DIN EN ISO 10601-2008 Micaceous iron oxide pigments for paints - Specifications and test methods (ISO 10601 2007) German version EN ISO 10601 2008《涂料用云母氧化铁颜料 规范和试验方法》.pdf

1、August 2008DEUTSCHE NORM English price group 8No part of this standard may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 87.060.10!$Q2V“1461551ww

2、w.din.deDDIN EN ISO 10601Micaceous iron oxide pigments for paints Specifications and test methods (ISO 10601:2007)English version of DIN EN ISO 10601:2008-08Eisenglimmer-Pigmente fr Beschichtungsstoffe Anforderungen und Prfverfahren (ISO 10601:2007)Englische Fassung DIN EN ISO 10601:2008-08www.beuth

3、.deDocument comprises 11 pagesDIN EN ISO 10601:2008-08 2 National foreword This standard falls in the domain of Technical Committee CEN/TC 298 “Pigments and extenders” (Secretariat: DIN, Germany). It is identical with International Standard ISO 10601:2007 which was prepared by Technical DIN, Germany

4、). The responsible German bodies involved in its preparation was the Normenausschuss Pigmente und Fllstoffe (Pigments and Extenders Standards Committee), Technical Committee NA 078-00-10 AA Prfver-fahren und Kennwerte fr Pigmente. The DIN Standards corresponding to the International Standards referr

5、ed to in clause 2 of the EN are as follows: ISO 150 DIN EN ISO 150 ISO 787-2 DIN EN ISO 787-2 ISO 787-3 DIN EN ISO 787-3 ISO 787-5 DIN EN ISO 787-5 ISO 787-9 DIN EN ISO 787-9 ISO 1248 DIN EN ISO 1248 ISO 3549 DIN EN ISO 3696 ISO 15528 DIN EN ISO 15528 National Annex NA (informative) Bibliography DIN

6、 EN ISO 150, Raw, refined and boiled linseed oil for paints and varnishes Specifications and methods of test DIN EN ISO 787-2, General methods of test for pigments and extenders Determination of matter volatile at 105 C DIN EN ISO 787-3, General methods of test for pigments and extenders Part 3: Det

7、ermination of matter soluble in water Hot extraction method DIN EN ISO 787-5, General methods of test for pigments and extenders Determination of oil absorption value DIN EN ISO 787-9, General methods of test for pigments and extenders Determination of pH value of an aqueous suspension DIN EN ISO 12

8、48, Iron oxide pigments Specifications and methods of test DIN EN ISO 3549, Zinc dust pigments for paints Specifications and test methods DIN EN ISO 15528, Paints, varnishes and raw materials for paints and varnishes Sampling Committee ISO/TC 35 “Paints and varnishes”, Subcommittee SC 2 “Pigments an

9、d extenders” (Secretariat: EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN ISO 10601May 2008ICS 87.060.10English VersionMicaceous iron oxide pigments for paints - Specifications andtest methods (ISO 10601:2007)Pigments doxyde de fer micac pour peintures -Spcifications et mthodes dessai (ISO 10601:

10、2007)Eisenglimmer-Pigmente fr Beschichtungsstoffe -Anforderungen und Prfverfahren (ISO 10601:2007)This European Standard was approved by CEN on 12 April 2008.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the

11、status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German).

12、 A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic

13、, Denmark, Estonia, Finland,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALI

14、SATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2008 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN ISO 10601:2008: EContents Page Foreword Introduction 1 Scope . 2 Normative references . 3

15、 Terms and definitions. 4 Classification. 5 Required characteristics and their tolerances 6 Sampling 7 Assessment of thin-flake content . 8 Test report . DIN EN ISO 10601:2008-08 EN ISO 10601:2008 (E) 2 455666787. 3Foreword The text of ISO 10601:2007 has been prepared by Technical Committee ISO/TC 3

16、5 “Paints and varnishes” of the International Organization for Standardization (ISO) and has been taken over as EN ISO 10601:2008 by Technical Committee CEN/TC 298 “Pigments and extenders” the secretariat of which is held by DIN. This European Standard shall be given the status of a national standar

17、d, either by publication of an identical text or by endorsement, at the latest by November 2008, and conflicting national standards shall be withdrawn at the latest by November 2008. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights.

