and the volume of the dry cement, additives and waterEN ISO 10426-5:2005 (E)5B55EB1B3E14C22109E918E8EA43EDB30F09CC9B7EF8DD9NormCD - Stand 200

37、7-03 4 Sampling 4.1 General Samples of the neat cement or cement blend, solid and liquid additives, and mixing water are required to test a slurry according to this part of ISO 10426. Accordingly, the best available sampling technology should be employed to ensure the laboratory test conditions and

38、materials match as closely as possible those found at the wellsite. Some commonly used sampling devices are shown in ISO 10426-2:2003, Figure 1. 4.2 Method Applicable sampling techniques for the fluids and materials used are specified in ISO 10426-2:2003, Clause 4.5 Determination of shrinkage or exp

39、ansion under conditions of free access of water at atmospheric pressure Annular ring test 5.1 General information The annular expansion mould is a device suitable for measuring only the linear bulk shrinkage or expansion properties of a cement formulation. The magnitude of expansion depends on the a

40、mount of expanding agent, cement powder, slurry design and curing condition (pressure, temperature, time, fluid access). It should be noted that expansion is strongly affected by boundary conditions. The chemical process of mineral growth is strongly controlled by the state of stress and mineral gro

41、wth will tend to occur where the stress value is the lowest, i.e. in pore space or empty spaces. Therefore, the degree of cement shrinkage and expansion is dependent on a number of conditions, not all of which can be uniquely defined. The test does not represent fully the annulus of a well. 5.2 Appa

42、ratus 5.2.1 Mould 5.2.1.1 General Use corrosion-resistant material (e.g. stainless steel). The outer diameter (OD) of the inner ring shall be 50,8 mm (2 in) and the inner diameter (ID) of the outer expansion ring shall be 88,9 mm (3,5 in). See Figures 1, 2 and 3. Figure 1 Typical mould assembly (top

43、 view) Figure 2 Typical mould assembly (side view) EN ISO 10426-5:2005 (E)6B55EB1B3E14C22109E918E8EA43EDB30F09CC9B7EF8DD9NormCD - Stand 2007-03 Dimensions in millimetres (inches) a) Base b) Lidc) Internal ring d) Annular ring moulde) External ring f) Spacer blockFigure 3 Schema of typical mould asse

44、mbly partsEN ISO 10426-5:2005 (E)7B55EB1B3E14C22109E918E8EA43EDB30F09CC9B7EF8DD9NormCD - Stand 2007-03 5.2.1.2 Mould calibration The resilience of the ring of the mould shall be calibrated annually. The resilience shall be such that the mass of 1 000 g r 1 g (2,204 6 lb r 0,002 lb) applied as shown in Figure 4 shall increase the distance between the two steel measurement balls (see Figure 9) by 2 mm r 0,3 mm (0,078 7 in r 0,011 8 in) without permanent deformation. Attention must be paid to ensure that the loa