18、 CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech

19、 Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. Endorsement notice The text of ISO 10601:2007

20、has been approved by CEN as a EN ISO 10601:2008 without any modification. EN ISO 10601:2008 (E) DIN EN ISO 10601:2008-08 3 Introduction Micaceous iron oxide pigments were previously included in ISO 1248 (classified in the colour group “grey with metallic sheen”) but are explicity excluded from the r

21、evised edition published in 2006. In this revised edition of ISO 10601, the requirements for micaceous iron oxide pigment have been defined more clearly and relate to an essentially lamellar particle shape. Micaceous iron oxide pigments can vary in composition, particle size range, and particle shap

22、e depending on whether they are produced synthetically or, if a refined natural oxide, on the location where the ore was mined. The primary use of micaceous iron oxide is in protective coatings for steelwork, and for optimum performance the pigment should have a high content of thin flake-like parti

23、cles. The protective action is ascribed to the close packing of pigment platelets within the paint film, forming overlapping layers that lie roughly parallel to the substrate. This impedes penetration of corrosion promoters, reduces ultra-violet degradation of the binder and improves film strength.

24、For less critical requirements, micaceous iron oxide pigment with a lower content of thin flakes may be acceptable. Therefore in this International Standard, micaceous iron oxide pigments are classified into two groups according to their thin-flake content as determined by microscopic examination (s

25、ee Table 1). For the purposes of this International Standard, pigments with a lamellar-particle content below 50 % are not considered to be “micaceous” or classified as “lamellar”. DIN EN ISO 10601:2008-08 EN ISO 10601:2008 (E) 4 1 Scope This International Standard specifies the requirements and cor

26、responding test methods for manufactured and natural micaceous iron oxide (MIO) pigments, in dry form, used primarily in protective coatings for steelwork. In accordance with current practice, the general requirements for micaceous iron oxide pigments have been sub-divided to give a) those requireme

27、nts that are essential (see Table 2) and b) those requirements that are conditional upon prior agreement between the interested parties (see Table 3). In certain instances, reference may be made to an agreed reference pigment. 2 Normative references The following referenced documents are indispensab

28、le for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. ISO 150, Raw, refined and boiled linseed oil for paints and varnishes Specifications and methods of

29、 test ISO 787-2, General methods of test for pigments and extenders Part 2: Determination of matter volatile at 105 C ISO 787-3, General methods of test for pigments and extenders Part 3: Determination of matter soluble in water Hot extraction method ISO 787-5, General methods of test for pigments a

30、nd extenders Part 5: Determination of oil absorption value ISO 787-9, General methods of test for pigments and extenders Part 9: Determination of pH value of an aqueous suspension ISO 1248, Iron oxide pigments Specifications and methods of test ISO 3549, Zinc dust pigments for paints Specifications

31、and test methods ISO 15528, Paints, varnishes and raw materials for paints and varnishes Sampling EN ISO 10601:2008 (E) DIN EN ISO 10601:2008-08 5 3 Terms and definitions For the purposes of this document, the following terms and definitions apply. 3.1 micaceous iron oxide pigment refined mineral (a

32、lso known as specular haematite) or a manufactured product consisting essentially of iron(III) oxide, Fe2O3, that is grey in colour with a metallic sheen and consists essentially of particles having lamellar form 4 Classification In this International Standard, micaceous iron oxide pigments are clas

33、sified by grades according to their thin-flake content as shown in Table 1 and by types according to their residue on sieve as shown in Table 2. Thin-flake micaceous iron oxide particles are defined as having a thickness such that they appear as sharply defined red translucent platelets when viewed

34、under an optical microscope by transmitted light, i.e. with the light source behind the specimen under examination (see test method in Clause 7). Table 1 Lamellar classification Grade Thin-flake content % A 65 B 50 to 65 5 Required characteristics and their tolerances For micaceous iron oxide pigmen

35、ts complying with this International Standard, the essential requirements are specified in Tables 1 and 2 and the conditional requirements are referred to in Table 3. The reference pigment and the conditional requirements set out in Table 3 shall be the subject of agreement between the interested pa

36、rties. The reference pigment shall comply with the requirements given in Table 1 (grade A or B) and Table 2 (type 1, 2 or 3). DIN EN ISO 10601:2008-08 EN ISO 10601:2008 (E) 6 Table 2 Essential requirements Characteristic Requirement for MIO of type Test method 1 2 3 Iron content, expressed as iron(I

37、ll) oxide (Fe2O3) (determined on the pigment after drying at 105 C) % (by mass) min. 85 ISO 1248aMatter volatile at 105 C % (by mass) max. 0,5 ISO 787-2 Matter soluble in water (hot-extraction method) % (by mass) max. 0,5 ISO 787-3 63 m max. 5 5 but u 15 15 but u 35 Residue on sieve, % (by mass) 105

38、 m max. 0,1 max. 0,1 max. 0,1 ISO 3549 aThe use of 60 ml of 37 % (by mass) hydrochloric acid, approximately 1,19 g/ml, and 0,5 g of potassium chlorate is recommended to facilitate dissolution of the sample. Table 3 Conditional requirements Characteristic Requirement Test method pH of aqueous suspens

39、ion Shall not differ by more than 1 pH unit from that of the agreed reference pigment ISO 787-9 Oil absorption value Shall not differ by more than 15 % from that of the agreed reference pigment ISO 787-5 Total calcium, expressed as calcium oxide, % (by mass) To be agreed between the interested parti

40、es ISO 1248 6 Sampling Take a representative sample of the product to be tested, as described in ISO 15528. 7 Assessment of thin-flake content 7.1 Reagent 7.1.1 Refined linseed oil, complying with the requirements of ISO 150. 7.2 Apparatus 7.2.1 Glass microscope slide, approximately 25 mm 75 mm 1 mm

41、, and cover slip. 7.2.2 Glass rod, approximately 100 mm long and 5 mm in diameter, with rounded end. 7.2.3 Optical microscope, capable of 200 magnification, with a 20 objective lens and fitted with high-intensity sub-stage illumination. EN ISO 10601:2008 (E) DIN EN ISO 10601:2008-08 7 7.3 Procedure

42、Prepare a microscope slide (7.2.1) by one of the following methods: a) Place a few milligrams of a representative sample of the dry pigment (see Clause 6) on the glass slide. Add a few drops of refined linseed oil (7.1.1) and gently incorporate the pigment into the oil using the glass rod (7.2.2). P

43、lace the cover slip over the pigment/oil dispersion and position on the microscope stage. b) Spread a few milligrams of the sample of the dry pigment on the glass slide and examine it in the way described below without adding linseed oil. Adjust the intensity of the light below the slide to the high

44、est practical level. Focus sharply at 200 magnification and scan the slide until a field of view is obtained that is considered to be representative, and in which at least 50 particles can be seen. Thin-flake micaceous iron oxide particles appear as sharply defined red translucent platelets, whilst

45、thicker and/or granular particles appear as black shapes. Assess the proportion of red to black particles and classify as the appropriate grade (see Table 4). Table 4 Thin-flake content Grade Appearance Thin-flake content % A High proportion of red particles 65 B Considerable proportion of red parti

46、cles 50 to 65 If the thin-flake content is not obvious, count the number of red and black particles in a group of at least 50 particles. A frame-image device is recommended to assist in this operation. Repeat the count on a duplicate slide and calculate the mean percentage of red particles. Typical

47、photographs of the two grades of micaceous iron oxide pigment viewed with an optical microscope by transmitted light are shown in Figures 1 a) and 1 b). For comparison purposes, scanning electron photomicrographs of the two grades are shown in Figures 2 a) and 2 b). 8 Test report The test report sha

48、ll contain at least the following information: a) all details necessary to identify the product tested; b) a reference to this International Standard (ISO 10601); c) the results of the tests and whether or not the product complies with the relevant specification limits; d) any deviation from the tes

49、t methods specified; e) the date(s) of the test(s). DIN EN ISO 10601:2008-08 EN ISO 10601:2008 (E) 8 a) Grade A Proportion of lamellar particles (red): 65 % b) Grade B Proportion of lamellar particles (red): 50 % to 65 %Figure 1 Micaceous iron oxide viewed with an optical microscope by transmitted light a) Grade A Proportion of lamellar particles: 65 % b) Grade B Proportion of lamellar particles: 50 % to 65 % Figure 2 Micaceous iron oxide viewed with a scanning electron microscope EN ISO 10601: